bharati vidyapeeth deemed university,pune (india) …...solid-state chemistry an introduction ( 2nd...

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BHARATI VIDYAPEETH

DEEMED UNIVERSITY,PUNE (INDIA)

MASTER OF SCIENCE (INORGANIC CHEMISTRY)

M.Sc.-II ( INORGANIC CHEMISTRY)

SEMESTER III& IV

[CBCS-2018 COURSE]

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BHARATI VIDYAPEETH

DEEMED UNIVERSITY,PUNE, INDIA

M.Sc.-II (INORGANIC CHEMISTRY)

COURSE STRUCTURE

(SEMESTER-III)

Course Code Course Name Credits

PGIC-301 Advanced Coordination Chemistry 4 Credits

PGIC-302 Bioinorganic Chemistry and Heterogeneous

Catalysis

4 Credits

PGIC-303 Inorganic Solid State Chemistry and Inorganic

Polymer Chemistry

4 Credits

PGIC-304 Inorganic Analytical Chemistry 4 Credits

PGSEC-305 Skill Enhancement Course 2 Credits

(SEMESTER-IV)

PGIC-401 Organo metallic Chemistry 4 Credits

PGIC-402 Material Chemistry and Nanoscience and

Nanotechnology Related to Inorganic Systems

4 Credits

# Elective Paper (Any One from PGIC-403 to PGIC-

405)

PGIC-403 Modern Instrumental Techniques for Inorganic

Analysis

3+1 Credits

PGIC-404 Inorganic Pharmaceutical Chemistry 3+1 Credits

PGIC-405 Applications of Inorganic Chemistry in Agriculture,

Environmental Science and Space Science

3+1 Credits

PGIC-407 Practical Course-I* 2 Credits

PGIC-408 Practical Course-II* 2 Credits

PGIC-409 Research Project OR Practical Course-III* 2 Credits

* Examination for practical courses will be conducted at the end of academic year.

# Core Elective Course includes Core: Elective subjects and Industrial project.

Industrial Project includes one day visit, Internet survey, project writing, presentation or oral and be evaluated as the internal marks for Core: Elective Course (PGIC-403, PGIC-404, PGIC-405).

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MSc. II INORGANIC CHEMISTRY

SEMESTER-III

(CBCS-2018 COURSE)

PGIC-301: ADVANCED COORDINATION CHEMISTRY

Total Credits 04 Total Lectures 60 Hrs

Course Content

1. Theories of Metal-Ligand bonding

Molecular Orbital treatment, Octahedral (with and without pi bonding) tetrahedral and

square planer complexes in a qualitative manner, comparison of theories of bonding, BT,

CFT, LFT and MOT.

2. Structural studies of coordination compounds

Compounds of first transition series elements, with respect to their electronic spectral,

magnetic & thermal properties (DTA, TGA)

3. Inorganic Reaction Mechanism:

A] Classification of Inorganic reactions, reaction intermediates, order of a reaction and reaction

mechanism, techniques to follow rate of reactions, lability of complexes and crystal field

interpretation.

B] Electron Transfer reactions: Potential energy diagrams as a conceptual tool, Marcus equation,

Types of and factors affecting electron transfer reactions, Inner and Outer sphere reactions.

4. Kinetics and Thermodynamic Aspects of Metal Complexes

a) Kinetic aspects of Metal complexes

Mechanism of Substitution reactions in octahedtal complexes,Mechanism of Substitution

reactions in square planar complexes,Racemization of tris chelates, Redox reactions, Fluxoinal

molecules.

b) Thermodinamic aspects of Metal complexes

Thermodynamic stability constants, methods for the determination of stability constants,

thermodynamic parameters of complexes, entropy, enthalpy and free energy.

Books:

1. Jones: Elementary Coordination Chemistry. J. Weily

2. Graddon: Introduction to Coordination Chemistry. J. Weily

3. “Comprehensive Coordination Chemistry”, Pergamon G. Wilkinson, R. D.

Gillard and J. A. McCleverty, , Vol. 1, pp 281-322, 331- 379, 385-411,415-

458 (Chapt. 7.4) and 463-471, (1987).

