busak+shamban in the grooveeditorial 3 welcome to our second edition of ‘in the groove’ focusing...

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Busak+Shamban 01/2006 in the groove The world of seals and service Chemical, Pharmaceutical, Food and Beverages Sealing for a green alternative Making hydrogen fueling possible Oil & Gas Gaining the seals of approval Compliance to Norsok M-710 standard Semiconductor Semiconductor sealing one-stop-shop Semiconductor sealing one-stop-shop

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Page 1: Busak+Shamban in the grooveEditorial 3 Welcome to our second edition of ‘in the groove’ focusing on semiconductor sealing solutions. The semiconductor industry requires continuous

Busak+Shamban 01/2006

in thegrooveThe world of seals and service

Chemical, Pharmaceutical, Food and Beverages

Sealing for a green alternativeMaking hydrogen fueling possible

Oil & Gas

Gaining the seals of approvalCompliance to Norsok M-710 standard

Semiconductor

Semiconductor sealing one-stop-shopSemiconductor sealing one-stop-shop

Page 2: Busak+Shamban in the grooveEditorial 3 Welcome to our second edition of ‘in the groove’ focusing on semiconductor sealing solutions. The semiconductor industry requires continuous

Contents

Semicon

Editorial 3

News 4

Semiconductor sealing one-stop-shop 6Aiming to maximize semiconductor equipment performance

Working in a vacuum 10Sealing to overcome the challenge of vacuum operationin semiconductor manufacturing equipment

Sealing for a green alternative 12To make hydrogen fueling possible an effective filling system is required

Isolast® J9503 is the champion 14One of our customers, a chemical manufacturer, put Isolast® seals, through some of the most demanding testsever, for seals of this kind

From Russia with oil 18New Moscow office established

Gaining the seals of approval 20Busak+Shamban has a range of seal materials that complyto NORSOK M-710 standard

Sealing Solutions Toolkit 16Great things come in small packages

Benefitplus – what does it mean? 22That little bit extra that makes Busak+Shamban differentfrom the competition

Oil & Gas

CPI

Extras

Page 3: Busak+Shamban in the grooveEditorial 3 Welcome to our second edition of ‘in the groove’ focusing on semiconductor sealing solutions. The semiconductor industry requires continuous

Editorial

3

Welcome to our second edition of ‘in the groove’ focusing onsemiconductor sealing solutions.

The semiconductor industry requires continuous improvement intheir processes to increase plant productivity. This has led to rapidchanges, innovation being the key to remaining competitive.Effective sealing solutions play an important role. This issue willtell you about the wide range of options available tosemiconductor equipment manufacturers and specifically aboutsealing in the challenging area of vacuum processing.

Busak+Shamban is exhibiting at SEMICON Europa 2006 in Munich.Why not meet us on our stand to discuss your applications? Ortake up our offer of ordering a free Semiconductor SealingSolutions Toolkit, to make designing your assemblies quicker andeasier.

The chemical processing section outlines results that prove,against all competition, Isolast® J9503 was a winner. Thisperformed better than any other FFKM material tested inchemical immersion trials. And on a subject much talked aboutrecently, details are given of sealing solutions provided to WEH,who manufacture filling systems for the alternative fuel,hydrogen.

Busak+Shamban is proud to announce details of certificates forcompliance to NORSOK gained on 11 materials, in our oil and gassection. A great achievement, meaning Busak+Shamban has moreNORSOK compliant sealing compounds than any other supplier. A new marketing company opens in Russia, set up mainly tosupport our oil and gas companies in that region. We can now offer excellent service including applicationengineering at over 40 locations globally – 11 in the Americas, 15 in Asia Pacific, and 17 in Europe.

After the success of the first edition of ‘in the groove’, I amconfident that you will enjoy this second issue. Happy reading!

Dr. Sandro SilverioDirector - CPI Segment Europe

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newsnews

Keep it watertightDrinking water is a precious commodity. Making sure as little aspossible is lost is important and domestic water pipes must beguaranteed watertight for 50 years. Key to achieving this iseffective sealing.

Sealing requirements are demanding, as most new pipes are plasticand increasingly quick fit connections are used to speed fitment.When you consider still 70% of the world’s population do not haveaccess to clean drinking water, installation of water systems asquickly as possible, that are virtually leak free, is a major priority.And when most of those systems are required in the developingworld, minimizing cost is vital.

Sealing material development for water system applications hastherefore focused not just on performance but also on making costof production as low as possible. Which means to meet cost criteria,O-Rings need to be produced by injection molding.

To make injection molding of O-Rings possible, softeners are usuallyadded to the elastomer to give better flow of material into theinjection tool. The resulting better fill increases seal output andmakes production costs lower. But, softener may migrate into plasticcomponents such as pipes and quick connectors. This can lead tocracks in the plastic parts , which is not acceptable.

Busak+Shamban has solved this problem. We now have a broadrange of materials available that balance the use of softeners withmaterial performance. They also meet approvals to variousinternational standards, making them universally compliantglobally.

