ch. 6 - introduction to chemical bonding

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4/4/2013 1 Mr. Sudbury You must know the number of valence electrons for each atom. (Pattern on PT) (Pattern on PT) (Pattern on PT) (Pattern on PT) Electron Electron Electron Electron- - -dot notation dot notation dot notation dot notation can also be used to represent molecules. Lewis Structures Lewis Structures Lewis Structures Lewis Structures – Formulas in which atomic symbols represent nuclei and inner-shell electrons, dot pairs or dashes represent electron pairs SHARED in covalent bonds H 2 F 2 A single bond is a covalent bond produced by the sharing of one pair of electrons between atoms The electrons that are not used in bonding are called the unshared pair or lone pair. C 2 H 4 A double bond is a covalent bond produced by the sharing of two pairs of electrons between atoms N 2 A triple bond is a covalent bond produced by the sharing of three pairs of electrons between atoms VSEPR VSEPR VSEPR VSEPR – “Valence Shell Electron-Pair Repulsion” VSEPR Theory VSEPR Theory VSEPR Theory VSEPR Theory states that the repulsion between the sets of valence-level electrons surrounding an atom causes these sets to be as far apart as possible. VSEPR explains VSEPR explains VSEPR explains VSEPR explains why compounds take the shape they do. (Their molecular geometry.)

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4/4/2013

1

Mr. Sudbury

� You must know the number of valence electrons for each atom. (Pattern on PT)(Pattern on PT)(Pattern on PT)(Pattern on PT)

� ElectronElectronElectronElectron----dot notation dot notation dot notation dot notation can also be used to represent molecules.

� Lewis Structures Lewis Structures Lewis Structures Lewis Structures – Formulas in which atomic symbols represent nuclei and inner-shell electrons, dot pairs or dashes represent electron pairs SHARED in covalent bonds

� HHHH2222

� F2

� A single bond is a covalent bond produced by the sharing of one pair of electrons between atoms

� The electrons that are not used in bonding are called the unshared pair or lone pair.

� C2H4

� A double bond is a covalent bond produced by the sharing of two pairs of electrons between atoms

� N2

� A triple bond is a covalent bond produced by the sharing of three pairs of electrons between atoms

� VSEPRVSEPRVSEPRVSEPR – “Valence Shell Electron-Pair Repulsion”

� VSEPR Theory VSEPR Theory VSEPR Theory VSEPR Theory states that the repulsion between the sets of valence-level electrons surrounding an atom causes these sets to be as far apart as possible.

� VSEPR explains VSEPR explains VSEPR explains VSEPR explains why compounds take the shape they do. (Their molecular geometry.)

4/4/2013

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� Hybrid means something that is created from two different sources.

� Hybridization in atoms is when two or more atomic orbitals of similar energies on the same atoms combine to produce new orbitals of equal energies.

� Molecular Geometry is the study of the shapes that molecules make when they bond.

� Also, studying if a compound is polar or nonpolar.

� Electron Dot Diagrams

� Lewis Diagrams for compounds

� VSEPR – Molecule shapes