c11600 lecture syl summer 2016

7/26/2019 C11600 Lecture Syl Summer 2016

http://slidepdf.com/reader/full/c11600-lecture-syl-summer-2016 1/6

GENERAL CHEMISTRY Chm 11600--Summer 2016

drop by.

Lecture: CLO-132, T,W,Th 12:00-2:50pm, Dr. Kathryn RowberMaterials: !"#berber, $enera# Chem"%try, &th or 'th ed"t"on, ()$raw*"##. +r"n a )a#)#ator to )#a%% eery day and to #ab. n-)#a%%"n%tr)t"on% w"## be "en /or the Tea% n%trment )a#)#ator%, a#thohany )a#)#ator "% a##owed.

Laboratory oteboo: Compo%"t"on or +ond oteboo.(ana##y pa"nate "n pper r"ht hand )orner 1-&0. The Tab#e o/

Content% %ho#d be on pae one. Do not tear pae% ot. o may )ont"ne to %e yor mana# /rom Chm 11500 "/there are at #ea%t ha#/ o/ the pae% n%ed.

Lab !pp#"e%: o#e%, 1 permanent marer, 1 part"a# ro## o/paper towe#% and a #o).

La!rat!r": Con)rrent re"%trat"on re4"red $-202#rere$uisites: Chm 11500 or e4"a#ent and a))eptab#e mathp#a)ement

C%&RSE 'ESCRI#TI%N: Chem"%try 11&00 "ntrod)e% the #aw% andpr"n)"p#e% o/ enera# )hem"%try. mer")a# prob#em% and re#at"on%h"p%are "ntrod)ed wheneer 4ant"tat"e treatment "% po%%"b#e.

%()ECTI*E: Chm 11&00 "% a )o##aborat"e )or%e 6mer"t ba%ed andno )ompet"t"on /or rade%7 w"th a oa# o/ %))e%% /or a##. The ob8e)t"eo/ th"% )or%e "% to tea)h the #aw% and pr"n)"p#e% beh"nd the%e top")%and a"n a )on)epta# nder%tand"n, to nder%tand the mode#% %ed

to pred")t )hem")a# beha"or, to mae )a#)#at"on% %"n the%e)on)ept% and to #earn the app#")at"on o/ the%e top")% "n order to %o#eprob#em%. The %tdent %ho#d a"n a deeper nder%tand"n o/)hem"%try )on)ept%--%o#t"on%, %o#b"#"ty, a)"d% and ba%e%, b9er%,e4"#"br"m, thermo)hem"%try, "net")%, e#e)tro)hem"%try, and n)#ear)hem"%try. !pe)"a# e9ort% are d"re)ted to dee#op %ma## rop prob#em-%o#"n %"##%.

mailto:[email protected]



LECT&RE ATTEN'ANCE: ttendan)e at a## )#a%%e% "% epe)ted. Thebe%t way to part")"pate "n the #e)tre "% to tae note% on the mater"a#)oered and wor on the prob#em% pre%ented "n )#a%%. +r"n a)a#)#ator to )#a%% %o yo )an )he) yor )omptat"on%. w"## %how)omptat"ona# te)hn"4e% /or mo%t Tea% n%trment )a#)#ator%.

h"h#y re)ommend T-;<, bt other% w"## wor.

=a)h %tdent "%re%pon%"b#e /or a## the mater"a# pre%ented "n the #e)tre and the #e)trew"## %b%tant"a##y ament the mater"a# "n the boo, there/ore yornote% %ho#d be he#p/# when %tdy"n /or an eam. / yo m"%% a)#a%%, p#ea%e et the )#a%% note% /rom a )#a%%mate and %ee me dr"no>)e hor% to )#ar"/y any 4e%t"on% reard"n the mater"a#. Keep "nm"nd that )hem"%try "% a r"oro% d"%)"p#"ne that re4"re% ma%tery o/pre)ed"n mater"a# to /##y nder%tand /tre mater"a#. o w"## pro?treat#y by eep"n p to date w"th the prob#em% a%%"ned and byread"n ahead "n the tet.