Grab your coatBusak+Shamban is a leader in coatingstechnology, identifying many treatments thatimprove the friction characteristics of ourseals. These aid automated assembly byhelping stop seals sticking together or twisting in their housing.

In food and beverage production coatingsmust be compliant with a number ofapprovals. One of our coatings, FF coating, hasrecently gained compliance with the standardsof the German Federal Environmental Agency(FEA), valid for the area D2 (seals). This is inaddition to its FDA compliance, making itsuitable for use in most food, beverage and drinking water applications.

FF Coating features:• Used at a thickness between 2-10µ• Water based• Solvent-free • Transparent • Operating temperature from -40ºC

to +150ºC (-40ºF to +302ºF)• Does not affect the seal’s natural elasticity• Suited for both static and low-level

dynamic applications, with infrequentmovement and short stroke rate.

www.busakshamban.com/grooveBrochure at:

Go to the Shop!

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Busak+Shamban - in the groove, no. 1/2006© Busak+Shamban, 2006. All rights reserved® All trademarks are the property of Busak+Shamban andTrelleborg AB.

Editorial Office:Busak+Shamban Deutschland GmbH, Handwerkstraße 5-7,70565 Stuttgart, Germany Email: [email protected] Web: www.busakshamban.com/groove

Editorial team:Dr. Sandro Silverio, Donna Guinivan, Elke Voehringer-Klein, Dr. Burkhard Ledig, Bill Allan, Whitney Killip,Heather Castleman

Responsible under German Press Law: Robert ZahiriGraphic Arts: dialogart, Stuttgart, GermanyPrinting: W. Kohlhammer, Stuttgart, Germany

Disclaimer: The information in this magazine is intended to be for general reference purposes only and is notintended to be a specific recommendation for anyindividual application. The application limits for pressure,temperature, speed and media given are maximum valuesdetermined in laboratory conditions. In application, due to the interaction of operating parameters, maximumvalues may not be achieved. It is vital therefore, thatcustomers satisfy themselves as to the suitability ofproduct and material for each of their individualapplications. Any reliance on information is therefore at the user’s ownrisk. While every effort is made to ensure the accuracy of information contained herewith, Busak+Shambancannot warrant the accuracy or completeness ofinformation. For exceptional operating conditions, please contact yourBusak+Shamban representative.

Come and see usIn April 2006, Busak+Shamban will be attending SemiconEuropa. Why not visit us? You will find us in Hall A2, Stand 175.

We will also be happy to meet you at other exhibitions wherewe will be present this year.

Semicon West, USA 10 - 14 JulySemicon Taiwan 11 - 13 SeptemberSemicon Japan 7 - 9 December

Very approvingSeals, integral in products and processingsystems, must meet or comply withnumerous international approvals.Perhaps some of the most stringent relateto pharmaceutical, food and beverageprocessing which call for FDA and USPcompliance. While for the water and gasindustry, there is a wide variety differingby region, especially relating to potable water.

Busak+Shamban has invested heavily indevelopment of materials inline withthese requirements. We offer the broadestrange of compliant sealing materialsavailable from any seal developer andmanufacturer. In fact, we believe there isnot an approval we cannot meet with oneof our compounds. And if there is, we’llmake sure a compliant material will beavailable as soon as possible.

Isolast® Seals, a Business Unit of Trelleborg Sealing SolutionsAshchurch, an associated manufacturing company ofBusak+Shamban, is now in its 9th year of operation. From itsproduction base in Gloucestershire, England, a full range of Isolast®

FFKM materials are available for aggressive sealing environments.The team makes sure that customer demands are met as quicklyand efficiently as possible, priding itself in its cleanroom facilityand excellent delivery record, even achieving same-day turnaroundwhen required.

Meet the Isolast® Team

From left to right:

Paul NeathProduction Manager Ellen SargeantGlobal Accounts ExecutiveIan PhillipsInternal Sales and PlanningCoordinatorChris Stowell Technical ManagerUrsula Porelle Product ManagerJohn ChandlerSenior Product Engineer

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Semicon

Aiming to maximizesemiconductor equipmentperformance

At Busak+Shamban, we know that designers ofsemiconductor equipment want to maximizethe performance of the machines theymanufacture. Selecting the optimum sealmaterial and type can help ensure that. Usingthe right seal increases service life and extendsmeantime between planned maintenance(MTBM). This will reduce downtime, maximizeproduction efficiency, yields and processreliability, meaning overall, total cost ofownership is minimized for the customer.

The experience and range tooffer the right seal for the job

Busak+Shamban has lots of experience inproviding sealing solutions to semiconductorequipment manufacturers. This allows us torecommend the best possible option from ourextensive range of innovative seal materialsand products. Many of these are specificallyengineered to meet the increasinglydemanding requirements of the semiconductorindustry, giving exceptional sealing integrity.We are a one-stop-shop for the majority ofsealing needs, even the most difficult withinthis critical manufacturing process.

