c&f automotive ltd. · 2017-04-26 · smp 2015 c&f automotive ltd solvent management plan...

C&F AUTOMOTIVE LTD T/A IRALCO®

COLLINSTOWN, CO. WESTMEATH, REP. OF IRELAND

TELEPHONE +353 44 96 66600 FAX +353 44 96 66690

Document No: SMP016-C&F

Description:

Solvent Management Plan Report 2016

Revision No

Document purpose Originated Author Date

01 Compliance report C&F Niall Nally

Senior Environmental Officer

24/02/2017

SOLVENT MANAGEMENT PLAN REPORT 2016

FOR

C&F AUTOMOTIVE LTD. IEL licence no: P0690-02

FACILITY AT

COLLINSTOWN, MULLINGAR, CO WESTMEATH

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SMP 2015 C&F Automotive LTD

Solvent Management Plan 2016

Licence No: P0690-02

SMP015-C&F of 15 Version 1

Report Content

1.0 Introduction ………………………………………………………. 3

2.0 Basis and Methodology ………………………………………………………. 6

3.0 Mass Balance and Article Findings …………………………………………. 8

3.1 Inputs and Losses ………………………………………………….. 8

3.2 Annex VII of the Directive …………………………………………..9

3.3 VOCs with Designated Risk Phrases ………………………………. 10

3.4 Halogenated VOCs …………………………………………………11

4.0 Conclusions ……………………………………… 14

Tables:

Table 1: Mass Balance Terminology ………………………………………………………… 7

Table 2: Summary of Mass Balance ……………………………………………………… 8

Table 3: Summary of Itemised Solvent Consumption …………………………………… 9

Table 4: Summary of Solvent Consumption …………………………………………… 10

Table 5: Balance of IPA Consumption……………………………………………………… 11

Table 6: Halogenated VOC with R phrase of R40……………………………………………. 13

Appendices:

Appendix I: Definitions in the Directive

Appendix II: Calculation of Solvent Input

Appendix III: Calculation of Solvent

Output

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1.1 Introduction

This Solvent Management Plan (SMP) is in response to Condition 5.4 of the

licence which states; ‘The total fugitive emissions to air of volatile organic compounds

shall not exceed 25% of total solvent input’.

In addition, Condition 6.17 states ‘The licensee shall maintain a solvent management

plan for the site. The substances to be included in the SMP shall be determined by

reference to the definition of a solvent in the Council Directive 2010/75/EU, and

shall be assessed by the Agency each year. The SMP shall be prepared in

accordance with any relevant guidelines in Annex III of the Directive or as issued

by the Agency and shall be submitted as part of the AER (Annual Environmental

Report).

The Solvent Management Plan was established in accordance with the Directive

2010/75/EU of the European Parliament and of the council of 24 November 2010

on Industrial Emissions.

The aim of the directive is to limit and control emission of volatile organic

compounds to atmosphere. This directive is incorporated into the IEL through

Conditions 5 & 6.

Schedule 1 of S.I. 565 of 2012 outlines two activities that come under the remit of

the directive, namely:

Vehicle Refinishing: Any industrial or commercial coating activity and

associated degreasing activities performing:

(a) the original coating of road vehicles as defined in Directive

2007/46/EC or part of them with refinishing-type materials, where this is

carried out away from the original manufacturing line;

(b) the coating of trailers (including semi-trailers) (category O in Directive

2007/46/EC).

Surface Cleaning: Any activity except dry cleaning using organic solvents

to remove contamination from the surface of material including

degreasing. A cleaning activity consisting of more than one step before or

after any other activity shall be considered as one surface cleaning

activity. This activity does not refer to the cleaning of equipment but the

cleaning of surface products.

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The IE licence stipulates under Condition 5.4 that the company shall not exceed a

25% threshold for fugitive emissions from site reflecting the requirements of S.I.

565 of 2012, Schedule 2.

