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    Car Refrigerant for India

    HFC 134a

    New Age CarRefrigerant for India

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    Executive Summary

    Unprecedented rise in the demand for Car

    Refrigerants in India due to phenomenal growthin the Automobile Industry.

    Current Refrigerants used : CFC 12 and otherfluorocarbons and their environmental impact.

    Use of newer and eco friendly Refrigerants likeHFC 134a , their advantages and futureprospects.

    Indian Scenario in regard to MAC( Mobile Air

    Conditioning)

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    Indian Automobile Industry 03 -04

    Landmark Year - 1 Million mark achieved. *

    Sales grew 32.20 % in 03 - 04(9,00,752 units indomestic sales and 129,316 units of exports)

    Growth expected to inundate the market in theforthcoming years.

    Tremendous boost to Indian economic growth. Increased demand for mobile air conditioning

    (MAC) units.

    *Source : Society of Indian Automobile Manufacturers {SIAM})

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    Repercussions of Growth

    Excessive usage of CFCs contributing to

    Global Warming , damage to stratosphericozone layer.

    CFCs used in the MAC units in India are notregulated for their release ,when the carsare scrapped & junked.

    CFCs released have a long atmosphericshell life of around 100 years.

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    Fluorocarbons

    CFCs , HCFCs , HFCs

    Excellent Thermodynamic properties , non flammable .

    Ozone Depletion Potential (ODPs) of the fluorocarbons :

    Ozone Dep et on Potent a s

    1 0

    0 11

    0 065

    0 055

    0 0

    Fuorocarbons

    F -134a

    F -22

    F -142b

    F -141b

    F -12

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    Destruction of Ozone

    CFCs absorb the UV rays , and then disintegrate

    through photochemical reactions releasing freeChlorine atoms.

    CFCl3 (g) + hv CFCl2 (g) +Cl(g)CF2Cl2 (g) + hv CF2Cl (g) +Cl(g)

    The Final Reaction thus :

    203 (g) 302 (g)

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    Destruction of Ozone(Cont..)

    Fluorocarbon

    Atmospheric Life

    (Years)

    HFC-134a 14

    HCFC-22 13.3CFC-12 102

    Ozone Distribution in the Atmosphere

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    CFC 12 v HFC 134a

    High ODP of 1.0

    Much Higher GlobalWarming Potential thanHFC 134a

    Longer Atmospheric Life 100 years

    Not affected by naturalprocesses thus tend toaccumulate.

    Negligible ODP of 0.0

    Weak greenhouse gas Short atmospheric life

    14 years

    Easily destroyed bynatural processes , does

    not accumulate

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    Production Data

    Production o uorocar on

    0

    25

    50

    75

    100

    125

    150

    175

    200

    225

    250

    1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002

    Ti

    ar

    E

    i

    ion

    '

    M

    trictonn

    CFC - 12

    HFC - 134a

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    Emissions Data

    Emissions o oro ar ons

    0.0

    25.0

    50.0

    75.0

    100.0

    125.0

    150.0

    175.0

    200.0

    225.0

    250.0

    275.0

    300.0

    1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002

    im

    ars

    Emissions

    M

    tri

    !

    tonn

    s"

    C C 12

    H C 134a

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    Global Conventions Fluorocarbons

    United Nations Environment Programme (UNEP) in

    1976 Issue of Ozone Depletion was tackled. The 1985 Vienna Convention Systematic

    observation of the ozone layer, monitoring of CFCs.

    The Montreal protocol on substances that depletethe ozone layer September 1987 Phase out till2000.

    The Kyoto Protocol aims at reducing Greenhousegases emissions including CFCs.

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    HFC 134a Car Refrigerant

    The HFC-134a refrigerant has replaced CFC-12 in the

    western countries.

    US EPA has recommended HFC 134a as a eco friendly

    refrigerant , promoting it as a replacement for CFCs.

    HFC 134a has met with the desired performance and

    system durability.

    Global giants like Honda , Toyota , Mitsubishi , Audi ,

    Hyundai have embraced HFC 134a .

    Smaller units due to smaller molecular size of HFCs

    Higher efficiency units which require lesser parts , tubes

    etc

    Cost effective in the long run.

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    Indian Scenario

    The heavy usage of local a/c , in various small towns.

    Scrapping & Junking.

    Excessive leakages and poor efficiency units .

    Bright Prospects:

    Arrival of multinationals bringing in HFC 134atechnologies.

    Emergence of Original equipment manufacturers (OEMs)authorized service agents, a/c manufactured and fitted inthe factories.

    The World Bank has decided to give India $ 82 millioncompensation for phase out of CFCs , if India meets the2010 deadline.

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    Review

    The colossal growth of Indian Car Industry and therelated environmental impacts with regard to a/cunits.

    Introduction to fluorocarbons ,ozone depletion , thedetrimental effects of CFCs.

    Evaluation of HFC 134a as a car refrigerant in

    India. The benefits of using HFC 134a units especially in

    India.

    Good solutions exist today if chosen wisely!!!!

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    References

    Websites :

    www.afeas.orgwww.indiacar.net

    www.eia.doe.gov

    www.autocar.com

    www.epa.gov

    Reports :

    Chemical Economic Handbook(CEH) on Fluorocarbonsby SRI International Limited.

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    Thanking you!!!

    Presented By :

    Abhishek Srivastava , Mukul Pathak

    3rd Year , Environmental Engg.

    Delhi College ofEngineering.