Semiconductorsealing one-stop-shop

Semiconductor manufacturing processes areextremely aggressive. Seals are often housed inareas of the processing system where they mustwithstand highly destructive liquids, gases andplasmas, at elevated temperatures or in vacuumconditions. To ensure long service life, equipmentdesigners must have available the right seals tostand up to the job.

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Wet processapplications

Aggressive plasmasystems

These chemically intensive processes involve wetprocess chemicals including acids, such ashydrofluoric, alkaline solutions l ike sodiumhydroxide and solvents, typically N-methylpyrrolidoneor acetone. Wet manufacturing process steps include etching,stripping, plating and CMP (Chemical MechanicalPlanarization). These are followed by wafercleaning, removal of all surface contamination ofparticulates, organics, metallics and native oxidesand all liquids used must have extremely high purity.Optimum seal performance is critical in ensuringmaximum uptime throughout the ULSI (ultra largescale integration) process. A range of products isoffered that give almost universal chemicalresistance, minimum leach out of ionic impuritiesand extremely low particulation.

Plasma is used at various stages during waferfabrication. The plasma state is created when a gas issubjected to energy, breaking down its molecularintegrity and dissociating it into ions and electrons.Many of the gases used to do this in semiconductorprocesses are toxic, reactive and pyrophoric. It isessential that seals withstand this harsh plasmaenvironment where they will be subject to highenergy and possibly elevated temperatures.Inadequate sealing can lead to contamination andaffect product yield. Ultra pure sealing solutions fromBusak+Shamban ensure long-term reliability withminimal particulation and extremely low outgassing.

J9610 J9650 FEPCom-petitiveFFKM

0

500

1,000

1,500

2,000

ppb

0

NF3 SF6 CF4

1,0

0,5

2,0

2,5

1,5

J9630J9670Com-petitorFFKM 1

Com-petitorFFKM 2

%

Total Metallic Extrables in UPDI at +85°C (+185°F), 1 week by ICP/MS

Weight Loss in Plasma Environments

Page 8: Busak+Shamban in the grooveEditorial 3 Welcome to our second edition of ‘in the groove’ focusing on semiconductor sealing solutions. The semiconductor industry requires continuous

J9650J9670 Com-petitor 1

Com-petitor 2

0,5

1,0

0

1,5

2,0

2,5

%

8

Semicon

High temperature wafer processing and plasmaapplications include Rapid Thermal Processing(RTP), Chemical Vapor Deposition (CVD) and dryplasma etch. Seals must withstand temperaturesabove +300°C (+572°F) with main requirements oflow outgassing and minimum particle generation.Two Isolast® materials, J9650 and J9670 are provento successfully operate at continuously elevatedtemperatures while withstanding aggressivechemicals and media. Other leading edge optionsfor this environment are based on our engineeredplastic and metal technology, proprietary productsTurcon® Varilip® PDR and Wills Rings® being anideal choice.

High temperatureresistance

Seals recommended for semiconductor applications:

O-RingsBusak+Shamban offers a wide range of O-Rings thatbalance cost-effectiveness with performance. Any size ofO-Ring is available (standard or custom), in materialsranging from basic elastomer grades to leading edgecompounds specifically developed for the industry.

V-Ring®

A unique all rubber seal for rotary shafts, it offers theperfect solution to prevent ingress of media includingdirt, dust and water while retaining lubricant. Typicalapplications are on chemical mechanical polish or waferdicing equipment, where it operates at a velocity up to12 m/sec (39 ft/sec).

Varilip® PDRThese seals consist of a PTFE based Turcon® sealing lipretained in a crimped or clamped metal case. They areideal for use in process pumps where they preventgearbox oil from entering the processing system andallow the introduction of an inert gas barrier.

Variseal®

Variseal® spring energized PTFE based Turcon® seals havebeen used in the most demanding of semiconductorsealing applications including vacuum and corrosiveenvironments. They are field proven to give high sealingintegrity in extreme gas and liquid handling situations.

Relative weight loss of various elastomersTemperature range: +50°C to +320°C (+122°F to +608°F)detected with GC/MS

www.busakshamban.com/grooveLiterature at:

Go to the Shop!

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Temperature resistance from cryogenic up to +850°C (+1562°F)

Resistance to dry and wet process chemistry

Excellent stability - thermal and within a vacuum or under pressure

Extremely low levels of ionic impurities and TOCs (Total Organic Carbon)

Minimal particle generation and outgassing, evenat high temperatures

Low permeation rates

Reduced IR absorption and weight loss

Good mechanical performance

Low long term compression set

Materials recommendedfor semiconductorapplications:

Wills Rings®

The original metal seals, Wills Rings® provide theoptimum solution in static sealing on connectors,flanges and plates for gases and liquids under extremeconditions. They operate in temperatures fromcryogenic up to +850°C (+1562°F) and in pressures fromhard vacuum and up to 1000 MPa (145038 psi, 10000 bar).

PneumasealPneumaseals are inflatable seals, of tubular elastomer;they are activated by internal pressurization. These areideal for load locks and access doors includingcleanroom doors, where they replace traditional flatgasketing and O-Rings, giving improved integrity inthese specialized applications.