In terms of risk substances at the facility, the following conditions apply;

Condition 5.5.1 ‘Substances or preparations which, because of their content of

VOCs classified as carcinogens, mutagens or toxic to reproduction under

Regulation (EC) No 1272/2008, are assigned or need to carry the hazard

statements H340, H350, H350i, H360D, H360F, (or the risk phrases R45, R46,

R49, R60 and R61) shall not be used in coating operations at the installation,

without the prior written agreement of the Agency.’

Condition 5.5.2 ‘Substances or preparations which contain halogenated VOCs

which are assigned the hazard statement H351 or Risk Phrase R40 where the usage

rate is such that the mass emission to atmosphere of the sum of the R40 compounds

would exceed 100g/h, shall not be used in coating operations at the installation,


Condition 5.5.3 ‘The licensee shall assess all new VOC containing substances and

preparations employed at the site, prior to use, for compliance with Conditions

5.5.1 and 5.5.2. All such assessments shall be reported annually as part of the AER.

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To assess the site for compliance with these criteria:

Raw Material SDS’s were assessed for inclusion of the hazard statements

H340, H350, H350i, H360D, H360F and/or risk phrases R45, R46, R49, R60

and R61. The only raw materials in use on site with a risk rating outlined

above include:

None used on site

Raw Material SDS’s were assessed for inclusion of H351 and/or R40. The

only raw materials in use on site with a risk rating outlined above include:

BASF Thinner R40 and H351. Constituents were

naphthalene (3 to 5%).

Fuller Primer Anthrazite R40 and H351. Constituents were

naphthalene (0.1 to 0.25%) and formaldehyde (0.1-<0.2%) make-up

of product.

Clearcoat stargloss R40 and H351. Constituents were

naphthalene (0.5 to 1%) and formaldehyde (0.1-<0.2%) make-up of

product.

Standard thinners R40 and H351. Constituents were

tetrahydrofuran (0.5 to 1%) make-up of product.

For the purpose of this plan, the EPA’s Best Practice Guidelines for Surface

Cleaning using Solvents was also used as a reference document for this SMP in

the absence of any specific guidelines for the Part II Activities Licensed.

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2.0 Basis and Methodology

The basis for an SMP is a mass balance, accounting for all inputs and outputs of

organic solvents, as defined in the Solvents Directive. A mass balance identifies

where solvent goes into a process, where it is consumed and where it comes out.

The mass balance approach used in this exercise is that outlined in European

Union (Installation and Activities using Organic Solvents) Regulations 2012,

S.I. 565 of 2012. Reference was also made to guidelines issued by the Agency for

Surface cleaning using solvents.

The following methodology was carried out to determine the quantity of solvents

used on site throughout the calendar year 2015 at the facility:

1. All substances containing VOCs were collated in spreadsheets,

2. MSDS were assessed to determine the concentration of VOC in each

substance,

3. Purchasing details were assessed for each substance,

4. Substances containing VOCs sent off site as hazardous waste were totaled,

5. Emissions to atmosphere were evaluated for the year,

6. A mass balance was carried out for each activity.

Figure 1: Pictorial Display of an SMP Balance

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Table 1: Mass Balance Terminology

Table 1: Mass Balance Terminology and Relevance to C&F Automotive

Inputs of Organic Solvent (I)

I1

The quantity of organic solvents, in a pure

state or in preparations purchased, which are

used as input into the process in the time

frame over which the mass balance is being

calculated.

For the purpose of this plan the mass balance will

be based on purchases during 2016.

I2

The quantity of organic solvents, in a pure

state or in preparations recovered and

reused, as solvent input into the process

Solvents are not reused or recovered on site.

Solvent waste is removed off site for

disposal/recovery and is therefore included in

waste records.

Outputs of Organic Solvent (O)

O1

Emissions in waste gases

Air emissions monitoring were carried out on all

emission points on a quarterly basis for flow and

TOC. This information will be used to estimate total

emissions to air during the year of 2016.