4. “Inorganic Chemistry”, D. F. Shriver, P. W. Atkins and C. H. Langford, 2nd

edn.Oxford, Chapt.15, p.559, (1994).

5. “Inorganic Chemistry – Principles of Structure and Reactivity”, J. E. Huheey,

E. A.Keiter and R. L. Keiter, 4th edn. Harper Collins College Publ. New York,

Chapt.13, p.537-76, (1993).

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M.Sc II INORGANIC CHEMISTRY

SEMESTER-III

(CBCS-2018 COURSE)

PGIC-302 : BIOINORGANIC CHEMISTRY AND HETEROGENEOUS CATALYSIS

Total Credits:04 Total Lectures:60

Course content:

(A) Bioinorganic Chemistry

1. Recapitulation of Biological Roles of Metals & Ligands a) Structural Information

b) Metal Activity, Specificity & Selectivity

c) Biochemical Evolution of Metals in Biological System

2. Biological Chemistry of Iron a) Transport of Iron

b) Hemoglobin & Myoglobin (including their model compound

c) Storage & Transport Proteins of Iron viz,. Ferritin & Transferrin

d) Cytochromes

e) Iron-Sulfur Proteins

3. Biochemistry of Cobalt

a) B12 Coenzymes and Model compounds

b) Actions of Cobalmins & Cobinamides

c) Adenosylcobalmin as a Coenzyme

d) Ribonucleotide reductase

e) Methylcobalmin as cofactor

4. Biological Chemistry of Copper a) Type I, II & III

b) Blue Copper Proteins (Plastocyanins Azurins & Blue Oxidases)

c) Models of Blue Copper Compounds

d) Non-blue copper proteins e.g. Tyrosinase, Galactose Oxidase, SOD etc.

5. Biochemistry of Calcium, Magnesium and silica a) biochemistry of calcium in biological processes

b) biochemistry of Magnesium in biological processes

c) biochemistry of Silica in biological processes

(B) Heterogeneous Catalysis

1.General aspects of heterogeneous catalysis:

Definition of Catalysis, classification of catalytic systems, classification of solid

catalysts, Adsorption of molecules at the solid surfaces, Adsorbed states of

molecules on metals, potential-energy curves for adsorption,descriptive

chemistry of chemisorption on metals, chemisorption and catalysis by metals-

quantitative aspects,catalysis by unsupported and supported bimetals,catalytic

oxidations,Different types of reactors.

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2. Zeolites and Heterogeneous Catalysis:

a) Porous materials and their nature:

Division into micro, meso and micro porous materials, Pores and it

significans, distinction from condensed materials.

b) Introduction to Zeolites:

Definition and classification of zeolites into natural and synthetic zeolite or

aluminosilicates, the primary and secondary building blocks, final framework

structures, Lowensteins rule, sodalite and other structures,Nomenclature:

Atlas of zeolite; structural distinctions, Novel zeolites, examplels of,small

medium, large and extralarge pore zeolites;general properties and and

application of molecular sieves.

c) Characterization of zeolite:

XRD, SEM and other techniques; spectral techniques: FT-IR and solid-state

NMR; sorption capacity, surface area by BET method, pore volume and pore

structure, the origin of Brönsted and lewis acidity in zeolites, the number and

the strength, techniques for the estimation of acidity:adsorption of bases and

IR spectra, temperature programmed desorption.

Books:

1. Bioinorganic Chemistry: A Short Course- Rosette Malone,Wiley

Interscience, 2002.

2. Biological Inorganic Chemistry –An Introduction, Robert Crichton, Elsevier

Science, 2007

3. The Biological Chemistry of the Elements- The Inorganic Chemistry of Life

J.J.R.Frausto da Silva and R.J.P.Williams Clarendon Press, Oxford,1991.