Bonded to metalBusak+Shamban effectively bonds FKM and Isolast®

seals to surfaces such as stainless and mild steel,aluminum, brass and various plastics. The majoradvantage of this is that it maximizes sealing integrityand prevents contamination in groove voids. It alsoeases assembly and reduces inventory.

Isolast® Fab Range™

High performance perfluoroelastomers speciallydesigned for semiconductor use, they are virtuallyinert and have almost universal chemicalcompatibility. With a continuous operatingtemperature up to +315°C (+599°F), they are idealfor upstream solutions such as wet processingsystems and in plasma.

ElastomersFluoroelastomer (FKM) seals are ideal fordownstream applications such as vacuum pumps andin wet processing where temperatures do not exceed+220°C (+428°F). They give excellent resistance tomany semiconductor chemicals, while offering highpurity, low permeation and outgassing levels.

Engineered thermoplasticsA variety of sealing options are available inengineered thermoplastics. These include novelsolutions in PEEK™ and polyimide with goodchemical and plasma resistance, electrostaticcontrol and low outgassing. HiMod® wear rings andbearings have good dimensional stability and lowparticle shedding.

The range of Busak+Shamban products for the Semiconductor industry offers:

Page 10: Busak+Shamban in the grooveEditorial 3 Welcome to our second edition of ‘in the groove’ focusing on semiconductor sealing solutions. The semiconductor industry requires continuous

Semicon

Vacuum technology plays a critical role insemiconductor manufacturing, being key toprocess yield and productivity. Applicationsrange from dry pumps to more complexsubsystems for processes such asphotolithography. Maintaining a consistentvacuum is vital, as even minor fluctuations canhave a negative affect on the whole productioncycle.

Effective sealing is an important element inachieving this. Seals must not only be capableof sealing in a vacuum but also be able to

withstand corrosive gases, plasmas andaggressive media, often at high temperatures.Sealing is further complicated by possibleexposure to condensables and gels withoperation in oxidizing or reducingenvironments. They must demonstrate low levels of ionic impurities (anionic andcationic) and TOCs (Total Organic Carbon) with minimal particle generation, outgassingand permeation. On top of all of theserequirements is the need for supply of oftenspecialized seals to meet very short lead times,minimizing downtime.

Working in a

10

Sealing to overcome the challenge of vacuum operation in semiconductor manufacturing equipment

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11

Semicon

FEA modelingtechniques wereused to provesealing solutions forhigh-speedsemiconductorpumps and boosters

vacuumAnalysis of sealingintegrity in vacuumconditions is carriedout on a helium testrig

A unique one-off purpose designed and built test-rigchecks the performance of a Varilip® PDR seal

A unique one-off purpose designed and built test-rigchecks the performance of a Varilip® PDR seal

Recommended sealingsolutions for vacuumconditions

Fluoroelastomer (FKM) sealsLow permeation and outgassing levels

Varilip® PDRCustom designed they can include an inert gasbarrier system

Variseal®Operate at high vacuum in corrosive environments

Wills Rings®

Suitable for low and high temperatures at hard vacuum and up to 1000 Mpa (145038 psi,10000 bar)

Unique test facilitiesensure unique results

Neville Sleigh manages the Researchand Development test faci l ity at Busak+Shamban associatedmanufacturing company TrelleborgSealing Solutions, Ashchurch inGloucestershire, England. From there, much of the development workhas been undertaken for a majorglobal semiconductor equipmentmanufacturer. Neville explains whathas been involved.

“When we started we were inunknown territory. As a company, wemay have been providing sealingsolutions for over fifty years but whenit came to solving the challenges thatsemiconductor manufacturingpresented, we faced something new.”

“Still though, basic principles ofeffective sealing could be applied.Finding a solution is al l aboutdefining the problem first. Weworked with our customer to identify

all those critical elements that mightaffect performance such as operatingpressures, temperatures and types ofmedia, gases and plasmas presentwithin the system. Then we needed to know other criteria specific to the application. In the case ofsemiconductor equipment, thatmeant l imitations on particlegeneration, outgassing, permeation, ionic impurities and TOCs.”

“To provide a unique solution, werequired unique testing capabilities.Over the last 15 years the companyhas invested heavily in purposedesigned and built one-off test rigsand undertaken extensive long-termtesting in conjunction with ourcustomers’ product developmentprograms. This was combined withdevelopment work in the virtualenvironment using advanced FEAmodeling. Through this methodologywe were able to prove a range ofsolutions that are now effectivelyoperating in semiconductorequipment globally.”

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Busak+Shamban seals are used in rotarytransmission ‘lead-throughs’, fitted intothe tank filling systems.

Hydrogen filling stations, using WEHsystems and including Busak+Shambanseals, are being built at a number ofEuropean locations.

greenSealing

for aMaking hydrogen fueling possible

To make hydrogen fueling possible an effectivefilling system is required. Hydrogen is a veryvolatile fuel and extremely explosive when incontact with oxygen. A filling system musttherefore make sure there is no chance ofhydrogen mixing with oxygen, before it hitsthe fuel cell, if hydrogen fueling is ever goingto be successfully implemented.