O2

Organic Solvents lost in water, if appropriate

taking into account wastewater treatment

when calculating O5

There are negligible VOCs that could be lost

through this route.

O3

The quantity of organic solvents which

remains as contamination or residue in

products output from the process.

Treated materials are dried in ovens on site at

elevated temperatures which would liberate any

volatile solvent from the products and thus lost as

emissions to air.

O4

Uncaptured emissions of organic solvents to

air. This includes the general ventilation of

rooms, where air is released to the outside

environment via windows, doors, vents and

similar openings.

This information will be estimated based on mass

balance. This is required to be carried out for

compliance with the Solvents Directive and

condition 5.4 of the IEL.

O5

Organic solvents lost due to chemical or

physical reactions including for example

those which are destroyed, e.g. by

incineration or other waste gas or waste

water treatments, or captured e.g. by

adsorption, as long as they are not counted

under O6, O7 or O8.

There was no data available outlining the pre and

post concentrations for organic compounds at the

treatment systems. It is therefore not known the

concentrations of solvent lost through the treatment

process.

O6

Organic solvents contained in collected

waste on-site, i.e. spent paint gun wash

consisting of thinners.

Spent thinners (paint gun wash) collected in

200litre metal drums on-site for off-site disposal

and/or recovery. Waste packaging and solvent

used rags and contain minimal waste solvent

product on disposal. These are weighed on receipt

by the waste management company. Paint sludge

in 200litre drums.

O7

Organic solvents or organic solvents

contained in preparations, which are sold or

are intended to be sold as a commercially

valuable product.

Not Applicable

O8

Organic solvents contained in preparations

recovered for reuse, but not as input into the

process, as long as not counted under O7.

Not Applicable

O9 Organic solvents released in other ways. Not Applicable

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3.1 Mass Balance and Article Compliance

3.2 Inputs and Losses

Table 2: Summary of Mass Balance

Reference Component Total Solvent Content

Kg / Year (TOC as C)

I1 Inputs 15,336

I2 Internal Recycle 0

I Total Input 15,336

O1 Organic Solvent in Waste Gases (Average 2016) 9,347

O2 Organic Solvent Lost in Water 0

O3 Organic Solvent retained on Product <1Note 1

O4 Fugitive Organic Solvent Emissions 2,494Not 2

O5 Wastewater Treatment or Reacted 0Note 3

O6 Collected Waste Solvent (TOC as C for 2016) 3,494Note 4

O7 Solvents Sold Off 0

O8 Recovered Solvent but not Reused 0

O9 Solvents Released in Other ways 0

O Total Output 12,841

U Organic Solvent Over Accounted For 0

Note 1 Products are dried in ovens which would liberate all solvents used.

Note 2 Fugitive Emissions (F) has been calculated from Input – measured outputs, i.e.

F = I1-O1-O5-O6-O7-O8 = 15,336 – 9,347-0-3,494-0-0= 2,494.20 or 16%

Note 3 The license does not require pre and post analysis; therefore there is no detail available on

solvent losses at the treatment systems.

Note 4

Waste disposed of has been converted to an average carbon equivalent based on the

ratios applied in solvent input calculations.

Note 5

The mass balance for this site was estimated for the following reasons:

There is a certain degree of uncertainty from air emissions monitoring as these are only spot

checks carried out four times per year as opposed to continuous analysers. The 4 results

were averaged for all stacks and multiplied by the operating house for an annual emission

value.

The concentrations and flow rates can vary between monitoring sessions, so this does lead

to a degree of inaccuracy when bringing 30 minute samples period up to annual emissions.

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3.3 Annex VII of the Directive

3.3.1 Vehicle Coating (<15) and Vehicle Refinishing

The first scope of activities determined on site was listed under “Vehicle

Refinishing” in Schedule I of the directive:

The original coating of road vehicles as defined in Directive 2007/46/EC, or

part of them, with refinishing type materials, where this is carried out away

from the original manufacturing line.