4. Heterogeneous catalysis principles and application, G.C.Bond.

5. Introduction to zeolite science and practice, H. Van Bekkum, E. M. Flanigen,

P. A.Jacobs and J. C. Jansen (Elseviver Pub. Amsterdam, 2001)

6. Catalysis: Principles and Applications, B.Vishwanathan, S. Sivasankar and

A.V.Ramaswamy (Narosa Pub. House, New Delhi, 2004)

7. Advanced material in catalysis, James J. Burton and Robert L.Garten

(Academic press, Newyork, 1977)

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MSc-II (INORGANIC CHEMISTRY)

SEMESTER-III

(CBCS-2018 COURSE)

PGIC-303: INORGANIC SOLID STATE CHEMISTRY AND INORGANIC POLYMER

CHEMISTRY

Total Credits:04 Total Lectures:60Hrs

Course content:

(A) Inorganic Solid State Chemistry

1. The Structure of solids:

The types of matter, classification of solids, close packing of atoms; Voids in closest packings;

Radius ratio rule, Structure of ionic Crystals; Ionic

Crystals with stoichiometry MX, Ionic Crystals with stoichiometry MX2,

spinel structure, perovskite structure.

2. Crystal Defects and non-stoichiometry:

Classification of Defects: subatomic,atomic and lattice defects in solids;

Thermodynamics of vacancy in metals; Thermodynamics of Schottky defects

in ionic solids ; Thermodynamics of Frenkel defects in silver halides;

Calculation of number of defects and average energy required for defect,

Other examples of defect structure; Non-stoichiometry and its

classifications.

3. Diffusion in solids:

Mechanism of Diffusion; Ficks first law and second law of diffusion in solids;

Kirkendal effects in solids.

4. Solid State reactions and Crystal Growth

Classification of solid state reactions and their kinetics and mechanisms;

thermal decomposition reaction; law governing nucleation;Growth of nuclei;

Reaction between two solids;Improving the reactivity of solids;Zone refining

method;Crystal growth.

(B) Inorganic Polymer Chemistry

(a) General aspects of polymer chemistry

a) Classification of inorganic polymers,

b) types of Inorganic polymers

c) Methods for determination of molecular weight.

(b)Inorganic Polymers

Chemistry of following polymers.

a) Silicones.

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b) Phosphonitric halides.

c) Condensed phosphates.

d) coordinated polymers.

e) Silicates.

f) Isopoly & heteropoly acids.

Books:

1. Solid-State Chemistry an Introduction ( 2nd Edition) – Lasley Smart and

Elaine Moore ( Chapman & Hall 1996)

2. Solid State Chemistry- D.K.Chakraborty ( New Age International Pvt.Ltd.New

Delhi, 2000)

3. Introduction to Soilds-L.V.Azaroff ( tata McGraw Hill Publication Ltd. New

York)

4. Principles of the Solid State-H.V.Keer ( Wiley Eastern Ltd.New Delhi, 1994)

5. Solid state Chemistry –N.B.Hannay ( Prentice Hall, New Jersey, 1967)

6. I. S. Butler and J. F. Harrod, Inorganic Chemistry – Principles and

Applications,The Benjamin/Cummings Publishing Co., Inc., Redwood City,

California (USA) (1989) Chapt. 15 to 17, pp 441-503.

7. N. H. Ray, Inorganic Polymers, Academic Press (1978).

8. A. F. Wells, Structural Inorganic Chemistry, 5th edn., Oxford (1984).

9. S. J. Lippard and J. M. Berg, Principles of Bioinorganic Chemistry,

University Science Books, Mill valley, California (USA) (1994).

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SEMESTER-III

(CBCS-2018 COURSE)

PGIC-304 INORGANIC ANALYTICAL CHEMISTRY

Total Credits: 04 Total Lectures:60

Course Contents:

1. Analysis of ore and alloys:

Defination of mimarals ores, alloy, Quantitative methods of analysis of ores like Haematite,

Dolamite, chalkopurite, steel, solder,gun metal etc.

2. Analysis of fertilizers

Defination and principles of analysis of fertilizers, Classification and types of fertilizers,Essential

inorganic ingradients in fertilizers.Analytical methods for quantitative estimation of total

phosphorus,nitrogen,potassium,sodium,Ca,Mg,Mn etc. from fertilizer samples.

3. Analysis of paper

Principles of analysis of different types of papers,Sampling procedure,Analytical methods for

determination of humidity, ash,starch, mineral filler and mineral,Coating on paper Al,Fe,Ba,Mg

etc. from paper samples.