WEH is a leader in fuelingtechnology

German company WEH has spent yearsdeveloping filling systems for alternative fuels.The latest patented system from WEH offersthe best possible safety for the user. The fillingnozzle is connected tightly, until there is nopressure in the space between the inlet valveand connector.

Higher pressure, bigger sealingchallenge

The higher the input pressure of a fillingsystem, the faster the tanks can be filled. WEHis developing a system that can fill the tank at an even higher pressure than the current450 bar (6525 psi). These pressures need high-performance seals, because the force toenergize the seals must be as low as possiblewhen the filling system is turned on.

Busak+Shamban seals selected

To meet operating requirements WEH chose agroup of seals, including PTFE seals, O-Rings,Stepseal® and Glyd Ring® in conjunction withBusak+Shamban as their sealing partner. Theseseals use standard Busak+Shamban materialsand also ones specially developed for thisapplication, including some capable ofwithstanding temperatures as low as

–40°C (-40°F).

Page 13: Busak+Shamban in the grooveEditorial 3 Welcome to our second edition of ‘in the groove’ focusing on semiconductor sealing solutions. The semiconductor industry requires continuous

CPI

alternativeThe search is on for an alternative fuel to gasoline. Not only do governments want to lessen our use of fossil fuels, whichare rapidly depleting, but they also want us to be greener. A major aim is to reduce the significant contribution vehicles have onglobal warming. The leading alternative atthe moment is hydrogen fueling.

What about global warming?

Global warming is caused by the collection ofcarbon dioxide emissions in the atmosphere. Theyact like a blanket, trapping in the sun’s heat. Thelargest source of carbon dioxide pollution is coalburning power plants; the second largest sourceis vehicles. Over the past 50 years average globaltemperatures have increased at the fastest rate inhistory. The consequences of this could becatastrophic. Extreme predictions are that largeareas of the world could become uninhabitable,with massive food and water shortages, sparkingwidespread migrations and war.

Is oil running out?

It is quite frightening when you realize howquickly we are using up the world’s fossil fuelreserves, considering we are all so dependent onoil for energy and transport. “Peak oil” is thepoint at which half the total oil, known to exist,has been consumed. Once this has been reached,though demand for oil is still forecast toincrease, production will steadily decline year onyear. This will cause prices to rise, not just for oilbut for its byproducts too. And at the momentestimates are for us to reach “peak oil”anywhere between now and 2020.

How hydrogen fuel cells work

A hydrogen fuel cell is a device that uses hydrogen andoxygen to create electricity. The type of fuel celltypically used in automotive applications is a PolymerElectrolyte Membrane (PEM). In this, hydrogen fuel ischanneled through flow plates to an anode on one sideof the fuel cell while oxygen is channeled to a cathodeon the other side of the cell. At the anode the hydrogenis split into positive hydrogen ions (protons) andnegatively charged ions (electrons). The protons passthrough the Polymer Electrolyte Membrane (PEM)directly to the cathode while the electrons are forcedalong an external circuit to the cathode, creating theelectrical current used for vehicle propulsion. At thecathode the protons and electrons mix with the oxygento form water, which flows out of the cell. Totally green,hydrogen fuel cells produce electricity with only waterand heat as byproducts.

A hydrogen fuel cell uses hydrogen and oxygen to createelectricity for vehicle propulsion.

13

Hydrogen Water/Heat

OxygenFuel Cell

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CPI

Isolast®

J9503

is thechampion

One of our customers, a chemicalmanufacturer, put Isolast® sealsthrough some of the mostdemanding tests ever, for seals ofthis kind. Against all competition,they proved to be the winner,performing better than any otherFFKM material tested, in thesechemical immersion trials.

www.busakshamban.com/grooveMaterial leaflets at:

Isolast® performs well in demanding tests

The chemical company’s tests involved keeping Isolast® J9503 along with other competitive FFKMcompounds, immersed in various extremely aggressivechemical media for 112 days, at varying temperatures.After this time, the material volume was measured. Avolume increase of 20% is classed as a ‘critical thresholdvalue’ for seals in this type of experiment. Beyond that,the sealing material would not be considered suitablefor sealing in a chemical media, at the temperatureswhere a volume change above 20% was seen.

Isolast® J9503 proved to be an outright winner

Isolast® J9503 proved to be an outright winner in theseindependent tests to find the best performingperfluoroelastomer from a range of FFKM materials.Isolast® J9503 offered the best value in terms of cost andperformance compared to all other perfluoroelastomerstested.

14

Go to the Shop!