Table 3 outlines the substances containing VOCs used at C&F Automotive in

this activity.

Table 3: Summary of Itemised Solvent Consumption for coatings

Substance Total

TOC

as C

Consumption

Threshold

Solvent

Consumption

Emission

Limit Value

Fugitive

Emissions

Values

Tonnes / 2016

Tonnes /

Year

mgC/Nm3

% of

Solvent

Input

Standard Thinners 4.467

> 0.5

50

25

Thinner SV13-033 2.060

Brilliant Schwartz 1.074

Primer Antracite 0.828

Clear coat star gloss 1.278

Total Input 9.707

Notes:

1: Compliance with Article 17 should be demonstrated on 15 minute averaging periods.

Solvent consumption in this activity has a threshold of >0.5 tonnes per year as

indicated in Column 3 of Annex VII Part 2 of the Directive. Solvent consumed

in 2016, referenced as carbon, for this activity was determined above the

consumption threshold i.e. 9.707 tonnes and therefore does come under the remit

of the Directive and its associated Regulation S.I. 565 of 2012. The actual

fugitive % for 2016 data is [fugitive emissions 2,494 TOC divided by solvent

input as TOC 15,335.5 = 16%.

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3.3.2 Surface Cleaning

The second scope listed was “Surface Cleaning”, defined as following under the

Directive:

Any activity except dry cleaning using organic solvents to remove

contamination from the surface of material including degreasing. A cleaning

activity consisting of more than one step before or after any other activity shall

be considered as one surface cleaning activity. This activity does not refer to the

cleaning of equipment but the cleaning of surface products.

Table 4 outlines the substances containing VOCs used at C&F Automotive in this

activity.

Table 4: Summary of Solvent Consumption

Substance Total

VOC

Input

Threshold

Solvent

Consumption

Solvent

Consumption

Emission

Limit

Value

Tonnes / 2015 Tonnes /

Year

Tonnes /

Year mgC/Nm3

IPA Consumption

5% of Total IPA Input (9,120kg) to facility

0.456

>11

1 – 51

>51

202

202

Notes:

1: Using compounds specified in Article 5(6) and 5(8)

2: Limit refers to mass of compounds in mg/m3 and not to total carbon

This activity has a threshold of 1 tonne per year which was not exceeded at this

site during 2015. An assessment using compounds specified in Article 5(6) and

(8) was also carried out:

Isopropyl Alcohol is characterised with risk phrases R11 R36 R67, and

therefore does not come under the Risk Phrase specific terms of the Directive.

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3.3.3 Balance of IPA for 2016

The remaining IPA input on site is used for the purposes of machine coolant.

This activity is not covered under the remit of the regulations or the directive.

Table 5: Balance of IPA Consumption

Substance Total

VOC

Input

Threshold

Solvent

Consumption

Solvent

Consumption

Emission

Limit

Value

Tonnes / 2014 Tonnes /

Year

Tonnes /

Year mgC/Nm3

IPA Input Used as Coolant

95% of Total IPA Input to facility

8.664

None applied

N/a

N/a

Notes:

3.4 VOCs with designated Risk Phrases

The Directive deals specifically with risk phrases applied to substances

potentially used on site.

Condition 5.5.1 ‘Substances or preparations which, because of their content of

VOCs classified as carcinogens, mutagens or toxic to reproduction under

Regulation (EC) No 1272/2008, are assigned or need to carry the hazard

statements H340, H350, H350i, H360D, H360F, (or the risk phrases R45, R46,

R49, R60 and R61) shall not be used in coating operations at the installation,


A full review of solvents used on site in 2016 and their respective Material

Safety Data Sheets was carried out.

The were no solvents with the risk phrases mentioned above.

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3.5 Halogenated VOCs

The Solvent Regulations outlines specific requirements for halogenated organic

compounds with a risk phrase of R40.

