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www.caymanchem.com · (800) 364-9897 RESIDUAL SOLVENTS Cannabis Testing Standards As the Cannabis industry grows, various stakeholders are working towards standardization within the industry. To identify and quantitatively measure the components found in a Cannabis product, Cayman offers analytical reference standards and ISO 17034-produced Certified Reference Materials. Along with single-component standards for potency testing, terpene profiling, and analysis of contaminants, we specialize in the production of pre-made, multi-component mixtures that are designed to improve quantitation accuracy and streamline workflows. PHYTOCANNABINOIDS TERPENES & IMPROVE ACCURACY REDUCE CONSUMABLE COST, VARIABILITY, AND TIME! PESTICIDES & MYCOTOXINS

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Page 1: Cayman Chemical - Cannabis Testing Standards · 2020-04-06 · · (800) 364-9897 RESIDUAL SOLVENTS Cannabis Testing Standards As the Cannabis industry grows, various stakeholders

www.caymanchem.com · (800) 364-9897

RESIDUAL SOLVENTS

Cannabis Testing StandardsAs the Cannabis industry grows, various stakeholders are working towards standardization within the industry. To identify and quantitatively measure the components found in a Cannabis product, Cayman offers analytical reference standards and ISO 17034-produced Certified Reference Materials. Along with single-component standards for potency testing, terpene profiling, and analysis of contaminants, we specialize in the production of pre-made, multi-component mixtures that are designed to improve quantitation accuracy and streamline workflows.

PHYTOCANNABINOIDS

TERPENES

&

IMPROVEACCURACY

REDUCE CONSUMABLE COST, VARIABILITY,

AND TIME!

PESTICIDES & MYCOTOXINS

Page 2: Cayman Chemical - Cannabis Testing Standards · 2020-04-06 · · (800) 364-9897 RESIDUAL SOLVENTS Cannabis Testing Standards As the Cannabis industry grows, various stakeholders

www.caymanchem.com · (800) 364-9897

CoA-S OH

O O3 x

OH

OHCannabigerovarin (CBGV) (E isomer)

(9002437)Cannabinerovarin (CBNRV) (Z isomer)

OH

OH

HO

O

Cannabigerovarinic Acid (CBGVA) (E isomer)(25469)

Cannabinerovarinic Acid (CBNRVA) (Z isomer)Tetrahydrocannabivarinic Acid A (Δ9-THCVA-A)

O

O

HO

OH

exo-Tetrahydrocannabivarin (exo-THCV)O

OHΔ8-Tetrahydrocannabivarin (Δ8-THCV)

O

OH

Δ9-Tetrahydrocannabivarin (THCV) (Δ9-THCV)(18091)

O

OH

O

OH HH

H

Cannabicyclovarin (CBLV)

O

OCannabicitravarin (CBTV) (citran)

O

OH

Cannabichromevarin (CBCV)(21974)

Cannabichromevarinic Acid (CBCVA)

O

OH

HO

O

OH

OH

Cannabidivarin (CBDV)(20165 | 9001574)

OH

OH

Cannabinodivarin (CBNDV)

Cannabielsovarin (CBEV)

O

OH

OH

O

OHCannabifuravarin (CBFV)

Cannabivarin (CBV)(21664)

O

OH

Cannabivarinic Acid (CBVA)O

OHO

HO

S-CoA

O

Butanoyl-CoA

Varinolic Acid

OH

OH

OHO

polyketidesynthase

geranyl-transferase

geranyl-transferase

geranyl-transferase

Cannabitrivarinol (CBTV) (triol)O

OH

OHHO

Cannabiripsovarinol (CBRV)O

OHHO

HO

HO

O

OH

OH

Cannabidivarinic Acid (CBDVA)

OH

HO

OH

O

Cannabigerolic Acid (CBGA) (E isomer)(20019 | 9001572)

Cannabinerolic Acid (CBNRA) (Z isomer)

OH

HOCannabigerol (CBG) (E isomer)

(20164 | 15293)Cannabinerol (CBNR) (Z isomer)

HO

OH

Cannabinodiol (CBND)(9002479)