Page 15: Busak+Shamban in the grooveEditorial 3 Welcome to our second edition of ‘in the groove’ focusing on semiconductor sealing solutions. The semiconductor industry requires continuous

Chemical % volume increase % volume increaseimmersion 112 days

Aniline, +184°C (+363°F)

Nitrotoluene, +175°C (+347°F)

ODB, +180°C (+356°F)

CSS, RT

20% HCL, +108°C (+226°F)

87% H2SO4, +175°C (+347°F)

78% H2SO4+ Nitro dilution, +175°C (+347°F)

65% HNO3, +50°C (+122°F)

65% HNO3, +85°C (+185°F)

Air, +180°C (+356°F)

ODB = Ortho Dicloro Benzene, CSS = Chlorosulfonic Acid

15

Summary of results

Isolast® J9503 had the lowest volume change ofall perfluoroelastomer tested in all chemicals

Volume change of Isolast® J9503 was below 20%at all temperatures in aniline, nitrotoluene, o-dichlorobenzene, chlorosulfonic acid,hydrochloric acid, nitric acid

In many of these chemicals the volume change ofIsolast® J9503 was in fact, below 10%

Isolast® J9503 had the widest chemical resistanceof all perfluoroelastomers tested

The Isolast® Range

Perfluoroelastomers were originallydeveloped to meet the needs ofchemical processing companies for asealing material that had the elasticityof a Fluoroelastomer but the chemicalresistance of a PTFE material.

The Isolast® range of materials areperfluoroelastomers specif ical lydeveloped by Busak+Shamban for themanufacture of seals. They are resistantto virtually all chemicals and haveoperating temperatures from –25°C to+325°C (-13°F to +617°F).

The range gives real benefits and costadvantages by providing optimum sealreliability and extending service life.Seal performance is further enhancedby superior hysteresis and compressionset characteristics, which ensures highelasticity and dynamic recovery,minimizing risk of seal failure.

Compounds are available that havebeen specially developed to meet thespecif ic requirements of variousindustries, including general chemical,oi l and gas and semiconductorprocessing. They are produced asstandard and non-standard O-Rings,custom molded designs and bondedproducts. If required parts can bemanufactured in cleanroom conditions,washed and packed to class 100standards.

Tests were in the following media andtemperature ranges:

• Hot aniline up to +184°C (+363°F)• Nitrotoluene up to +175°C (+347°F)• O-dichlorobenzene (ODCB) up to

+180°C (+356°F)• Ethylene diamine (EDA) up to +100°C

(+212°F)• Chlorosulfonic acid (CSS RT)• 20% solution of hydrochloric acid up to

+108°C (+226°F)• Sulfuric acid and sulfuric acid

compounds at a solution up to 87% upto +175°C (+347°F)

• 65% nitric acid at between +50°C(+122°F) and +122°C (+252°F)

• Hot air at +180°C (+356°F)

Isolast® Competitive J9503 FFKM

Hardness +/- 5 75 Shore A 75 Shore A

Color Black Black

Specific Gravity g/cm3 1.94 2.00

Tensile Strength MPa N/mm2 12.5 22

Elongation at Break 120% 192%

Compression set 72 hours at +200°C (+392°F) 25% 25%

Continuous Service Temperature:

Maximum +240°C (+464°F) +320°C (+608°F)

Minimum -25°C (-13°F) -15°C (+5°F)

TR10 Point -18°C (-0.4°F) -5°C (+23°F)

0 25 0 25

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www. busakshamban.com/groove

Order your Free Sealing Solutions Toolkit now!

Busak+Shamban is one of the leading sealing solutionsexperts in the world. To make the job of engineersspecifying seals in their components easier, we have puttogether a pack of tools that no design or applicationengineer should be without. All of them are aimed atmaking your job simpler and saving you time.

What the pack contains:

O-Ring Calculator

The CD version of our acclaimed O-Ring calculator makesspecifying the correct O-Ring for your application easy. Itincludes a sizing capability, recommendations on designparameters and complete measurements. Using a greatdeal of ‘sealing expertise’, the calculator even takes intoaccount compression, seal expansion and groove fill. Reallysimple to use, its unique functions enable you to calculatethe right seal every time.

SemiconductorGlossary

Ever wondered what thearhenius plot is or whetherthere is zeta potential.Find out in our handySemiconductor Glossary wherewe explain the meaning of wordsused in the semiconductor industry. Thisbook is specially produced by Busak+Shamban,in conjunction with Jerzy Ruzyllo, a renownedexpert in the area of semiconductor materials,processes and devices. A useful publication to make lifeeasy.

Expert on Demand

Are you looking for a sealing solution to fit your needs?The engineers at Busak+Shamban are ready to meet thischallenge. This voucher entitles you to a free consultingtalk. Give us a call, and we’ll provide the expertise.

Great thingscome in small packages

Order your FREE Sealing Solutions Toolkit at

Page 17: Busak+Shamban in the grooveEditorial 3 Welcome to our second edition of ‘in the groove’ focusing on semiconductor sealing solutions. The semiconductor industry requires continuous

17

Extras

Lunch and LearnVoucher

Let’s meet for a ‘Lunch and Learn’.We will take your engineers through

the basics of sealing technology. Contactus for your tailor-made training. All that

and we’ll provide the lunch too!

Our latest literature

In the Toolkit you will also find the latest literaturerelevant to your market. We will send you brochures on oursemiconductor and oil & gas sealing capabilities, along withmaterial data sheets on our Isolast® range.