Condition 5.5.2 ‘Substances or preparations which contain halogenated VOCs

which are assigned the hazard statement H351 or Risk Phrase R40 where the

usage rate is such that the mass emission to atmosphere of the sum of the R40

compounds would exceed 100g/h, shall not be used in coating operations at the

installation, without the prior written agreement of the Agency.’

The compounds used at C&F Automotive were assessed for composition as

classification with R40. The following compound and quantity was used on site

in 2016:

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Table 6: Halogenated VOCs with Risk Phrases of 40

Substance Volume

of

Product

kg

R40

Constituent

Average

VOC

Content

%

2016

Usage

Kg/yr

Estimated

Sum of

Daily

Usage

Directive

Threshold

Primer

Naphthalene

0.175

6.426

Anthracite 3,672

Formaldehyde 0.150 5.508

79.160 100

Thinner

2,605

Naphthalene

4

104.2

g/hour g/hour

Clearcoat

star gloss

3,240

Naphthalene

Formaldehyde

0.750

0.150

24.30

4.860

Standard

thinners

6,200

Tetrahydrofuran

0.50

13.025

The estimated daily usage is based on 2000 hours of operation per year (attained from air

emissions operating times in 2016).

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4.1 Conclusions

Two activities as per Schedule I of the Regulations (SI 565 of 2012) were

carried out at C&F Automotive, namely Surface cleaning and Vehicle

Coating (or parts thereof);

There were a total of 8 raw materials used on site that contributed solvent

into process activities;

The total input of solvent into the process in 2016 was 15,335.5 Kgs

(Referenced as Carbon);

The estimated air emissions of solvent was 9,347 Kgs (Referenced as

Carbon),

The calculated fugitive emissions from site were 2,494.1 kg, which is

approximately 16%. The licence limit for fugitive emissions for the site is

25%.

Most of the remaining solvent was disposed of as waste solvent 3,494.4 kg

(Referenced as Carbon);

Three raw materials; BASF thinner, Primer Anthracite, Clearcoat star

gloss and standard thinners contains Naphthalene and/or Formaldehyde,

tetrahydrofuran which have a Risk Phrase of R40. The sum of the volumes

of raw materials used were within the threshold outlined by condition 5.5.2

of the license insofar as the limit of 100g/hour was not exceeded.

Under the activity “surface cleaning”, the only product used was IPA. The

solvent content used in 2016 was well within the thresholds outlined in

Schedule 2 of SI 565 of 2012.

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Appendix I Definitions of the Directive

Organic Compound Organic Compound shall mean any compound containing at

least the element carbon and one or more of hydrogen,

halogens, oxygen, sulphur, phosphorous, silicon or nitrogen,

with the exception of carbon oxides and inorganic carbonates

and bi-carbonates.

Volatile

Organic

Compounds

VOC shall mean any organic compound having at 293.15 K a

vapour pressure of 0.01 kPa or more, or having a corresponding

volatility under the particular conditions of use. For the purpose

of this Directive, the fraction of creosote which exceeds this

value of vapour pressure at 293.15 K shall be considered as a

VOC.

Organic Solvent An organic solvent is a VOC which is used alone or in

combination with other agents, and without undergoing a

chemical change, to dissolve raw materials, products or waste

materials or is used as a cleaning agent to dissolve

contaminants, or as a dissolver, or as a dispersion medium or as

a viscosity adjuster, or as a surface tension adjuster, or as a

plasticizer, or as a preservative.

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Appendix II - Solvent Input Calculations.

