carbozinc 858 (3k) part a altex coatings ltd

Carbozinc 858 (3K) Part AAltex Coatings Ltd Chemwatch Hazard Alert Code: 4

Version No: 2.3.2.4Safety Data Sheet according to the Health and Safety at Work (Hazardous Substances) Regulations 2017

Issue Date: 07/06/2021Print Date: 07/06/2021

S.GHS.NZL.EN

SECTION 1 Identification of the substance / mixture and of the company / undertaking

Product Identifier

Product name Carbozinc 858 (3K) Part A

Chemical Name Not Applicable

Synonyms Not Available

Proper shipping namePAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL(including paint thinning or reducing compound)

Other means of identification Not Available

Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses Part A of an industrial coating

Details of the supplier of the safety data sheet

Registered company name Altex Coatings Ltd

Address 91-111 Oropi Road Tauranga 3112 New Zealand

Telephone +64 7 541 1221

Fax +64 7 541 1310

Website

Email [email protected]

Emergency telephone number

Association / Organisation NZ POISONS (24hr 7 days) CHEMWATCH EMERGENCY RESPONSE

Emergency telephonenumbers

0800 764766 +61 2 9186 1132

Other emergency telephonenumbers

Not Available +64 800 700 112

Once connected and if the message is not in your prefered language then please dial 01

SECTION 2 Hazards identification

Classification of the substance or mixture

Considered a Hazardous Substance according to the criteria of the New Zealand Hazardous Substances New Organisms legislation. Classified as Dangerous Goods for transportpurposes.

Classification [1]Flammable Liquid Category 3, Specific target organ toxicity - single exposure Category 2, Specific target organ toxicity - repeated exposureCategory 2, Acute Toxicity (Oral) Category 4, Skin Corrosion/Irritation Category 2, Eye Irritation Category 2, Reproductive Toxicity Category 2,Skin Sensitizer Category 1, Carcinogenicity Category 2, Chronic Aquatic Hazard Category 3

Legend: 1. Classified by Chemwatch; 2. Classification drawn from CCID EPA NZ; 3. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI

Determined by Chemwatchusing GHS/HSNO criteria

3.1C, 6.1D (oral), 6.3A, 6.4A, 6.5B (contact), 6.7B, 6.8B, 6.9B, 9.1C

Label elements

Hazard pictogram(s)

Signal word Warning

Hazard statement(s)

H226 Flammable liquid and vapour.

H371 May cause damage to organs.

H373 May cause damage to organs through prolonged or repeated exposure.

H302 Harmful if swallowed.

H315 Causes skin irritation.

www.altexcoatings.com

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CAS No Name

H319 Causes serious eye irritation.

H361 Suspected of damaging fertility or the unborn child.

H317 May cause an allergic skin reaction.

H351 Suspected of causing cancer.

H412 Harmful to aquatic life with long lasting effects.

Precautionary statement(s) Prevention

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

P233 Keep container tightly closed.

P260 Do not breathe mist/vapours/spray.

P280 Wear protective gloves, protective clothing, eye protection and face protection.

P240 Ground and bond container and receiving equipment.

P241 Use explosion-proof electrical/ventilating/lighting/intrinsically safe equipment.

P242 Use non-sparking tools.

P243 Take action to prevent static discharges.

P270 Do not eat, drink or smoke when using this product.

P264 Wash all exposed external body areas thoroughly after handling.

P273 Avoid release to the environment.

P272 Contaminated work clothing should not be allowed out of the workplace.

Precautionary statement(s) Response

P370+P378 In case of fire: Use alcohol resistant foam or normal protein foam to extinguish.

P302+P352 IF ON SKIN: Wash with plenty of water and soap.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P308+P311 IF exposed or concerned: Call a POISON CENTER/doctor/physician/first aider.

P314 Get medical advice/attention if you feel unwell.

P333+P313 If skin irritation or rash occurs: Get medical advice/attention.

P337+P313 If eye irritation persists: Get medical advice/attention.

P362+P364 Take off contaminated clothing and wash it before reuse.

P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/physician/first aider if you feel unwell.

P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].

P330 Rinse mouth.

Precautionary statement(s) Storage

P403+P235 Store in a well-ventilated place. Keep cool.

P405 Store locked up.

Precautionary statement(s) Disposal

P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation.

SECTION 3 Composition / information on ingredients

Substances

See section below for composition of Mixtures

Mixtures

%[weight]

1330-20-7 30-40

Not Available 20-30

71-36-3 1-10

78-93-3 1-10

Legend: 1. Classified by Chemwatch; 2. Classification drawn from CCID EPA NZ; 3. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI;4. Classification drawn from C&L; * EU IOELVs available

SECTION 4 First aid measures

Description of first aid measures

Eye Contact

If this product comes in contact with the eyes: Wash out immediately with fresh running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upperand lower lids. Seek medical attention without delay; if pain persists or recurs seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

xylene

epoxy resin

n-butanol

methyl ethyl ketone

Version No: 2.3.2.4 of 14

Carbozinc 858 (3K) Part A

Issue Date: 07/06/2021

Print Date: 07/06/2021

Continued...

Skin Contact

If skin contact occurs:Immediately remove all contaminated clothing, including footwear. Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation.

InhalationIf fumes, aerosols or combustion products are inhaled remove from contaminated area. Other measures are usually unnecessary.

Ingestion

If spontaneous vomiting appears imminent or occurs, hold patient's head down, lower than their hips to help avoid possible aspiration ofvomitus. If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Seek medical advice. Avoid giving milk or oils. Avoid giving alcohol.

Indication of any immediate medical attention and special treatment needed

Any material aspirated during vomiting may produce lung injury. Therefore emesis should not be induced mechanically or pharmacologically. Mechanical means should be used if it isconsidered necessary to evacuate the stomach contents; these include gastric lavage after endotracheal intubation. If spontaneous vomiting has occurred after ingestion, the patientshould be monitored for difficult breathing, as adverse effects of aspiration into the lungs may be delayed up to 48 hours.

SECTION 5 Firefighting measures

Extinguishing media

Special hazards arising from the substrate or mixture

Fire Incompatibility Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result

Advice for firefighters

Fire Fighting

Fire/Explosion Hazard

Liquid and vapour are flammable. Moderate fire hazard when exposed to heat or flame. Vapour forms an explosive mixture with air. Moderate explosion hazard when exposed to heat or flame. Vapour may travel a considerable distance to source of ignition. Heating may cause expansion or decomposition leading to violent rupture of containers. On combustion, may emit toxic fumes of carbon monoxide (CO).

Combustion products include:carbon monoxide (CO)carbon dioxide (CO2)aldehydesother pyrolysis products typical of burning organic material.

SECTION 6 Accidental release measures

Personal precautions, protective equipment and emergency procedures

See section 8

Environmental precautions

See section 12

Methods and material for containment and cleaning up

Minor Spills

Remove all ignition sources. Clean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. Control personal contact with the substance, by using protective equipment. Contain and absorb small quantities with vermiculite or other absorbent material. Wipe up. Collect residues in a flammable waste container.

Major Spills

Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves. Prevent, by any means available, spillage from entering drains or water course. Stop leak if safe to do so. Contain spill with sand, earth or vermiculite. Collect recoverable product into labelled containers for recycling. Neutralise/decontaminate residue (see Section 13 for specific agent). Collect solid residues and seal in labelled drums for disposal. Wash area and prevent runoff into drains. After clean up operations, decontaminate and launder all protective clothing and equipment before storing and re-using. If contamination of drains or waterways occurs, advise emergency services.

Personal Protective Equipment advice is contained in Section 8 of the SDS.





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+ x + x + + +

X — Must not be stored together0 — May be stored together with specific preventions+ — May be stored together

Source Ingredient Material name TWA STEL Peak Notes

SECTION 7 Handling and storage

Precautions for safe handling

Safe handling

Containers, even those that have been emptied, may contain explosive vapours. Do NOT cut, drill, grind, weld or perform similar operations on or near containers. Electrostatic discharge may be generated during pumping - this may result in fire. Ensure electrical continuity by bonding and grounding (earthing) all equipment. Restrict line velocity during pumping in order to avoid generation of electrostatic discharge (<=1 m/sec until fill pipe submerged to twice itsdiameter, then <= 7 m/sec). Avoid splash filling. Do NOT use compressed air for filling discharging or handling operations. Avoid all personal contact, including inhalation. Wear protective clothing when risk of overexposure occurs. Use in a well-ventilated area. Prevent concentration in hollows and sumps. DO NOT enter confined spaces until atmosphere has been checked. Avoid smoking, naked lights or ignition sources. Avoid generation of static electricity. DO NOT use plastic buckets. Earth all lines and equipment. Use spark-free tools when handling. Avoid contact with incompatible materials. When handling, DO NOT eat, drink or smoke. Keep containers securely sealed when not in use. Avoid physical damage to containers. Always wash hands with soap and water after handling. Work clothes should be laundered separately. Use good occupational work practice. Observe manufacturer's storage and handling recommendations contained within this SDS.Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions. DO NOT allow clothing wet with material to stay in contact with skin

Other information

Store in original containers in approved flammable liquid storage area.Store away from incompatible materials in a cool, dry, well-ventilated area. DO NOT store in pits, depressions, basements or areas where vapours may be trapped. No smoking, naked lights, heat or ignition sources. Storage areas should be clearly identified, well illuminated, clear of obstruction and accessible only to trained and authorised personnel -adequate security must be provided so that unauthorised personnel do not have access. Store according to applicable regulations for flammable materials for storage tanks, containers, piping, buildings, rooms, cabinets, allowablequantities and minimum storage distances. Use non-sparking ventilation systems, approved explosion proof equipment and intrinsically safe electrical systems. Have appropriate extinguishing capability in storage area (e.g. portable fire extinguishers - dry chemical, foam or carbon dioxide) andflammable gas detectors. Keep adsorbents for leaks and spills readily available. Protect containers against physical damage and check regularly for leaks. Observe manufacturer's storage and handling recommendations contained within this SDS.

Conditions for safe storage, including any incompatibilities

Suitable container

Packing as supplied by manufacturer. Plastic containers may only be used if approved for flammable liquid. Check that containers are clearly labelled and free from leaks. Manufactured product that requires stirring before use and having a viscosity of at least 20 cSt (25 deg. C): (i) Removable head packaging;(ii) Cans with friction closures and (iii) low pressure tubes and cartridges may be used

Storage incompatibility

Note: Depending on other risk factors, compatibility assessment based on the table above may not be relevant to storage situations, particularly where large volumes of dangerous goodsare stored and handled. Reference should be made to the Safety Data Sheets for each substance or article and risks assessed accordingly.

SECTION 8 Exposure controls / personal protection

Control parameters

Occupational Exposure Limits (OEL)

INGREDIENT DATA

New Zealand WorkplaceExposure Standards (WES)

xylene Dimethylbenzene50 ppm / 217mg/m3

Not Available Not Available Not Available


n-butanol n-Butyl alcohol Not Available Not Available50 ppm / 150mg/m3

skin-Skin absorption





Continued...


Ingredient TEEL-1 TEEL-2 TEEL-3

Ingredient Original IDLH Revised IDLH


methyl ethylketone

MEK (Methyl ethyl ketone,2-Butanone)

150 ppm / 445mg/m3

890 mg/m3 /300 ppm

Not Availablebio-Exposure can also beestimated by biological monitoring.

Emergency Limits

xylene Not Available Not Available Not Available

n-butanol 60 ppm 800 ppm 8000** ppm

methyl ethyl ketone Not Available Not Available Not Available

xylene 900 ppm Not Available

n-butanol 1,400 ppm Not Available

methyl ethyl ketone 3,000 ppm Not Available

Exposure controls

Appropriate engineeringcontrols

Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls canbe highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection.The basic types of engineering controls are:Process controls which involve changing the way a job activity or process is done to reduce the risk.Enclosure and/or isolation of emission source which keeps a selected hazard 'physically' away from the worker and ventilation that strategically'adds' and 'removes' air in the work environment. Ventilation can remove or dilute an air contaminant if designed properly. The design of aventilation system must match the particular process and chemical or contaminant in use.Employers may need to use multiple types of controls to prevent employee overexposure.

For flammable liquids and flammable gases, local exhaust ventilation or a process enclosure ventilation system may be required. Ventilationequipment should be explosion-resistant.Air contaminants generated in the workplace possess varying 'escape' velocities which, in turn, determine the 'capture velocities' of freshcirculating air required to effectively remove the contaminant.

Type of Contaminant: Air Speed:

solvent, vapours, degreasing etc., evaporating from tank (in still air).0.25-0.5 m/s(50-100f/min.)

aerosols, fumes from pouring operations, intermittent container filling, low speed conveyer transfers, welding, spray drift,plating acid fumes, pickling (released at low velocity into zone of active generation)

0.5-1 m/s(100-200f/min.)

direct spray, spray painting in shallow booths, drum filling, conveyer loading, crusher dusts, gas discharge (active generationinto zone of rapid air motion)

1-2.5 m/s(200-500f/min.)

Within each range the appropriate value depends on:

Lower end of the range Upper end of the range

1: Room air currents minimal or favourable to capture 1: Disturbing room air currents

2: Contaminants of low toxicity or of nuisance value only. 2: Contaminants of high toxicity

3: Intermittent, low production. 3: High production, heavy use

4: Large hood or large air mass in motion 4: Small hood-local control only

Simple theory shows that air velocity falls rapidly with distance away from the opening of a simple extraction pipe. Velocity generally decreaseswith the square of distance from the extraction point (in simple cases). Therefore the air speed at the extraction point should be adjusted,accordingly, after reference to distance from the contaminating source. The air velocity at the extraction fan, for example, should be a minimum of1-2 m/s (200-400 f/min.) for extraction of solvents generated in a tank 2 meters distant from the extraction point. Other mechanicalconsiderations, producing performance deficits within the extraction apparatus, make it essential that theoretical air velocities are multiplied byfactors of 10 or more when extraction systems are installed or used.

Personal protection

Eye and face protection

Safety glasses with side shields.Chemical goggles.Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describingthe wearing of lenses or restrictions on use, should be created for each workplace or task. This should include a review of lens absorptionand adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained intheir removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately andremove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed ina clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 ornational equivalent]

Skin protection See Hand protection below

Hands/feet protection

NOTE:The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves and other protectiveequipment, to avoid all possible skin contact. Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed.