To order your Sealing Solutions Toolkit go towww.busakshamban.com/groove and click the SealingSolutions Toolkit symbol. Or email us directly [email protected], to make your request.

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Oil & Gas

New Moscow officeexpandsBusak+Shambanpresence in EasternEurope

From Russia with oilBusak+Shamban is strategical lyexpanding our presence in EasternEurope, primarily to support ourcustomers in the expanding Russianoil and gas market. An alreadyrecognized supplier to this region, tomore effectively serve the equipmentmanufacturers and oil and gas fielddevelopers, we are establishing a newRussian office, based in Moscow.Up and running from January thisyear, it will initially operate with thehelp of personnel from the Bulgarianmarketing company. The mainobjective will be to recruit Russianengineers to work with designers andfield engineers locally, advising themon the right sealing solutions for theirspecific applications.

“Busak+Shamban is one of the largestglobal sealing developers andmanufacturers in the world”,Manager of the Moscow office,Yordan Vassilev, explained, “but wefeel it is vital that service and supportis provided at a local level. Ourexperience as an Internationalcompany is that we must never loosesight of our roots. When it comes todeveloping individual solutions it isimportant that we are close to thespecifiers, not only in terms oflocation but in language and culturetoo. That is how we have succeeded sofar and that is how we intend tosucceed in the future.”

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Semicon

The new marketing team inMoscow has already madetheir presence known inRussia. They exhibited at lastyear’s International Oil andGas show and this year planto exhibit at NEF Gas.

The Russian oil and gas industry

Russia has the largest natural gas reserves inthe world and the eighth largest oil reserves.It is now the world’s largest exporter ofnatural gas and the second largest oilexporter; its economic growth over the lastfive years primarily being fueled by its energyexports.Oil reserves in Russia are known to be around60 billion barrels, most of which are locatedin Western Siberia, between the UralMountains and the Central Siberian Plateau.In 2004 liquids production was just above9 billion bbl/d with only Saudi Arabiaproducing more crude oil during that year.

Russia to increase oil & gasproduction

Around 70% of Russia’s production is exportedas crude oil, much transported to EasternEurope via its major export pipeline, theDruzhba (meaning friendship). Approximately30% of crude oil is refined locally in Russia’sforty plus refineries.Russia’s 1680 trillion cubic feet (Tcf) of naturalgas reserves is nearly twice that of the nextlargest country, Iran. The majority of gasproduction is through three major fields (calledthe 'Big Three') in Western Siberia - Urengoy,Yamburg, and Medvezh'ye. Historically mostnatural gas exports were to Eastern Europe butthis has diversified with supply now to the EUand emerging markets of Turkey, Japan andother Asian countries.Russia is expected to significantly increase oiland gas production, along with crude exportsby 2015. The expansion of gas production willbe primarily through the development of newfields with transportation eased by theNorthern Gas Pipeline, linking Russia directlywith Germany.

www.busakshamban.com/grooveOil & Gas brochure at:

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Gaining the seals ofapprovalBusak+Shamban has a range of sealmaterials that comply to NORSOK M-710standard

Busak+Shamban has been a leading supplier of sealingsolutions to the oil and gas industry for over twenty-fiveyears. To support their customers supplying the Norwegianoil and gas industry in gaining NORSOK approval for theirassemblies, Busak+Shamban has had a number of sealingmaterials tested to NORSOK standards.

We can now offer the largest range of sealing materialswith certificates of compliance to NORSOK M-710, availablefrom any seal developer and manufacturer. And most ofthese are already proven and in long-term use in manydemanding exploration, offshore and onshore production,upstream and downstream environments.

Bill Allan, Busak+Shamban Oil and Gas Segment Managersays, “We are thrilled to have been so successful in thesetests. The availability of compliant materials will make iteasier for existing and new customers to achieve fullapproval for their assemblies from NORSOK.”

The sealing materials are available in a range of seal types.The PTFE based materials are commonly used in theindustry in the form of Turcon® Variseal®, back up rings andsupport rings.

Details of tests:

A number of grades of Busak+Shamban polymers wereinvolved in rigorous independent tests, undertaken andsupervised by MERL - materials engineering researchlaboratory, a respected independent laboratory in theUnited Kingdom. The main focus of the testing was topredict service life of the materials within an offshoreworking environment, as specified in NORSOK M-710standard, Annex C. Ideally materials should exceedexpected well production lifetime of an oil and gas facilityof 30 years.Thermoplastic sealing compounds, PTFE based grades andPEEK based materials, were immersed in a sour (2% H2S)multi-phase fluid at +200°C to +220°C (+392°F to + 428°F),for periods of 7 to 70 days. After saturation in this liquidthe mechanical properties, including tensile strength,elongation Young’s modulus and volume changes, weremeasured. These results were used to predict ageing andestimated service life of the materials.

Summary of results:

All eleven thermoplastic materials tested met NORSOKacceptance criteria, showing them to have good chemicalstability. Changes in tensile strength remained well withinthe NORSOK acceptance range for thermoplastics and alleasily exceeded the 30 year expected well productionlifetime.