Substance Constituents CAS No. Molecul

ar Formula

Mean Compositi

on %

Molar Mass

Carbon Molar Mass

No. of atoms

No of Carbon atoms

Molar Mass of

Carbon in substance

Solvent Input 2016

kg

Solvent (TOC as C Input) kg 2016

Primer anthracite Xylene 1330-20-7 C8H10 7.500% 106 12 18 8 96 275.40 249.42

Butan-1-ol 71-36-3 C4H10O 6.000% 74 12 15 4 48 220.32 142.91

Epoxy resin 25036-25-3

C18H22O3 10.500% 286 12 43 18 216 385.56 291.19

Solvent naptha (Petroleum) heavy aromatic

64742-94-5 C9 1.375% - 12 - 9 108 50.49 41.31

Solvent naptha (Petroleum) light aromatic

64742-95-6 C9 1.375% - 12 - 9 108 50.49 41.31

Ethyl benzene 100-41-4 C8H10 1.500% 106 12 18 8 96 55.08 49.88

Napthalene 91-20-3 C10H8 0.175% 128 12 18 10 120 6.43 6.02

Naptha (petroleum) hydrosulferized heavy

64742-82-1 C6H14 0.125% 86 12 20 6 72 4.59 3.84

Formaldehyde 50-00-0 CH2O 0.150% 30 12 4 1 12 5.51 2.20

Total 1,053.86 828.10

Brillintschwarz N-butyl acetate 123-86-4 C6H12O2 22.500% 116 12 20 6 72 611.78 379.72

Xylene 1330-20-7 C8H10 16.250% 106 12 18 8 96 441.84 400.15

Butan-1-ol 71-36-3 C4H10O 6.000% 74 12 15 4 48 163.14 105.82

2-methoxy-1-methylethyl acetate 108-65-6

C6H12O3 3.000% 132 12 21 6 72 81.57 44.49

[3-(2,3-epoxypropoxy) propyl] trimethoxysilane, Naphtha (petroleum), hydrotreated light 2530-83-8

C9H20O5Si 3.750% 230 12 35 9 108 101.96 47.88

Ethyl benzene 100-41-4 C8H10 1.500% 106 12 18 8 96 40.79 36.94

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2-(2-butoxyethoxy) ethanol 112-34-5

C8H18O3 3.000% 162 12 29 8 96 81.57 48.34

Butyl glycollate 7397-62-8 C6H12O3 0.750% 132 12 21 6 72 20.39 11.12

Total 1,543.03 1,074.47

Isopropyl alcohol Isopropyl alcohol 67-63-0 C3H8O 100.000% 60 12 12 3 36 9,120.00 5472.00

Total 9,120.00 5,472.00

Thinner sv13-0333 Ethyl benzene 100-41-4 C8H10 3.500% 106 12 18 8 96 91.18 82.57

Xylene 1330-20-7 C8H10 22.500% 106 12 18 8 96 586.13 530.83

Mesitylene 108-67-8 C9H12 2.000% 120 12 21 9 108 52.10 46.89

1,2,4-trimethylbenzene 95-63-6 C9H12 8.500% 120 12 21 9 108 221.43 199.28

Butan-1-ol 71-36-3 C4H10O 11.000% 74 12 15 4 48 286.55 185.87

N-butyl acetate 123-86-4 C6H12O2 8.000% 116 12 20 6 72 208.40 129.35

Solvent naphta (heavy)

64742-94-5 C9 27.000% 12 9 108 703.35 575.47

Solvent naphta (light)

64742-95-6 C9 8.500% 12 9 108 221.43 181.17

Napthalene 91-20-3 C10H8 4.000% 128 12 18 10 120 104.20 86.83

N-propylbenzene 103-65-1 C9H12 2.000% 120 12 21 9 108 52.10 42.63

Total 2,526.85 2,060.89

Clearcoat stargloss 5910 Xylene 1330-20-7 C8H10 1.500% 106 12 18 8 96 48.60 44.02