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The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from manufacturer tomanufacturer. Where the chemical is a preparation of several substances, the resistance of the glove material can not be calculated in advanceand has therefore to be checked prior to the application.The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and has to be observed whenmaking a final choice.Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, hands should bewashed and dried thoroughly. Application of a non-perfumed moisturiser is recommended.Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include:· frequency and duration of contact,· chemical resistance of glove material,· glove thickness and· dexteritySelect gloves tested to a relevant standard (e.g. Europe EN 374, US F739, AS/NZS 2161.1 or national equivalent).· When prolonged or frequently repeated contact may occur, a glove with a protection class of 5 or higher (breakthrough time greater than240 minutes according to EN 374, AS/NZS 2161.10.1 or national equivalent) is recommended.· When only brief contact is expected, a glove with a protection class of 3 or higher (breakthrough time greater than 60 minutes according toEN 374, AS/NZS 2161.10.1 or national equivalent) is recommended.· Some glove polymer types are less affected by movement and this should be taken into account when considering gloves for long-termuse.· Contaminated gloves should be replaced.As defined in ASTM F-739-96 in any application, gloves are rated as:· Excellent when breakthrough time > 480 min· Good when breakthrough time > 20 min· Fair when breakthrough time < 20 min· Poor when glove material degradesFor general applications, gloves with a thickness typically greater than 0.35 mm, are recommended.It should be emphasised that glove thickness is not necessarily a good predictor of glove resistance to a specific chemical, as the permeationefficiency of the glove will be dependent on the exact composition of the glove material. Therefore, glove selection should also be based onconsideration of the task requirements and knowledge of breakthrough times.Glove thickness may also vary depending on the glove manufacturer, the glove type and the glove model. Therefore, the manufacturers’technical data should always be taken into account to ensure selection of the most appropriate glove for the task.Note: Depending on the activity being conducted, gloves of varying thickness may be required for specific tasks. For example:· Thinner gloves (down to 0.1 mm or less) may be required where a high degree of manual dexterity is needed. However, these gloves areonly likely to give short duration protection and would normally be just for single use applications, then disposed of.· Thicker gloves (up to 3 mm or more) may be required where there is a mechanical (as well as a chemical) risk i.e. where there is abrasionor puncture potentialGloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumedmoisturiser is recommended.When handling liquid-grade epoxy resins wear chemically protective gloves , boots and aprons.The performance, based on breakthrough times ,of:

· Ethyl Vinyl Alcohol (EVAL laminate) is generally excellent· Butyl Rubber ranges from excellent to good· Nitrile Butyl Rubber (NBR) from excellent to fair.· Neoprene from excellent to fair· Polyvinyl (PVC) from excellent to poor

As defined in ASTM F-739-96· Excellent breakthrough time > 480 min· Good breakthrough time > 20 min· Fair breakthrough time < 20 min· Poor glove material degradation

Gloves should be tested against each resin system prior to making a selection of the most suitable type. Systems include both the resin and anyhardener, individually and collectively)

· DO NOT use cotton or leather (which absorb and concentrate the resin), natural rubber (latex), medical or polyethylene gloves(which absorb the resin).· DO NOT use barrier creams containing emulsified fats and oils as these may absorb the resin; silicone-based barrier creamsshould be reviewed prior to use.

Replacement time should be considered when selecting the most appropriate glove. It may be more effective to select a glove with lowerchemical resistance but which is replaced frequently than to select a more resistant glove which is reused many times

Body protection See Other protection below

Other protection

Overalls. PVC Apron. PVC protective suit may be required if exposure severe. Eyewash unit. Ensure there is ready access to a safety shower. Some plastic personal protective equipment (PPE) (e.g. gloves, aprons, overshoes) are not recommended as they may produce staticelectricity.For large scale or continuous use wear tight-weave non-static clothing (no metallic fasteners, cuffs or pockets).Non sparking safety or conductive footwear should be considered. Conductive footwear describes a boot or shoe with a sole made from aconductive compound chemically bound to the bottom components, for permanent control to electrically ground the foot an shall dissipatestatic electricity from the body to reduce the possibility of ignition of volatile compounds. Electrical resistance must range between 0 to500,000 ohms. Conductive shoes should be stored in lockers close to the room in which they are worn. Personnel who have been issuedconductive footwear should not wear them from their place of work to their homes and return.

Recommended material(s)

GLOVE SELECTION INDEX

Glove selection is based on a modified presentation of the: 'Forsberg Clothing Performance Index'. The effect(s) of the following substance(s) are taken into account in the computer-generated selection: Carbozinc 858 (3K) Part A

BUTYL C

BUTYL/NEOPRENE C

Material CPI

Respiratory protection

Type A Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001,ANSI Z88 or national equivalent)

Where the concentration of gas/particulates in the breathing zone, approaches orexceeds the 'Exposure Standard' (or ES), respiratory protection is required.Degree of protection varies with both face-piece and Class of filter; the nature ofprotection varies with Type of filter.

Required MinimumProtection Factor

Half-FaceRespirator

Full-FaceRespirator

Powered AirRespirator





Continued...

CPE C

HYPALON C

NAT+NEOPR+NITRILE C

NATURAL RUBBER C

NATURAL+NEOPRENE C

NEOPRENE C

NEOPRENE/NATURAL C

NITRILE C

NITRILE+PVC C

PE C

PE/EVAL/PE C

PVA C

PVC C

PVDC/PE/PVDC C

SARANEX-23 C

SARANEX-23 2-PLY C

TEFLON C

VITON C

VITON/CHLOROBUTYL C

VITON/NEOPRENE C

* CPI - Chemwatch Performance IndexA: Best SelectionB: Satisfactory; may degrade after 4 hours continuous immersionC: Poor to Dangerous Choice for other than short term immersionNOTE: As a series of factors will influence the actual performance of the glove, a finalselection must be based on detailed observation. -* Where the glove is to be used on a short term, casual or infrequent basis, factors suchas 'feel' or convenience (e.g. disposability), may dictate a choice of gloves which mightotherwise be unsuitable following long-term or frequent use. A qualified practitionershould be consulted.

up to 5 x ES A-AUS / Class 1 -A-PAPR-AUS /Class 1

up to 25 x ES Air-line* A-2 A-PAPR-2

up to 50 x ES - A-3 -

50+ x ES - Air-line** -

^ - Full-faceA(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas orhydrogen cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfurdioxide(SO2), G = Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO =Oxides of nitrogen, MB = Methyl bromide, AX = Low boiling point organiccompounds(below 65 degC)

Cartridge respirators should never be used for emergency ingress or in areas ofunknown vapour concentrations or oxygen content.The wearer must be warned to leave the contaminated area immediately ondetecting any odours through the respirator. The odour may indicate that the mask isnot functioning properly, that the vapour concentration is too high, or that the mask isnot properly fitted. Because of these limitations, only restricted use of cartridgerespirators is considered appropriate.Cartridge performance is affected by humidity. Cartridges should be changed after 2hr of continuous use unless it is determined that the humidity is less than 75%, inwhich case, cartridges can be used for 4 hr. Used cartridges should be discardeddaily, regardless of the length of time used

SECTION 9 Physical and chemical properties

Information on basic physical and chemical properties

Appearance coloured viscous liquid

Physical state Liquid Relative density (Water = 1) 1.14

Odour Not AvailablePartition coefficient n-octanol

/ waterNot Available

Odour threshold Not Available Auto-ignition temperature (°C) 446

pH (as supplied) Not Available Decomposition temperature Not Available

Melting point / freezing point(°C)

Not Available Viscosity (cSt) Not Available

Initial boiling point and boilingrange (°C)

130 Molecular weight (g/mol) Not Available

Flash point (°C) 24 Taste Not Available

Evaporation rate 1 BuAC = 1 Explosive properties Not Available

Flammability Flammable. Oxidising properties Not Available

Upper Explosive Limit (%) 8.1Surface Tension (dyn/cm or

mN/m)Not Available

Lower Explosive Limit (%) 0.9 Volatile Component (%vol) Not Available

Vapour pressure (kPa) 2.4 Gas group Not Available

Solubility in water Immiscible pH as a solution (%) Not Available

Vapour density (Air = 1) 3.6 VOC g/L 376.13

SECTION 10 Stability and reactivity

Reactivity See section 7

Chemical stabilityUnstable in the presence of incompatible materials.Product is considered stable.Hazardous polymerisation will not occur.

Possibility of hazardousreactions

See section 7





Continued...

Conditions to avoid See section 7

Incompatible materials See section 7

Hazardous decompositionproducts

See section 5

SECTION 11 Toxicological information

Information on toxicological effects

Inhaled

The material is not thought to produce either adverse health effects or irritation of the respiratory tract following inhalation (as classified by ECDirectives using animal models). Nevertheless, adverse systemic effects have been produced following exposure of animals by at least one otherroute and good hygiene practice requires that exposure be kept to a minimum and that suitable control measures be used in an occupationalsetting.Inhalation of vapours may cause drowsiness and dizziness. This may be accompanied by sleepiness, reduced alertness, loss of reflexes, lack ofco-ordination, and vertigo.Inhalation of high concentrations of gas/vapour causes lung irritation with coughing and nausea, central nervous depression with headache anddizziness, slowing of reflexes, fatigue and inco-ordination.

Ingestion

Swallowing of the liquid may cause aspiration into the lungs with the risk of chemical pneumonitis; serious consequences may result.(ICSC13733)The material has NOT been classified by EC Directives or other classification systems as 'harmful by ingestion'. This is because of the lack ofcorroborating animal or human evidence.Accidental ingestion of the material may be damaging to the health of the individual.Not a likely route of entry into the body in commercial or industrial environments. The liquid may produce considerable gastrointestinal discomfortand be harmful or toxic if swallowed.

Skin Contact

The material may accentuate any pre-existing dermatitis conditionOpen cuts, abraded or irritated skin should not be exposed to this materialEntry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects. Examine the skinprior to the use of the material and ensure that any external damage is suitably protected.Skin contact with the material may be harmful; systemic effects may result following absorption.The material may cause moderate inflammation of the skin either following direct contact or after a delay of some time. Repeated exposure cancause contact dermatitis which is characterised by redness, swelling and blistering.

Eye

There is evidence that material may produce eye irritation in some persons and produce eye damage 24 hours or more after instillation. Severeinflammation may be expected with pain.The liquid produces a high level of eye discomfort and is capable of causing pain and severe conjunctivitis. Corneal injury may develop, withpossible permanent impairment of vision, if not promptly and adequately treated.

Chronic

There has been concern that this material can cause cancer or mutations, but there is not enough data to make an assessment.Skin contact with the material is more likely to cause a sensitisation reaction in some persons compared to the general population.Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. This material can cause serious damage if one is exposed to it for long periods. It can be assumed that it contains a substance which canproduce severe defects.Ample evidence exists from experimentation that reduced human fertility is directly caused by exposure to the material.

Carbozinc 858 (3K) Part ATOXICITY IRRITATION

Not Available Not Available

xylene

TOXICITY IRRITATION

Dermal (rabbit) LD50: >1700 mg/kg[2] Eye (human): 200 ppm irritant

Inhalation(Rat) LC50; 5922 ppm4h[1] Eye (rabbit): 5 mg/24h SEVERE

Oral(Mouse) LD50; 1548 mg/kg[2] Eye (rabbit): 87 mg mild

Eye: adverse effect observed (irritating)[1]

Skin (rabbit):500 mg/24h moderate

Skin: adverse effect observed (irritating)[1]

n-butanol

TOXICITY IRRITATION

Dermal (rabbit) LD50: ~3430 mg/kg[1] Eye (human): 50 ppm - irritant

Inhalation(Rat) LC50; >17.76 mg/l4h[2] Eye (rabbit): 1.6 mg-SEVERE

Oral(Mouse) LD50; 100 mg/kg[2] Eye (rabbit): 24 mg/24h-SEVERE

Eye: adverse effect observed (irreversible damage)[1]

Skin (rabbit): 405 mg/24h-moderate


methyl ethyl ketone

TOXICITY IRRITATION

Dermal (rabbit) LD50: ~6400-8000 mg/kg[2] Eye (human): 350 ppm -irritant

Inhalation(Mouse) LC50; 32 mg/L4h[2] Eye (rabbit): 80 mg - irritant





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Oral(Rat) LD50; 2054 mg/kg[1] Skin (rabbit): 402 mg/24 hr - mild

Skin (rabbit):13.78mg/24 hr open

Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwisespecified data extracted from RTECS - Register of Toxic Effect of chemical Substances