CLASSR%%M #%LICY : Chm 11&00 "% a )o##aborat"e )or%e 6mer"tba%ed and )r"ter"on-ba%e, %o no )ompet"t"on /or rade%7 w"th a oa# o/%))e%% /or a##. !tdent% are epe)ted to behae pro/e%%"ona##y "n the)#a%%room. Ce## phone% and beeper% m%t be trned o9 or %et to"brate dr"n )#a%%. Tet"n dr"n )#a%% d"%trb% tho%e arond yo, %obe )orteo% and tet a/ter )#a%%. rr"a# and departre to )#a%% %ho#dbe t"me#y, w"th m"n"ma# "nterrpt"on "n etenat"n )"r)m%tan)e%where one m%t #eae ear#y 6p#ea%e %"t by the door7. @%e o/%martphone%, e#e)tron") tran%#ator%, tab#et%, #aptop% or other de")e%)apab#e o/ a))e%%"n any other de")e or the "nternet w"## not bea##owed dr"n the eam%. A"o#at"on o/ th"% po#")y w"## be )on%"dered a

"o#at"on o/ the n"er%"tyB% *onor Code, and )an re%#t "n pena#t"e%ran"n /rom /a"#"n the eam to ep#%"on /rom the n"er%"ty.

+E(-SITE: Chm 11&00 "% aa"#ab#e on rde orthwe%t +#a)board. To a))e%% the %"te, o to the rde orthwe%t homepae and o toyor e-)or%e%. =nter "nto Chm 11&00 and )hoo%e /rom the aa"#ab#emen the "n/ormat"on yo want. There w"## be )op"e% o/ the %y##ab%,%amp#e% o/ eam% /rom pre"o% year%, handot% /rom )#a%%,annon)ement% /rom )#a%%, a## #aboratory mater"a#%, and he#p/# %"te%et). n add"t"on, yo )an ema"# me /rom the %"te w"th any 4e%t"on% or)omment% yo m"ht hae, a#thoh pre/er ema"# /rom the addre%%

yo )he) re#ar#y. %a##y )he) my ema"# da"#y e)ept onweeend% and dr"n brea%.

GRA'ING AN' E,AMINATI%NS: !)ore% /rom the top /or o/ ?e4"e% 620 po"nt% ea)h7, %)ore% /rom 10 o/ 11 #ab per"od%, homewor610 pt% maE)hapter7, three eam% 6100 pt% ea)h7, and the ?na#)m#at"e eam 6150 pt%7 w"## be %ed to )a#)#ate yor rade.Le)tre 4"e% w"## be "en e"ther "n )#a%% or on#"ne and %a##y



annon)ed a /ew day% "n adan)e. o maep 4"e% are "en, btthe #owe%t #e)tre 4" %)ore w"## be dropped.

The #owe%t la report %)ore w"## be dropped. Th"% a##ow% /or ann/ore%een ab%en)e that w"## not )ont aa"n%t yo. Lab mae-p% areranted /or e)%ed ab%en)e% that are )omp#eted on a t"me#y ba%"%.(ore than two ne)%ed ab%en)e% /rom the #ab "% rea%on to "n"t"ate

adm"n"%trat"e w"thdrawa# o/ the %tdent. The oera## #ab %)ore w"## bereported a% a per)entae, wh")h w"## be m#t"p#"ed by 2.0 /or the #ab%)ore.

H!me!r. "% to be )omp#eted on#"ne by the de date /o##ow"nthe #a%t #e)tre /or that )hapter. The on#"ne homewor )he)% yoran%wer and "/ "t "%nFt )orre)t, yo w"## be "n/ormed and a##owed to tryaa"n and aa"n howeer, ea)h %))e%%"e try de)rea%e% the %)ore /orthe 4e%t"on by 5G. am w"##"n to "e a %tdent an eten%"on on thehomewor /or #e"t"mate rea%on%. To pr)ha%e the homewor a))e%%,read the homewor a))e%% ?#e nder %tdy mater"a#%.

