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N 2 P F 6 N S 2 O S 1 X Building Blocks in Hand: SUPRAMOLECULAR PSEUDOROTAXANE AND ROTAXANE POLYMERS Harry W. Gibson, Virginia Tech, Blacksburg, VA 24061-0212 A Current Goal: Proven Model Systems with dimethyl paraquat: K a = 2 x 10 4 M -1 (acetone) J. Org. Chem. 2008, 73, 5570-5573. K a = 5 x 10 6 M -1 (acetone) J. Org. Chem. 2005, 70, 3231-3241. O O O O O O O O O O O O A 32 O O O O O O O O O O O O 32 N O O A

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SUPRAMOLECULAR PSEUDOROTAXANE AND ROTAXANE POLYMERS Harry W. Gibson, Virginia Tech, Blacksburg, VA 24061-0212. A Current Goal:. Building Blocks in Hand:. K a = 2 x 10 4 M -1 (acetone) J. Org. Chem. 2008 , 73 , 5570-5573. Proven Model Systems with dimethyl paraquat:. - PowerPoint PPT Presentation

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Page 1: Building Blocks in Hand:

N

2 PF6

N S2O S1 X

Building Blocks in Hand:

SUPRAMOLECULAR PSEUDOROTAXANE AND ROTAXANE POLYMERS

Harry W. Gibson, Virginia Tech, Blacksburg, VA 24061-0212

A

Current

Goal:

Proven Model Systems with dimethyl paraquat:

Ka = 2 x 104 M-1

(acetone)

J. Org. Chem. 2008, 73, 5570-5573.

Ka = 5 x 106 M-1 (acetone)J. Org. Chem. 2005, 70, 3231-3241.

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O

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OO

A

32

O

O

OOOO

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OO

32

NOO

A

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