ch 21 intro to met.ppt
TRANSCRIPT
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Metamorphic Petrology
Fresh basalt
weathered basalt
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The Limits of Metamorphism
• Low-temperature limit grades into diagenesis
• Diagenesis is a change in form that occurs in sedimentary
rocks. In geology, however, we restrict diagenetic
processes to those which occur at temperatures below
200o
C and pressures below about 300 MPa (MPa stands for Mega Pascals), this is equivalent to about 3,000
atmospheres of pressure.
Processes are indistinguishable
Metamorphism begins in the range of 100-150oC for the
more unstable types of protolith
Some zeolites are considered diagenetic and others
metamorphic – pretty arbitrary
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• Metamorphism, therefore occurs at temperatures
and pressures higher than 200oC and 300
MPa. Rocks can be subjected to these higher
temperatures and pressures as they become
buried deeper in the Earth. Such burial usually
takes place as a result of tectonic processes such
as continental collisions or subduction.
• The upper limit of metamorphism occurs at the
pressure and temperature of wet partial meltingof the rock in question. Once melting begins,
the process changes to an igneous process rather
than a metamorphic process.
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Metamorphic Agents and Changes
• Temperature: typically the
most important factor in
metamorphism
Figure 1-9. Estimated ranges of oceanic and
continental steady-state geotherms to a depth of
100 km using upper and lower limits based on heat
flows measured near the surface. After Sclater etal. (1980), Earth. Rev. Geophys. Space Sci., 18,
269-311.
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Metamorphic Agents and Changes
Increasing temperature has several effects Promotes recrystallization increased grain size
Larger surface/volume ratio of a mineral lower
stability Increasing temperature eventually overcomes kinetic
barriers to recrystallization, and fine aggregates coalesce
to larger grains
• Especially for fine-grained and unstable materials in a
static environment (shear stresses often reduce grain size)
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2) Drive reactions (endothermic)
Heating to conditions outside the stability
range of some mineral(s) may cause a reaction to take place that consumes the unstable
mineral(s) and produces new minerals that are
stable under the new conditions 3) Overcomes kinetic barriers
Disequilibrium is relatively common in sediments and
diagenesis
Mineral assemblages are usually simpler at higher
grades and the phase rule is applicable
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Metamorphic Agents and Changes
• Pressure
“Normal” gradients may be perturbed in several
ways, typically:
High T/P geotherms in areas of plutonicactivity or rifting
Low T/P geotherms in subduction zones
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Figure 21-1. Metamorphic field gradients (estimated P-T conditions along surface traverses directly up metamorphic grade) forseveral metamorphic areas. After Turner (1981). Metamorphic Petrology: Mineralogical, Field, and Tectonic Aspects. McGraw-
Hill.
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Metamorphic Agents and Changes
• Metamorphic grade:
• As the temperature and/or pressure increases on a body
of rock we say that the rock undergoes progrademetamorphismor that the grade of metamorphism
increases. Metamorphic gradeis a general term for
describing the relative temperature and pressure
conditions under which metamorphic rocks form, such asthose depicted in metamorphic field gradients.
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Four Divisions of Grade are recognized:
Very low gradeLow grade
Medium grade
High grade
The boundaries between the four divisions of grade are
marked by significant changes of mineral assemblages in
common rocks, corresponding with specific mineral reactions.
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Examples of hydrous minerals that occur in low
grade metamorphic rocks:
Clay MineralsSerpentine
Chlorite
High-grade metamorphism takes place at
temperatures greater than 320oC and relatively high
pressure. As grade of metamorphism increases,
hydrous minerals become less hydrous, by losing
H2O and non-hydrous minerals become morecommon.
Examples of less hydrous minerals and non-hydrous
minerals that characterize high grade metamorphic
rocks:
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Muscovite - hydrous mineral that eventually disappears at
the highest grade of metamorphism
Biotite - a hydrous mineral that is stable to very high
grades of metamorphism.
Pyroxene - a non hydrous mineral.
Garnet - a non hydrous mineral.
• Retrograde Metamorphism
• As temperature and pressure fall due to erosion
of overlying rock or due to tectonic uplift, one
might expect metamorphism to a follow a
reverse path and eventually return the rocks totheir original unmetamorphosed state. Such a
process is referred to as retrograde
metamorphism.
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• If retrograde metamorphism were common, we
would not commonly see metamorphic rocks at
the surface of the Earth. Since we do see
metamorphic rocks exposed at the Earth's
surface retrograde metamorphism does not
appear to be common. The reasons for this
include:• chemical reactions take place more slowly as
temperature is decreased
• during prograde metamorphism, fluids such asH2O and CO2 are driven off, and these fluids are
necessary to form the hydrous minerals that are
stable at the Earth's surface.
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Metamorphic Agents and Changes
• Stress • Strain deformation
• Deviatoric stress affects the textures and
structures, but not the equilibrium mineralassemblage
• Strain energy may overcome kinetic barriers to
reactions
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• Metamorphic Agents and Changes
• Metamorphism occurs because some minerals are stableonly under certain conditions of pressure and
temperature. When pressure and temperature change,
chemical reactions occur to cause the minerals in the rock
to change to an assemblage that is stable at the new pressure and temperature conditions. But, the process is
complicated by such things as how the pressure is applied,
the time over which the rock is subjected to the higher
pressure and temperature, and whether or not there is afluid phase present during metamorphism.
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• TemperatureTemperature increases with depth in the Earth along
the Geothermal Gradient. Thus higher temperature can
occur by burial of rock.
• Temperature can also increase due to igneous intrusion.
• Pressure increases with depth of burial, thus, both
pressure and temperature will vary with depth in the
Earth. Pressure is defined as a force acting equally
from all directions.
• Lithostatic pressure is uniform stress (hydrostatic)
• Deviatoric stress = unequal pressure in different
directions
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• Resolved into three mutually perpendicular stress
(s) components:
s1 is the maximum principal stresss2 is an intermediate principal stress
s3 is the minimum principal stress
• In hydrostatic situations all three are equal
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• If differential stress is present during
metamorphism, it can have a profound effect
on the texture of the rock.
• rounded grains can become flattened in the
direction of maximum stress.
• minerals that crystallize or grow in the
differential stress field can have a preferred
orientation. This is especially true of the sheet
silicate minerals (the micas: biotite and
muscovite, chlorite, talc, and serpentine).
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• In Tension s1 is negative, and the resultant strain is
extension, or pulling apart.
• In Compression one stress direction(s1 ) is dominant,
which may cause folding or a more homogeneous deformation
called flattening. The general term for a planar texture or
structure is called Foliation. Lineation is the non-genetic term
that refers to such a parallel alignment of elongated features.
• Shear is an alternative response to compression in whichmotion occurs along a set of planes at an angle to s1 , like
pushing the top of a deck of cards.
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• Foliation is a common result, which allows us to
estimate the orientation of s1
s
1
> s2
= s3
foliation and no lineation
s1 = s2 > s3 lineation and no foliation
s1 > s2 > s3 both foliation and lineation
Figure 21-3. Flattening of a ductile homogeneous sphere (a) containing randomly oriented flat disks or flakes. In (b), the matrix
flows with progressive flattening, and the flakes are rotated toward parallelism normal to the predominant stress. Winter
(2001) An Introduction to Igneous and Metamorphic Petrology. Prentice Hall.
s1
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Metamorphic Agents and Changes
Shear motion occurs along planes at an angle to s1
Figure 21-2. The three main types of deviatoric stress with an example of possible resulting structures. b. Shear, causing slip
along parallel planes and rotation. Winter (2001) An Introduction to Igneous and Metamorphic Petrology. Prentice Hall.
s1
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• Fluid Phase - Any existing open space between
mineral grains in a rocks can potentially contain a
fluid. This fluid is mostly H2O, but contains dissolvedmineral matter. The fluid phase is important because
chemical reactions that involve one solid mineral
changing into another solid mineral can be greatly
speeded up by having dissolved ions transported by thefluid. Within increasing pressure of metamorphism,
the pore spaces in which the fluid resides is reduced,
and thus the fluid is driven off. Thus, no fluid will be
present when pressure and temperature decrease and, asdiscussed earlier, retrograde metamorphism will be
inhibited.
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Metamorphic Agents and Changes
FluidsEvidence for the existence of a metamorphic fluid:
Fluid inclusions
Fluids are required for hydrous or carbonate phases
Volatile-involving reactions occur at
temperatures and pressures that require finitefluid pressures
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• Time - The chemical reactions involved in
metamorphism, along with recrystallization, and
growth of new minerals are extremely slow
processes. Laboratory experiments suggest that
the longer the time available for metamorphism,
the larger are the sizes of the mineral grains produced. Thus, coarse grained metamorphic
rocks involve long times of
metamorphism. Experiments suggest that thetime involved is millions of years.
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Metamorphic Agents and Changes
• Pfluid
is the sum of the partial pressures of
each component (Pfluid = pH2O + pCO2 + …)
• Mole fractions of the components, which
must sum to 1.0 (XH2O + XCO2 + … = 1.0) • Gradients in T, P, Xfluid
• Zonation in mineral assemblages
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The Types of Metamorphism
Different approaches to classification
1. Based on principal process or agent
Dynamic Metamorphism
Thermal Metamorphism Dynamo-thermal Metamorphism
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The Types of Metamorphism Different approaches to classification
2. Based on setting Contact Metamorphism
Pyrometamorphism
Regional Metamorphism Orogenic Metamorphism
Burial Metamorphism
Ocean Floor Metamorphism Hydrothermal Metamorphism
Fault-Zone Metamorphism
Impact or Shock Metamorphism
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Contact Metamorphism
• Adjacent to igneous intrusions• Thermal (± metasomatic) effects of hot magma
intruding cooler shallow rocks
• Occurs over a wide range of pressures, including
very low
• Contact aureole
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The Types of Metamorphism
Contact Metamorphism
The size and shape of an aureole is controlled by:
The nature of the pluton
The nature of the country rocks
Size
Shape
Orientation
Temperature
Composition
Composition Depth and metamorphic grade prior to intrusion
Permeability
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The Types of Metamorphism
Contact Metamorphism
Most easily recognized where a pluton is introduced into
shallow rocks in a static environment
Hornfelses (granofelses) commonly with relict
textures and structures
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The Types of Metamorphism
Contact Metamorphism
Polymetamorphic rocks are common, usually
representing an orogenic event followed by a
contact one
• Spotted phyllite (or slate)
• Overprint may be due to:
Lag time for magma migration
A separate phase of post-orogenic collapse
magmatism
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The Types of Metamorphism
Pyrometamorphism
Very high temperatures at very low pressures,
generated by a volcanic or subvolcanic body
Also developed in xenoliths
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The Types of Metamorphism
Regional Metamorphism sensu lato: metamorphism
that affects a large body of rock, and thus covers agreat lateral extent
Three principal types:
Orogenic metamorphism
Burial metamorphism
Ocean-floor metamorphism
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The Types of Metamorphism
Orogenic Metamorphism is the type of metamorphism
associated with convergent plate margins
• Dynamo-thermal: one or more episodes of
orogeny with combined elevated geothermal
gradients and deformation (deviatoric stress)• Foliated rocks are a characteristic product
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The Types of Metamorphism
Orogenic
Metamorphism
Figure 21-6. Schematic model for
the sequential (a c) development
of a “Cordilleran-type” or active
continental margin orogen. The
dashed and black layers on the
right represent the basaltic and
gabbroic layers of the oceanic
crust. From Dewey and Bird (1970)
J . Geophys. Res., 75, 2625-2647;
and Miyashiro et al. (1979)
Orogeny. John Wiley & Sons.
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The Types of Metamorphism
Orogenic Metamorphism
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The Types of Metamorphism
Orogenic Metamorphism
• Polymetamorphic patterns
• Continental collision
• Batholiths are usually present in the highest grade areas
• If plentiful and closely spaced, may be called regional
contact metamorphism
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The Types of Metamorphism
Burial metamorphism
• Southland Syncline in New Zealand: thick pile (> 10 km)
of Mesozoic volcaniclastics
• Mild deformation, no igneous intrusions discovered
• Fine-grained, high-temperature phases, glassy ash: very
susceptible to metamorphic alteration
• Metamorphic effects attributed to increased temperatureand pressure due to burial
• Diagenesis to the formation of zeolites, prehnite,
pumpellyite, laumontite, etc.
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The Types of Metamorphism
Hydrothermal metamorphism • Hot H2O-rich fluids
• Usually involves metasomatism
• Difficult type to constrain: hydrothermal effectsoften play some role in most of the other types of
metamorphism
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The Types of Metamorphism
Burial metamorphism occurs in areas that have not
experienced significant deformation or orogeny
• Restricted to large, relatively undisturbed
sedimentary piles away from active plate margins
The Gulf of Mexico?
Bengal Fan?
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The Types of Metamorphism
Ocean-Floor Metamorphism affects the oceanic
crust at ocean ridge spreading centers
• Considerable metasomatic alteration, notably loss
of Ca and Si and gain of Mg and Na
• Highly altered chlorite-quartz rocks- distinctive
high-Mg, low-Ca composition
• Exchange between basalt and hot seawater • Another example of hydrothermal metamorphism
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The Types of Metamorphism
Impact metamorphism at meteorite (or other
bolide) impact craters
Both correlate with dynamic metamorphism,
based on process
Fault-Zone and Impact Metamorphism
High rates of deformation and strain with only
minor recrystallization
• If the strain is high enough and the temperature
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If the strain is high enough, and the temperature
low enough, minerals may be broken, bent or
crushed without much accompanying
recrystallization. This processes is known as“Cataclasis” , and occurs at impacts and in the
very shallow portions of the fault zones where
rocks behave in a very brittle fashion.
• Common products in shallow fault zones are
“Fault Breccia (a broken and crushed filling infault zones)” and “Fault Gouge (a clayey alteration
of breccia resulting from interaction with
groundwater that permeates down along the
”
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• With increased depth, faults gradually change
from brittle fractures to wider shear zones
involving a combination of catalysis and
recrystallization. Intense localized shear
produces a fine-grained foliated flint-like rock
called “Mylonite”.
• At deeper level yet, shear movement is
distributed more evenly throughout the zone,and the rocks are almost entirely ductile.
( ) Sh ll f l
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(a) Shallow fault
zone with fault
breccia
(b) Slightly deeper
fault zone (exposed
by erosion) with
some ductile flowand fault mylonite
Figure 21-7. Schematic cross
section across fault zones. After
Mason (1978) Petrology of theMetamorphic Rocks. George Allen
& Unwin. London.
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Prograde Metamorphism
• Prograde: increase in metamorphic grade with time
as a rock is subjected to gradually more severe
conditions
Prograde metamorphism: changes in a rock that
accompany increasing metamorphic grade
• Retrograde: decreasing grade as rock cools and
recovers from a metamorphic or igneous event
Retrograde metamorphism: any accompanyingchanges
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The Progressive Nature of Metamorphism
• A rock at a high metamorphic grade probably progressed through a sequence of mineral
assemblages rather than hopping directly from an
unmetamorphosed rock to the metamorphic rock that we find today
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The Progressive Nature of Metamorphism
Retrograde metamorphism typically of minor
significance
• Prograde reactions are endothermic and easily
driven by increasing T
• Devolatilization reactions are easier than
reintroducing the volatiles
• Geothermometry indicates that the mineral
compositions commonly preserve the maximum
temperature
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Types of Protolith
Lump the common types of sedimentary and igneous
rocks into six chemically based-groups
1. Ultramafic - very high Mg, Fe, Ni, Cr
2. Mafic - high Fe, Mg, and Ca
3. Shales (pelitic) - high Al, K, Si
4. Carbonates- high Ca, Mg, CO2
5. Quartz - nearly pure SiO2.6. Quartzo-feldspathic - high Si, Na, K, Al
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Why Study Metamorphism?
• Interpretation of the conditions and evolution of
metamorphic bodies, mountain belts, and ultimately the
state and evolution of the Earth's crust
• Metamorphic rocks may retain enough inherited
information from their protolith to allow us to interpretmuch of the pre-metamorphic history as well
Orogenic Regional Metamorphism of
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Orogenic Regional Metamorphism of
the Scottish Highlands
• George Barrow (1893, 1912)
• SE Highlands of Scotland - Caledonian Orogeny
~ 500 Ma
• Nappes
• Granites
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Barrow’s
Area
Figure 21-8. Regional metamorphic
map of the Scottish Highlands,
showing the zones of minerals that
develop with increasing
metamorphic grade. From Gillen
(1982) Metamorphic Geology. AnIntroduction to Tectonic andMetamorphic Processes. George
Allen & Unwin. London.
Orogenic Regional Metamorphism of
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Orogenic Regional Metamorphism of
the Scottish Highlands
• Barrow studied the pelitic rocks
• Could subdivide the area into a series of
metamorphic zones, each based on the appearance
of a new mineral as metamorphic grade increased
The sequence of zones now recognized and the typical
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The sequence of zones now recognized, and the typical
metamorphic mineral assemblage in each, are:
Chlorite zone. Pelitic rocks are slates or phyllites and typically
contain chlorite, muscovite, quartz and albite
Biotite zone. Slates give way to phyllites and schists, with biotite,
chlorite, muscovite, quartz, and albite
Garnet zone. Schists with conspicuous red almandine garnet,
usually with biotite, chlorite, muscovite, quartz, and albite or oligoclase
Staurolite zone. Schists with staurolite, biotite, muscovite, quartz,
garnet, and plagioclase. Some chlorite may persist
Kyanite zone. Schists with kyanite, biotite, muscovite, quartz,
plagioclase, and usually garnet and staurolite
Sillimanite zone. Schists and gneisses with sillimanite, biotite,
muscovite, quartz, plagioclase, garnet, and perhaps staurolite.
Some kyanite may also be present (although kyanite and
sillimanite are both polymorphs of Al2SiO5)
• Sequence = “Barrovian zones”
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• Sequence = Barrovian zones
• The P-T conditions referred to as “Barrovian-type”
metamorphism (fairly typical of many belts)
• Now extended to a much larger area of the Highlands
• Isograd = line that separates the zones (a line in the field
of constant metamorphic grade)
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Figure 21-8. Regional
metamorphic map of the
Scottish Highlands, showing
the zones of minerals that
develop with increasingmetamorphic grade. From
Gillen (1982) MetamorphicGeology. An Introduction to
Tectonic and MetamorphicProcesses. George Allen &
Unwin. London.
To summarize:
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To summarize:
• An isograd represents the first appearance of a particular
metamorphic index mineral in the field as one progressesup metamorphic grade
• When one crosses an isograd, such as the biotite isograd,
one enters the biotite zone
• Zones thus have the same name as the isograd that forms
the low-grade boundary of that zone
• Because classic isograds are based on the first appearanceof a mineral, and not its disappearance, an index mineral
may still be stable in higher grade zones
A variation occurs in the area just to the north of
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A variation occurs in the area just to the north of
Barrow’s, in the Banff and Buchan district
• Pelitic compositions are similar, but the sequenceof isograds is:
chlorite
biotite cordierite
andalusite
sillimanite
The stability field of andalusite occurs at pressures less than
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0.37 GPa (~ 10 km), while kyanite sillimanite at the
sillimanite isograd only above this pressure
Figure 21-9. The P-T phase diagram for the system Al2SiO5 showing the stability fields for the three polymorphs andalusite, kyanite, and
sillimanite. Also shown is the hydration of Al2SiO5 to pyrophyllite, which limits the occurrence of an Al2SiO5 polymorph at low grades inthe presence of excess silica and water. The diagram was calculated using the program TWQ (Berman, 1988, 1990, 1991).
Regional Burial Metamorphism
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Regional Burial Metamorphism
Otago, New Zealand
• Jurassic graywackes, tuffs, and volcanics in a deeptrough metamorphosed in the Cretaceous
• Fine grain size and immature material is highly
susceptible to alteration (even at low grades)
Regional Burial Metamorphism
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Otago, New Zealand Section X-Y shows more detail
Figure 21-10. Geologic sketch map of the South Island of
New Zealand showing the Mesozoic metamorphic rocks east
of the older Tasman Belt and the Alpine Fault. The Torlese
Group is metamorphosed predominantly in the prehnite-
pumpellyite zone, and the Otago Schist in higher grade
zones. X-Y is the Haast River Section of Figure 21-11. From
Turner (1981) Metamorphic Petrology: Mineralogical, Field,and Tectonic Aspects. McGraw-Hill.
Regional Burial Metamorphism
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Regional Burial Metamorphism
Otago, New Zealand
Isograds mapped at the lower grades:1) Zeolite
2) Prehnite-Pumpellyite
3) Pumpellyite (-actinolite)4) Chlorite (-clinozoisite)
5) Biotite
6) Almandine (garnet)7) Oligoclase (albite at lower grades is replaced by a
more calcic plagioclase)
Regional Burial Metamorphism
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Regional Burial Metamorphism Figure 21-11. Metamorphic zones of the Haast
Group (along section X-Y in Figure 21-10).
After Cooper and Lovering (1970) Contrib.
Mineral. Petrol., 27, 11-24.
Paired Metamorphic Belts of Japan
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Paired Metamorphic Belts of Japan
Figure 21-12. The Sanbagawa and Ryoke
metamorphic belts of Japan. From Turner
(1981) Metamorphic Petrology:Mineralogical, F ield, and Tectonic Aspects.McGraw-Hill and Miyashiro (1994)
Metamorphic Petrology. Oxford University
Press.
P i d M t hi B lt f J
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Paired Metamorphic Belts of Japan
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Figure 21-13. Some of the
paired metamorphic belts
in the circum-Pacific
region. From Miyashiro
(1994) MetamorphicPetrology. Oxford
University Press.
Contact Metamorphism of Pelitic Rocks
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Contact Metamorphism of Pelitic Rocks
in the Skiddaw Aureole, UK
• Ordovician Skiddaw Slates (English Lake District)
intruded by several granitic bodies
• Intrusions are shallow
• Contact effects overprinted on an earlier low-grade
regional orogenic metamorphism
Contact Metamorphism of Pelitic Rocks
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Contact Metamorphism of Pelitic Rocks
in the Skiddaw Aureole, UK
• The aureole around the Skiddaw granite was sub-
divided into three zones, principally on the basis of
textures:
Unaltered slates
Outer zone of spotted slates
Middle zone of andalusite slates
Inner zone of hornfels
Skiddaw granite
Increasing
Metamorphic
Grade
Contact
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Figure 21-14. Geologic
Map and cross-section of
the area around theSkiddaw granite, Lake
District, UK. After
Eastwood et al (1968).
Geology of the Countryaround Cockermouth andCaldbeck. Explanation
accompanying the 1-inch
Geological Sheet 23, New
Series. Institute of
Geological Sciences.
London.
Contact Metamorphism of Pelitic Rocks
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Contact Metamorphism of Pelitic Rocks
in the Skiddaw Aureole, UK
• Middle zone: slates more thoroughly recrystallized, contain biotite + muscovite + cordierite + andalusite + quartz
Figure 21-15. Cordierite-
andalusite slate from the
middle zone of the
Skiddaw aureole. From
Mason (1978) Petrology of the Metamorphic Rocks.
George Allen & Unwin.
London. 1 mm
Contact Metamorphism of Pelitic Rocks
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Contact Metamorphism of Pelitic Rocks
in the Skiddaw Aureole, UK
Inner zone:
Thoroughly recrystallized
Lose foliation
Figure 21-16. Andalusite-cordierite
schist from the inner zone of the
Skiddaw aureole. Note the chiastolitecross in andalusite (see also Figure 22-
49). From Mason (1978) Petrology of the Metamorphic Rocks. George Allen
& Unwin. London.
1 mm
Contact Metamorphism of Pelitic Rocks
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Contact Metamorphism of Pelitic Rocks
in the Skiddaw Aureole, UK
• The zones determined on a textural basis
• Prefer to use the sequential appearance of
minerals and isograds to define zones
• But low-P isograds converge in P-T
• Skiddaw sequence of mineral development with
grade is difficult to determine accurately
Contact Metamorphism and Skarn
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Contact Metamorphism and Skarn
Formation at Crestmore, CA, USA
• Crestmore quarry in the Los Angeles basin
• Quartz monzonite porphry intrudes Mg-bearing
carbonates (either late Paleozoic or Triassic)
• Brunham (1959) mapped the following zones and the
mineral assemblages in each (listed in order of increasing
grade):
Forsterite Zone:
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Forsterite Zone:
calcite + brucite + clinohumite + spinel
calcite + clinohumite + forsterite + spinel
calcite + forsterite + spinel + clintonite
Monticellite Zone:
calcite + forsterite + monticellite + clintonite
calcite + monticellite + melilite + clintonite
calcite + monticellite + spurrite (or tilleyite) + clintonite
monticellite + spurrite + merwinite + melilite
Vesuvianite Zone:
vesuvianite + monticellite + spurrite + merwinite +melilite
vesuvianite + monticellite + diopside + wollastonite
Garnet Zone:
grossular + diopside + wollastonite
Contact Metamorphism and Skarn
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Contact Metamorphism and Skarn
Formation at Crestmore, CA, USA
An idealized cross-section through the aureole
Figure 21-17.
Idealized N-S cross
section (not to scale)
through the quartz
monzonite and the
aureole atCrestmore, CA.
From Burnham
(1959) Geol. Soc.Amer. Bull., 70, 879-
920.
Contact Metamorphism and Skarn
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Contact Metamorphism and Skarn
Formation at Crestmore, CA, USA
1. The mineral associations in successive zones (in allmetamorphic terranes) vary by the formation of new
minerals as grade increases
This can only occur by a chemical reaction in which some
minerals are consumed and others produced
Contact Metamorphism and Skarn
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Contact Metamorphism and Skarn
Formation at Crestmore, CA, USA
a) Calcite + brucite + clinohumite + spinel zone to theCalcite + clinohumite + forsterite + spinel sub-zone
involves the reaction:
2 Clinohumite + SiO2 9 Forsterite + 2 H2O
b) Formation of the vesuvianite zone involves the reaction:
Monticellite + 2 Spurrite + 3 Merwinite + 4 Melilite
+ 15 SiO2 + 12 H2O 6 Vesuvianite + 2 CO2
Contact Metamorphism and Skarn
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Co c e o p s d S
Formation at Crestmore, CA, USA
2) Find a way to display data in simple, yet useful ways
• If we think of the aureole as a chemical system, we note
that most of the minerals consist of the components
CaO-MgO-SiO2-CO2-H2O (with minor Al2O3)
Figure 21-17. CaO-MgO-SiO2 diagram at a fixed
pressure and temperature showing the
compositional relationships among the minerals
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Zones are numbered
(from outside inward)
compositional relationships among the minerals
and zones at Crestmore. Numbers correspond to
zones listed in the text. After Burnham (1959) Geol.Soc. Amer. Bull., 70, 879-920; and Best (1982)
Igneous and Metamorphic Petrology. W. H.
Freeman.
Figures not used
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Figure 21-4. A situation in which
lithostatic pressure (Plith) exerted by the
mineral grains is greater than the
intergranular fluid pressure (Pfluid). At a
depth around 10 km (or T around 300oC)
minerals begin to yield or dissolve at the
contact points and shift toward orprecipitate in the fluid-filled areas,
allowing the rock to compress. The
decreased volume of the pore spaces will
raise Pfluid until it equals Plith. Winter
(2001) An Introduction to Igneous and
Metamorphic Petrology. Prentice Hall.
Figures not used
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