The following information refers to contact allergens as a group and may not be specific to this product. Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's oedema. The pathogenesis of contacteczema involves a cell-mediated (T lymphocytes) immune reaction of the delayed type. Other allergic skin reactions, e.g. contact urticaria,involve antibody-mediated immune reactions. The significance of the contact allergen is not simply determined by its sensitisation potential: thedistribution of the substance and the opportunities for contact with it are equally important. A weakly sensitising substance which is widelydistributed can be a more important allergen than one with stronger sensitising potential with which few individuals come into contact. From aclinical point of view, substances are noteworthy if they produce an allergic test reaction in more than 1% of the persons tested.Animal testing over 13 weeks showed bisphenol A diglycidyl ether (BADGE) caused mild to moderate, chronic, inflammation of the skin.Reproductive and Developmental Toxicity: Animal testing showed BADGE given over several months caused reduction in body weight but had noreproductive effects.Cancer-causing potential: It has been concluded that bisphenol A diglycidyl ether cannot be classified with respect to its cancer-causing potentialin humans.Genetic toxicity: Laboratory tests on genetic toxicity of BADGE have so far been negative.Immunotoxicity: Animal testing suggests regular injections of diluted BADGE may result in sensitization.Consumer exposure: Comsumer exposure to BADGE is almost exclusively from migration of BADGE from can coatings into food. Testing has notfound any evidence of hormonal disruption.The chemical structure of hydroxylated diphenylalkanes or bisphenols consists of two phenolic rings joined together through a bridging carbon.This class of endocrine disruptors that mimic oestrogens is widely used in industry, particularly in plastics.Bisphenol A (BPA) and some related compounds exhibit oestrogenic activity in human breast cancer cell line MCF-7, but there were remarkabledifferences in activity. Several derivatives of BPA exhibited significant thyroid hormonal activity towards rat pituitary cell line GH3, which releasesgrowth hormone in a thyroid hormone-dependent manner. However, BPA and several other derivatives did not show such activity. Resultssuggest that the 4-hydroxyl group of the A-phenyl ring and the B-phenyl ring of BPA derivatives are required for these hormonal activities, andsubstituents at the 3,5-positions of the phenyl rings and the bridging alkyl moiety markedly influence the activities.Bisphenols promoted cell proliferation and increased the synthesis and secretion of cell type-specific proteins. When ranked by proliferativepotency, the longer the alkyl substituent at the bridging carbon, the lower the concentration needed for maximal cell yield; the most activecompound contained two propyl chains at the bridging carbon. Bisphenols with two hydroxyl groups in the para position and an angularconfiguration are suitable for appropriate hydrogen bonding to the acceptor site of the oestrogen receptor.In vitro cell models were used to evaluate the ability of 22 bisphenols (BPs) to induce or inhibit estrogenic and androgenic activity. BPA,Bisphenol AF (BPAF), bisphenol Z (BPZ), bisphenol C (BPC), tetramethyl bisphenol A (TMBPA), bisphenol S (BPS), bisphenol E (BPE),4,4-bisphenol F (4,4-BPF), bisphenol AP (BPAP), bisphenol B (BPB), tetrachlorobisphenol A (TCBPA), and benzylparaben (PHBB) inducedestrogen receptor (ER)alpha and/or ERbeta-mediated activity. With the exception of BPS, TCBPA, and PHBB, these same BPs were alsoandrogen receptor (AR) antagonists. Only 3 BPs were found to be ER antagonists. Bisphenol P (BPP) selectively inhibited ERbeta-mediatedactivity and 4-(4-phenylmethoxyphenyl)sulfonylphenol (BPS-MPE) and 2,4-bisphenol S (2,4-BPS) selectively inhibited ERalpha-mediated activity.None of the BPs induced AR-mediated activity.The various members of the bisphenol family produce hormone like effects, seemingly as a result of binding to estrogen receptor-relatedreceptors (ERRs; not to be confused with estrogen receptors)A suspected estrogen-related receptors (ERR) binding agent:Estrogen-related receptors (ERR, oestrogen-related receptors) are so named because of sequence homology with estrogen receptors but do notappear to bind estrogens or other tested steroid hormones. The ERR family have been demonstrated to control energy homeostasis, oxidativemetabolism and mitochondrial biogenesis ,while effecting mammalian physiology in the heart, brown adipose tissue, white adipose tissue,placenta, macrophages, and demonstrated additional roles in diabetes and cancer.ERRs bind enhancers throughout the genome where they exert effects on gene regulationAlthough their overall functions remain uncertain, they also share DNA-binding sites, co-regulators, and target genes with the conventionalestrogen receptors ERalpha and ERbeta and may function to modulate estrogen signaling pathways.· ERR-alpha has wide tissue distribution but it is most highly expressed in tissues that preferentially use fatty acids as energy sources suchas kidney, heart, brown adipose tissue, cerebellum, intestine, and skeletal muscle. ERRalpha has been detected in normal adrenal cortextissues, in which its expression is possibly related to adrenal development, with a possible role in fetal adrenal function, indehydroepiandrosterone (DHEAS) production in adrenarche, and also in steroid production of post-adrenarche/adult life. DHEA and otheradrenal androgens such as androstenedione, although relatively weak androgens, are responsible for the androgenic effects of adrenarche, suchas early pubic and axillary hair growth, adult-type body odor, increased oiliness of hair and skin, and mild acne.· ERR-beta is a nuclear receptor . Its function is unknown; however, a similar protein in mouse plays an essential role in placentaldevelopment· ERR-gamma is a nuclear receptor that behaves as a constitutive activator of transcription. There is evidence that bisphenol A functions asan endocrine disruptor by binding strongly to ERRgamma BPA as well as its nitrated and chlorinated metabolites seems to binds strongly toERR-gamma (dissociation constant = 5.5 nM), but not to the estrogen receptor (ER). BPA binding to ERR-gamma preserves its basal constitutiveactivity.Different expression of ERR-gamma in different parts of the body may account for variations in bisphenol A effects. For instance,ERR-gamma has been found in high concentration in the placenta, explaining reports of high bisphenol A accumulation thereOxiranes (including glycidyl ethers and alkyl oxides, and epoxides) share many common characteristics with respect to animal toxicology. Onesuch oxirane is ethyloxirane; data presented here may be taken as representative.

XYLENE

Reproductive effector in ratsThe substance is classified by IARC as Group 3:NOT classifiable as to its carcinogenicity to humans.Evidence of carcinogenicity may be inadequate or limited in animal testing.

N-BUTANOL

For n-butanol:Acute toxicity: In animal testing, n-butanol (BA) was only slightly toxic, following exposure by swallowing, skin contact or irritation. Animal testingand human experience suggest that n-butanol is moderately irritating to the skin but severely irritating to the eye. Human studies show that BA isnot likely to cause skin sensitization. Warning of exposure occurs before irritation of the nose, because n-butanol has an odour which can bedetected below concentration levels cause irritation.Repeat dose toxicity: Animal testing showed temporarily reduction in activity and food intake following repeated exposure to BA, but otherwisethere was no evidence of chronic toxicity.Reproductive toxicity: Several animal studies indicate BA does not possess reproductive toxicity, and does not affect fertility.Developmental toxicity: BA only caused developmental changes and toxic effects on the foetus near or at levels that were toxic to the mother.Genetic toxicity: Testing shows that BA does not possess genetic toxicity.Cancer-causing potential: Based on negative results from testing for potential of n-butanol to cause mutations and chromosomal aberrations, BAhas a very small potential for causing cancer.

METHYL ETHYL KETONE

Methyl ethyl ketone is considered to have a low order of toxicity; however, methyl ethyl ketone is often used in combination with other solventsand the mixture may have greater toxicity than either solvent alone. Combinations of n-hexane with methyl ethyl ketone, and also methyl n-butylketone with methyl ethyl ketone may result in an increased in peripheral neuropathy, a progressive disorder of the nerves of the extremities.





Continued...

Ingredient Persistence: Water/Soil Persistence: Air

Combinations with chloroform also show an increase in toxicity.

XYLENE & N-BUTANOLThe material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure to irritants mayproduce conjunctivitis.

XYLENE & N-BUTANOL &METHYL ETHYL KETONE

The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production ofvesicles, scaling and thickening of the skin.

N-BUTANOL & METHYLETHYL KETONE

Asthma-like symptoms may continue for months or even years after exposure to the material ends. This may be due to a non-allergic conditionknown as reactive airways dysfunction syndrome (RADS) which can occur after exposure to high levels of highly irritating compound. Maincriteria for diagnosing RADS include the absence of previous airways disease in a non-atopic individual, with sudden onset of persistentasthma-like symptoms within minutes to hours of a documented exposure to the irritant. Other criteria for diagnosis of RADS include a reversibleairflow pattern on lung function tests, moderate to severe bronchial hyperreactivity on methacholine challenge testing, and the lack of minimallymphocytic inflammation, without eosinophilia. RADS (or asthma) following an irritating inhalation is an infrequent disorder with rates related tothe concentration of and duration of exposure to the irritating substance. On the other hand, industrial bronchitis is a disorder that occurs as aresult of exposure due to high concentrations of irritating substance (often particles) and is completely reversible after exposure ceases. Thedisorder is characterized by difficulty breathing, cough and mucus production.

Acute Toxicity Carcinogenicity

Skin Irritation/Corrosion Reproductivity

Serious Eye Damage/Irritation STOT - Single Exposure

Respiratory or Skinsensitisation

STOT - Repeated Exposure

Mutagenicity Aspiration Hazard

Legend: – Data either not available or does not fill the criteria for classification – Data available to make classification

SECTION 12 Ecological information

Toxicity

Carbozinc 858 (3K) Part AEndpoint Test Duration (hr) Species Value Source

Not Available Not Available Not Available Not Available Not Available

xylene

Endpoint Test Duration (hr) Species Value Source

EC50 72h Algae or other aquatic plants 4.6mg/l 2

LC50 96h Fish 2.6mg/l 2

EC50 48h Crustacea 1.8mg/l 2

NOEC(ECx) 73h Algae or other aquatic plants 0.44mg/l 2

n-butanol


NOEC(ECx) 504h Crustacea 4.1mg/l 2

EC50 72h Algae or other aquatic plants >500mg/l 1

LC50 96h Fish 100-500mg/l 4

EC50 48h Crustacea >500mg/l 1

EC50 96h Algae or other aquatic plants 225mg/l 2

methyl ethyl ketone


NOEC(ECx) 48h Crustacea 68mg/l 2


LC50 96h Fish >324mg/L 4

EC50 48h Crustacea 308mg/l 2


Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 3. EPIWIN SuiteV3.12 (QSAR) - Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard AssessmentData 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data

Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean high water mark. Do not contaminate water when cleaning equipment or disposingof equipment wash-waters.Wastes resulting from use of the product must be disposed of on site or at approved waste sites.DO NOT discharge into sewer or waterways.

Persistence and degradability

xylene HIGH (Half-life = 360 days) LOW (Half-life = 1.83 days)

n-butanol LOW (Half-life = 54 days) LOW (Half-life = 3.65 days)

methyl ethyl ketone LOW (Half-life = 14 days) LOW (Half-life = 26.75 days)





Continued...

Ingredient Bioaccumulation

Ingredient Mobility

Bioaccumulative potential

xylene MEDIUM (BCF = 740)

n-butanol LOW (BCF = 0.64)

methyl ethyl ketone LOW (LogKOW = 0.29)

Mobility in soil

n-butanol MEDIUM (KOC = 2.443)

methyl ethyl ketone MEDIUM (KOC = 3.827)

SECTION 13 Disposal considerations

Waste treatment methods

Product / Packaging disposal

Containers may still present a chemical hazard/ danger when empty. Return to supplier for reuse/ recycling if possible.

Otherwise:If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used to store the sameproduct, then puncture containers, to prevent re-use, and bury at an authorised landfill. Where possible retain label warnings and SDS and observe all notices pertaining to the product.

Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws operating in theirarea. In some areas, certain wastes must be tracked.A Hierarchy of Controls seems to be common - the user should investigate:

Reduction Reuse Recycling Disposal (if all else fails)

This material may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for its intended use. If it has beencontaminated, it may be possible to reclaim the product by filtration, distillation or some other means. Shelf life considerations should also beapplied in making decisions of this type. Note that properties of a material may change in use, and recycling or reuse may not always beappropriate.

DO NOT allow wash water from cleaning or process equipment to enter drains. It may be necessary to collect all wash water for treatment before disposal. In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first. Where in doubt contact the responsible authority.

Ensure that the hazardous substance is disposed in accordance with the Hazardous Substances (Disposal) Notice 2017

Disposal Requirements

Packages that have been in direct contact with the hazardous substance must be only disposed if the hazardous substance was appropriately removed and cleaned out from thepackage. The package must be disposed according to the manufacturer's directions taking into account the material it is made of. Packages which hazardous content have beenappropriately treated and removed may be recycled.The hazardous substance must only be disposed if it has been treated by a method that changed the characteristics or composition of the substance and it is no longer hazardous.DO NOT deposit the hazardous substance into or onto a landfill or a sewage facility.Burning the hazardous substance must happen under controlled conditions with no person or place exposed to(1) a blast overpressure of more than 9 kPa; or(2) an unsafe level of heat radiation.The disposed hazardous substance must not come into contact with class 1 or 5 substances.

SECTION 14 Transport information

Labels Required

Marine Pollutant NO

HAZCHEM •3Y

Land transport (UN)

UN number 1263

UN proper shipping namePAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL(including paint thinning or reducing compound)

Transport hazard class(es)Class 3

Subrisk Not Applicable

Packing group III

Environmental hazard Not Applicable





Continued...

Product name Group

Product name Ship Type

HSR Number Group Standard

Special precautions for userSpecial provisions 163; 223; 367

Limited quantity 5 L

Air transport (ICAO-IATA / DGR)

UN number 1263

UN proper shipping namePaint (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base); Paint related material (including paintthinning or reducing compounds)

Transport hazard class(es)

ICAO/IATA Class 3

ICAO / IATA Subrisk Not Applicable

ERG Code 3L

Packing group III


Special precautions for user

Special provisions A3 A72 A192

Cargo Only Packing Instructions 366

Cargo Only Maximum Qty / Pack 220 L

Passenger and Cargo Packing Instructions 355

Passenger and Cargo Maximum Qty / Pack 60 L

Passenger and Cargo Limited Quantity Packing Instructions Y344

Passenger and Cargo Limited Maximum Qty / Pack 10 L

Sea transport (IMDG-Code / GGVSee)

UN number 1263

UN proper shipping namePAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL(including paint thinning or reducing compound)

Transport hazard class(es)IMDG Class 3

IMDG Subrisk Not Applicable

Packing group III



EMS Number F-E , S-E

Special provisions 163 223 367 955

Limited Quantities 5 L

Transport in bulk according to Annex II of MARPOL and the IBC code

Not Applicable

Transport in bulk in accordance with MARPOL Annex V and the IMSBC Code

xylene Not Available

epoxy resin Not Available

n-butanol Not Available

methyl ethyl ketone Not Available

Transport in bulk in accordance with the ICG Code


epoxy resin Not Available

n-butanol Not Available

methyl ethyl ketone Not Available

SECTION 15 Regulatory information

Safety, health and environmental regulations / legislation specific for the substance or mixture

This substance is to be managed using the conditions specified in an applicable Group Standard

HSR002669 Surface Coatings and Colourants Flammable Carcinogenic Group Standard 2020

Please refer to Section 8 of the SDS for any applicable tolerable exposure limit or Section 12 for environmental exposure limit.

xylene is found on the following regulatory lists





Continued...