HO

OH

Cannabidiol (CBD)(ISO60156 | 90080)

CBCAsynthase

THCAsynthase

CBDAsynthase

Δ9-Tetrahydrocannabinol (THC) (Δ9-THC)(ISO60157 | 12068)

O

OH

Cannabielsoin (CBE)

O

HO

HO

exo-Tetrahydrocannabinol (exo-THC)O

OH O

OH

Cannabichromene (CBC)(ISO60163)

O

OHH H

H

Cannabicyclol (CBL)(22036 | 9002438)

O

OCannabicitran (CBT) (citran)

(21295)

Cannabichromenic Acid (CBCA)(9001573)

O

OH O

OH

Cannabifuran (CBF)

O

HO

O

O

OH

OH

Δ9-Tetrahydrocannabiorcinic Acid (Δ9-THCOA-A)

OH

HOCannabigerorcin (CBGO) (E isomer)

(23257)Cannabinerorcin (CBNRO) (Z isomer)

OH

O

HO

OH

Cannabidiorcinic Acid (CBDOA)

O

OH

Δ9-Tetrahydrocannabiorcin (THCO) (Δ9-THCO)O

OH

Δ8-Tetrahydrocannabiorcin (Δ8-THCO)

O

OH

exo-Tetrahydrocannabiorcin (exo-THCO)

O

HO

HO

Cannabielsorcinol (CBEO)

HO

OH

Cannabidiorcin (CBDO)Also known as O-1821

(10006804)

HO

OH

Cannabinodiorcin (CBNDO)

HO

O

Cannabifuraorcin (CBFO)

O

OHH H

H

Cannabicyclorcinol (CBLO)

O

OH

Cannabichromeorcin (CBCO)(21742)

O

OH

OH

O

Cannabichromeorcinic Acid (CBCOA)

O

OCannabicitraorcin (CBTO) (citran)

OH

O

HO

OH

Cannabidiolic Acid (CBDA)(18090)

Cannabinolic Acid (CBNA)O

OH

OH

O

Cannabinol (CBN)(ISO60183)

O

OH

O

OH O

OH

Cannabinorcinic Acid (CBOA)O

OH

Cannabinorcin (CBO)

CoA-S

O

Ethanoyl-CoA

OH

HO

OH

O

Cannabigerorcinic Acid (CBGOA) (E isomer)(23258)

Cannabinerorcinic Acid (CBNROA) (Z isomer)

Orcinolic Acid

HO

HO

OOH

CoA-S

O

Hexanoyl-CoA

Olivetolic Acid

HO

HOOH

O

Cannabitriorcinol (CBTO) (triol)O

OH

HOOH

Cannabiripsorcinol (CBRO)O

OH

HOOH

Δ9-Tetrahydrocannabinolic Acid A (THCA-A) (Δ9-THCA-A)(ISO60175)

O

O

OH

OH

Δ9-Tetrahydrocannabinolic Acid B (Δ9-THCA-B)

O

OH

OHO

Cannabitriol (CBT) (triol)O

OH

HOOH

Cannabiripsol (CBR)O

OH

HOOH

PHYTOCANNABINOID GUIDEBIOSYNTHESIS, NAMING, AND NUMBERING

Δ8-Tetrahydrocannabinol (Δ8-THC)(ISO60158 | 14042)

OH

O

NUMBERINGCONVENTIONS

NAMINGCONVENTIONS

Resorcinol Root Name

Main Scaffold Motifs and Names

When naming phytocannabinoids, the prefix “cannabi” always appears in the main scaffold which drives the name and acronym of each compound.4 The resorcinol root will designate the original C5 series and its C3 and C1 homologs. Listed here are the main scaffolds observed in phytocannabinoids. Because of the prevalence of the olivetolic root, the standard names will all contain the suffix -OL or –NOL, with a few exceptions. When describing the C3 and C1 homologs, the scaffold name is amended by dropping the -OL and replacing the suffix with -VARIN/VARINOL (C3) or -ORCIN/ORCINOL (C1). The oricinolic series is unique in that the suffix has also been placed within the scaffold name(-ORC- as in cannabichromene → cannabiorcochromene).

“M” is indicative of methyl ester when added to the end of the acronym(e.g., CBDM = cannabidiol methyl ester). “A” is indicative of the carboxylated olivetolic acid and is added to the very end of the acronym(e.g., THCA = tetrahydrocannabinolic acid).

4. Brenneisen, R. Chemistry and analysis of phytocannabinoids and other Cannabis constituents. In Marijuana and the Cannabinoids. 17-49, Totowa, US: Humana Press (2007).

1. Mechoulam, R. and Gaoni, Y. Fortschr. Chem. Org. Naturst. 25, 175-213 (1967).2. ElSohly, M.A. and Slade, D. Life Sci. 78(5), 539-548 (2005).3. Hanuš, L.O., Meyer, S.M., Muñoz, E., et al. Nat. Prod. Rep. 33(12), 1357-1392 (2016).

The two most common conventions for numbering THC are the dibenzopyran and monoterpene systems.1,2 The biphenyl and Lord Alexander Todd numbering systems are older and less common.1,2 A simple terpenoid numbering system is used for CBC, CBG, CBE, and CBL structures.2,3

Dibenzopyran numbering designates the double bond of interest as Δ8 or Δ9.

Monoterpene numbering designates the dibenzopyran Δ8 configuration as Δ6. The dibenzopyran Δ9 configuration is Δ1 (or Δ2).

OH

HOOlivetol-OL

OH

HODivarin-VARIN, -VARINOL

OH

HOOrcinol-ORCIN, -ORCINOL, -ORC-

OH

HO RCannaBiGerol

CBG

O

OH

R

CannaBiChromeneCBC

O R

OH

TetraHydroCannabinolTHC

O R

OH

CannaBiNolCBN

O R

OHHO OH

CannaBiTriol‘Triol’ CBT

O R

OHHO OH

CannaBiRipsolCBR

O

HO Riso-TetraHydroCannabinol

iso-THC

R

O

OCannaBiciTran

‘Citran’ CBT

Monocyclic Bicyclic Tricyclic Tetracyclic

7

61

2

354

8

10 9

1'2'

3'

4'5'

6'

76

1

2

3

5

48

1'2'

3'

4'5'

6'O

OH

H

H

11

9

10

10a6a

8

7

6

1

2

3

45

O

OH

H

H

11

9

10

10a6a

8

7

6

1

2

3

45

Δ8

O

OH

H

H

11

9

10

10a6a

8

7

6

1

2

3

45

Δ9

7

2

354

8

10 9

1'2'

3'

4'5'

6'

Δ6

7

6

354

8

10 9

1'2'

3'

4'5'

6'

Δ1(2)

Dibenzopyran Numbering

Most Common Systems

Older/Less Common Systems Terpenoid SystemBiphenyl Numbering Terpenoid Numbering

Todd Numbering

Monoterpene Numbering

O

61'

2'

3' 5

1

2

3

49'

4'

5'

6'

10'

7'

8'

OH

Cannabichromene(CBC)

O

OHHH

H

7'6'

5'

4'3'

1'2' 61

2

3

4

5

Cannabicyclol(CBL)

HO

6

5

1

2

3

4

OH9'

1'

2'3'

4'

5'

6'

10'

7'

8'

Cannabigerol(CBG)

CannaBicycLolCBL

O

OH

R

CannaBiDiolCBD

RHO

OH

CannaBiNoDiolCBND

RHO

OH

CannaBiElsoinCBE

O

HO R

HO

CannaBiFuranCBF

O

HO R

Cannabielsoin(CBE)

7

6

354

8

10 9

1' 2'

3'

4'5'

6'

O

HO

12

HO

612

3

54

1'2'

3'

4'

5'

6'

O

1"

5'6'

42'

4'3' 6"

123

4"

5

1'5"

3"2"

VARINOL SERIESVarinolic cannabinoids were once rare but are now targets of selective breeding. They have also beenexhibited in higher abundance in C. indica over C. sativa.

ORCINOL SERIESOrcinolic phytocannabinoids have been identifiedin Nepalese and Brazilian samples but are also foundas major compounds in non-Cannabis speciessuch as Rhododendron.

CLASSIC OLIVETOL SERIESOlivetolic phytocannabinoids are considered classic, as these are the compounds that are ubiquitous to all varietals of marijuana. This series is not only the most dominant in the Cannabis species but also the most widely studied in the literature.

BiosynthesisEnzymes

Heat, Light, andOxidation Exposure

© 2018 Cayman ChemicalRevised June 2018

Request a PHYTOCANNABINOID POSTER

for your lab!

A guide to the biosynthesis, naming, and numbering of phytocannabinoids

Visit www.caymanchem.com/literature

Page 3: Cayman Chemical - Cannabis Testing Standards · 2020-04-06 · · (800) 364-9897 RESIDUAL SOLVENTS Cannabis Testing Standards As the Cannabis industry grows, various stakeholders

1180 East Ellsworth Road · Ann Arbor, MI · 48108 · USA

INCLUDED IN MULTI-COMPONENT PHYTOCANNABINOID MIXTURES

Item No. Single CRMs

Phytocannabinoid Mixture 4 (CRM) Item No. 25106 1 mg/ml each

Phytocannabinoid Mixture 5 (CRM) Item No. 25076 500 µg/ml each

Phytocannabinoid Mixture 6 (CRM) Item No. 25077 500 µg/ml each

Phytocannabinoid Mixture 10 (CRM)

Item No. 21305 250 µg/ml each

ISO60156 Cannabidiol (CRM)*

ISO60157 Δ9-THC (CRM)*

ISO60175 THCA-A (CRM)

ISO60183 Cannabinol (CRM)

18090 Cannabidiolic Acid (CRM)

20164 Cannabigerol (CRM)*

ISO60163 (±)-Cannabichromene (CRM)*

20165 Cannabidivarin (CRM)

20019 Cannabigerolic Acid (CRM)

ISO60158 Δ8-THC (CRM)*

18091 Tetrahydrocannabivarin (CRM)

21742 (±)-Cannabichromeorcin (CRM)

21974 (±)-Cannabichromevarin (CRM)

22036 (±)-Cannabicyclol (CRM)

21295 Cannabicitran (CRM)

29117 Cannabigerovarin (CRM)

29787 Cannabigerovarinic Acid (CRM)

Phytocannabinoids

Single Standards & Pre-Made Mixtures Available as CRMs

*Isotopically labeled standards are available for mass spec analysis

Cayman offers a suite of ISO 17034-produced single Certified Reference Materials (CRMs) and multi-component phytocannabinoid mixtures that are designed and engineered to the highest standards to give you confidence in your analytical data.

Cayman’s CRMs are...

· Sold as quantitative solutions in sealed ampules

· Formulated as DEA exempt preparations

· Manufactured and tested to meet ISO/IEC 17025 and ISO 17034 international standards

· Given a certified property and uncertainty value for metrological traceability

View our range of pre-made CRM mixtures designedand engineered to the highest standards to give you

confidence in your analytical data while saving time and consumable cost at www.caymanchem.com/phytomix

Page 4: Cayman Chemical - Cannabis Testing Standards · 2020-04-06 · · (800) 364-9897 RESIDUAL SOLVENTS Cannabis Testing Standards As the Cannabis industry grows, various stakeholders

www.caymanchem.com · (800) 364-9897

TerpenesConveniently build a terpene profile for different strains of Cannabis using a pre-made, multi-component solution containing commonly found terpenes – single standards are also available.

View a complete list of our terpene standards at www.caymanchem.com

For custom quantities or formulations, please email [email protected]

Qualitative Single Standards

Multi-Component Mixtures

Item No. Product Name

14007 (+)-Aphidicolin

9002495 (–)-α-Bisabolol

23467 (+)-Borneol

23468 (−)-Borneol

24478 (±)-Camphene

21572 β-Caryophyllene

21573 (−)-Caryophyllene oxide

23464 (+)-β-Citronellol

25770 α-Copaene

23159 p-Cymene

25126 23-epi-26-Deoxyactein

19641 β-Elemene

22183 Eucalyptol

25771 β-Eudesmol

23162 (+)-Fenchol

11018 Forskolin

22184 Geranyl Acetate

Terpene Mixture 1 Terpene Mixture 2Item No. 25928 Item No. 25929

· A 21-component mixture of terpenes that can be isolated from Cannabis

· Contains 1 mg/ml of each compound, including β-myrcene, linalool, β-caryophyllene, and (–)-caryophyllene oxide

· Includes a certified concentration and uncertainty value for each analyte

· A 21-component mixture of terpenes that can be isolated from Cannabis

· Contains 1 mg/ml of each compound, including (+)-limonene, α-humulene, α-pinene, and (–)-β-pinene

· Includes a certified concentration and uncertainty value for each analyte

Item No. Product Name

23172 (−)-Guaiol

21574 α-Humulene

14620 (−)-Huperzine A

23161 (−)-Isopulegol

21719 (+)-Limonene

21575 (±)-Linalool

23463 (+)-Menthol

21720 β-Myrcene

25774 Nerol

11345 Paxilline

23179 α-Phellandrene

21576 α-Pinene

21577 (−)-β-Pinene

25777 Sabinene

23722 γ-Terpinene

23173 Terpineol

21712 Terpinolene

Page 5: Cayman Chemical - Cannabis Testing Standards · 2020-04-06 · · (800) 364-9897 RESIDUAL SOLVENTS Cannabis Testing Standards As the Cannabis industry grows, various stakeholders

1180 East Ellsworth Road · Ann Arbor, MI · 48108 · USA

Mycotoxins Residual SolventsQualitative Single Standards Quantitative Single StandardsItem No. Product Name

11293 Aflatoxin B1

11294 Aflatoxin B2

11295 Aflatoxin G1

11296 Aflatoxin G2

11297 Aflatoxin M1

11298 Aflatoxin M2

20437 Aflatoxin R0

11439 Ochratoxin A

16167 Ochratoxin B

20183 Ochratoxin C

11441 Sterigmatocystin

22070 O-methyl Sterigmatocystin

Item No. Product Name

25932 Butane Residual Solvent Standard

25933 Isobutane Residual Solvent Standard

25934 Propane Residual Solvent Standard

View a complete list of our pesticide, mycotoxin, and residual solvent standards at www.caymanchem.com

Item No. Product Name

26192 Pesticide Mixture 1

26193 Pesticide Mixture 2

26194 Pesticide Mixture 3

26195 Pesticide Mixture 4

26196 Pesticide Mixture 5

Pesticides

Multi-Component Mixtures

Test for the presence of insecticides, acaricides, herbicides, fungicides, carbamates, and more using Cayman’s collection of pesticide mixtures and single standards.

· Contain 8-15 pesticides per mixture at 100 μg/ml of each compound, including insecticides, herbicides, fungicides, acaricides, pesticide metabolites, and pesticide degradation products

· Include a certified concentration and uncertainty value for each analyte

· Intended for use as a calibration or quality control standard

Item No. Product Name

26197 Pesticide Mixture 6

26198 Pesticide Mixture 7

26199 Pesticide Mixture 8

26200 Pesticide Mixture 9

26201 Pesticide Mixture 10

Testing a larger panel of pesticides? Find our collection of more than 100 individual pesticide compounds at www.caymanchem.com

Be the first to know when we release new Cannabis testing standards.

Follow us on social media!

www.facebook.com/caymanchemical

@CaymanChemical

Page 6: Cayman Chemical - Cannabis Testing Standards · 2020-04-06 · · (800) 364-9897 RESIDUAL SOLVENTS Cannabis Testing Standards As the Cannabis industry grows, various stakeholders

www.caymanchem.com · (800) 364-9897

Synthetic Cannabinoids

Other Cannabinoids of Interest

Synthetic Cannabinoid Screening LibraryItem No. 9002891

View a complete list of more than 700 cannabinoid standards at www.caymanchem.com

Synthetic cannabinoids designed to mimic the effects of THC have appeared in herbal products.Cayman offers DEA exempt preparations of classic and emerging synthetic cannabinoids compounds as well as a high-throughput mixture to rapidly screen for synthetic cannabinoid adulterants.

· Contains >350 synthetic cannabinoids in five 96-well plates

· Includes parent compounds and their positional isomers, analogs, and homologs

· Supplied in a 96-well Matrix tube rack format as 10 mM stocks in DMSO

Quantitative Single Standards

Qualitative Single Standards

Item No. Product Name

27237 AB-CHMINACA (CRM)

19805 4-fluoro ADB (CRM)

27043 AM2201 (CRM)

28624 APP-BUTINACA (CRM)

19948 CUMYL-PINACA (CRM)

27973 JWH 018 (CRM)

22047 MAB-CHMINACA (CRM)

28186 4-fluoro MDMB-BUTINACA (CRM)

18203 PB-22 (CRM)

ISO60055 UR-144 (CRM)

ISO60059 XLR11 (CRM)

Item No. Product Name

29780 (6aR,9R)-Δ10-THC (exempt preparation)

29781 (6aR,9S)-Δ10-THC (exempt preparation)

29779 9(R)-Δ6a,10a-THC (exempt preparation)

29782 9(S)-Δ6a,10a-THC (exempt preparation)

Request the Synthetic Cannabinoid Lab Guide wall poster at

www.caymanchem.com/literature

www.caymanchem.com

Laboratory Guide for

SYNTHETICCANNABINOID

Identification and Naming

NH

R

HEAD GROUPS

CORE GROUPS

m/z = 386-304

m/z = 304-100

TAIL GROUPS

PERPETRATOR

MMB-FUBINACA

HEAD

CORE

TAIL

Systematic Name: MMB-FUBINACASynonyms: AMB-FUBINACA, FUB-AMB

Molecular Weight: 383.4Cayman Item No.: 9001960

Our online Synthetic Cannabinoid Flipbook Tool can be found at www.caymanchem.com/flipbook© 2018 Cayman Chemical · Revised July 2019

Mass Spectrum ofMMB-FUBINACA

Common Synthetic CannabinoidMS Fragments

Synthetic Cannabinoid Naming Chart

DEA Schedule: Schedule IDEA No.: DEA 7021Date of Fed Schedule: Nov. 3rd, 2017

HNO

NH2

AB = ADBExcept:

MAB-CHMINACA

=

MDMBAlso: ADB

=

MPPAlso: MPhP

=

CHMAlso: CH, CH-Me

=

HNO

NH2

APP =

HNO

NH2

HNO

OMeMMB

Also:MAB, AMB, MA

=O

OMe

HNEMB

Also: AEB =

O

OEt

HN

N

A =NH

QU =

O

N

MEPIRA =N

N

NA =

· R=H, CUMYL =· R=F, 4F-CUMYL =· R=Cl, 4Cl-CUMYL =

4F-BUTAlso: 4F-B

=

THP =PIPET = 5F-P =

INAM = CZCA =5,3-FUPPYCA =

PY =CYP = NH BEPIRA =

NN

AMP =HN

O

NH2

INACA =N

N

ONH

ICA =

ONH

N

7-AICA =

IM =O

N

IC =

OO

N

5-AICA =

INAC =

N

OO

NN

O

N

NHO

N

3,5-FUPPYCAAlso:

FUPYCA,FUPPYCA

=

NN

ONH

F

1

3

5

NN

ONH

F

15

3

PAlso: Pe

=

FUB =F

ON

B =

NN

ONH

F

O

OMe

Common Synthetic CannabinoidMS Fragments

Tips for GC-MS Interpretation: Swapping the synthetic cannabinoid core: · The difference in mass (m/z) for the indole version of a comparable indazole is -1. Here are some common substituents to replace an H (such as where R is noted in the Common MS Fragments section above): · If R = CH3, the m/z is +14 · If R = F, the m/z is +18 · If R = CN, the m/z is +25

NN

ONH

Fm/z: 338

NN

ONH

m/z: 326

NN

ONH

Fm/z: 324

NN

ONH

m/z: 318F

NN

ONH

m/z: 308

NN

ONH

m/z: 304F

NN

ONH

m/z: 312

m/z: 304

NN

ONH

m/z: 300

NN

ONH

m/z: 286

NN

O

R=H, m/z: 285

R

m/z: 253

NN

O

F

NN

O

Om/z: 243

NN

O

m/z: 241 m/z: 233

NN

O

F

NN

O

m/z: 215 m/z: 145

NH

N

O

· If R = CH2CH3, the m/z is +28· If R = OCH3, the m/z is +30· If R = Cl, the m/z is +34

30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210 220 230 240 250 260 270 280 290 300 310 320 330 340 350 360 370 380 3900

100000

200000

300000

400000

500000

600000

700000

800000

900000

1000000

1100000

1200000

1300000

1400000

1500000

1600000

1700000

1800000

m/z-->

Abundance 109

253

324

269

14583

4359 225 38310290 13071 172 207196 281117 34151 215 242 309 352159 331235186179

NH

N

O

NN

ONH

F

NN

O

F

NN

ONH

F

O

OMe

HNO

OEt

HNO

OEt

HNO

HN

HNO

NH2AEP =

EMP = EDMB =

EADB = · R=H, MMP =· R=CH3, MEP =

m/z = 109

m/z = 253

m/z = 383

m/z = 324

m/z = 145

F

RR=H, m/z: 127

F

m/z: 109

NO

m/z: 100

BUTAlso: B

=

F

R=H, m/z: 155

O

R

m/z: 135

4CN-BUTAlso: 4CN-B,CYB, CB-P

=CN

NN

ONH

m/z: 334

NN

ONH

m/z: 298

NN

ONH

m/z: 290F

NN

ONH

m/z: 352F

NN

ONH

m/z: 368

Cl

NN

ONH

m/z: 352

F

NN

ONH

m/z: 370

F

F

NN

ONH

m/z: 386

Cl

F

NN

ONH

m/z: 320

NN

ONH

m/z: 306

N

NHO

m/z: 254

NN

HONH

Fm/z: 269

N

NHO

m/z: 272F

NN

HONH

Fm/z: 249

NN

HONH

m/z: 229

N

ONH

m/z: 227

NN

ONH

m/z: 272

N

NHO

m/z: 280

NN

HONH

m/z: 231

NN

O

Nm/z: 226

O

NN

O

m/z: 235

N

NHO

m/z: 197

NN

O

m/z: 213

N NH

m/z: 117

OMe

m/z: 121

m/z: 135

O

OMe

HNO

OMe

HNO

OMeR

NO

N

GACLONE = N

ONH

1

5

7

4

6 N N

ONH

17

4

6

5

N

4en-PAlso: PEN

=

NN

ONH

Fm/z: 372 m/z: 362

NN

ONH

O

m/z: 360

NN

ONH

m/z: 352

NN

ONH

Fm/z: 352

NN

ONH

Fm/z: 345

NN

ONH

N

m/z: 338

NN

ONH

F

NN

ONH

m/z: 320

NN

O

Fm/z: 219

NN

O

m/z: 201

F

NN

ONH

F

Page 7: Cayman Chemical - Cannabis Testing Standards · 2020-04-06 · · (800) 364-9897 RESIDUAL SOLVENTS Cannabis Testing Standards As the Cannabis industry grows, various stakeholders

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High-Throughput Sample Preparation

Cayman Chemical is a proud distributor of Bertin Instruments’ homogenizers and consumables in the United States. Learn more at www.caymanchem.com/Precellys

Precellys® Evolution from Bertin TechnologiesGrind, lyse, and homogenize samples in less than 30 seconds!

· Super Efficient: homogenizes in a powerful figure-8 multi-directional motion at speeds up to 10,000 rpm

· Super Flexible: processes four sizes of tubes from 0.3 ml to 15 ml

· Super Easy: includes automatic tube locking system

Plant Extraction Application Notes

To request a copy, email [email protected]

DNA Extraction from Rice LeafMycoviral double-stranded RNA extraction from plant leaf with Minilys Protein extraction from Nicotiana benthamiana leaf

ASK US ABOUT A DEMO!

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