N-propylbenzene 103-65-1 C9H12 1.500% 120 12 21 9 108 48.60 43.74

Mesitylene 108-67-8 C9H12 2.250% 120 12 21 9 108 72.90 65.61

1,2,4-trimethylbenzene 95-63-6 C9H12 8.500% 120 12 21 9 108 275.40 247.86

Napthalene 91-20-3 C10H8 0.750% 128 12 18 10 120 24.30 22.78

Butan-1-ol 71-36-3 C4H10O 8.500% 74 12 15 4 48 275.40 178.64

Butyl diglycol 112-43-5 C8H18O3 2.250% 258 12 29 8 96 72.90 27.13

Formaldehyde 50-00-0 CH2O 0.150% 30 12 4 1 12 4.86 1.94

N-butylacetate 123-86-4 C6H12O2 4.000% 116 12 20 6 72 129.60 80.44

Hydroxyphenyl-alkylbenzotriazole

127519-17-9

C27H39N3O3 0.400% 495 12 72 27 324 12.96 8.48

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Methyl 1,2,2,6,6 pentamethyl-4-piperidyl sebacate

82919-37-7

C21H39N04 0.150% 363 12 65 21 252 4.86 3.37

Isopropylbenzene 98-82-8 C9H12 1.500% 120 12 21 9 108 48.60 43.74

Bis-(1,2,2,6,6-pentamethyl-4-piperidinyl)-sebacate

41556-26-7

C30H56N2O4 0.400% 536 12 92 30 360 12.96 8.70

O-xylene 95-47-6 C8H10 1.500% 106 12 18 8 96 48.60 44.02

Solvent naptha (Petroleum) heavy aromatic

64742-94-5 C9 6.000% - 12 - 9 108 194.40 159.05

Solvent naptha (Petroleum) light aromatic

64742-95-6 C9 11.250% - 12 - 9 108 364.50 298.23

Total 1,639.44 1,277.75

Standard Thinner Acetone 67-64-1 C3H6O 15.000% 58 12 10 3 36 930.00 577.24

Ethyl acetate 141-78-6 C4H802 2.500% 88 12 14 4 48 155.00 84.55

Toluene 108-88-3 C7H8 15.000% 92 12 15 7 84 930.00 849.13

MIBK 108-10-1 C6H12O 2.000% 100 12 19 6 72 124.00 89.28

Propan-2-ol 67-63-0 C3H8O 7.500% 50 12 12 3 36 465.00 334.80

Tetrahydrofuran 109-99-9 C4H8O 0.500% 72 12 13 4 48 31.00 20.67

Xylene 1330-20-7 C8H10 7.500% 106 12 18 8 96 465.00 421.13

Heptane 142-82-5 C7H16 15.000% 100 12 23 7 84 930.00 781.20

Butan-1-ol 71-36-3 C4H10O 2.000% 74 12 15 4 48 124.00 80.43

N-butylacetate 123-86-4 C6H12O2 2.500% 116 12 20 6 72 155.00 96.21

Cyclohexane 100-82-7 C6H12 7.500% 84 12 18 6 72 465.00 398.57

Ethanol 64-17-5 C2H5OH 7.000% 46 12 9 2 24 434.00 226.43

Ethyl benzene 100-41-4 C8H10 5.000% 106 12 18 8 96 310.00 280.75

Methyl Acetate 79-20-9 C3H6O2 6.000% 74 12 11 3 36 372.00 180.97

Methanol 67-56-1 C1H3OH 2.000% 32 12 6 1 12 124.00 46.50

Total 6,014.00 4,467.87

Boiling additive

2-(2-butoxyethoxy) ethyl acetate 124-17-4

C10H20O4 99.770% 204 12 34 10 120 119.72 70.43

Dualion M8V2 N-propanol 23519-77-9 C3H8O 20.000% 60 12 12 3 36 140.00 84.00

259.72 154.43

Overall Total 22,156.91 15,335.5

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Appendix III - Solvent Output Calculations