Hazard Class Quantity (Closed Containers) Quantity (Open Containers)

Class of substance Quantities

Hazard Class Gas (aggregate water capacity in mL) Liquid (L) Solid (kg) Maximum quantity per package for each classification

National Inventory Status

International Agency for Research on Cancer (IARC) - Agents Classified by the IARCMonographs

New Zealand Approved Hazardous Substances with controls

New Zealand Hazardous Substances and New Organisms (HSNO) Act - Classificationof Chemicals

New Zealand Hazardous Substances and New Organisms (HSNO) Act - Classificationof Chemicals - Classification Data

New Zealand Inventory of Chemicals (NZIoC)

New Zealand Workplace Exposure Standards (WES)

n-butanol is found on the following regulatory lists






methyl ethyl ketone is found on the following regulatory lists






Hazardous Substance Location

Subject to the Health and Safety at Work (Hazardous Substances) Regulations 2017.

3.1C 500 L in containers more than 5 L 250 L

3.1C 1 500 L in containers up to and including 5 L 250 L

Certified Handler

Subject to Part 4 of the Health and Safety at Work (Hazardous Substances) Regulations 2017.

Not Applicable Not Applicable

Refer Group Standards for further information

Maximum quantities of certain hazardous substances permitted on passenger service vehicles

Subject to Regulation 13.14 of the Health and Safety at Work (Hazardous Substances) Regulations 2017.

6.5A or 6.5B 120 1 3

3.1C or 3.1D 10 L

Tracking Requirements

Not Applicable


Australia - AIIC / AustraliaNon-Industrial Use

Yes

Canada - DSL Yes

Canada - NDSL No (xylene; epoxy resin; n-butanol; methyl ethyl ketone)

China - IECSC Yes

Europe - EINEC / ELINCS / NLP Yes

Japan - ENCS Yes

Korea - KECI Yes

New Zealand - NZIoC Yes

Philippines - PICCS Yes

USA - TSCA Yes

Taiwan - TCSI Yes

Mexico - INSQ Yes

Vietnam - NCI Yes

Russia - FBEPH Yes

Legend:Yes = All CAS declared ingredients are on the inventoryNo = One or more of the CAS listed ingredients are not on the inventory and are not exempt from listing(see specific ingredients in brackets)

SECTION 16 Other information

Revision Date 07/06/2021

Initial Date 07/06/2021

SDS Version Summary





Continued...

Version Date of Update Sections Updated

1.3.2.1 29/04/2021 Regulation Change

1.3.2.2 30/05/2021 Template Change



1.3.2.4 07/06/2021 Classification, Environmental, Ingredients

Other information

Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classificationcommittee using available literature references.The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace orother settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.

Definitions and abbreviations

PC－TWA: Permissible Concentration-Time Weighted AveragePC－STEL: Permissible Concentration-Short Term Exposure LimitIARC: International Agency for Research on CancerACGIH: American Conference of Governmental Industrial HygienistsSTEL: Short Term Exposure LimitTEEL: Temporary Emergency Exposure Limit。IDLH: Immediately Dangerous to Life or Health ConcentrationsES: Exposure StandardOSF: Odour Safety FactorNOAEL :No Observed Adverse Effect LevelLOAEL: Lowest Observed Adverse Effect LevelTLV: Threshold Limit ValueLOD: Limit Of DetectionOTV: Odour Threshold ValueBCF: BioConcentration FactorsBEI: Biological Exposure IndexAIIC: Australian Inventory of Industrial ChemicalsDSL: Domestic Substances ListNDSL: Non-Domestic Substances ListIECSC: Inventory of Existing Chemical Substance in ChinaEINECS: European INventory of Existing Commercial chemical SubstancesELINCS: European List of Notified Chemical SubstancesNLP: No-Longer PolymersENCS: Existing and New Chemical Substances InventoryKECI: Korea Existing Chemicals InventoryNZIoC: New Zealand Inventory of ChemicalsPICCS: Philippine Inventory of Chemicals and Chemical SubstancesTSCA: Toxic Substances Control ActTCSI: Taiwan Chemical Substance InventoryINSQ: Inventario Nacional de Sustancias QuímicasNCI: National Chemical InventoryFBEPH: Russian Register of Potentially Hazardous Chemical and Biological Substances

Powered by AuthorITe, from Chemwatch.





end of SDS

Carbozinc 858 3K Part BAltex Coatings Ltd Chemwatch Hazard Alert Code: 3

Version No: 1.2.2.4Safety Data Sheet according to the Health and Safety at Work (Hazardous Substances) Regulations 2017


S.GHS.NZL.EN


Product Identifier

Product name Carbozinc 858 3K Part B

Chemical Name Not Applicable


Proper shipping namePAINT, FLAMMABLE, CORROSIVE (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINTRELATED MATERIAL, FLAMMABLE, CORROSIVE (including paint thinning or reducing compound)



Relevant identified uses Part B of a multi-pack industrial coating




Telephone +64 7 541 1221

Fax +64 7 541 1310

Website





0800 764766 +61 2 9186 1132







Classification [1]Skin Corrosion/Irritation Category 1B, Specific target organ toxicity - repeated exposure Category 2, Flammable Liquid Category 2, Serious EyeDamage/Eye Irritation Category 1, Acute Toxicity (Oral) Category 4, Reproductive Toxicity Category 2, Skin Sensitizer Category 1, AspirationHazard Category 1, Carcinogenicity Category 2



3.1B, 6.1D (oral), 6.1E (aspiration), 8.2B, 8.3A, 6.5B (contact), 6.7B, 6.8B, 6.9B

Label elements

Hazard pictogram(s)

Signal word Danger

Hazard statement(s)

H314 Causes severe skin burns and eye damage.

H373 May cause damage to organs through prolonged or repeated exposure.

H225 Highly flammable liquid and vapour.

H302 Harmful if swallowed.

H361 Suspected of damaging fertility or the unborn child.


Page 1 continued...

CAS No Name

H317 May cause an allergic skin reaction.

H304 May be fatal if swallowed and enters airways.

H351 Suspected of causing cancer.


P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

P233 Keep container tightly closed.

P260 Do not breathe mist/vapours/spray.

P264 Wash all exposed external body areas thoroughly after handling.

P280 Wear protective gloves, protective clothing, eye protection and face protection.

P240 Ground and bond container and receiving equipment.

P241 Use explosion-proof electrical/ventilating/lighting/intrinsically safe equipment.

P242 Use non-sparking tools.

P243 Take action to prevent static discharges.

P270 Do not eat, drink or smoke when using this product.

P272 Contaminated work clothing should not be allowed out of the workplace.


P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor/physician/first aider.

P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P308+P313 IF exposed or concerned: Get medical advice/ attention.

P370+P378 In case of fire: Use alcohol resistant foam or normal protein foam to extinguish.

P302+P352 IF ON SKIN: Wash with plenty of water and soap.

P363 Wash contaminated clothing before reuse.

P333+P313 If skin irritation or rash occurs: Get medical advice/attention.

P362+P364 Take off contaminated clothing and wash it before reuse.

P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/physician/first aider if you feel unwell.

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.


P403+P235 Store in a well-ventilated place. Keep cool.

P405 Store locked up.




Substances


Mixtures

%[weight]

67-63-0 40-50

1330-20-7 30-40

135108-88-2 1-10

100-51-6 1-10

140-31-8 1-10

1761-71-3 <=1

90-72-2 1-10

Legend: 1. Classified by Chemwatch; 2. Classification drawn from CCID EPA NZ; 3. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI;4. Classification drawn from C&L; * EU IOELVs available



Eye Contact

If this product comes in contact with the eyes:Immediately hold eyelids apart and flush the eye continuously with running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upperand lower lids. Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes.

isopropanol

xylene

formaldehyde/ benzenamine, hydrogenated

benzyl alcohol

N-aminoethylpiperazine

4,4'-methylenebis(cyclohexylamine)

2,4,6-tris[(dimethylamino)methyl]phenol

Version No: 1.2.2.4 Page 2 of 15

Carbozinc 858 3K Part B



Continued...

Transport to hospital or doctor without delay. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

Skin Contact

If skin or hair contact occurs:Immediately flush body and clothes with large amounts of water, using safety shower if available. Quickly remove all contaminated clothing, including footwear. Wash skin and hair with running water. Continue flushing with water until advised to stop by the Poisons Information Centre. Transport to hospital, or doctor.

Inhalation

If fumes or combustion products are inhaled remove from contaminated area. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained.Perform CPR if necessary. Transport to hospital, or doctor, without delay. Inhalation of vapours or aerosols (mists, fumes) may cause lung oedema. Corrosive substances may cause lung damage (e.g. lung oedema, fluid in the lungs). As this reaction may be delayed up to 24 hours after exposure, affected individuals need complete rest (preferably in semi-recumbentposture) and must be kept under medical observation even if no symptoms are (yet) manifested. Before any such manifestation, the administration of a spray containing a dexamethasone derivative or beclomethasone derivative may beconsidered.

This must definitely be left to a doctor or person authorised by him/her.(ICSC13719)

Ingestion

For advice, contact a Poisons Information Centre or a doctor at once. Urgent hospital treatment is likely to be needed. If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Transport to hospital or doctor without delay. If spontaneous vomiting appears imminent or occurs, hold patient's head down, lower than their hips to help avoid possible aspiration ofvomitus. Avoid giving milk or oils. Avoid giving alcohol.


Any material aspirated during vomiting may produce lung injury. Therefore emesis should not be induced mechanically or pharmacologically. Mechanical means should be used if it isconsidered necessary to evacuate the stomach contents; these include gastric lavage after endotracheal intubation. If spontaneous vomiting has occurred after ingestion, the patientshould be monitored for difficult breathing, as adverse effects of aspiration into the lungs may be delayed up to 48 hours.Depending on the degree of exposure, periodic medical examination is indicated. The symptoms of lung oedema often do not manifest until a few hours have passed and they areaggravated by physical effort. Rest and medical observation is therefore essential. Immediate administration of an appropriate spray, by a doctor or a person authorised by him/hershould be considered.(ICSC24419/24421


Extinguishing media

Alcohol stable foam. Dry chemical powder. BCF (where regulations permit). Carbon dioxide. Water spray or fog - Large fires only.


Fire Incompatibility Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result


Fire Fighting

Alert Fire Brigade and tell them location and nature of hazard. May be violently or explosively reactive. Wear full body protective clothing with breathing apparatus. Prevent, by any means available, spillage from entering drains or water course. Consider evacuation (or protect in place). Fight fire from a safe distance, with adequate cover. If safe, switch off electrical equipment until vapour fire hazard removed. Use water delivered as a fine spray to control fire and cool adjacent area. Avoid spraying water onto liquid pools. Do not approach containers suspected to be hot. Cool fire exposed containers with water spray from a protected location. If safe to do so, remove containers from path of fire. Equipment should be thoroughly decontaminated after use.


Liquid and vapour are highly flammable. Severe fire hazard when exposed to heat, flame and/or oxidisers. Vapour may travel a considerable distance to source of ignition. Heating may cause expansion or decomposition leading to violent rupture of containers. On combustion, may emit toxic fumes of carbon monoxide (CO).

Combustion products include:carbon dioxide (CO2)nitrogen oxides (NOx)





Continued...

other pyrolysis products typical of burning organic material.WARNING: Long standing in contact with air and light may result in the formationof potentially explosive peroxides.



See section 8


See section 12


Minor Spills

Remove all ignition sources. Clean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. Control personal contact with the substance, by using protective equipment. Contain and absorb small quantities with vermiculite or other absorbent material. Wipe up. Collect residues in a flammable waste container. Drains for storage or use areas should have retention basins for pH adjustments and dilution of spills before discharge or disposal ofmaterial. Check regularly for spills and leaks.

Major Spills

Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. May be violently or explosively reactive. Wear full body protective clothing with breathing apparatus. Prevent, by any means available, spillage from entering drains or water course. Consider evacuation (or protect in place). No smoking, naked lights or ignition sources. Increase ventilation. Stop leak if safe to do so. Water spray or fog may be used to disperse vapour. Contain or absorb spill with sand, earth or vermiculite. Use only spark-free shovels and explosion proof equipment. Collect recoverable product into labelled containers for recycling. Collect solid residues and seal in labelled drums for disposal. Wash area and prevent runoff into drains. After clean up operations, decontaminate and launder all protective clothing and equipment before storing and re-using. If contamination of drains or waterways occurs, advise emergency services.




Safe handling

Containers, even those that have been emptied, may contain explosive vapours. Do NOT cut, drill, grind, weld or perform similar operations on or near containers. Electrostatic discharge may be generated during pumping - this may result in fire. Ensure electrical continuity by bonding and grounding (earthing) all equipment. Restrict line velocity during pumping in order to avoid generation of electrostatic discharge (<=1 m/sec until fill pipe submerged to twice itsdiameter, then <= 7 m/sec). Avoid splash filling. Do NOT use compressed air for filling discharging or handling operations. Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. Prevent concentration in hollows and sumps. DO NOT enter confined spaces until atmosphere has been checked. Avoid smoking, naked lights, heat or ignition sources. When handling, DO NOT eat, drink or smoke. Vapour may ignite on pumping or pouring due to static electricity. DO NOT use plastic buckets. Earth and secure metal containers when dispensing or pouring product. Use spark-free tools when handling. Avoid contact with incompatible materials. Keep containers securely sealed. Avoid physical damage to containers. Always wash hands with soap and water after handling. Work clothes should be laundered separately. Use good occupational work practice. Observe manufacturer's storage and handling recommendations contained within this SDS.Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions. DO NOT allow clothing wet with material to stay in contact with skin

Other information

Store in original containers in approved flame-proof area. No smoking, naked lights, heat or ignition sources. DO NOT store in pits, depressions, basements or areas where vapours may be trapped.Keep containers securely sealed. Store away from incompatible materials in a cool, dry well ventilated area.





Continued...

+ x + x + + +



Ingredient TEEL-1 TEEL-2 TEEL-3

Ingredient Original IDLH Revised IDLH

Ingredient Occupational Exposure Band Rating Occupational Exposure Band Limit

Notes: Occupational exposure banding is a process of assigning chemicals into specific categories or bands based on a chemical's potency and theadverse health outcomes associated with exposure. The output of this process is an occupational exposure band (OEB), which corresponds toa range of exposure concentrations that are expected to protect worker health.

Protect containers against physical damage and check regularly for leaks.Observe manufacturer's storage and handling recommendations contained within this SDS.


