broad spectrum light absorbing polymers for photovoltaics

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Broad Spectrum Light Absorbing Polymers for Photovoltaics Qiquan Qiao, Center for Advanced Materials, Department of Electrical Engineering, South Dakota State University, Brookings, SD 57006; Collaborator: Seth Darling, Argonne National Laboratory We also studied the planarity of the newly designed polymers via DFT calculation. A high degree of planarity was found in these polymers, which was expected to lead to a high possibility of packing and carrier mobility. In addition, an efficient delocalization throughout the backbone chain was observed in the LUMO orbitlas. The UV-VIS-NIR absorption spectra showing the polymer has a very efficient light harvesting capability because its absorption spectrum matches the solar spectrum very well. The absorption was obtained from DFT based quantum chemical calculation. 0.0 0.2 0.4 0.6 0.8 1.0 1.2 0.0 0.3 0.6 0.9 1.2 1.5 1.8 300 500 700 900 1100 G lobal TiltS olarS pectrum (W m -2 nm -1 ) N orm alized A bsorbance W avelength (nm ) S olarSpectrum U V-V is A bsorption

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Broad Spectrum Light Absorbing Polymers for Photovoltaics. Qiquan Qiao , Center for Advanced Materials, Department of Electrical Engineering , South Dakota State University, Brookings, SD 57006; Collaborator: Seth Darling, Argonne National Laboratory. - PowerPoint PPT Presentation

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  • Broad Spectrum Light Absorbing Polymers for PhotovoltaicsQiquan Qiao, Center for Advanced Materials, Department of Electrical Engineering, South Dakota State University, Brookings, SD 57006; Collaborator: Seth Darling, Argonne National Laboratory We also studied the planarity of the newly designed polymers via DFT calculation. A high degree of planarity was found in these polymers, which was expected to lead to a high possibility of packing and carrier mobility. In addition, an efficient delocalization throughout the backbone chain was observed in the LUMO orbitlas. The UV-VIS-NIR absorption spectra showing the polymer has a very efficient light harvesting capability because its absorption spectrum matches the solar spectrum very well. The absorption was obtained from DFT based quantum chemical calculation.