TOC as C

result 2016

Average

mass flows

kg

Operating

hours

Mass flow

per annum

kg

Emission

point Parameter Unit Q1 Q2 Q3 Q4

A2-1 TOC (as C) mg/m3 7 4 16 3

Vol flow Nm3/hr 3,846 3,537 3,651 3,771

Mass flow per hr kg/hr 0.028 0.015 0.058 0.011 0.028 2,880 80.5

A2-2 TOC (as C) mg/m3 36 2 9 9

Vol flow Nm3/hr 17,114 15,667 14,938 26,555


A2-3 TOC (as C) mg/m3 10 4 5 5

Vol flow Nm3/hr 2,824 6,059 5,457 3,076


A2-4 TOC (as C) mg/m3 29 95 98 34

Vol flow Nm3/hr 1,597 1,032 1,075 608


A2-5 TOC (as C) mg/m3 40 13 36 86

Vol flow Nm3/hr 1,353 1,280 1,299 1,116


A2-6 TOC (as C) mg/m3 22 3 53 55

Vol flow Nm3/hr 23,189 35,590 36,558 35,110

Mass flow per hr kg/hr 0.518 0.123 1.935 1.937 1.128 1,920 2,166.1

A2-7 TOC (as C) mg/m3 20 4 11 18

Vol flow Nm3/hr 4,014 4,019 4,034 5,599


A2-8 TOC (as C) mg/m3 30 2 2 43

Vol flow Nm3/hr 17,916 29,738 30,791 30,201


A2-9 TOC (as C) mg/m3 45 33 35 21

Vol flow Nm3/hr 2,988 6,754 6,415 5,707


A2-10 TOC (as C) mg/m3 50 16 134 135

Vol flow Nm3/hr 1,300 921 870 575


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A2-11 TOC (as C) mg/m3 41 5 11 134

Vol flow Nm3/hr 1,407 500 573 1,159


A2-12 TOC (as C) mg/m3 45 27 34 33

Vol flow Nm3/hr 1,862 1,660 1,692 1,993


A2-14 TOC (as C) mg/m3 4 9 12 10

Vol flow Nm3/hr 16,396 16,827 14,617 14,028


A2-15 TOC (as C) mg/m3 16 12 9 10

Vol flow Nm3/hr 14,710 14,809 17,878 17,976

Mass flow per hr kg/hr 0.235 0.183 0.156 0.185 0.190 5,760 1,091.7

A2-16 TOC (as C) mg/m3 16 11

Vol flow Nm3/hr 21,476 21,592

Mass flow per hr kg/hr 0.339 0.239 0.000 0.193 5,760 1,110.4

A2-17 TOC (as C) mg/m3 10 6 10 12

Vol flow Nm3/hr 9,630 10,798 8,021 8,589


A2-18 TOC (as C) mg/m3 0 0 14 14

Vol flow Nm3/hr 0 0 4,916 4,811


A2-19 TOC (as C) mg/m3 13 11 18 17

Vol flow Nm3/hr 11,073 11,093 11,153 9,754


A2-21 TOC (as C) mg/m3 14.000 2.000 5.920 9

Vol flow Nm3/hr 2101.000 2518.000 3422.000 3492


A2-23 TOC (as C) mg/m3 43 415 52 17

Vol flow Nm3/hr 551 588 658 679


A2-25 TOC (as C) mg/m3 21.000 19.000 9.000 18.960

Vol flow Nm3/hr 2005.000 2336.000 2052.000 2336.000


A2-13 TOC (as C) mg/m3 5

Vol flow Nm3/hr 4,149

Mass flow per hr kg/hr 0.021 0.021 480 10.0

Total Mass Flow per annum (O1) 9,347.0

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Waste table of solvent related items (O6)

EWC code Quantity (kg) % carbon TOC as C lost Waste description

14 06 03 5914 56% 3312 Waste Solvent

08 01 13 2870 2.5% 71.8 Sludges from Paint

15 01 10 1495 3% 25.1 Containers used for

solvents/VOcs

15 02 02 3427 2.5% 85.7 Waste Rags & absorbents

Total VOC as Carbon in Waste 3,494 kg

Note: sludges is estimated using 2.5% which is a conservative %

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c&f automotive ltd. · 2017-04-26 · smp 2015 c&f automotive ltd solvent management plan...

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