Suitable container

DO NOT use aluminium or galvanised containersPacking as supplied by manufacturer. Plastic containers may only be used if approved for flammable liquid. Check that containers are clearly labelled and free from leaks. For low viscosity materials (i) : Drums and jerry cans must be of the non-removable head type. (ii) : Where a can is to be used as an innerpackage, the can must have a screwed enclosure.

Storage incompatibility Avoid contact with copper, aluminium and their alloys.

Note: Depending on other risk factors, compatibility assessment based on the table above may not be relevant to storage situations, particularly where large volumes of dangerous goodsare stored and handled. Reference should be made to the Safety Data Sheets for each substance or article and risks assessed accordingly.


Control parameters


INGREDIENT DATA


isopropanol Isopropyl alcohol 400 ppm / 983 mg/m3 1230 mg/m3 / 500 ppm Not Available Not Available


xylene Dimethylbenzene 50 ppm / 217 mg/m3 Not Available Not Available Not Available

Emergency Limits

isopropanol 400 ppm 2000* ppm 12000** ppm

xylene Not Available Not Available Not Available

benzyl alcohol 30 ppm 52 ppm 740 ppm

N-aminoethylpiperazine 6.4 mg/m3 71 mg/m3 420 mg/m3


6.5 mg/m3 72 mg/m3 430 mg/m3

isopropanol 2,000 ppm Not Available

xylene 900 ppm Not Available

formaldehyde/ benzenamine,hydrogenated


benzyl alcohol Not Available Not Available

N-aminoethylpiperazine Not Available Not Available

4,4'-methylenebis(cyclohexylamine) Not Available Not Available



Occupational Exposure Banding


E ≤ 0.1 ppm

benzyl alcohol E ≤ 0.1 ppm

N-aminoethylpiperazine D > 0.1 to ≤ 1 ppm

4,4'-methylenebis(cyclohexylamine) E ≤ 0.1 ppm


C > 1 to ≤ 10 parts per million (ppm)

Exposure controls





Continued...


CARE: Use of a quantity of this material in confined space or poorly ventilated area, where rapid build up of concentrated atmosphere may occur,could require increased ventilation and/or protective gearEngineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls canbe highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection.The basic types of engineering controls are:Process controls which involve changing the way a job activity or process is done to reduce the risk.Enclosure and/or isolation of emission source which keeps a selected hazard 'physically' away from the worker and ventilation that strategically'adds' and 'removes' air in the work environment. Ventilation can remove or dilute an air contaminant if designed properly. The design of aventilation system must match the particular process and chemical or contaminant in use.Employers may need to use multiple types of controls to prevent employee overexposure.

For flammable liquids and flammable gases, local exhaust ventilation or a process enclosure ventilation system may be required. Ventilationequipment should be explosion-resistant.Air contaminants generated in the workplace possess varying 'escape' velocities which, in turn, determine the 'capture velocities' of freshcirculating air required to effectively remove the contaminant.


solvent, vapours, degreasing etc., evaporating from tank (in still air).0.25-0.5 m/s(50-100f/min.)

aerosols, fumes from pouring operations, intermittent container filling, low speed conveyer transfers, welding, spray drift,plating acid fumes, pickling (released at low velocity into zone of active generation)

0.5-1 m/s(100-200f/min.)

direct spray, spray painting in shallow booths, drum filling, conveyer loading, crusher dusts, gas discharge (active generationinto zone of rapid air motion)

1-2.5 m/s(200-500f/min.)







Simple theory shows that air velocity falls rapidly with distance away from the opening of a simple extraction pipe. Velocity generally decreaseswith the square of distance from the extraction point (in simple cases). Therefore the air speed at the extraction point should be adjusted,accordingly, after reference to distance from the contaminating source. The air velocity at the extraction fan, for example, should be a minimum of1-2 m/s (200-400 f/min.) for extraction of solvents generated in a tank 2 meters distant from the extraction point. Other mechanicalconsiderations, producing performance deficits within the extraction apparatus, make it essential that theoretical air velocities are multiplied byfactors of 10 or more when extraction systems are installed or used.

Personal protection


Chemical goggles.Full face shield may be required for supplementary but never for primary protection of eyes.Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describingthe wearing of lenses or restrictions on use, should be created for each workplace or task. This should include a review of lens absorptionand adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained intheir removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately andremove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed ina clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 ornational equivalent]



Wear chemical protective gloves, e.g. PVC. Wear safety footwear or safety gumboots, e.g. Rubber When handling corrosive liquids, wear trousers or overalls outside of boots, to avoid spills entering boots.

NOTE:The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves and other protectiveequipment, to avoid all possible skin contact. Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed.

The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from manufacturer tomanufacturer. Where the chemical is a preparation of several substances, the resistance of the glove material can not be calculated in advanceand has therefore to be checked prior to the application.The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and has to be observed whenmaking a final choice.Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, hands should bewashed and dried thoroughly. Application of a non-perfumed moisturiser is recommended.Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include:· frequency and duration of contact,· chemical resistance of glove material,· glove thickness and· dexteritySelect gloves tested to a relevant standard (e.g. Europe EN 374, US F739, AS/NZS 2161.1 or national equivalent).· When prolonged or frequently repeated contact may occur, a glove with a protection class of 5 or higher (breakthrough time greater than240 minutes according to EN 374, AS/NZS 2161.10.1 or national equivalent) is recommended.· When only brief contact is expected, a glove with a protection class of 3 or higher (breakthrough time greater than 60 minutes according toEN 374, AS/NZS 2161.10.1 or national equivalent) is recommended.





Continued...

· Some glove polymer types are less affected by movement and this should be taken into account when considering gloves for long-termuse.· Contaminated gloves should be replaced.As defined in ASTM F-739-96 in any application, gloves are rated as:· Excellent when breakthrough time > 480 min· Good when breakthrough time > 20 min· Fair when breakthrough time < 20 min· Poor when glove material degradesFor general applications, gloves with a thickness typically greater than 0.35 mm, are recommended.It should be emphasised that glove thickness is not necessarily a good predictor of glove resistance to a specific chemical, as the permeationefficiency of the glove will be dependent on the exact composition of the glove material. Therefore, glove selection should also be based onconsideration of the task requirements and knowledge of breakthrough times.Glove thickness may also vary depending on the glove manufacturer, the glove type and the glove model. Therefore, the manufacturers’technical data should always be taken into account to ensure selection of the most appropriate glove for the task.Note: Depending on the activity being conducted, gloves of varying thickness may be required for specific tasks. For example:· Thinner gloves (down to 0.1 mm or less) may be required where a high degree of manual dexterity is needed. However, these gloves areonly likely to give short duration protection and would normally be just for single use applications, then disposed of.· Thicker gloves (up to 3 mm or more) may be required where there is a mechanical (as well as a chemical) risk i.e. where there is abrasionor puncture potentialGloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumedmoisturiser is recommended.


Other protection

Overalls. PVC Apron. PVC protective suit may be required if exposure severe. Eyewash unit. Ensure there is ready access to a safety shower. Some plastic personal protective equipment (PPE) (e.g. gloves, aprons, overshoes) are not recommended as they may produce staticelectricity.For large scale or continuous use wear tight-weave non-static clothing (no metallic fasteners, cuffs or pockets).Non sparking safety or conductive footwear should be considered. Conductive footwear describes a boot or shoe with a sole made from aconductive compound chemically bound to the bottom components, for permanent control to electrically ground the foot an shall dissipatestatic electricity from the body to reduce the possibility of ignition of volatile compounds. Electrical resistance must range between 0 to500,000 ohms. Conductive shoes should be stored in lockers close to the room in which they are worn. Personnel who have been issuedconductive footwear should not wear them from their place of work to their homes and return.

Recommended material(s)

GLOVE SELECTION INDEX

Glove selection is based on a modified presentation of the: 'Forsberg Clothing Performance Index'. The effect(s) of the following substance(s) are taken into account in the computer-generated selection: Carbozinc 858 3K Part B

BUTYL C

BUTYL/NEOPRENE C

HYPALON C

NAT+NEOPR+NITRILE C

NATURAL RUBBER C

NATURAL+NEOPRENE C

NEOPRENE C

NEOPRENE/NATURAL C

NITRILE C

NITRILE+PVC C

PE/EVAL/PE C

PVA C

PVC C

PVDC/PE/PVDC C

TEFLON C

VITON C

* CPI - Chemwatch Performance IndexA: Best SelectionB: Satisfactory; may degrade after 4 hours continuous immersionC: Poor to Dangerous Choice for other than short term immersionNOTE: As a series of factors will influence the actual performance of the glove, a finalselection must be based on detailed observation. -* Where the glove is to be used on a short term, casual or infrequent basis, factors suchas 'feel' or convenience (e.g. disposability), may dictate a choice of gloves which mightotherwise be unsuitable following long-term or frequent use. A qualified practitionershould be consulted.

Material CPI


Type AK-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001,ANSI Z88 or national equivalent)

Where the concentration of gas/particulates in the breathing zone, approaches orexceeds the 'Exposure Standard' (or ES), respiratory protection is required.Degree of protection varies with both face-piece and Class of filter; the nature ofprotection varies with Type of filter.

Required MinimumProtection Factor

Half-FaceRespirator

Full-FaceRespirator

Powered AirRespirator

up to 5 x ESAK-AUS / Class1 P2

-AK-PAPR-AUS /Class 1 P2

up to 25 x ES Air-line* AK-2 P2 AK-PAPR-2 P2

up to 50 x ES - AK-3 P2 -

50+ x ES - Air-line** -

^ - Full-faceA(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas orhydrogen cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfurdioxide(SO2), G = Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO =Oxides of nitrogen, MB = Methyl bromide, AX = Low boiling point organiccompounds(below 65 degC)

Cartridge respirators should never be used for emergency ingress or in areas ofunknown vapour concentrations or oxygen content.The wearer must be warned to leave the contaminated area immediately ondetecting any odours through the respirator. The odour may indicate that the mask isnot functioning properly, that the vapour concentration is too high, or that the mask isnot properly fitted. Because of these limitations, only restricted use of cartridgerespirators is considered appropriate.Cartridge performance is affected by humidity. Cartridges should be changed after 2hr of continuous use unless it is determined that the humidity is less than 75%, inwhich case, cartridges can be used for 4 hr. Used cartridges should be discardeddaily, regardless of the length of time used






Continued...


Appearance Amber liquid

Physical state Liquid Relative density (Water = 1) 0.86



Odour threshold Not Available Auto-ignition temperature (°C) 417



Not Available Viscosity (cSt) 32.00


109 Molecular weight (g/mol) Not Available

Flash point (°C) 21 Taste Not Available

Evaporation rate 1.7 BuAC = 1 Explosive properties Not Available

Flammability HIGHLY FLAMMABLE. Oxidising properties Not Available

Upper Explosive Limit (%) 10.3Surface Tension (dyn/cm or

mN/m)Not Available

Lower Explosive Limit (%) 1.5 Volatile Component (%vol) 80

Vapour pressure (kPa) 4.1 Gas group Not Available

Solubility in water Immiscible pH as a solution (%) Not Available

Vapour density (Air = 1) 2.77 VOC g/L 723.62



Chemical stabilityUnstable in the presence of incompatible materials.Product is considered stable.Hazardous polymerisation will not occur.


See section 7




See section 5



Inhaled

The material can cause respiratory irritation in some persons. The body's response to such irritation can cause further lung damage.Inhalation of vapours may cause drowsiness and dizziness. This may be accompanied by sleepiness, reduced alertness, loss of reflexes, lack ofco-ordination, and vertigo.Inhalation of amine vapours may cause irritation of the mucous membrane of the nose and throat, and lung irritation with respiratory distress andcough. Swelling and inflammation of the respiratory tract is seen in serious cases; with headache, nausea, faintness and anxiety.Inhalation hazard is increased at higher temperatures.Inhalation of quantities of liquid mist may be extremely hazardous, even lethal due to spasm, extreme irritation of larynx and bronchi, chemicalpneumonitis and pulmonary oedema.Inhalation of high concentrations of gas/vapour causes lung irritation with coughing and nausea, central nervous depression with headache anddizziness, slowing of reflexes, fatigue and inco-ordination.

Ingestion

The material can produce chemical burns within the oral cavity and gastrointestinal tract following ingestion.Ingestion of amine epoxy-curing agents (hardeners) may cause severe abdominal pain, nausea, vomiting or diarrhoea. The vomitus may containblood and mucous.Swallowing of the liquid may cause aspiration into the lungs with the risk of chemical pneumonitis; serious consequences may result.(ICSC13733)The material has NOT been classified by EC Directives or other classification systems as 'harmful by ingestion'. This is because of the lack ofcorroborating animal or human evidence.Accidental ingestion of the material may be damaging to the health of the individual.

Skin Contact

The material can produce chemical burns following direct contact with the skin.Amine epoxy-curing agents (hardeners) may produce primary skin irritation and sensitisation dermatitis in predisposed individuals. Cutaneousreactions include erythema, intolerable itching and severe facial swelling.Open cuts, abraded or irritated skin should not be exposed to this materialEntry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects. Examine the skinprior to the use of the material and ensure that any external damage is suitably protected.#511ipaSkin contact with the material may be harmful; systemic effects may result following absorption.

EyeThe material can produce chemical burns to the eye following direct contact. Vapours or mists may be extremely irritating.If applied to the eyes, this material causes severe eye damage.





Continued...

Vapours of volatile amines irritate the eyes, causing excessive secretion of tears, inflammation of the conjunctiva and slight swelling of thecornea, resulting in 'halos' around lights. This effect is temporary, lasting only for a few hours. However this condition can reduce the efficiency ofundertaking skilled tasks, such as driving a car. Direct eye contact with liquid volatile amines may produce eye damage, permanent for the lighterspecies.The liquid produces a high level of eye discomfort and is capable of causing pain and severe conjunctivitis. Corneal injury may develop, withpossible permanent impairment of vision, if not promptly and adequately treated.