E/ams are raded )are/##y. / yo w"%h to hae yor eam

reraded, wr"te the prob#em nmber at the top /ront o/ the eam andthe rea%on /or rerad"n. On#y %tdent% "en perm"%%"on "n adan)e bythe "n%tr)tor and tho%e w"th e)%ed ab%en)e% w"## be perm"tted totae a mae-p eam.

## %tdent% are he#d a))ontab#e to the *onor #ede. nya)adem") d"%hone%ty w"## be dea#t w"th a))ord"n to @n"er%"ty o#")y6%ee handboo7. $""n or re)e""n nathor"ed a"d "% %tr")t#y/orb"dden. When dobt e"%t% )on)ern"n a"d, a% "/ "t "% perm"tted. Horeamp#e, do"n homewor prob#em% "n a rop "% not on#y a##owed, bten)oraed. Hrthermore, note% are not a##owed "n 4"e%, a#thohyo may a% the "n%tr)tor 4e%t"on% dr"n the 4". ny a)t o/

d"%hone%ty dr"n a 4", eam, or "n the #ab w"## be pena#"ed at thed"%)ret"on o/ the "n%tr)tor.

!pe)"a# #e)tre eent% and etra )red"t a%%"nment% w"## bement"oned "n )#a%%. Hor eamp#e, etra )red"t may be "en /or an "n-)#a%% rop a)t""ty.

The eam date% hae been %et and are "n th"% %y##ab%. #ea%enote them and tran%/er them to yor day p#anner. nyone m"%%"n aneam w"## re)e"e a ero /or h"% or her %)ore. *oweer, the%tandard"ed C! eam w"## be "en dr"n )he)ot "n the #ab. Thetran%/ormed %)ore /rom th"% )an %b%t"tte /or the #owe%t eam %)oreyo hae %o "t "% worth re"ew"n /or th"%.

SI a CHM 11600 Tut!ri: Or ! /or the %eme%ter "% w"##"n topro"de any he#p yo need /or the )or%e mater"a#. nd""da# androp he#p "% a#%o aa"#ab#e at the !"##% %%e%%ment and Dee#opmentCenter 6)a##ed the Ttor"n Center $-1027. !ee the"r %)hed#e /oraa"#ab#e ttor%.

C%&RSE #%INT 'ISTRI(&TI%N:



I"e% ;0*omewor <0Lab% 200 6G earned "n #ab 27=am% , and 300H"na# 150 Tota# ;20 pt% po%%"b#e

The a%%"nment o/ rade% w"## be ba%ed on tota# per)entae o/po"nt% earned. The %)a#e repre%ent"n the m"n"mm per)entae o/po"nt% needed /or the #etter rade% "% be#ow.

;5G + '5G C &5G D 50GKeep yor per%ona# re)ord o/ po"nt% and re/er to (y rade% on+#a)board.I" JJJ JJJ JJJ JJJ JJJ JJJE;0 6drop#owe%t7*omewor JJJ JJJ JJJ JJJ JJJ JJJ JJJ JJJ JJJ JJJE<0=am% JJJ JJJ JJJ JJJE300

Lab JJJ JJJ JJJ JJJ JJJ JJJ JJJ JJJ JJJ JJJ JJJE2006drop #owe%t7H"na# JJJ JJJE150=tra Cred"t and bon%e% JJJ JJJ JJJ

Tota# JJJJJJJE;20

C%&RSE %&TLINE: ne 2;,2< Ch 12.1-12.& ntermo#e)#ar Hor)e% n 2<,30 Ch 13 ropert"e% o/ ("tre%

E/am I )ul" 3 Cha4ters 1251 #y 5,& Ch 1& K"net")%

#y ' Ch 1' =4"#"br"aE/am II )ul" 12 Cha4ters 16517

#y 12,13 Ch 1; )"d-+a%e =4"#"br"a #y 1 Ch 1< on") =4"#"br"a #y 1<, 20 Ch 20 Thermodynam")%

E/am III )ul" 21 Cha4ters 18519520 #y 21 Ch 21 =#e)tro)hem"%try #y 2' Ch 2.1-2.,2.' )#ear Chem"%try #y 2; Re"ew 10-12 H"na# 12:30-2:30

ial Cumulati;e ial 12:0-2:0. The ?na# w"## hae 50

po"nt% oer Ch 21,2 and 100 po"nt% oer )m#at"e mater"a# /romChm 11&00.