4. Analysis of soils

5. Physical analysis of soils, soil moisture,bulk density and particle density, soil structure and

aeration. Quantitative analytical methods of determination of organic matter, total

nitrogen,silica,Mn,S,P,B etc. from given sample of soil.

6. Water analysis

Sampling of water,removel of suspended matter from water sample, Analytical methods of

estimation of acidity,alkalinity,Al, B, Cd,CO2, Cl - , CN- ,F- etc.from given water sample.

Books:

1. Standard method of chemical analysis. Sixth edition, Part-B, Vol. II by frank J. Welcher.

2. A textbook of quantitative inorganic analysis by A.I. Vogel.

3. Mannual on water is waste water analysis by NEERI Nagpur, D.S.Ramteke and C.A. Maghee.

4. Synthetic inorganic chemistry by W.L. Jolly.

5. Experimental inorganic chemistry by W.G.Palmer.

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SEMESTER-IV

(CBCS-2018 COURSE)

PGIC-401: ORGANOMETALLIC CHEMISTRY

Total Credits:04 Total Lectures: 60 Hrs

Course Content:

1. Organometallic compounds of non transition elements

a) General Survey.

b) Lithium alkyls and aryls.

c) Organomagnesium compounds.

d) Organometalic compounds of aluminum.

f) Organometalic compounds of group IV elements.

2. Organometallic compounds of transition metals

a) Olefin complexes.

b) Cyclopentadienyl compounds.

c) Alkyne Complexes.

d) Arene metal complexes.

f) Hertocyclic sandwitch compounds.

3. Organometallic compounds in homogeneous catalysis

A) Stoichometric reactions.

a) Coordinative unsaturation.

b) The acid-base behavior of metal atoms.

c) Insertion reaction.

d) Reactions of coordinated ligands.

B) Catalytic reactions of alkenes.

a) Isomerization reactions.

b) Hydrogenation reactions.

c) Hydroformylation reaction.

d) Hydrosilyation of alkenes.

f) Polymerization and oligomerization.

g) Palladium-catalysed reactions.

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Books:

1. Inorganic Chemistry 3rd edn. D.F.Shriver and P.W.Atkins, Oxford University

Press, 1999, Chapter 16.

2. F.A. Cotton and R.G. Willikinson: Advanced Inorganic Chemistry.

3. Organotransition Metal Chemistry, Anthony F.Hill, Royal Society of

Chemistry,Tutorial Chemistry Text, 2002. Chapters 1 to 7.

4. Organometallics: A concise Introduction, Ch.Elshebroicn and A Salzer, VCH,

Chapters 12 to 16.

5. Organotransition Metal Chemistry: Applications to Organic Synthesis, S.G.Davies,Pergamon

1982.

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SEMESTER-IV

(CBCS-2018)

PGIC-402 : MATERIAL CHEMISTRY AND NANOSCIENCE AND

NANOTECHNOLOGY RELATED TO INORGANIC CHEMISTRY

Total Credits:04 Total Lectures:60 Hrs

Course Content:

A) Material Chemistry

1. Magnetic Materials

Atomic magnetism and solids, type of magnetic materials, the exchange interactions,hysteresis

loops and their classification, calculation of magnetic moment from saturation magnetization,

magnetic domains. Examples off magnetic materials: soft and hard ferrites, i.e. structure and

magnetic interactions in spinels, garnets, hexagonal ferrites.Application of magnetic materials

2. Ceramic Materials

Classification of ceramics, dielectric properties and polarization properties of ceramics,piezo-,

pyro- and ferro-electric effect of ceramics, sol-gel processing of ceramics.Examples and

application of ceramics: oxides, carbides, borides, nitrides.

3. Cementitious Materials and bio-materials

a) Cementitious Materials-

Difference between Blended and Non-Portland cements; Non-portland cements; high alumina

cements, calcium sulfoaluminate cements, phosphate cements.

Chemicals in cement hydration; hydration process, set retarders and accelerators,plasticizers,

slip-casting processing. Application of cementitous materials

b) Bio-materials-

Definition, Type of bio-materials; dense hydroxyapatite ceramics, bioactive glasses,bioactive

glass ceramics and bioactive composites

B) Nanoscience and Nanotechnology related to Inorganic chemistry

1.Principles of nanoscience and nanotechnology

2. Synthesis of nanomaterials- Physical methods, Chemical methods, biological

methods.