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Semicon

Caption:MERL report relating to NORSOK M710standards for Busak+Shamban materials usedin the engineering of their seals for oil & gasapplications.

Oil & GasMERL report relatingto NORSOK M-710standards forBusak+Shambanmaterials.

The NORSOK Standards

The Norwegian petroleum industry has developedthe NORSOK standards to ensure safety, add value toand improve cost effectiveness of petroleumindustry developments and operations. Usually the NORSOK standards are based onrecognized international standards withmodifications to specifically meet the needs of theNorwegian petroleum industry. One of theobjectives of these standards is to contributeNorwegian knowledge to improve internationalstandards.Different from previous approvals, is that allindividual components within an assembly mustmeet and be approved to NORSOK standards, ratherthan just the complete assembly. The preparation and publication of the NORSOKstandards is supported by OLF (The Norwegian OilIndustry Association) and TBL (Federation ofNorwegian Manufacturing Industries). NORSOKstandards are managed and issued by StandardsNorway.

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Benefitplus –what does itmean?A seal or molding may only appear to be a minor partof a component but they are critical to its operation.Not only is the seal’s function important but also thesupport that goes along with their supply

Long before seals aremanufactured, the results of thedesign work are verified with theaid of the FEM.

Many seal manufacturers would liketo supply seals for cleanroomapplications. Only a few manufacturethem in one.

Benefitplus – what does it mean? Benefitplus is the little bitextra Busak+Shamban does that makes us different fromother seal suppliers. It is about our service. About thatadded something, that is often unseen but which can addreal benefits to you, our customer.

Pioneering Research

Busak+Shamban is a leader in sealing technology. Researchand Development facilities at six important locationsworldwide aim at matching new products to industryneeds. Our materials laboratories continue to add to thecurrent range of more than 2,000 proprietary compounds.Expertise in polymers shortens the lead-time betweenidentification of a specific requirement and formulation ofa new material to meet it, reducing our customers’ time tomarket.

Development support

We work with our chemical processing customers fromconcept stage to production. Rapid product design ishelped by use of the latest computer design and modellingsystems, fully customer-compatible CAD systems andleading edge Finite Element Analysis (FEA). In-houseprototyping means samples and urgently needed spares canbe fabricated quickly. Test sites prove manufacture involume before supply to customers.

On-line services

Busak+Shamban is making it easy to design and specifyseals, on-line. Our simple O-Ring calculator, with uniquefunctions, allows you to easily specify the correct O-Ring foryour application. With the CAD On-line service, at the clickof a mouse, you can download seal profiles to use incomponent designs. These free of charge programs arecompatible with all commonly used CAD systems and saveusers design time.

www.busakshamban.comVisit us at:

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Extras

Our supply chainincludes anefficient logisticscenter deliveringon-timeshipments.

That little bit extra!

Pioneering ResearchOur technology and expertise shortens time to

market

Development supportAccelerated design, with support from productconcept

On-line servicesEasing your design process at the touch of amouse

Industry expertiseWorking closely with customers speeds solutiondevelopment

Effective deliveryNo hold ups and downtime waiting for product

Continuous improvementQuality assurance ensures production efficiency

Industry expertise

Busak+Shamban focuses on important industries. Adedicated chemical processing team, covering the chemicalindustry, oil and gas, food and beverage production,pharmaceuticals and semiconductor manufacturing, worksfrom our head office in Stuttgart. They identify the globalindustry needs and make sure that products, materials andservices are developed to match the market requirements.Key accounts are globally co-ordinated with local contactsat our marketing companies worldwide.

Effective delivery

The amount of variations of seals Busak+Shamban cansupply is almost uncountable. This means that effectivelogistics are vital to ensure that the correct product isdelivered to our customers on time. A company-widecomputer system is at the center of our supply chainmanagement, linked to our strategically-placed logistics

centers globally and directly to some of our customers. Ourtrack and trace facility means we know exactly where goodsare once despatched and we can even accelerate delivery intransit, if necessary.

Continuous improvement

For us, quality is a given. To ensure this, global facilities arecertified and continuously monitored to a variety ofinternational standards including BS EN ISO 9001:2000, QS 9000, AS 9000, VDA 6.1 and TS 16949. We work with customers to prove their applications in ourtest facilities and have a range of materials and productsthat meet the specific standards of the chemical industry.This includes FDA, USP Class VI for food andpharmaceuticals, special water processing approvals andothers such as NORSOK for oil and gas.

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Part of Trelleborg Sealing Solutions, a business area of the Trelleborg Group

Employees: 6000 (Trelleborg Sealing Solutions)

Research and Development Centers in Europe andAmerica

30 manufacturing plants worldwide

Quality Certifications: ISO 9001, QS 9000, VDA 6.1

In-house polytetrafluor-ethylene, polyurethanedevelopment and elastomer development

More than 2000 material formulations

Worldwide distribution network

Contact your local Busak+Shamban MarketingCompany at:

www.busakshamban.com

Busak+Shambanat a glance

Contact the editorial team: [email protected]