C%NTACT +ITH #R%ESS%R: #ea%e /ee# /ree to drop by my o>)eand ta# abot the )or%e, )hem"%try 4e%t"on%, )areer "dea%, %mmer 8ob%, et). wo#d #"e to /o%ter %tdent part")"pat"on "n %)"en)ea)t""t"e% and want to be a re%or)e to yo "n a)h"e"n yor oa#%.Remember Chm 11&00 "% a )o##aborat"e )or%e 6mer"t-ba%ed and no



)ompet"t"on /or rade%7 w"th a oa# o/ %))e%% /or a##.

EMERGENCY #R%CE'&RES: n )a%e o/ emeren)y, p#ea%e not"/ypo#")e a% %oon a% po%%"b#e 6d"a# <117. +e aware o/ emeren)y e"t% "nthe )#a%%room% and /am"#"ar"e yor%e#/ w"th the ea)at"on p#anpo%ted "n ea)h room. #ea%e d"%)%% %a/ety )on)ern% w"th the

"n%tr)tor%. n =meren)y r"ntot "% aa"#ab#e /rom the "n%tr)tor.

S#ECIAL ASSISTANCE: !tdent% who may need a))ommodat"on%de to d"%ab"#"ty %ho#d )onta)t the O>)e o/ D"%ab"#"ty Re%or)e% 6ODR7to d"%)%% %pe)"?) need%. The ODR "% #o)ated on the th"rd Moor o/ the!tdent @n"on N L"brary +"#d"n, Room 31. / a))ommodat"on% /or a%tdent are approed by that o>)e, the %tdent m%t pro"de h"%Eher"n%tr)tor w"th a )opy o/ the o>)"a# a))ommodat"on% #etter a% %oon a%"t "% re)e"ed "n order to obta"n a))ommodat"on%. !tdent% may)onta)t the O>)e o/ D"%ab"#"ty Re%or)e% by )a##"n 21<-<;<-255 orema"#"n odrprde)a#.ed.

H%ME+%R< ASSIGNMENTS AN' %#ERATI%NAL S<ILLS 6%ee a#%oLearn"n Ob8e)t"e% at the end o/ ea)h )hapter7. @%e th"% whenre"ew"n /or eam%.

Ch 12.1-12.& ntermo#e)#ar Hor)e%!"##%: red")t re#at"e entrop"e%, re)on"e the /or)e% )a%"n phy%")a#e9e)t% "n #"4"d% and %o#"d%, "nterpret pha%e d"aram%, "dent"/y"ntermo#e)#ar /or)e%, %e the C#a%"%-C#apeyron e4at"on, now the)hara)ter"%t")% o/ )b") n"t )e##%, app#y band theory, 4ant"/y theheatEentha#py o/ ar"o% pro)e%%e%

Ch 13 ropert"e% o/ ("tre%!"##%: De%)r"be "ntermo#e)#ar "ntera)t"on%, pred")t re#at"e entha#p"e%and entrop"e%, determ"ne the e9e)t o/ temperatre and pre%%re onapor pre%%re, app#y Rao#tB% Law, app#y *enryF% Law, )a#)#ate%o#t"on )on)entrat"on%, )onert )on)entrat"on n"t%, )a#)#ate apor-pre%%re #ower"n, )a#)#ate bo"#"n-po"nt e#eat"on and /ree"n-po"ntdepre%%"on, )a#)#ate o%mot") pre%%re, de%)r"be d"%t"##at"on.

Chapter 1& Chem")a# K"net")%!"##%: Re#ate d"9erent way% o/ epre%%"n rea)t"on rate%, determ"ne

the order o/ rea)t"on /rom the rate #aw, determ"ne the rate #aw /rom"n"t"a# rate%, )a#)#ate rea)tant )on)entrat"on or t"me per"od %"n therate #aw, )a#)#ate ha#/ #"e%, %e the rrhen"% e4at"on, de%)r"be thee9e)t o/ a )ata#y%t, )a#)#ate enery o/ a)t"at"on, ded)e the rate #aw/rom the me)han"%m.

Chapter 1' =4"#"br"a!"##%: Wr"te the rea)t"on 4ot"ent, wr"te e4"#"br"m epre%%"on%,



determ"ne and de%)r"be the e4"#"br"m )on%tant% and n"t%, "nterprete4"#"br"m p#ot%, )reate e4"#"br"m tab#e%, app#y %to")h"ometry to ane4"#"br"m m"tre, re#ate the pre%%re e4"#"br"m )on%tant to the)on)entrat"on e4"#"br"m )on%tant, re#ate the rea)t"on 4ot"ent to thee4"#"br"m )on%tant, app#y Le Chate#"erB% pr"n)"p#e.

Chapter 1; )"d-+a%e =4"#"br"a!"##%: dent"/y a)"d% and ba%e% 6and )on8ate%7, determ"ne thepo%"t"on o/ an a)"dEba%e e4"#"br"m, )a#)#ate )on)entrat"on% o/ a)"dand ba%e, )a#)#ate the a)"d or ba%e d"%%o)"at"on )on%tant, )a#)#atep*, pred")t trend% "n a)"d"tyEba%")"ty, determ"ne e4"#"br"m po%"t"on,determ"ne the e9e)t o/ )ommon "on.

Chapter 1< on") =4"#"br"a!"##%: pp#y *ender%on-*a%%e#ba)h e4at"on, ep#a"n how "nd")ator%wor and how to %e#e)t one, per/orm t"trat"on )a#)#at"on% w"th a %tronba%e, )a#)#ate the )on)entrat"on% o/ "on% "n the pre%en)e o/ a )omp#e

"on, wr"te %o#b"#"ty prod)t epre%%"on%, )a#)#ate the K%p /rom the%o#b"#"ty, )a#)#ate the %o#b"#"ty /rom the K%p, pred")t whetherpre)"p"tat"on w"## o))r, )ompare %o#b"#"t"e%.

Chapter 20 Thermodynam")%!"##%: pp#y the thermodynam") #aw%, pred")t the %"n o/ the entropy)hane o/ a rea)t"on, )a#)#ate /ree enery )hane /romthermodynam") data, "nterpret the %"n o/ the )hane "n /ree enery,determ"ne the e9e)t o/ temperatre on the )hane "n /ree enery,)a#)#ate the /ree enery at non%tandard )ond"t"on%, )a#)#ate /ree

enery )hane at non%tandard temperatre%.

Chapter 21 =#e)tro)hem"%try!"##%: !et)h and #abe# a o#ta") )e##, wr"te the )e## rea)t"on /rom the)e## notat"on, )a#)#ate the )e## potent"a#, app#y the ern%t e4at"on,determ"ne the e9e)t o/ )on)entrat"on o/ )e## potent"a#, )a#)#ate /reeenery )hane /rom e#e)trode potent"a#%, )a#)#ate the e4"#"br"m)on%tant /rom )e## em/, de%)r"be how a battery wor%.

Chapter 2 %e)t"on% 1- and ' )#ear Chem"%try!"##%: Wr"te a n)#ear rea)t"on, pred")t a prod)t or rea)tant "n a

n)#ear e4at"on, determ"ne the ha#/-#"/e /rom the de)ay )on%tant,determ"ne the /ra)t"on o/ n)#e" rema"n"n a/ter a t"me per"od, "nterpreta de)ay %er"e%, ep#a"n ?%%"on and /%"on.

c11600 lecture syl summer 2016

Documents