Chronic

Repeated or prolonged exposure to corrosives may result in the erosion of teeth, inflammatory and ulcerative changes in the mouth and necrosis(rarely) of the jaw. Bronchial irritation, with cough, and frequent attacks of bronchial pneumonia may ensue.Long-term exposure to respiratory irritants may result in airways disease, involving difficulty breathing and related whole-body problems.There has been concern that this material can cause cancer or mutations, but there is not enough data to make an assessment.Skin contact with the material is more likely to cause a sensitisation reaction in some persons compared to the general population.Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. This material can cause serious damage if one is exposed to it for long periods. It can be assumed that it contains a substance which canproduce severe defects.Ample evidence exists from experimentation that reduced human fertility is directly caused by exposure to the material.Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupational exposure.

Carbozinc 858 3K Part BTOXICITY IRRITATION


isopropanol

TOXICITY IRRITATION

Dermal (rabbit) LD50: 12792 mg/kg[1] Eye (rabbit): 10 mg - moderate

Inhalation(Mouse) LC50; 27.2 mg/l4h[2] Eye (rabbit): 100 mg - SEVERE

Oral(Rabbit) LD50; 667 mg/kg[2] Eye (rabbit): 100mg/24hr-moderate

Skin (rabbit): 500 mg - mild

xylene

TOXICITY IRRITATION

Dermal (rabbit) LD50: >1700 mg/kg[2] Eye (human): 200 ppm irritant

Inhalation(Rat) LC50; 5922 ppm4h[1] Eye (rabbit): 5 mg/24h SEVERE

Oral(Mouse) LD50; 1548 mg/kg[2] Eye (rabbit): 87 mg mild

Eye: adverse effect observed (irritating)[1]

Skin (rabbit):500 mg/24h moderate



TOXICITY IRRITATION

Dermal (rabbit) LD50: >1000 mg/kg[1] Skin: adverse effect observed (corrosive)[1]

Oral(Rat) LD50; >50<300 mg/kg[1]

benzyl alcohol

TOXICITY IRRITATION

Dermal (rabbit) LD50: >2000 mg/kg[1] Eye (rabbit): 0.75 mg open SEVERE

Inhalation(Rat) LC50; >4.178 mg/L4h[1] Eye: adverse effect observed (irritating)[1]

Oral(Rabbit) LD50; 1040 mg/kg[2] Skin (man): 16 mg/48h-mild

Skin (rabbit):10 mg/24h open-mild

Skin: no adverse effect observed (not irritating)[1]


TOXICITY IRRITATION

dermal (mouse) LD50: 250 mg/kg[2] Eye (rabbit): 20 mg/24h - mod

Oral(Rat) LD50; >1000 mg/kg[1] Eye: adverse effect observed (irritating)[1]

Skin (rabbit): 0.1 mg/24h - mild

Skin (rabbit): 5 mg/24h - SEVERE

Skin: adverse effect observed (corrosive)[1]


TOXICITY IRRITATION

Dermal (rabbit) LD50: >1000 mg/kg[1] Eye (rabbit): 10uL./24h SEVERE

Inhalation(Mouse) LC50; 0.4 mg/L4h[2] Eye: adverse effect observed (irreversible damage)[1]

Oral(Rat) LD50; 350 mg/kg[1] Eye: adverse effect observed (irritating)[1]

Skin (rabbit): SEVERE Corrosive **






Continued...


TOXICITY IRRITATION

dermal (rat) LD50: >973 mg/kg[1] Eye (rabbit): 0.05 mg/24h - SEVERE

Oral(Rat) LD50; 2169 mg/kg[1] Eye: adverse effect observed (irreversible damage)[1]

Skin (rabbit): 2 mg/24h - SEVERE











Toxicity

Carbozinc 858 3K Part BEndpoint Test Duration (hr) Species Value Source


isopropanol


EC50(ECx) 24h Algae or other aquatic plants 0.011mg/L 4


LC50 96h Fish 4200mg/l 4



xylene



LC50 96h Fish 2.6mg/l 2


NOEC(ECx) 73h Algae or other aquatic plants 0.44mg/l 2






EC10(ECx) 72h Algae or other aquatic plants 1.2mg/l 2

benzyl alcohol





NOEC(ECx) 336h Fish 5.1mg/l 2





LC50 96h Fish >100mg/l 2


NOEC(ECx) 48h Crustacea 18mg/l 1





Continued...



Ingredient Mobility



EC50 72h Algae or other aquatic plants 140-200mg/l 2



EC0(ECx) 48h Crustacea 2.5mg/l 2



EC50(ECx) 72h Algae or other aquatic plants 2.8mg/l 2




Toxic to aquatic organisms. Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean high water mark. Do not contaminate water when cleaning equipment or disposingof equipment wash-waters.Wastes resulting from use of the product must be disposed of on site or at approved waste sites.DO NOT discharge into sewer or waterways.


isopropanol LOW (Half-life = 14 days) LOW (Half-life = 3 days)

xylene HIGH (Half-life = 360 days) LOW (Half-life = 1.83 days)

benzyl alcohol LOW LOW

N-aminoethylpiperazine HIGH HIGH

4,4'-methylenebis(cyclohexylamine) HIGH HIGH


HIGH HIGH


isopropanol LOW (LogKOW = 0.05)

xylene MEDIUM (BCF = 740)

benzyl alcohol LOW (LogKOW = 1.1)

N-aminoethylpiperazine LOW (LogKOW = -1.5677)

4,4'-methylenebis(cyclohexylamine) LOW (LogKOW = 3.2649)


LOW (LogKOW = 0.773)

Mobility in soil

isopropanol HIGH (KOC = 1.06)

benzyl alcohol LOW (KOC = 15.66)

N-aminoethylpiperazine LOW (KOC = 171.7)

4,4'-methylenebis(cyclohexylamine) LOW (KOC = 672.4)


LOW (KOC = 15130)




Containers may still present a chemical hazard/ danger when empty. Return to supplier for reuse/ recycling if possible.

Otherwise:If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used to store the sameproduct, then puncture containers, to prevent re-use, and bury at an authorised landfill. Where possible retain label warnings and SDS and observe all notices pertaining to the product.







Continued...

This material may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for its intended use. If it has beencontaminated, it may be possible to reclaim the product by filtration, distillation or some other means. Shelf life considerations should also beapplied in making decisions of this type. Note that properties of a material may change in use, and recycling or reuse may not always beappropriate.

DO NOT allow wash water from cleaning or process equipment to enter drains. It may be necessary to collect all wash water for treatment before disposal. In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first. Where in doubt contact the responsible authority. Recycle wherever possible. Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable treatment ordisposal facility can be identified. Treat and neutralise at an approved treatment plant. Treatment should involve: Neutralisation with suitable dilute acid followed by: burial in aland-fill specifically licensed to accept chemical and / or pharmaceutical wastes or Incineration in a licensed apparatus Decontaminate empty containers. Observe all label safeguards until containers are cleaned and destroyed.



Packages that have been in direct contact with the hazardous substance must be only disposed if the hazardous substance was appropriately removed and cleaned out from thepackage. The package must be disposed according to the manufacturer's directions taking into account the material it is made of. Packages which hazardous content have beenappropriately treated and removed may be recycled.The hazardous substance must only be disposed if it has been treated by a method that changed the characteristics or composition of the substance and it is no longer hazardous.DO NOT deposit the hazardous substance into or onto a landfill or a sewage facility.Burning the hazardous substance must happen under controlled conditions with no person or place exposed to(1) a blast overpressure of more than 9 kPa; or(2) an unsafe level of heat radiation.The disposed hazardous substance must not come into contact with class 1 or 5 substances.


Labels Required

Marine Pollutant NO

HAZCHEM •3WE

Land transport (UN)

UN number 3469

UN proper shipping namePAINT, FLAMMABLE, CORROSIVE (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINTRELATED MATERIAL, FLAMMABLE, CORROSIVE (including paint thinning or reducing compound)


Subrisk 8

Packing group II


Special precautions for userSpecial provisions 163; 367

Limited quantity 1 L


UN number 3469

UN proper shipping namePaint, flammable, corrosive (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base); Paint relatedmaterial, flammable, corrosive (including paint thinning or reducing compound)


ICAO/IATA Class 3

ICAO / IATA Subrisk 8

ERG Code 3CH

Packing group II



Special provisions A3 A72 A192 A803


Cargo Only Maximum Qty / Pack 5 L


Passenger and Cargo Maximum Qty / Pack 1 L


Passenger and Cargo Limited Maximum Qty / Pack 0.5 L





Continued...

Product name Group

Product name Ship Type



UN number 3469

UN proper shipping namePAINT, FLAMMABLE, CORROSIVE (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or PAINTRELATED MATERIAL, FLAMMABLE, CORROSIVE (including paint thinning or reducing compound)


IMDG Subrisk 8

Packing group II



EMS Number F-E , S-C

Special provisions 163 367

Limited Quantities 1 L


Not Applicable

Transport in bulk in accordance with MARPOL Annex V and the IMSBC Code

isopropanol Not Available



Not Available

benzyl alcohol Not Available

N-aminoethylpiperazine Not Available

4,4'-methylenebis(cyclohexylamine) Not Available


Not Available

Transport in bulk in accordance with the ICG Code

isopropanol Not Available



Not Available

benzyl alcohol Not Available

N-aminoethylpiperazine Not Available

4,4'-methylenebis(cyclohexylamine) Not Available


Not Available




HSR002664 Surface Coatings and Colourants Flammable Corrosive Carcinogenic Group Standard 2020

Please refer to Section 8 of the SDS for any applicable tolerable exposure limit or Section 12 for environmental exposure limit.

isopropanol is found on the following regulatory lists







xylene is found on the following regulatory lists







formaldehyde/ benzenamine, hydrogenated is found on the following regulatory lists


benzyl alcohol is found on the following regulatory lists





Continued...

Hazard Class Quantity (Closed Containers)Quantity (OpenContainers)

Quantity (ComplianceCertificate)

Quantity (Compliance Certificate -Farms >4 ha)


Hazard Class Gas (aggregate water capacity in mL) Liquid (L) Solid (kg) Maximum quantity per package for each classification






N-aminoethylpiperazine is found on the following regulatory lists





4,4'-methylenebis(cyclohexylamine) is found on the following regulatory lists





2,4,6-tris[(dimethylamino)methyl]phenol is found on the following regulatory lists







3.1B 100 L in containers more than 5 L 50 L

3.1B250 L in containers up to andincluding 5 L

50 L

8.2B 250 kg or 250 L 3500 kg or 3500 L

Certified Handler


Not Applicable Not Applicable


Maximum quantities of certain hazardous substances permitted on passenger service vehicles

Subject to Regulation 13.14 of the Health and Safety at Work (Hazardous Substances) Regulations 2017.

6.5A or 6.5B 120 1 3

8.2B 120 1 3

3.1B 1 L


Not Applicable


Australia - AIIC / AustraliaNon-Industrial Use

Yes

Canada - DSL Yes

Canada - NDSLNo (isopropanol; xylene; formaldehyde/ benzenamine, hydrogenated; benzyl alcohol; N-aminoethylpiperazine;4,4'-methylenebis(cyclohexylamine); 2,4,6-tris[(dimethylamino)methyl]phenol)

China - IECSC Yes

Europe - EINEC / ELINCS / NLP No (formaldehyde/ benzenamine, hydrogenated)

Japan - ENCS No (formaldehyde/ benzenamine, hydrogenated)

Korea - KECI Yes



USA - TSCA Yes

Taiwan - TCSI Yes

Mexico - INSQ No (formaldehyde/ benzenamine, hydrogenated; 4,4'-methylenebis(cyclohexylamine))

Vietnam - NCI Yes

Russia - FBEPH No (formaldehyde/ benzenamine, hydrogenated)







Continued...

VersionDate ofUpdate

Sections Updated



SDS Version Summary

0.2.2.1 29/04/2021 Regulation Change




0.2.2.4 08/06/2021Acute Health (eye), Acute Health (inhaled), Acute Health (skin), Chronic Health, Environmental, Exposure Standard,Ingredients

Other information



PC－TWA: Permissible Concentration-Time Weighted AveragePC－STEL: Permissible Concentration-Short Term Exposure LimitIARC: International Agency for Research on CancerACGIH: American Conference of Governmental Industrial HygienistsSTEL: Short Term Exposure LimitTEEL: Temporary Emergency Exposure Limit。IDLH: Immediately Dangerous to Life or Health ConcentrationsES: Exposure StandardOSF: Odour Safety FactorNOAEL :No Observed Adverse Effect LevelLOAEL: Lowest Observed Adverse Effect LevelTLV: Threshold Limit ValueLOD: Limit Of DetectionOTV: Odour Threshold ValueBCF: BioConcentration FactorsBEI: Biological Exposure IndexAIIC: Australian Inventory of Industrial ChemicalsDSL: Domestic Substances ListNDSL: Non-Domestic Substances ListIECSC: Inventory of Existing Chemical Substance in ChinaEINECS: European INventory of Existing Commercial chemical SubstancesELINCS: European List of Notified Chemical SubstancesNLP: No-Longer PolymersENCS: Existing and New Chemical Substances InventoryKECI: Korea Existing Chemicals InventoryNZIoC: New Zealand Inventory of ChemicalsPICCS: Philippine Inventory of Chemicals and Chemical SubstancesTSCA: Toxic Substances Control ActTCSI: Taiwan Chemical Substance InventoryINSQ: Inventario Nacional de Sustancias QuímicasNCI: National Chemical InventoryFBEPH: Russian Register of Potentially Hazardous Chemical and Biological Substances






end of SDS

Zinc FillerAltex Coatings Ltd Chemwatch Hazard Alert Code: 3

Version No: 5.9Safety Data Sheet according to HSNO Regulations


S.GHS.NZL.EN


Product Identifier

Product name Zinc Filler


Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.



Relevant identified uses Part of a multi-component industrial coating




Telephone +64 7 541 1221

Fax +64 7 541 1310

Website





0800 764766 +61 2 9186 1132







Classification [1] Acute Aquatic Hazard Category 1, Chronic Aquatic Hazard Category 1



9.1A

Label elements

Hazard pictogram(s)

Signal word Warning

Hazard statement(s)

H410 Very toxic to aquatic life with long lasting effects.


P273 Avoid release to the environment.


P391 Collect spillage.



Page 1 continued...

CAS No %[weight] Name

Not Applicable




Substances


Mixtures

7440-66-6 98

1314-13-2 1.5

7631-86-9 0.1



Eye Contact

If this product comes in contact with eyes: Wash out immediately with water. If irritation continues, seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. DO NOT attempt to remove particles attached to or embedded in eye .Lay victim down, on stretcher if available and pad BOTH eyes, make sure dressing does not press on the injured eye by placing thick padsunder dressing, above and below the eye. Seek urgent medical assistance, or transport to hospital.

