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EM 530 Composite Structural Analysis Lecture Notes Chapter 1: Introduction Based on the text Mechanics of Composite Materials, Robert M. Jones, 1999. Slides courtesy of Robert M. Jones, and Mohanned Mahdi

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Page 1: Chapter 1

EM 530 Composite Structural Analysis

Lecture Notes

Chapter 1: Introduction

Based on the text

Mechanics of Composite Materials, Robert M. Jones, 1999.

Slides courtesy of

Robert M. Jones, and Mohanned Mahdi

Page 2: Chapter 1

Motivation

http://unsilentgeneration.files.wordpress.com/2009/06/pub_gt_air

craft_composite_content_1980-2010_lg1.jpg?w=280&h=360

Page 3: Chapter 1
Page 4: Chapter 1

Course objective

• Introduce the nature,manufacture,and applications of various composite materials

• Give a through grounding in issuer of the fundamental mechanics of composite materials

• Treat a broad spectrum of analysis topics essential to basic understanding

• Compare theoretical predictions of behavior with actual measurements to validate or reject possible design analysis approaches

• Survey topics of more advanced interest

Page 5: Chapter 1

Outline

• Introduction to composite materials and structures

• Micromechanical behavior of a lamina

• Micromechanical behavior of a lamina

• Micromechanical behavior of a laminate

• Bending ,buckling, and vibration of laminated plates

• Other topics

• Computer analysis of composite structures

• Introduction to design of composite structures

Page 6: Chapter 1

THE WHAT, THE WHY , AND

THE HOW

Introduction to

composite materials & structures

Page 7: Chapter 1

Outline 1. The what

• What is a composite materials?

• Classification and characteristics

• Laminated fiber-reinforce composite materials

• Manufacturing

2. The why

• Why are composite material used instead of metals?

• Advantages (stiffness, strength , weight , cost ,etc)

3. The how

• How are composite materials used in structural applications?

• Case histories of important applications

Page 8: Chapter 1

Definition of Composite Materials

• It contains two or more physically distinct and mechanically separable materials

• It is made by dispersing one material in the other in a controlled way to achieve optimum properties

• The properties of the composite are superior and possibly unique in some specific respects to the properties of individual components

Professor Derek Hull

University of Liverpool

Page 9: Chapter 1

The what

What is a composite materials

Composite materials • Definition: Two or more materials combined on a

macroscopic scale to form a useful third material with enhanced material properties

• Properties to be improved:– Strength -- Thermal insulation

– Stiffness -- Thermal conductivity

– Weight -- Corrosion resistance

– Fatigue life -- Acoustical insulation

– Wear resistance -- Temperature-dependent behavior

Page 10: Chapter 1
Page 11: Chapter 1

Characteristics and classification

of composite materials

Page 12: Chapter 1
Page 13: Chapter 1

Classification of composite materials

• Fibrous composite

• fibers in a matrix

• Laminated composites

• layers of various materials

• Particulate composites

• Particles in a matrix

• Combinations of above

• Reinforce concrete

• Laminated fiber-reinforced composite

George H. Staab, LAMINAR COMPOSITES, Buuterworth_Heinmann, 1999.

Page 14: Chapter 1

3

Particle-reinforced

• Examples:Adapted from Fig.

10.10, Callister 6e.

(Fig. 10.10 is

copyright United

States Steel

Corporation, 1971.)

Adapted from Fig.

16.4, Callister 6e.

(Fig. 16.4 is

courtesy Carboloy

Systems,

Department,

General Electric

Company.)

Adapted from Fig.

16.5, Callister 6e.

(Fig. 16.5 is

courtesy Goodyear

Tire and Rubber

Company.)

COMPOSITE SURVEY: Particle-I

Page 15: Chapter 1

Laminated Composites

Page 16: Chapter 1

Classification of composite materials

• Fibrous composite

• fibers in a matrix

• Laminated composites

• layers of various materials

• Particulate composites

• Particles in a matrix

• Combinations of above

• Reinforce concrete

• Laminated fiber-reinforced composite

Page 17: Chapter 1

Fibrous composites

• Long fibers stronger and stiffer than bulk form

• Fibers have a more perfect structure

• Fibers

• High length-to-diameter ratio

• Near crystal-size diameter

• High strength-to-density & stiffness - to – density

• Whiskers

• Low length-to-diameter ratio

• More perfect than fibers

Page 18: Chapter 1

Compressive Strengths• Crushing, shearing and buckling effects under a

compressive load.

• where E is the tensile modulus and d/L is the reciprocal of the aspect ratio

• Larger-diameter fibers tend to resist buckling effect better than small-diameter fibers

• Ideally, fibers’ tensile strength is the same as compressive strength. However, Kevlar fibers’ compressive strength is only 20% of their tensile strength.

• Bonding condition (via matrix) can help reduce buckling effect

22

bucklingEuler 16 L

dE

Page 19: Chapter 1
Page 20: Chapter 1

Flexibility• The flexibility of a fiber, defined as k/M, can be

expressed in moment, M.

• Where E is the tensile modulus, d is the fiber

diameter and k is the reciprocal of the radius of

the curvature

64

4EkdM

Page 21: Chapter 1
Page 22: Chapter 1

History of the Carbon Fiber

• The father of carbon fiber is British research chemist Sir Leslie

Philips of the Royal Aircraft Establishment ,Farnborough

• He says “we sat down one day and decided we had to do

something. From a little chemical formula written on the back of an

envelope to reality took only months and nothing could have fallen

out better according to the theory we devised. I don’t suppose initial

work cost more than a few thousand pounds”

• “we settled on the formula in autumn 1963, had an illicit can of beer

to celebrate the test result in spring 1964, got commercial production

by July 1966,and life’s been a ding-dong ever since. When you fall

on something good like this and see it used all over the world ,

satisfaction is complete”

Page 23: Chapter 1

Carbon/ Graphite Fiber

• A carbon fibers used a reinforcing material

– Filaments/fiber are long, thin strand of material about 0.0002-0.0004 in (0.005-

0.010 mm) in diameter and composed mostly of carbon atoms

– The carbon atoms are bonded together in microscopic crystals that are more or

less aligned parallel to the long axis of the fiber.

– The crystal alignment makes the fiber incredibly strong for its

size.

• Production Materials

– 1950’s – Rayon decomposition process was used to obtain fiber having 20-50%

carbon

– 1960s, polyacrylonitrile (PAN) based fiber production introduced. Contains about

55% carbon and has better properties.

– 1980’s process developed to use petroleum pitch as precursor, can produce

fiber with upto 85% or better carbon content

Page 24: Chapter 1

Fiber Classifications

• Carbon fibers are classified by the tensile modulus

– Low modulus, standard or intermediate modulus, high modulus,

and ultrahigh modulus

– Low modulus (34.8 million psi or 240 million kPa),

– Ultrahigh modulus 72.5-145.0 million psi (500 million-1.0 billion

kPa)

– Steel 29 million psi (200 million kPa)

• “Graphite fiber” refers to ultrahigh modulus fibers made

from petroleum pitch

– These fibers have an internal structure that closely approximates

the three-dimensional crystal alignment that is characteristic of a

pure form of carbon known as graphite.

Page 25: Chapter 1

• A 6 μm diameter carbon filament (running

from bottom left to top right) compared to a

human hair.

http://www.statemaster.com/encyclopedia/Image:Cfaser-haarrp.jpg

Page 26: Chapter 1

Graphite Fiber Production

ProcessProcess is used for making carbon fibers has many steps

– Spinning: The precursor is drawn into long strands or fibers

– Stabilizing: Fibers are heat to produce desirable molecular

structure by heating them in air or some gaseous atmosphere

– Carbonization: Heated to a very high temperature with-out

allowing it to come in contact with oxygen.

– Surface treatment: The fiber surface is slightly oxidized to

improve their ability to chemically bond better with expoxy. This

also etches and roughens the surface for better mechanical

bonding properties.

– Sizing: The fibers are coated to protect them from damage

during winding or weaving. The coated fibers are wound onto

cylinders called bobbins.

Page 27: Chapter 1

Schematic of Carbon Fiber

Production

Page 28: Chapter 1

Graphite or carbon fibers

• Precursor fiber

• Pitch

• Pan (polyacrilonitrile)

• Heat fibers in an inert atmosphere (don’t burn)

• Carbonize

• Partially graphitize

• Fiber tension is a key processing parameter

• Carbon fiber – processed below 1700 C

• Graphic fibers-processed above 1700 C

• The higher the temperature

• The higher the modulus

• The lower the strength

(some recent exceptions)

Page 29: Chapter 1

Boron Fiber

E= 60 106 psi

σ = 450 103 psi

ρ = .09 Ib/in3

http://www.specmaterials.com/images/hyborgraphic.png

Page 30: Chapter 1

Fiber or wire

Density, ρ

Ib/in3

(KN/m3)

Tensile

strength, S

103 Ib/in2

(GN/m2)

S/ρ

105 in

.(km)

Tensile

stiffness,

E 106

Ib/in2.

(GN/m2)

E/ρ

107 in.

(Mm)

Aluminium .097(26.3) 90(.62) 9(24) 10.6(73) 11(2.8)

Titanium .170(46.1) 280(1.9) 16(41) 16.7(115) 10(2.5)

Steel .282(76.6) 600(4.1) 21(54) 30(207) 11(2.7)

E-glass .092(25.0) 500(3.4) 54(136) 10.5(72) 11(2.9)

S-glass .090(24.4) 700(4.8) 78(197) 12.5(86) 14(3.5)

Carbon .051(13.8) 250(1.7) 49(123) 27(190) 53(14)

Beryllium .067(18.2) 250(1.7) 37(93) 44(300) 66(16)

Boron .093(25.2) 500(3.4) 54(137) 60(400) 65(16)

Graphite .051(13.8) 250(1.7) 49(123) 37(250) 72(18)

Fiber and wire properties

Page 31: Chapter 1
Page 32: Chapter 1

Whisker

Density, ρ

Ib/in3

(KN/m3)

Theoretical

strength, ST 103

Ib/in2 (GN/m2)

Theoretica

l strength,

SE 103

Ib/in2

(GN/m2)

S/ρ

105 in

.(km)

Tensile

stiffness, E

106 Ib/in2.

(GN/m2)

E/ρ

107 in.

(Mm)

Copper .322(87.4) 1.8(12) .43(3.0) 13(34) 18(124) 5.6(1.4)

Nickel .324(87.9) 3.1(21) .56(3.9) 17(44) 31(215) 9.6(2.4)

Iron .283(76.8) 2.9(20) 1.9(13) 67(170) 29(200) 10.2(2.6)

B4 C .091(24.7) 6.5(45) .97(6.7) 106(270) 65(450) 71(18)

Sic .115(31.2) 12(83) 1.6(11) 139(350) 122(840) 106(27)

AL2 O3 .143(38.8) 6(41) 2.8(19) 196(490) 60(410) 42(11)

C .060(16.3) 14.2(98) 3(21) 500(1300) 142(980) 237(60)

Whisker Properties

Page 33: Chapter 1

Matrix Materials

• Metals

Metals can be made to flow around an in-place fiber system by

diffusion bonding or heating and vacuum infiltration, E.G.,

Aluminum, Titanium, and Nickel-chromium alloys

• Carbon

Carbon can be vapor deposited on an in-place Fiber system or

liquid material can be infiltrated around the fibers and carbonized

place by heating

• Ceramic

Ceramic material can be cast from a molten slurry around

stirred-in fibers with random orientation or with preferred

orientation because of flow or vapor deposited around a bed of

in-place fibers.

Page 34: Chapter 1

Matrices• Thermosetting polymeric resins – epoxy,

polyester, phenolics, polurethane, polyimides

• Thermoplastic resins – polyamide (nylon),

polypropylene (PP), poly ether ether ketone

(PEEK)

• Elastomers – silicone, neoprene (CR), NBR,

SBR

• Metal matrix

• