certificate of analysis – revised report€¦ · maxxam analytics maxxam job #: b4b4991 report...

Your C.O.C. #: A122303

Attention: STEPHEN LEGAREEMAXXAM ANALYTICSEDMONTON 93319331 - 48 StreetEDMONTON, ABCANADA T6B 2R4

Report Date: 2015/01/14Report #: R1787645

Version: 2R

CERTIFICATE OF ANALYSIS – REVISED REPORT

MAXXAM JOB #: B4B4991Received: 2014/12/18, 08:52

Sample Matrix: Soil# Samples Received: 2

Date DateAnalyses Quantity Extracted Analyzed Laboratory Method Analytical MethodBoron (Hot Water Soluble) 2 2014/12/22 2014/12/22 AB SOP-00034 / AB EPA 200.7 CFR 2012 m

SOP-00042Hexavalent Chromium 2 2014/12/22 2014/12/23 AB SOP-00063 SM 22 3500-Cr B m Elements by ICPMS - Soils 2 2014/12/23 2014/12/23 AB SOP-00001 / AB EPA 200.8 R5.4 m

SOP-00043Moisture 2 N/A 2014/12/22 AB SOP-00002 CCME PHC-CWS Ammonia-N (Available) 2 2014/12/24 2014/12/24 AB SOP-00027 / AB EPA 350.1 R2.0 m

SOP-00007NO2 + NO3 Available (10:1 Wet) 2 2014/12/19 2014/12/24 AB SOP-00027/AB Auto Calc

SOP-00023Nitrite Available (10:1 Wet) 2 2014/12/23 2014/12/23 AB SOP-00027/AB SM 22 4110 B m

SOP-00023Nitrogen - Nitrate (as N) 2 N/A 2014/12/24 AB SOP-00023 SM 4110 B Nitrate Available (10:1 Wet) 2 2014/12/23 2014/12/23 AB SOP-00027/AB SM 22 4110 B m

SOP-00023pH @25C (1:2 Calcium Chloride Extract) 2 2015/01/14 2015/01/14 AB SOP-00033 / AB Carter 2nd ed 16.2 m

SOP-00006Phosphorus, Potassium - Available 2 2014/12/28 2014/12/28 AB SOP-00028 / AB EPA 200.7 CFR 2012 m

SOP-00042Sulphur (Available) 2 2014/12/28 2014/12/28 AB SOP-00029 / AB EPA 200.7 CFR 2012 m

SOP-00042

Sample Matrix: Water# Samples Received: 2

Date DateAnalyses Quantity Extracted Analyzed Laboratory Method Analytical MethodCadmium - low level CCME (Total) 2 2014/12/19 2014/12/23 AB SOP-00014 / AB EPA 200.8 R5.4m

SOP-00043Elements by ICP - Total 2 2014/12/23 2014/12/23 AB SOP-00014 / AB EPA 200.7 CFR 2012 m

SOP-00042Elements by ICPMS - Total 2 2014/12/23 2014/12/23 AB SOP-00014 / AB EPA 200.8 R5.4 m

SOP-00043

Maxxam Analytics International Corporation o/a Maxxam Analytics Edmonton: 9331 - 48th Street T6B 2R4 Telephone(780)577-7100 Fax(780)450-4187

of 16

Your C.O.C. #: A122303

Attention: STEPHEN LEGAREEMAXXAM ANALYTICSEDMONTON 93319331 - 48 StreetEDMONTON, ABCANADA T6B 2R4

Report Date: 2015/01/14Report #: R1787645

Version: 2R

CERTIFICATE OF ANALYSIS – REVISED REPORT-2-

Sample Matrix: Water# Samples Received: 2

Date DateAnalyses Quantity Extracted Analyzed Laboratory Method Analytical MethodAmmonia-N (Total) 2 N/A 2014/12/22 AB SOP-00007 EPA 350.1 R2.0 m Nitrate and Nitrite 2 N/A 2014/12/22 AB SOP-00023 Auto Calc Nitrate + Nitrite-N (calculated) 2 N/A 2014/12/22 AB SOP-00023 Auto Calc Nitrogen, (Nitrite, Nitrate) by IC 2 N/A 2014/12/20 AB SOP-00023 SM 22 4110 B m pH @25C 2 N/A 2015/01/10 AB SOP-00006 SM 22 4500 H+ B m Total Kjeldahl Nitrogen 2 2014/12/20 2014/12/22 AB SOP-00008 EPA 351.1 R 1978 m

* RPDs calculated using raw data. The rounding of final results may result in the apparent difference.

Encryption Key

Please direct all questions regarding this Certificate of Analysis to your Project Manager.

Jeremy Wakaruk, B.Sc., Senior Project ManagerEmail: [email protected]# (780) 577-7105 Ext:7105

====================================================================Maxxam has procedures in place to guard against improper use of the electronic signature and have the required "signatories", as per section5.10.2 of ISO/IEC 17025:2005(E), signing the reports. For Service Group specific validation please refer to the Validation Signature Page.

Total cover pages: 2


of 16

MAXXAM ANALYTICSMaxxam Job #: B4B4991Report Date: 2015/01/14

Sampler Initials: SL

NUTRIENT PACKAGE 2 (SOIL)

Maxxam ID L K 2 2 8 7 L K 2 2 8 8Sampling Date 2014/12/18 2014/12/18COC Number A122303 A122303 U N I T S UN-USED RDL USED RDL QC Batch

COFFEE COFFEEGROUNDS GROUNDS

Calculated Parameters

Available (KCl) Nitrate (N) mg/kg 3.6 0.50 8.3 2.5 7760284

Nutrients

Available (KCl) Nitrate plus Nitrite (N) mg/kg 3.6 0.50 8.3 2.5 7760283

Available (KCl) Nitrite (N) mg/kg <0.50 0.50 <2.5 ( 1 ) 2.5 7764013

Available (Mod Kel) Phosphorus (P) mg/kg 1400 ( 2 ) 10 880 ( 2 ) 10 7765513

Available (Mod Kel) Potassium (K) mg/kg 20000 ( 2 ) 100 6400 ( 2 ) 10 7765513

Available (CaCl2) Sulphur (S) mg/kg 290 ( 2 ) 20 120 ( 2 ) 20 7765514

RDL = Reportable Detection Limit( 1 ) Detection limits raised due to matrix interference.( 2 ) Detection limits raised based on sample weight used for analysis.

of 16



REGULATED METALS (CCME/AT1) - SOILS

Maxxam ID L K 2 2 8 7 L K 2 2 8 8Sampling Date 2014/12/18 2014/12/18COC Number A122303 A122303 U N I T S UN-USED RDL USED RDL QC Batch


Elements

Soluble (Hot water) Boron (B) mg/kg 2.2 ( 1 ) 2.0 <3.0 ( 1 ) 3.0 7762503

Hex. Chromium (Cr 6+) mg/kg <0.75 ( 2 ) 0.75 <0.15 0.15 7762131

Total Antimony (Sb) mg/kg <2.0 2.0 <2.0 2.0 7763321

Total Arsenic (As) mg/kg <2.0 2.0 <2.0 2.0 7763321

Total Barium (Ba) mg/kg <20 20 <20 20 7763321

Total Beryllium (Be) mg/kg <0.80 0.80 <0.80 0.80 7763321

Total Cadmium (Cd) mg/kg <0.20 0.20 <0.20 0.20 7763321

Total Chromium (Cr) mg/kg <2.0 2.0 <2.0 2.0 7763321

Total Cobalt (Co) mg/kg <2.0 2.0 <2.0 2.0 7763321

Total Copper (Cu) mg/kg 11 10 14 10 7763321

Total Lead (Pb) mg/kg <2.0 2.0 <2.0 2.0 7763321

Total Mercury (Hg) mg/kg <0.10 0.10 <0.10 0.10 7763321

Total Molybdenum (Mo) mg/kg <0.80 0.80 <0.80 0.80 7763321

Total Nickel (Ni) mg/kg <2.0 2.0 <2.0 2.0 7763321

Total Selenium (Se) mg/kg <1.0 1.0 <1.0 1.0 7763321

Total Silver (Ag) mg/kg <2.0 2.0 <2.0 2.0 7763321

Total Thallium (Tl) mg/kg <0.60 0.60 <0.60 0.60 7763321

Total Tin (Sn) mg/kg <2.0 2.0 <2.0 2.0 7763321

Total Uranium (U) mg/kg <2.0 2.0 <2.0 2.0 7763321

Total Vanadium (V) mg/kg <2.0 2.0 <2.0 2.0 7763321

Total Zinc (Zn) mg/kg <20 20 <20 20 7763321

RDL = Reportable Detection Limit( 1 ) Detection limits raised due to sample matrix and sample weight used in analysis.( 2 ) Detection limits raised due to matrix interference.

of 16



REGULATED METALS (CCME/AT1) - TOTAL

Maxxam ID L K 2 2 8 5 L K 2 2 8 6Sampling Date 2014/12/18 2014/12/18COC Number A122303 A122303 U N I T S STARBUCKS RDL STARBUCKS RDL QC Batch

COFFEE ESPRESSO

Low Level Elements

Total Cadmium (Cd) ug/L <0.50 0.50 <0.50 0.50 7760282

Elements

Total Aluminum (Al) mg/L <0.075 0.075 <0.075 0.075 7763215

Total Antimony (Sb) mg/L <0.015 0.015 <0.015 0.015 7763215

Total Arsenic (As) mg/L <0.0050 0.0050 <0.0050 0.0050 7763215

Total Barium (Ba) mg/L 0.055 0.050 0.16 0.050 7763225

Total Beryllium (Be) mg/L <0.025 0.025 <0.025 0.025 7763215

Total Boron (B) mg/L 0.31 0.10 1.4 0.10 7763225

Total Calcium (Ca) mg/L 16 1.5 75 1.5 7763225

Total Chromium (Cr) mg/L <0.025 0.025 <0.025 0.025 7763215

Total Cobalt (Co) mg/L <0.0075 0.0075 0.0081 0.0075 7763215

Total Copper (Cu) mg/L 0.12 0.0050 0.086 0.0050 7763215

Total Iron (Fe) mg/L <0.30 0.30 0.62 0.30 7763225

Total Lead (Pb) mg/L <0.0050 0.0050 <0.0050 0.0050 7763215

Total Lithium (Li) mg/L <0.10 0.10 <0.10 0.10 7763225

Total Magnesium (Mg) mg/L 52 1.0 310 1.0 7763225

Total Manganese (Mn) mg/L 0.28 0.020 1.2 0.020 7763225

Total Molybdenum (Mo) mg/L <0.0050 0.0050 <0.0050 0.0050 7763215

Total Nickel (Ni) mg/L <0.013 0.013 0.022 0.013 7763215

Total Phosphorus (P) mg/L 43 0.50 290 0.50 7763225

Total Potassium (K) mg/L 810 1.5 7000 ( 1 ) 15 7763225

Total Selenium (Se) mg/L <0.0050 0.0050 <0.0050 0.0050 7763215

Total Silicon (Si) mg/L 1.0 0.50 2.0 0.50 7763225

Total Silver (Ag) mg/L <0.0025 0.0025 <0.0025 0.0025 7763215

Total Sodium (Na) mg/L 4.9 2.5 4.8 2.5 7763225

Total Strontium (Sr) mg/L 0.12 0.10 0.43 0.10 7763225

Total Sulphur (S) mg/L 20 1.0 110 1.0 7763225

Total Thallium (Tl) mg/L <0.0050 0.0050 <0.0050 0.0050 7763215

Total Tin (Sn) mg/L <0.025 0.025 <0.025 0.025 7763215

Total Titanium (Ti) mg/L <0.025 0.025 0.048 0.025 7763215

Total Uranium (U) mg/L <0.0025 0.0025 <0.0025 0.0025 7763215

Total Vanadium (V) mg/L <0.025 0.025 <0.025 0.025 7763215

RDL = Reportable Detection Limit( 1 ) Detection limits raised due to dilution to bring analyte within the calibrated range.

of 16



REGULATED METALS (CCME/AT1) - TOTAL


COFFEE ESPRESSO

Total Zinc (Zn) mg/L 0.11 0.075 1.2 0.075 7763215

RDL = Reportable Detection Limit

of 16



RESULTS OF CHEMICAL ANALYSES OF SOIL

Maxxam ID L K 2 2 8 7 L K 2 2 8 8Sampling Date 2014/12/18 2014/12/18COC Number A122303 A122303 U N I T S UN-USED RDL QC Batch USED RDL QC Batch


Nutrients

Available (KCl) Ammonia (N) mg/kg <20 ( 1 ) 20 7764562 <20 ( 1 ) 20 7764562

Available (KCl) Nitrate (N) mg/kg 3.6 0.50 7764023 8.3 ( 2 ) 2.5 7764023

Soluble Parameters

Soluble (CaCl2) pH pH 5.88 N/A 7777314 5.40 N/A 7777281

Physical Properties

Moisture % 1.4 0.30 7761376 65 0.30 7761376

RDL = Reportable Detection Limit( 1 ) Detection limits raised due to sample matrix.( 2 ) Detection limits raised due to matrix interference.

of 16



RESULTS OF CHEMICAL ANALYSES OF WATER


COFFEE ESPRESSO

Calculated Parameters

Dissolved Nitrate (NO3) mg/L 2.6 2.2 11 2.2 7759701

Nitrate plus Nitrite (N) mg/L 0.58 0.50 2.6 0.50 7759702

Dissolved Nitrite (NO2) mg/L <1.6 1.6 <1.6 1.6 7759701

Misc. Inorganics

pH pH 5.10 ( 1 ) N/A 5.31 ( 1 ) N/A 7774809

Nutrients

Total Ammonia (N) mg/L <0.50 ( 2 ) 0.50 1.8 ( 2 ) 0.050 7761810

Total Total Kjeldahl Nitrogen mg/L 5.3 ( 3 ) 0.25 67 ( 3 ) 2.5 7761154

Dissolved Nitrite (N) mg/L <0.50 ( 2 ) 0.50 <0.50 ( 2 ) 0.50 7760794

Dissolved Nitrate (N) mg/L 0.58 ( 2 ) 0.50 2.6 ( 2 ) 0.50 7760794

RDL = Reportable Detection Limit( 1 ) Analysis requested past recommended holding time( 2 ) Detection limits raised due to sample matrix.( 3 ) Detection limits raised due to dilution to bring analyte within the calibrated range.

of 16



Package 1 37.3°CEach temperature is the average of up to three cooler temperatures taken at receipt

General Comments

Sample LK2285-01: Detection limits raised due to sample matrix. Parameters affected are total B, Ba, Ca, Fe, K, Li, Mg, Mn, Na, P, S, Si, Sr, Al,Cr, Co, Cu, Pb, Sb, Mo, Ni, Se, Ag, As, Tl, Sn, Ti, U, V, Zn, Be, Cd.

Sample LK2286-01: Detection limits raised due to sample matrix. Parameters affected are total B, Ba, Ca, Fe, K, Li, Mg, Mn, Na, P, S, Si, Sr, Al,Cr, Co, Cu, Pb, Sb, Mo, Ni, Se, Ag, As, Tl, Sn, Ti, U, V, Zn, Be, Cd.

Sample LK2287-01: Detection limits raised due to insufficient sample volume. Parameters affected are Cr, Co, Cu, Pb, Sb, Mo, Ni, Se, Ag, As,Tl, Sn, U, V, Zn, Be, Cd, Ba, Hg.

Sample LK2288-01: Detection limits raised due to insufficient sample volume. Parameters affected are Cr, Co, Cu, Pb, Sb, Mo, Ni, Se, Ag, As,Tl, Sn, U, V, Zn, Be, Cd, Ba, Hg.

Results relate only to the items tested.

of 16

MAXXAM ANALYTICSAttention: STEPHEN LEGAREE Client Project #: P.O. #: Site Location:

Quality Assurance ReportMaxxam Job Number: EB4B4991

QA/QC DateBatch AnalyzedNum Init QC Type Parameter yyyy/mm/dd Value Recovery UNITS QC Limits

7760794 MPH Matrix Spike Dissolved Nitrite (N) 2014/12/20 101 % 80 - 120Dissolved Nitrate (N) 2014/12/20 101 % 80 - 120

Spiked Blank Dissolved Nitrite (N) 2014/12/20 100 % 80 - 120Dissolved Nitrate (N) 2014/12/20 99 % 80 - 120

Method Blank Dissolved Nitrite (N) 2014/12/20 <0.010 mg/LDissolved Nitrate (N) 2014/12/20 <0.010 mg/L

RPD Dissolved Nitrite (N) 2014/12/20 NC % 20Dissolved Nitrate (N) 2014/12/20 NC % 20

7761154 AL2 Matrix Spike Total Total Kjeldahl Nitrogen 2014/12/22 NC % 80 - 120QC Standard Total Total Kjeldahl Nitrogen 2014/12/22 110 % 80 - 120Spiked Blank Total Total Kjeldahl Nitrogen 2014/12/22 106 % 80 - 120Method Blank Total Total Kjeldahl Nitrogen 2014/12/22 <0.050 mg/LRPD Total Kjeldahl Nitrogen 2014/12/22 0.2 % 20

7761376 HG3 Method Blank Moisture 2014/12/22 <0.30 %RPD Moisture 2014/12/22 0.9 % 20

7761810 AL2 Matrix Spike Total Ammonia (N) 2014/12/22 85 % 80 - 120Spiked Blank Total Ammonia (N) 2014/12/22 100 % 80 - 120Method Blank Total Ammonia (N) 2014/12/22 <0.050 mg/LRPD Total Ammonia (N) 2014/12/22 NC % 20

7762131 KD5 Matrix Spike Hex. Chromium (Cr 6+) 2014/12/23 99 % 75 - 125Spiked Blank Hex. Chromium (Cr 6+) 2014/12/23 104 % 80 - 120Method Blank Hex. Chromium (Cr 6+) 2014/12/23 <0.15 mg/kgRPD Hex. Chromium (Cr 6+) 2014/12/23 NC % 35

7762503 SDH Matrix Spike Soluble (Hot water) Boron (B) 2014/12/22 113 % 75 - 125Spiked Blank Soluble (Hot water) Boron (B) 2014/12/22 102 % 75 - 125Method Blank Soluble (Hot water) Boron (B) 2014/12/22 <0.10 mg/kgRPD Soluble (Hot water) Boron (B) 2014/12/22 NC % 35

7763215 APY Matrix Spike Total Aluminum (Al) 2014/12/23 NC % 80 - 120Total Antimony (Sb) 2014/12/23 117 % 80 - 120Total Arsenic (As) 2014/12/23 110 % 80 - 120Total Beryllium (Be) 2014/12/23 107 % 80 - 120Total Chromium (Cr) 2014/12/23 105 % 80 - 120Total Cobalt (Co) 2014/12/23 105 % 80 - 120Total Copper (Cu) 2014/12/23 102 % 80 - 120Total Lead (Pb) 2014/12/23 108 % 80 - 120Total Molybdenum (Mo) 2014/12/23 115 % 80 - 120Total Nickel (Ni) 2014/12/23 102 % 80 - 120Total Selenium (Se) 2014/12/23 110 % 80 - 120Total Silver (Ag) 2014/12/23 111 % 80 - 120Total Thallium (Tl) 2014/12/23 115 % 80 - 120Total Tin (Sn) 2014/12/23 125 ( 1 ) % 80 - 120Total Titanium (Ti) 2014/12/23 110 % 80 - 120Total Uranium (U) 2014/12/23 106 % 80 - 120Total Vanadium (V) 2014/12/23 111 % 80 - 120Total Zinc (Zn) 2014/12/23 NC % 80 - 120

Spiked Blank Total Aluminum (Al) 2014/12/23 107 % 80 - 120Total Antimony (Sb) 2014/12/23 104 % 80 - 120Total Arsenic (As) 2014/12/23 103 % 80 - 120Total Beryllium (Be) 2014/12/23 102 % 80 - 120Total Chromium (Cr) 2014/12/23 104 % 80 - 120Total Cobalt (Co) 2014/12/23 105 % 80 - 120Total Copper (Cu) 2014/12/23 103 % 80 - 120Total Lead (Pb) 2014/12/23 108 % 80 - 120Total Molybdenum (Mo) 2014/12/23 108 % 80 - 120Total Nickel (Ni) 2014/12/23 104 % 80 - 120


of 16


Quality Assurance Report (Continued)Maxxam Job Number: EB4B4991


7763215 APY Spiked Blank Total Selenium (Se) 2014/12/23 100 % 80 - 120Total Silver (Ag) 2014/12/23 110 % 80 - 120Total Thallium (Tl) 2014/12/23 117 % 80 - 120Total Tin (Sn) 2014/12/23 115 % 80 - 120Total Titanium (Ti) 2014/12/23 107 % 80 - 120Total Uranium (U) 2014/12/23 105 % 80 - 120Total Vanadium (V) 2014/12/23 109 % 80 - 120Total Zinc (Zn) 2014/12/23 97 % 80 - 120

Method Blank Total Aluminum (Al) 2014/12/23 <0.0030 mg/LTotal Antimony (Sb) 2014/12/23 <0.00060 mg/LTotal Arsenic (As) 2014/12/23 <0.00020 mg/LTotal Beryllium (Be) 2014/12/23 <0.0010 mg/LTotal Chromium (Cr) 2014/12/23 <0.0010 mg/LTotal Cobalt (Co) 2014/12/23 <0.00030 mg/LTotal Copper (Cu) 2014/12/23 <0.00020 mg/LTotal Lead (Pb) 2014/12/23 <0.00020 mg/LTotal Molybdenum (Mo) 2014/12/23 <0.00020 mg/LTotal Nickel (Ni) 2014/12/23 <0.00050 mg/LTotal Selenium (Se) 2014/12/23 <0.00020 mg/LTotal Silver (Ag) 2014/12/23 <0.00010 mg/LTotal Thallium (Tl) 2014/12/23 <0.00020 mg/LTotal Tin (Sn) 2014/12/23 <0.0010 mg/LTotal Titanium (Ti) 2014/12/23 <0.0010 mg/LTotal Uranium (U) 2014/12/23 <0.00010 mg/LTotal Vanadium (V) 2014/12/23 <0.0010 mg/LTotal Zinc (Zn) 2014/12/23 <0.0030 mg/L

RPD Total Antimony (Sb) 2014/12/23 NC % 20Total Arsenic (As) 2014/12/23 NC % 20Total Chromium (Cr) 2014/12/23 NC % 20Total Copper (Cu) 2014/12/23 4.9 % 20Total Lead (Pb) 2014/12/23 NC % 20Total Selenium (Se) 2014/12/23 NC % 20Total Uranium (U) 2014/12/23 NC % 20Total Zinc (Zn) 2014/12/23 6.3 % 20

7763225 JK9 Matrix Spike Total Barium (Ba) 2014/12/23 107 % 80 - 120Total Boron (B) 2014/12/23 103 % 80 - 120Total Calcium (Ca) 2014/12/23 NC % 80 - 120Total Iron (Fe) 2014/12/23 106 % 80 - 120Total Lithium (Li) 2014/12/23 98 % 80 - 120Total Magnesium (Mg) 2014/12/23 101 % 80 - 120Total Manganese (Mn) 2014/12/23 101 % 80 - 120Total Phosphorus (P) 2014/12/23 100 % 80 - 120Total Potassium (K) 2014/12/23 100 % 80 - 120Total Silicon (Si) 2014/12/23 104 % 80 - 120Total Sodium (Na) 2014/12/23 102 % 80 - 120Total Strontium (Sr) 2014/12/23 101 % 80 - 120

Spiked Blank Total Barium (Ba) 2014/12/23 107 % 80 - 120Total Boron (B) 2014/12/23 103 % 80 - 120Total Calcium (Ca) 2014/12/23 98 % 80 - 120Total Iron (Fe) 2014/12/23 111 % 80 - 120Total Lithium (Li) 2014/12/23 98 % 80 - 120Total Magnesium (Mg) 2014/12/23 102 % 80 - 120Total Manganese (Mn) 2014/12/23 102 % 80 - 120Total Phosphorus (P) 2014/12/23 102 % 80 - 120Total Potassium (K) 2014/12/23 101 % 80 - 120


of 16




7763225 JK9 Spiked Blank Total Silicon (Si) 2014/12/23 104 % 80 - 120Total Sodium (Na) 2014/12/23 106 % 80 - 120Total Strontium (Sr) 2014/12/23 102 % 80 - 120Total Sulphur (S) 2014/12/23 96 % 80 - 120

Method Blank Total Barium (Ba) 2014/12/23 <0.010 mg/LTotal Boron (B) 2014/12/23 <0.020 mg/LTotal Calcium (Ca) 2014/12/23 <0.30 mg/LTotal Iron (Fe) 2014/12/23 <0.060 mg/LTotal Lithium (Li) 2014/12/23 <0.020 mg/LTotal Magnesium (Mg) 2014/12/23 <0.20 mg/LTotal Manganese (Mn) 2014/12/23 <0.0040 mg/LTotal Phosphorus (P) 2014/12/23 <0.10 mg/LTotal Potassium (K) 2014/12/23 <0.30 mg/LTotal Silicon (Si) 2014/12/23 <0.10 mg/LTotal Sodium (Na) 2014/12/23 <0.50 mg/LTotal Strontium (Sr) 2014/12/23 <0.020 mg/LTotal Sulphur (S) 2014/12/23 <0.20 mg/L

RPD Total Barium (Ba) 2014/12/23 NC % 20Total Boron (B) 2014/12/23 NC % 20Total Iron (Fe) 2014/12/23 NC % 20Total Manganese (Mn) 2014/12/23 NC % 20Total Sodium (Na) 2014/12/23 3.7 % 20

7763321 HM3 Matrix Spike Total Antimony (Sb) 2014/12/23 83 % 75 - 125Total Arsenic (As) 2014/12/23 101 % 75 - 125Total Barium (Ba) 2014/12/23 NC % 75 - 125Total Beryllium (Be) 2014/12/23 107 % 75 - 125Total Cadmium (Cd) 2014/12/23 99 % 75 - 125Total Chromium (Cr) 2014/12/23 109 % 75 - 125Total Cobalt (Co) 2014/12/23 101 % 75 - 125Total Copper (Cu) 2014/12/23 103 % 75 - 125Total Lead (Pb) 2014/12/23 101 % 75 - 125Total Mercury (Hg) 2014/12/23 95 % 75 - 125Total Molybdenum (Mo) 2014/12/23 99 % 75 - 125Total Nickel (Ni) 2014/12/23 106 % 75 - 125Total Selenium (Se) 2014/12/23 103 % 75 - 125Total Silver (Ag) 2014/12/23 98 % 75 - 125Total Thallium (Tl) 2014/12/23 97 % 75 - 125Total Tin (Sn) 2014/12/23 110 % 75 - 125Total Uranium (U) 2014/12/23 92 % 75 - 125Total Vanadium (V) 2014/12/23 116 % 75 - 125Total Zinc (Zn) 2014/12/23 NC % 75 - 125

QC Standard Total Arsenic (As) 2014/12/23 128 % 50 - 150Total Barium (Ba) 2014/12/23 119 % 69 - 131Total Chromium (Cr) 2014/12/23 109 % 41 - 159Total Cobalt (Co) 2014/12/23 112 % 75 - 125Total Copper (Cu) 2014/12/23 109 % 73 - 127Total Lead (Pb) 2014/12/23 108 % 54 - 146Total Nickel (Ni) 2014/12/23 117 % 61 - 139Total Vanadium (V) 2014/12/23 123 % 50 - 150Total Zinc (Zn) 2014/12/23 118 % 72 - 128

Spiked Blank Total Antimony (Sb) 2014/12/23 96 % 75 - 125Total Arsenic (As) 2014/12/23 101 % 75 - 125Total Barium (Ba) 2014/12/23 102 % 75 - 125Total Beryllium (Be) 2014/12/23 108 % 75 - 125Total Cadmium (Cd) 2014/12/23 97 % 75 - 125


of 16




7763321 HM3 Spiked Blank Total Chromium (Cr) 2014/12/23 98 % 75 - 125Total Cobalt (Co) 2014/12/23 101 % 75 - 125Total Copper (Cu) 2014/12/23 99 % 75 - 125Total Lead (Pb) 2014/12/23 99 % 75 - 125Total Mercury (Hg) 2014/12/23 95 % 75 - 125Total Molybdenum (Mo) 2014/12/23 100 % 75 - 125Total Nickel (Ni) 2014/12/23 98 % 75 - 125Total Selenium (Se) 2014/12/23 103 % 75 - 125Total Silver (Ag) 2014/12/23 98 % 75 - 125Total Thallium (Tl) 2014/12/23 98 % 75 - 125Total Tin (Sn) 2014/12/23 106 % 75 - 125Total Uranium (U) 2014/12/23 97 % 75 - 125Total Vanadium (V) 2014/12/23 102 % 75 - 125Total Zinc (Zn) 2014/12/23 99 % 75 - 125

Method Blank Total Antimony (Sb) 2014/12/23 <1.0 mg/kgTotal Arsenic (As) 2014/12/23 <1.0 mg/kgTotal Barium (Ba) 2014/12/23 <10 mg/kgTotal Beryllium (Be) 2014/12/23 <0.40 mg/kgTotal Cadmium (Cd) 2014/12/23 <0.10 mg/kgTotal Chromium (Cr) 2014/12/23 <1.0 mg/kgTotal Cobalt (Co) 2014/12/23 <1.0 mg/kgTotal Copper (Cu) 2014/12/23 <5.0 mg/kgTotal Lead (Pb) 2014/12/23 <1.0 mg/kgTotal Mercury (Hg) 2014/12/23 <0.050 mg/kgTotal Molybdenum (Mo) 2014/12/23 <0.40 mg/kgTotal Nickel (Ni) 2014/12/23 <1.0 mg/kgTotal Selenium (Se) 2014/12/23 <0.50 mg/kgTotal Silver (Ag) 2014/12/23 <1.0 mg/kgTotal Thallium (Tl) 2014/12/23 <0.30 mg/kgTotal Tin (Sn) 2014/12/23 <1.0 mg/kgTotal Uranium (U) 2014/12/23 <1.0 mg/kgTotal Vanadium (V) 2014/12/23 <1.0 mg/kgTotal Zinc (Zn) 2014/12/23 <10 mg/kg

RPD Total Antimony (Sb) 2014/12/23 NC % 35Total Arsenic (As) 2014/12/23 2.1 % 35Total Barium (Ba) 2014/12/23 3.0 % 35Total Beryllium (Be) 2014/12/23 NC % 35Total Cadmium (Cd) 2014/12/23 NC % 35Total Chromium (Cr) 2014/12/23 6.3 % 35Total Cobalt (Co) 2014/12/23 0.4 % 35Total Copper (Cu) 2014/12/23 NC % 35Total Lead (Pb) 2014/12/23 NC % 35Total Mercury (Hg) 2014/12/23 NC % 35Total Molybdenum (Mo) 2014/12/23 NC % 35Total Nickel (Ni) 2014/12/23 1.2 % 35Total Selenium (Se) 2014/12/23 NC % 35Total Silver (Ag) 2014/12/23 NC % 35Total Thallium (Tl) 2014/12/23 NC % 35Total Tin (Sn) 2014/12/23 NC % 35Total Uranium (U) 2014/12/23 NC % 35Total Vanadium (V) 2014/12/23 3.3 % 35Total Zinc (Zn) 2014/12/23 NC % 35

7764013 SB8 Matrix Spike[LK2288-01] Available (KCl) Nitrite (N) 2014/12/23 93 % 75 - 125Spiked Blank Available (KCl) Nitrite (N) 2014/12/23 97 % 75 - 125


of 16




7764013 SB8 Method Blank Available (KCl) Nitrite (N) 2014/12/23 <0.50 mg/kgRPD [ L K 2 2 8 8 - 0 1 ] Available (KCl) Nitrite (N) 2014/12/23 NC % 35

7764023 SB8 Matrix Spike[LK2288-01] Available (KCl) Nitrate (N) 2014/12/23 90 % 75 - 125Spiked Blank Available (KCl) Nitrate (N) 2014/12/23 102 % 75 - 125Method Blank Available (KCl) Nitrate (N) 2014/12/23 0.62, RDL=0.50 mg/kgRPD [ L K 2 2 8 8 - 0 1 ] Available (KCl) Nitrate (N) 2014/12/23 NC % 35

7764562 MBB Matrix Spike[LK2288-01] Available (KCl) Ammonia (N) 2014/12/24 NC % 75 - 125Spiked Blank Available (KCl) Ammonia (N) 2014/12/24 86 % 80 - 120Method Blank Available (KCl) Ammonia (N) 2014/12/24 <2.0 mg/kgRPD [ L K 2 2 8 8 - 0 1 ] Available (KCl) Ammonia (N) 2014/12/24 NC % 35

7765513 SDH Spiked Blank Available (Mod Kel) Phosphorus (P) 2014/12/28 105 % 75 - 125Available (Mod Kel) Potassium (K) 2014/12/28 94 % 75 - 125

Method Blank Available (Mod Kel) Phosphorus (P) 2014/12/28 <4.0 mg/kgAvailable (Mod Kel) Potassium (K) 2014/12/28 <4.0 mg/kg

RPD [ L K 2 2 8 8 - 0 1 ] Available (Mod Kel) Phosphorus (P) 2014/12/28 2.1 % 35Available (Mod Kel) Potassium (K) 2014/12/28 2.9 % 35

7765514 SDH QC Standard Available (CaCl2) Sulphur (S) 2014/12/28 102 % 88 - 112Spiked Blank Available (CaCl2) Sulphur (S) 2014/12/28 97 % 80 - 120Method Blank Available (CaCl2) Sulphur (S) 2014/12/28 <2.0 mg/kgRPD [ L K 2 2 8 8 - 0 1 ] Available (CaCl2) Sulphur (S) 2014/12/28 3.7 % 35

7774809 CH7 Spiked Blank pH 2015/01/10 100 % 97 - 103RPD [ L K 2 2 8 5 - 0 1 ] pH 2015/01/10 0.2 % N/A

7777281 CJ5 QC Standard Soluble (CaCl2) pH 2015/01/14 97 % 97 - 103Spiked Blank Soluble (CaCl2) pH 2015/01/14 99 % 97 - 103RPD Soluble (CaCl2) pH 2015/01/14 0.6 % N/A

7777314 CJ5 QC Standard Soluble (CaCl2) pH 2015/01/14 99 % 97 - 103Spiked Blank Soluble (CaCl2) pH 2015/01/14 100 % 97 - 103RPD Soluble (CaCl2) pH 2015/01/14 0.3 % N/A

N/A = Not ApplicableDuplicate: Paired analysis of a separate portion of the same sample. Used to evaluate the variance in the measurement.Matrix Spike: A sample to which a known amount of the analyte of interest has been added. Used to evaluate sample matrix interference.QC Standard: A sample of known concentration prepared by an external agency under stringent conditions. Used as an independent check of methodaccuracy.Spiked Blank: A blank matrix sample to which a known amount of the analyte, usually from a second source, has been added. Used to evaluate methodaccuracy.Method Blank: A blank matrix containing all reagents used in the analytical procedure. Used to identify laboratory contamination.NC (Matrix Spike): The recovery in the matrix spike was not calculated. The relative difference between the concentration in the parent sample and thespiked amount was too small to permit a reliable recovery calculation (matrix spike concentration was less than 2x that of the native sampleconcentration).NC (Duplicate RPD): The duplicate RPD was not calculated. The concentration in the sample and/or duplicate was too low to permit a reliable RPDcalculation (one or both samples < 5x RDL).( 1 ) Recovery or RPD for this parameter is outside control limits. The overall quality control for this analysis meets acceptability criteria.


of 16

Validation Signature Page

Maxxam Job #: B4B4991

The analytical data and all QC contained in this report were reviewed and validated by the following individual(s).

Anna Koksharova, M.Sc., Senior Analyst

Dina Tleugabulova, Ph.D., Scientific Specialist, Inorganics Department

Kelly Gip, B.Sc., Senior Analyst

Sandy Yuan, M.Sc., Scientific Specialist

====================================================================Maxxam has procedures in place to guard against improper use of the electronic signature and have the required "signatories", as per section 5.10.2 ofISO/IEC 17025:2005(E), signing the reports. For Service Group specific validation please refer to the Validation Signature Page.

of 16

certificate of analysis – revised report€¦ · maxxam analytics maxxam job #: b4b4991 report...

Documents