3. Characterization of nanomaterials

4. Applications of nanomaterials

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Books

1. Materials Science and Engineering – V. Raghavan (2nd Edition 1980)

2. Elements of Materials Science and Engineering – Van Vlack (5th Edition, Wiley

1988)

3. Nature and Properties of Engineering Materials – Z. D. Jastrazebski (John Wiley

Sons,1989)

4. Principles of Materials Science and Engineering – William F. Smith (Wiley, 1991)

5. Insight into Speciality Inorganic Chemicals – David Thompson (The Royal

Society of Chemistry, 1995 chapter 13 and 14)

6. Nanotechnology principles and practice, Sulbha k. Kulkarni, Capital

publishing company, new delhi, 2nd ed.

7. Principals of nanoscience and nanotechnology, M.A. Shah, Tokeer Ahmad.,

Narosa publishing house.

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SEMESTER-IV

(CBCS-2018 COURSE)

PGIC-403: MODERN INSTRUMENTAL TECHNIQUES FOR INORGANIC ANALYSIS

Total Credits: 03 Total Lectures: 45 Hrs

Course Content:

Characterization by Analytical Methods

1. Thermal Analysis:

a) Thermogravmetry (TGA): Definition, Types of TGA, Instrumentation, Information from TGA

Curve; Factors affecting TGA curves (instrumental as well as characteristics of sample factors);

Application of thermogravimetry; Calculation of percent decomposition and composition of

compounds; Limitation and Advantages of TGA.

b) Derivative thermogravimetry(DTG) and its advantages

c) Differential Thermal Analysis (DTA) : Definition; Theoretical Basis of

DTA;Instrumentation for DTA apparatus; Factors affecting the DTA curve;

Application of DTA; Advantages and disadvantages of DTA.

d) Differential Scanning Calorimetry (DSC) : Definition ; Comparison of DTA and DSC

techniques; Istrumentation of DSC, Factors affecting DSC curves.

2. X-ray Diffraction:

a) X-ray powder diffraction (XRD):

X-ray source, Diffraction of X-rays,X-ray powder diffraction, Instrumentation and use of

standards, identification of compounds using powder diffraction.The

importance of intensities, Absences due to lattice centring;Determination of

unknown cubic crystal structure by sin2θ method; Parameter to be determined from XRD:

Qualitative analysis; Quantitative analysis-percent crystallinity,Crystallite size, surface area, unit

cell dimension.

b) Single crystal X-ray diffraction:

Solving single crystal structures; refining a structure, X-ray crystal structures in the literature.

3. X-ray Photoelectron spectroscopy(XPS): Introduction and basic theory; Instrumentation;Sample selection and preparation, Spectral

analysis; XPS imaging.

4. X-ray Fluorescence spectroscopy (XRF)

Introduction and basic theory; Instrumentation, spectral analysis; Analytical information and

applications.

5. Electron Microscopy

a) Scanning Probe microscopy : Scanning Tunneling Microscopy(STM); Atomic Force

Microscopy( AFM)

b) Electron Microscopy: Scanning Electron Microscopy(SEM); Transmission Electron

Microscopy (TEM).

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Books :

1. Thermal Analysis-Wendland

2. Instrumental Methods of Analysis-G-Chatwal and S. Anand ( Himalaya

Publication;1988)

3. Catalysis: Principles & Applications-B.Viswanathan,S.Savasankar and

A.V.Ramaswamy (Narosa Publication; 2004). ( For XRD part)

4. Solid State Chemistry: An Introduction-Lesley Smart and Elaine Moore ( 2nd

Edition,Chapman and hall, 1996).

5. Crystallography and its applications-L.S.Dent Glasser ( Van Nostrand, 1977)

6. Handbook of Applied Solid State Spectroscopy-D.R.Vij (Springer Science,

2006).

7. Optical Properties and Spectroscopy of Nanomaterials-Jin Zhong Zhang (

World Science Publication, 2004).

8. Solid Chemistry :techniques-A.K.Cheetham and P.Day (oxford University

Press, 1987).

9. Crystal Structure Analysis- M.J.Buerger ( John Wiley, 960).

10.Physical Methods for Chemists-R.S.Drago( 2nd Edition, Saunders).

Other Books:

11. Element of X-ray Diffraction-B.D.Cullity (1967)

12. The Synthesis and Characterization of Inorganic Compounds-W.L.Jolly

(Prentice Hall,1970).

13. Synthesis and Techniques in Inorganic Chemistry-R.J.Angelias ( 2nd

Edition,Saunders, 1977).

14. Structural Methods in Inorganic Chemistry –E.A.V.Ebsworth,D.W.H.Rankin

and S.Cradock ( Blackwell Scientific Publication, 1987).

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M.Sc-II (INORGANIC CHEMISTRY)

SEMESTER-IV

(CBCS-2018 COURSE)

PGIC-404:INORGANIC PHARMACEUTICAL CHEMISTRY

Total Credits: 03 Total Lectures: 45Hrs

Course Content:

1. Metallodrugs.

2. Radiopharmaceuticals.

3. MRI Contrast Reagents.

Books:

1.“Uses of Inorganic Chemistry in Medicine”, Nicholas P. Farrell, J.H. McNeil,

Royal society of chemistry, 1st Ed. (June 22, 1999)

2.Practical pharmaceutical Chemistry, A.h. Beckeff and J.B. Stenlack, CBS

publishers,New Delhi, 1st Indian Ed. Pp16-76 and 309-348(1986)

3.Biological Chemistry of Elements. J. J. R. Frausto da Silva, R. J. P.

Williams,Chapters 2,12,14, 15, 16, 17.

4. Principles of Bioinorganic chemistry by S. J. Lippard and J. M. Berg,

(I1994)University Science Books(USA)

5. Bioinorganic chemistry: inorganic elements in the chemistry of life, An

Introduction And Guide by Wolfgang Kaim, Brigille Schwederski91994) John Wiley

and Sons.

6. Bioinorganic chemistry, Bestini, Gray, Lippard, Vlentine, 1st SoutasianEdn.(1980)

Viva books pvt.ltd.

7. Comprehensive coordination chemistry Vol.VI

8. Bio-organic chemistry: a Chemical approach to enzyme action 3rd edition.

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SEMESTER-IV

(CBCS-2018 COURSE)

PGIC-405: APPLICATION OF INORGANIC CHEMISTRY AGRICULTURE,

ENVIRONMENTAL SCIENCE AND SPACE SCIENCE

Total Credits: 03 Total Lectures: 45 Hrs

Course Content:

1. Applications in Agriculture Science.

a) Inorganic Fertilizers.

b) Inorganic Fungisides and Pestisides.

c) Essential Micronutrients.

2. Applications in Environmental Science

a) Introduction to waste water analysis:

Specification of treated waste water for disposal into surface water, screening

chamber, grit chamber, oil and grease removal.

b) Energy sources for future:

Solar energy, energy from biomass, wind towers, geothermal, etc.

c) Inorganic metals in environmental.

3. Application in Space Science:

Books:

1.Advanced Inorganic Chemistry,Vol-II,Gurudeep Raj, 12th Ed.,Krishna

Prakashan Media(p) Ltd,Meerut (UP) India.

2. Environmental chemistry by A. K. Bagio.

3. Principle of environmental chemistry by James Girard. Bartlett publishers.

4. Wastewater engineering, Calf & Eddy.

5. Wastewater treatment for pollution control, Arceivala.

6. Manual on sewage & sewage treatment, Ministry of Works, Delhi.

7. Principles of water quality control, T.H.Y. Tebbut.

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SEMESTER-III & IV

(CBCS-2018 COURSE)

PGIC-407: INORGANIC PRACTICAL COURSE-I

Total Credits: 02

Course Content:

A: Analysis of the following samples (any ten)

a) Ore

b) Alloy

c) Cement

d) Manganese from tea leaves

e) Vitamin C from Lemon juice (Biological fluid)

f) fertilizer (PO43-)

g) Analysis of Na, K & Ca using Flame photometry

h) Soil analysis

i) Ion exchange

j) Copper from fungicide

B: Statistical Analysis of data obtained from the estimation of following

compounds using computational methods

a) Iron b) Copper c) Nickel d) Cobalt

e) Chromium f) Zinc g) Manganese

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SEMESTER-III & IV

(CBCS-2018 COURSE)

PGIC-408:INORGANIC PRACTICAL COURSE-II

Total Credits:02

Course Content:

A: Inorganic Instrumental Analysis and computer applications

1. To determine magnetic susceptibility of coordination compounds (two)

2. TGA analysis of coordination compounds (two)

3. Kinetics of aquation of a) Cobalt complex b) iron complex

4. Photochemical reaction – Metal to Ligand charge transfer

5. Table work on analysis coordination compounds using (ANY FOUR

Techniques)

a) IR

b) ESR

c) Cyclic voltammetry

d) NMR

e) XRD

6. Kinetics of dye degradation using CdS nanoparticles

7. Catalytic transfer hydrogenation of nitrobenzene to aniline using a catalyst

8. To study the Metal-DNA interaction spectrophotometrically

The structural analytical data should be analysed using computational

methods.

B: Preparation of inorganic compounds (any ten)

a) NiO b) Nickel ferrite c) Zinc ferrite d) trans-

[Co(en)2Cl2]Cl e) K3[Cr(ox)3] f) (NH4)3[Cr(ox)3] g) [Cu(acac)2]

h) [Mn(salen)] i) [Mn(acac)3] j) [Cu(thiourea)3]2SO4 k) Copper

phthalocyanin

l) copper-1,10-phenanthroline

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SEMESTER-III & IV

(CBCS-2018COURSE)

PGIC-409: RESEARCH PROJECT OR INORGANIC PRACTICAL COURSE-III

Total Credits: 02

Course Content:

A: Preparation and purity of following complexes of

1. DMG

2. 8-hydroxy quinoline

3. Salicyaldoxime

4. thiourea

with Copper, Nickel, Iron, Chromium & Manganese (any three metals)

B: Structural determination of above complexes using following

techniques i) UV-Visible spectroscopy

ii) Magnetic susceptibility

iii) Thermogravimetric analysis

iv) IR

v) Solution conductivity

C. Introduction to literature survey

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M. SC. II (INORGANIC CHEMISTRY)

SEMESTER III

(CBCS-2018 COURSE)

PGSEC 305: ASSESSMENT OF WATER QUALITY

Total Credits: 02 Total Lectures: 30Hrs

Course Content:

The main objective of course is to improve the awareness and skills of the students in

modern techniques of analysis of water for research and extension activities. Use of instruments

and their general upkeep/maintenance, interpretation of analytical data and formulation of

reports/recommendations.

The course is designed to cover water characteristics, testing techniques and methods of

interpretation of data, so as to make it more useful in the context of global competition in quality

and precision of analysis.. About the Course: The course will cover some theory lectures on

topics most relevant to the subject along with appropriate number of practical exercises with

greater emphasis on analytical techniques adopting a demonstration and learning-by-doing type

of approach. Interpretation of test results and formulation of recommendations and/or reports

will be a vital component.

The course context: Collect samples in scientific way from residential plumbing and

municipal distribution systems for analysis Take physical tests like (Colour, pH, Temp etc) at

the spot and use preservatives for further analysis Conduct chemical tests of samples in lab (e.g.

Alkalinity, Hardness, TDS. DO, COD etc with biological tests) as possible as. To conduct

chlorine residual or turbidity tests. Compare the obtained values with WHO, CPCB or BSI

Standards

References:

1. Hand Book of Methods in Env. Studies by S.K. MAITI ABD Publishers, Jaipur, India.

2. Instrumental methods of chem. Analysis G. R. Chatwal and Anand Himalaya publishing

house, New Delhi.

3. Environmental Science Principle & Pract. R. C. Das & Behera Prentice Hall of India pvt.

Ltd. New Delhi.

bharati vidyapeeth deemed university,pune (india) …...solid-state chemistry an introduction ( 2nd...

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