brief summary spring 2015 updated
DESCRIPTION
ghjTRANSCRIPT
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BRIEF SUMMARY
Chapter alkyl halides: Sn1, Sn2, E1, E2: (a) effect of solvents, base, etc. (b) Hoffman and Zaitsev
elimination. (c) reactions of Grignard (remember reactions of Grignard with esters and
compounds possessing acidic hydrogens).
Chapter alcohols: epoxide opening reactions, eliminations, esterification reactions.
Chapter carbonyl: aldol reactions, aldol condensation (be careful with intra-molecular reactions),
protection with diols and deprotection of acetals, reactions with Grignards, hemiacetal reactions
Acids, ester, amides: esterification reactions, 3 types of carboxylic acid, reduction, reactions with
Grignards.
Amines: diazonium salt reactions, selective reaction of dinitrobenzene by Na2S or (NH4)2S
(check at hand out), reactions with alkyl halides (remember: whenever you see the N-H and the
C-X in reactant molecules, products will be N-C and H-X).
There might be more important notes coming from now till before the test date. Please
check your e-learning as often as you can. Good luck!
There are several important transformations (please also consider last week note as your
key problems as well)