Skin Contact

If skin contact occurs:Immediately remove all contaminated clothing, including footwear. Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation.

InhalationIf fumes, aerosols or combustion products are inhaled remove from contaminated area. Other measures are usually unnecessary.

IngestionImmediately give a glass of water. First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.


Absorption of zinc compounds occurs in the small intestine. The metal is heavily protein bound. Elimination results primarily from faecal excretion. The usual measures for decontamination (Ipecac Syrup, lavage, charcoal or cathartics) may be administered, although patients usually have sufficient vomiting not to requirethem. CaNa2EDTA has been used successfully to normalise zinc levels and is the agent of choice.

[Ellenhorn and Barceloux: Medical Toxicology]


Extinguishing media

Metal dust fires need to be smothered with sand, inert dry powders.DO NOT USE WATER, CO2 or FOAM.

Use DRY sand, graphite powder, dry sodium chloride based extinguishers, G-1 or Met L-X to smother fire. Confining or smothering material is preferable to applying water as chemical reaction may produce flammable and explosive hydrogen gas. Chemical reaction with CO2 may produce flammable and explosive methane. If impossible to extinguish, withdraw, protect surroundings and allow fire to burn itself out. DO NOT use halogenated fire extinguishing agents.


Fire IncompatibilityReacts with acids producing flammable / explosive hydrogen (H2) gas Segregate from alcohol, water.


Fire Fighting

Alert Fire Brigade and tell them location and nature of hazard. May be violently or explosively reactive. Wear full protective clothing plus breathing apparatus. Prevent, by any means available, spillage from entering drains or water course. Consider evacuation (or protect in place) DO NOT use water on fires.

CAUTION: If only water available, use flooding quantities of water or withdraw personnel.DO NOT allow water to enter containers. DO NOT approach containers suspected to be hot. Cool fire exposed containers with flooding quantities of water from a protected location until well after fire is out. If safe to do so, remove undamaged containers from path of fire.

zinc powder

zinc oxide

silica amorphous

Version No: 5.9 Page 2 of 11

Zinc Filler



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If fire gets out of control withdraw personnel and warn against entry. Equipment should be thoroughly decontaminated after use. Fight fire from a protected position or use unmanned hose holders or monitor nozzles. Withdraw immediately in case of rising sound from venting safety devices or discolouration of tanks. ALWAYS stay away from tank ends.


Zinc dust clouds are potentially explosive. Electric sparks may ignite the dust cloud even in atmospheres containing low oxygen (10%). In air the dust may be ignited in contact with hot surfaces or flame where temperatures exceed 600 deg C. DO NOT disturb burning dust. Explosion may result if dust is stirred into a cloud, by providing oxygen to a large surface of hot metal. DO NOT use water or foam as generation of explosive hydrogen may result.

With the exception of the metals that burn in contact with air or water (for example, sodium), masses of combustible metals do not representunusual fire risks because they have the ability to conduct heat away from hot spots so efficiently that the heat of combustion cannot bemaintained - this means that it will require a lot of heat to ignite a mass of combustible metal. Generally, metal fire risks exist when sawdust,machine shavings and other metal 'fines' are present. Metal powders, while generally regarded as non-combustible:

May burn when metal is finely divided and energy input is high. May react explosively with water. May be ignited by friction, heat, sparks or flame. May REIGNITE after fire is extinguished. Will burn with intense heat.

Note:Metal dust fires are slow moving but intense and difficult to extinguish. Containers may explode on heating. Dusts or fumes may form explosive mixtures with air. Gases generated in fire may be poisonous, corrosive or irritating. Hot or burning metals may react violently upon contact with other materials, such as oxidising agents and extinguishing agents used on firesinvolving ordinary combustibles or flammable liquids. Temperatures produced by burning metals can be higher than temperatures generated by burning flammable liquids Some metals can continue to burn in carbon dioxide, nitrogen, water, or steam atmospheres in which ordinary combustibles or flammableliquids would be incapable of burning.



See section 8


See section 12


Minor Spills

Environmental hazard - contain spillage. Material from spill may be contaminated with water resulting in generation of gas which subsequently may pressure closed containers. Hold spill material in vented containers only and plan for prompt disposal Eliminate all ignition sources. Cover with DRY earth, sand or other non-combustible material. Then cover with plastic sheet to minimise spreading and to prevent exposure to rain or other sources of water. Use clean, non-sparking tools to collect absorbed material and place into loosely-covered metal or plastic containers ready for disposal. Wear gloves and safety glasses as appropriate.

Major Spills

Environmental hazard - contain spillage. · Do not use compressed air to remove metal dusts from floors, beams or equipment· Vacuum cleaners, of flame-proof design, should be used to minimise dust accumulation.· Use non-sparking handling equipment, tools and natural bristle brushes.· Provide grounding and bonding where necessary to prevent accumulation of static charges during metal dust handling and transferoperations· Cover and reseal partially empty containers.· Do not allow chips, fines or dusts to contact water, particularly in enclosed areas.

Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. Eliminate all ignition sources (no smoking, flares, sparks or flames) Stop leak if safe to do so; prevent entry into waterways, drains or confined spaces. May be violently or explosively reactive. DO NOT walk through spilled material. Wear full protective clothing plus breathing apparatus. DO NOT touch damaged containers or spilled material unless wearing appropriate protective clothing. Water spray may be used to knock down vapours or divert vapour clouds; DO NOT allow water to enter container or come into contact withthe material. Cover with DRY earth, sand, vermiculite or other non-combustible material. Then cover with plastic sheet to minimise spreading and to prevent exposure to rain or other sources of water. Use clean, non-sparking tools to collect absorbed material and place into loosely-covered metal or plastic containers ready for disposal. Alternately, the spill may be contained using DRY earth, sand, or vermiculite and then covered with a high boiling point mineral oil. Recover the liquid using non-sparking appliances and place in labelled, sealable container. Wash spill area with detergent and water and dike for later disposal. After clean up operations, decontaminate and launder all protective clothing and equipment before storing and re-using. If contamination of drains or waterways occurs, advise emergency services.





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+ + + + + + +



Safe handling

Avoid all personal contact, including inhalation. Wear protective clothing when risk of overexposure occurs. Use in a well-ventilated area. Avoid contact with moisture. Avoid smoking, naked lights or ignition sources. Avoid contact with incompatible materials. When handling, DO NOT eat, drink or smoke. Keep containers securely sealed when not in use. Avoid physical damage to containers. Always wash hands with soap and water after handling. Work clothes should be laundered separately and before re-use Use good occupational work practice. Observe manufacturer's storage and handling recommendations contained within this SDS.Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions are maintained.

Other information

KEEP DRY! Packages must be protected from water ingress.FOR MINOR QUANTITIES:

Store in an indoor fireproof cabinet or in a room of noncombustible construction and provide adequate portable fire-extinguishers in or near the storage area.

FOR PACKAGE STORAGE:Store in original containers in approved flame-proof area. No smoking, naked lights, heat or ignition sources. DO NOT store in pits, depressions, basements or areas where vapours may be trapped.Keep containers securely sealed. Store away from incompatible materials in a cool, dry well ventilated area. Protect containers against physical damage and check regularly for leaks. Protect containers from exposure to weather and from direct sunlight unless: (a) the packages are of metal or plastic construction; (b) thepackages are securely closed are not opened for any purpose while in the area where they are stored; (c) adequate precautions are taken toensure that rain water, which might become contaminated by the dangerous goods, is collected and disposed of safely. Ensure proper stock-control measures are maintained to prevent prolonged storage of dangerous goods. Automatic fire-sprinklers MUST NOT be installed in room or space. The room or space must be located at least five metres from the boundaries of the premises and from other buildings unless separated by awall with a fire resistance of at least four hours. Observe manufacturer's storage and handling recommendations contained within this SDS.


Suitable containerCARE: Packing of high density product in light weight metal or plastic packages may result in container collapse with product release Heavy gauge metal packages / Heavy gauge metal drums Storage containers must be hermetically sealed; the product must be stored under an inert, dry gas.

Storage incompatibility

Many metals may incandesce, react violently, ignite or react explosively upon addition of concentrated nitric acid. Reacts slowly with water. CAUTION contamination with moisture will liberate explosive hydrogen gas, causing pressure build up in sealed containers.Reacts violently with caustic soda, other alkalies - generating heat, highly flammable hydrogen gas. If alkali is dry, heat generated may ignite hydrogen - if alkali is in solution may cause violent foaming Segregate from alcohol, water. Finely divided metal powders develop pyrophoricity when a critical specific surface area is exceeded; this is ascribed to high heat of oxideformation on exposure to air.Safe handling is possible in relatively low concentrations of oxygen in an inert gas.Several pyrophoric metals, stored in glass bottles have ignited when the container is broken on impact. Storage of these materials moist andin metal containers is recommended.The reaction residues from various metal syntheses (involving vacuum evaporation and co-deposition with a ligand) are often pyrophoric.

Factors influencing the pyrophoricity of metals are particle size, presence of moisture, nature of the surface of the particle, heat of formation ofthe oxide, or nitride, mass, hydrogen content, stress, purity and presence of oxide, among others.

Many metals in elemental form react exothermically with compounds having active hydrogen atoms (such as acids and water) to formflammable hydrogen gas and caustic products. Elemental metals may react with azo/diazo compounds to form explosive products. Some elemental metals form explosive products with halogenated hydrocarbons.


Control parameters


INGREDIENT DATA


zinc powder Particulates not otherwise classified respirable dust 3 mg/m3 Not Available Not Available Not Available


zinc powder Particulates not otherwise classified 10 mg/m3 Not Available Not Available Not Available


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zinc oxide Zinc oxide fume respirable dust 3 mg/m3 10 mg/m3 Not Available Not Available


zinc oxide Zinc oxide Dust respirable dust 10 mg/m3 Not Available Not Available Not Available


silica amorphous Silica fused respirable dust 0.2 mg/m3 Not Available Not Available Not Available


silica amorphous Silica-Amorphous: Diatomaceous earth (not calcined) 10 mg/m3 Not Available Not Available Not Available


silica amorphous Silica gel (Silica-Amorphous) 10 mg/m3 Not Available Not Available Not Available


silica amorphous Silica-Amorphous: Silica gel 10 mg/m3 Not Available Not Available Not Available


silica amorphous Silica-Amorphous: Precipitated silica 10 mg/m3 Not Available Not Available Not Available


silica amorphous Silica fume respirable dust 2 mg/m3 Not Available Not Available Not Available


silica amorphous Precipitated silica (Silica-Amorphous) 10 mg/m3 Not Available Not Available Not Available

Exposure controls


Metal dusts must be collected at the source of generation as they are potentially explosive.Avoid ignition sources. Good housekeeping practices must be maintained. Dust accumulation on the floor, ledges and beams can present a risk of ignition, flame propagation and secondary explosions. Do not use compressed air to remove settled materials from floors, beams or equipment Vacuum cleaners, of flame-proof design, should be used to minimise dust accumulation. Use non-sparking handling equipment, tools and natural bristle brushes. Cover and reseal partially empty containers. Provide grounding andbonding where necessary to prevent accumulation of static charges during metal dust handling and transfer operations. Do not allow chips, fines or dusts to contact water, particularly in enclosed areas. Metal spraying and blasting should, where possible, be conducted in separate rooms. This minimises the risk of supplying oxygen, in theform of metal oxides, to potentially reactive finely divided metals such as aluminium, zinc, magnesium or titanium. Work-shops designed for metal spraying should possess smooth walls and a minimum of obstructions, such as ledges, on which dustaccumulation is possible. Wet scrubbers are preferable to dry dust collectors. Bag or filter-type collectors should be sited outside the workrooms and be fitted with explosion relief doors. Cyclones should be protected against entry of moisture as reactive metal dusts are capable of spontaneous combustion in humid or partiallywetted states. Local exhaust systems must be designed to provide a minimum capture velocity at the fume source, away from the worker, of 0.5 metre/sec. Local ventilation and vacuum systems must be designed to handle explosive dusts. Dry vacuum and electrostatic precipitators must not beused, unless specifically approved for use with flammable/ explosive dusts.

Air contaminants generated in the workplace possess varying 'escape' velocities which, in turn, determine the 'capture velocities' of freshcirculating air required to effectively remove the contaminant.


welding, brazing fumes (released at relatively low velocity into moderately still air) 0.5-1.0 m/s (100-200 f/min.)







Simple theory shows that air velocity falls rapidly with distance away from the opening of a simple extraction pipe. Velocity generally decreaseswith the square of distance from the extraction point (in simple cases). Therefore the air speed at the extraction point should be adjusted,accordingly, after reference to distance from the contaminating source. The air velocity at the extraction fan, for example, should be a minimumof 1-2.5 m/s (200-500 f/min.) for extraction of gases discharged 2 meters distant from the extraction point. Other mechanical considerations,producing performance deficits within the extraction apparatus, make it essential that theoretical air velocities are multiplied by factors of 10 ormore when extraction systems are installed or used.

Personal protection


Safety glasses with side shields.Chemical goggles.Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describingthe wearing of lenses or restrictions on use, should be created for each workplace or task. This should include a review of lens absorptionand adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained intheir removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately andremove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed ina clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 ornational equivalent]


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Wear chemical protective gloves, e.g. PVC. Wear safety footwear or safety gumboots, e.g. Rubber

The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from manufacturer tomanufacturer. Where the chemical is a preparation of several substances, the resistance of the glove material can not be calculated in advanceand has therefore to be checked prior to the application.The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and has to be observed whenmaking a final choice.Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, hands should bewashed and dried thoroughly. Application of a non-perfumed moisturiser is recommended.Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include:· frequency and duration of contact,· chemical resistance of glove material,· glove thickness and· dexteritySelect gloves tested to a relevant standard (e.g. Europe EN 374, US F739, AS/NZS 2161.1 or national equivalent).· When prolonged or frequently repeated contact may occur, a glove with a protection class of 5 or higher (breakthrough time greater than240 minutes according to EN 374, AS/NZS 2161.10.1 or national equivalent) is recommended.· When only brief contact is expected, a glove with a protection class of 3 or higher (breakthrough time greater than 60 minutes according toEN 374, AS/NZS 2161.10.1 or national equivalent) is recommended.· Some glove polymer types are less affected by movement and this should be taken into account when considering gloves for long-termuse.· Contaminated gloves should be replaced.As defined in ASTM F-739-96 in any application, gloves are rated as:· Excellent when breakthrough time > 480 min· Good when breakthrough time > 20 min· Fair when breakthrough time < 20 min· Poor when glove material degradesFor general applications, gloves with a thickness typically greater than 0.35 mm, are recommended.It should be emphasised that glove thickness is not necessarily a good predictor of glove resistance to a specific chemical, as the permeationefficiency of the glove will be dependent on the exact composition of the glove material. Therefore, glove selection should also be based onconsideration of the task requirements and knowledge of breakthrough times.Glove thickness may also vary depending on the glove manufacturer, the glove type and the glove model. Therefore, the manufacturers’technical data should always be taken into account to ensure selection of the most appropriate glove for the task.Note: Depending on the activity being conducted, gloves of varying thickness may be required for specific tasks. For example:· Thinner gloves (down to 0.1 mm or less) may be required where a high degree of manual dexterity is needed. However, these gloves areonly likely to give short duration protection and would normally be just for single use applications, then disposed of.· Thicker gloves (up to 3 mm or more) may be required where there is a mechanical (as well as a chemical) risk i.e. where there is abrasionor puncture potentialGloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumedmoisturiser is recommended.

Protective gloves eg. Leather gloves or gloves with Leather facing


Other protection

Overalls. Eyewash unit. Barrier cream. Skin cleansing cream. Some plastic personal protective equipment (PPE) (e.g. gloves, aprons, overshoes) are not recommended as they may produce staticelectricity.For large scale or continuous use wear tight-weave non-static clothing (no metallic fasteners, cuffs or pockets).Non sparking safety or conductive footwear should be considered. Conductive footwear describes a boot or shoe with a sole made from aconductive compound chemically bound to the bottom components, for permanent control to electrically ground the foot an shall dissipatestatic electricity from the body to reduce the possibility of ignition of volatile compounds. Electrical resistance must range between 0 to500,000 ohms. Conductive shoes should be stored in lockers close to the room in which they are worn. Personnel who have been issuedconductive footwear should not wear them from their place of work to their homes and return.


Particulate. (AS/NZS 1716 & 1715, EN 143:2000 & 149:001, ANSI Z88 or national equivalent)

Required Minimum Protection Factor Half-Face Respirator Full-Face Respirator Powered Air Respirator

up to 10 x ESP1Air-line*

--

PAPR-P1-

up to 50 x ES Air-line** P2 PAPR-P2up to 100 x ES - P3 -

Air-line* -100+ x ES - Air-line** PAPR-P3

* - Negative pressure demand ** - Continuous flowA(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfurdioxide(SO2), G = Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB = Methyl bromide, AX = Low boiling point organiccompounds(below 65 degC)

Respirators may be necessary when engineering and administrative controls do not adequately prevent exposures.The decision to use respiratory protection should be based on professional judgment that takes into account toxicity information, exposure measurement data, andfrequency and likelihood of the worker's exposure - ensure users are not subject to high thermal loads which may result in heat stress or distress due to personalprotective equipment (powered, positive flow, full face apparatus may be an option).Published occupational exposure limits, where they exist, will assist in determining the adequacy of the selected respiratory protection. These may be governmentmandated or vendor recommended.Certified respirators will be useful for protecting workers from inhalation of particulates when properly selected and fit tested as part of a complete respiratoryprotection program.Use approved positive flow mask if significant quantities of dust becomes airborne. Try to avoid creating dust conditions.


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Appearance grey powder

Physical state Divided Solid|Dust Relative density (Water = 1) 7.6



Odour threshold Not Available Auto-ignition temperature (°C) Not Available



Not Available Viscosity (cSt) Not Available


Not Available Molecular weight (g/mol) Not Available

Flash point (°C) Not Applicable Taste Not Available

Evaporation rate Not Available Explosive properties Not Available

Flammability Not Applicable Oxidising properties Not Available

Upper Explosive Limit (%) Not AvailableSurface Tension (dyn/cm or

mN/m)Not Applicable

Lower Explosive Limit (%) Not Available Volatile Component (%vol) Negligible

Vapour pressure (kPa) Not Available Gas group Not Available

Solubility in water Immiscible pH as a solution (1%) Not Available

Vapour density (Air = 1) Not Available VOC g/L 0.00



Chemical stability

· Unstable in the presence of incompatible materialsMay heat spontaneously Identify and remove sources of ignition and heating. Incompatible material, especially oxidisers, and/or other sources of oxygen may produce unstable product(s). Avoid sources of water contamination (e.g. rain water, moisture, high humidity). Avoid contact with oxygenated solvents/ reagents such as alcohols.


See section 7




See section 5



Inhaled

The material is not thought to produce adverse health effects or irritation of the respiratory tract (as classified by EC Directives using animalmodels). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable control measures be used in anoccupational setting.Persons with impaired respiratory function, airway diseases and conditions such as emphysema or chronic bronchitis, may incur further disabilityif excessive concentrations of particulate are inhaled.If prior damage to the circulatory or nervous systems has occurred or if kidney damage has been sustained, proper screenings should beconducted on individuals who may be exposed to further risk if handling and use of the material resultin excessive exposures.

Not normally a hazard due to non-volatile nature of productInhalation of dusts, generated by the material during the course of normal handling, may be damaging to the health of the individual.

IngestionThe material has NOT been classified by EC Directives or other classification systems as 'harmful by ingestion'. This is because of the lack ofcorroborating animal or human evidence.

Skin Contact

Skin contact is not thought to have harmful health effects (as classified under EC Directives); the material may still produce health damagefollowing entry through wounds, lesions or abrasions.Open cuts, abraded or irritated skin should not be exposed to this materialEntry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects. Examine the skinprior to the use of the material and ensure that any external damage is suitably protected.Skin contact with the material may be harmful; systemic effects may result following absorption.There is some evidence to suggest that the material may cause mild but significant inflammation of the skin either following direct contact or aftera delay of some time. Repeated exposure can cause contact dermatitis which is characterised by redness, swelling and blistering.

EyeAlthough the material is not thought to be an irritant (as classified by EC Directives), direct contact with the eye may cause transient discomfortcharacterised by tearing or conjunctival redness (as with windburn). Slight abrasive damage may also result.Contact with the eye by metal dusts may cause mechanical abrasion or foreign body penetration of the eyeball.


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ChronicRepeated or long-term occupational exposure is likely to produce cumulative health effects involving organs or biochemical systems.Metallic dusts generated by the industrial process give rise to a number of potential health problems. The larger particles, above 5 micron, arenose and throat irritants.

Zinc FillerTOXICITY IRRITATION


zinc powder

TOXICITY IRRITATION

Oral (rat) LD50: >2000 mg/kg[1] Eye: no adverse effect observed (not irritating)[1]


zinc oxide

TOXICITY IRRITATION

Oral (mouse) LD50: 7950 mg/kg[2] Eye (rabbit) : 500 mg/24 h - mild

Oral (rat) LD50: >5000 mg/kg[1] Eye: no adverse effect observed (not irritating)[1]

Oral (rat) LD50: >8437 mg/kg[2] Skin (rabbit) : 500 mg/24 h- mild


silica amorphous

TOXICITY IRRITATION

Dermal (rabbit) LD50: >5000 mg/kg[2] Eye (rabbit): non-irritating *

Inhalation (rat) LC50: >0.139 mg/l/14h**[Grace][2] Eye: no adverse effect observed (not irritating)[1]

Oral (rat) LD50: >15000 mg/kg[2] Skin (rabbit): non-irritating *

Oral (rat) LD50: >5000 mg/kg[1] Skin: no adverse effect observed (not irritating)[1]

Oral (rat) LD50: 3160 mg/kg[2]










Toxicity

Zinc FillerEndpoint Test Duration (hr) Species Value Source


zinc powder


LC50 96 Fish 0.001-0.58mg/L 2

EC50 48 Crustacea 0.001-0.833mg/L 2

NOEC 384 Algae or other aquatic plants 0.001-0.071mg/L 2

zinc oxide


LC50 96 Fish 0.001-0.65mg/L 2

EC50 48 Crustacea 0.001-0.014mg/L 2

EC50 72 Algae or other aquatic plants 0.037mg/L 2

NOEC 72 Algae or other aquatic plants 0.001mg/L 2

silica amorphous


LC50 96 Fish 1-33.016mg/L 2

EC50 72 Algae or other aquatic plants 440mg/L 1

NOEC 720 Crustacea 34.223mg/L 2


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Ingredient Mobility


Very toxic to aquatic organisms. Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean high water mark. Do not contaminate water when cleaning equipment or disposingof equipment wash-waters.Wastes resulting from use of the product must be disposed of on site or at approved waste sites.For Metal:Atmospheric Fate - Metal-containing inorganic substances generally have negligible vapour pressure and are not expected to partition to air.Environmental Fate: Environmental processes, such as oxidation, the presence of acids or bases and microbiological processes, may transform insoluble metals to more soluble ionicforms. Environmental processes may enhance bioavailability and may also be important in changing solubilities.Aquatic/Terrestrial Fate: When released to dry soil, most metals will exhibit limited mobility and remain in the upper layer; some will leach locally into ground water and/ or surfacewater ecosystems when soaked by rain or melt ice. A metal ion is considered infinitely persistent because it cannot degrade further. Once released to surface waters and moist soilstheir fate depends on solubility and dissociation in water. A significant proportion of dissolved/ sorbed metals will end up in sediments through the settling of suspended particles. Theremaining metal ions can then be taken up by aquatic organisms. Ionic species may bind to dissolved ligands or sorb to solid particles in water.Ecotoxicity: Even though many metals show few toxic effects at physiological pH levels, transformation may introduce new or magnified effects.DO NOT discharge into sewer or waterways.


silica amorphous LOW LOW


zinc oxide LOW (BCF = 217)

silica amorphous LOW (LogKOW = 0.5294)

Mobility in soil

silica amorphous LOW (KOC = 23.74)






This material may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for its intended use. Shelf lifeconsiderations should also be applied in making decisions of this type. Note that properties of a material may change in use, and recycling orreuse may not always be appropriate. In most instances the supplier of the material should be consulted.

DO NOT allow wash water from cleaning or process equipment to enter drains. It may be necessary to collect all wash water for treatment before disposal. In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first. Where in doubt contact the responsible authority. Recycle wherever possible. Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable treatment ordisposal facility can be identified. Dispose of by: burial in a land-fill specifically licensed to accept chemical and / or pharmaceutical wastes or Incineration in a licensedapparatus (after admixture with suitable combustible material) Decontaminate empty containers. Observe all label safeguards until containers are cleaned and destroyed.



Packages that have been in direct contact with the hazardous substance must be only disposed if the hazardous substance was appropriately removed and cleaned out from thepackage. The package must be disposed according to the manufacturer's directions taking into account the material it is made of. Packages which hazardous content have beenappropriately treated and removed may be recycled.The hazardous substance must only be disposed if it has been treated by a method that changed the characteristics or composition of the substance and it is no longer hazardous.Do not dispose to the environment any component, which may be biocumulative or not rapidly degradable.Only discharge the substance to the environment if an environmental exposure limit has been set for the substance. Only deposit the hazardous substance into or onto a landfill or sewage facility or incinerator, where the hazardous substance can be handled and treated appropriately.


Labels Required


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Marine Pollutant

HAZCHEM 2Z

Land transport (UN)

UN number 3077

UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.


Subrisk Not Applicable

Packing group III

Environmental hazard Environmentally hazardous

Special precautions for userSpecial provisions 274; 331; 335; 375

Limited quantity 5 kg


UN number 3077

UN proper shipping name Environmentally hazardous substance, solid, n.o.s. *


ICAO/IATA Class 9

ICAO / IATA Subrisk Not Applicable

ERG Code 9L

Packing group III

Environmental hazard Environmentally hazardous


Special provisions A97 A158 A179 A197


Cargo Only Maximum Qty / Pack 400 kg


Passenger and Cargo Maximum Qty / Pack 400 kg


Passenger and Cargo Limited Maximum Qty / Pack 30 kg G


UN number 3077

UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.


IMDG Subrisk Not Applicable

Packing group III

Environmental hazard Marine Pollutant


EMS Number F-A , S-F

Special provisions 274 335 966 967 969

Limited Quantities 5 kg


Not Applicable




HSR002670 Surface Coatings and Colourants (Subsidiary Hazard) Group Standard 2017


Zinc Filler



Continued...

Hazard Class Quantity (Closed Containers) Quantity (Open Containers)



Version Issue Date Sections Updated



Not Applicable Not Applicable Not Applicable

Certified Handler


Not applicable Not applicable



Not Applicable


Australia - AIIC Yes

Australia Non-Industrial Use No (zinc powder; zinc oxide; silica amorphous)

Canada - DSL Yes

Canada - NDSL No (zinc powder)

China - IECSC Yes

Europe - EINEC / ELINCS / NLP Yes

Japan - ENCS No (zinc powder)

Korea - KECI Yes



USA - TSCA Yes

Taiwan - TCSI Yes

Mexico - INSQ Yes

Vietnam - NCI Yes

Russia - ARIPS Yes





SDS Version Summary

4.9.1.1.1 15/09/2020 Classification, Environmental, Ingredients

Other information



PC－TWA: Permissible Concentration-Time Weighted AveragePC－STEL: Permissible Concentration-Short Term Exposure LimitIARC: International Agency for Research on CancerACGIH: American Conference of Governmental Industrial HygienistsSTEL: Short Term Exposure LimitTEEL: Temporary Emergency Exposure Limit。IDLH: Immediately Dangerous to Life or Health ConcentrationsOSF: Odour Safety FactorNOAEL :No Observed Adverse Effect LevelLOAEL: Lowest Observed Adverse Effect LevelTLV: Threshold Limit ValueLOD: Limit Of DetectionOTV: Odour Threshold ValueBCF: BioConcentration FactorsBEI: Biological Exposure Index



Zinc Filler



end of SDS

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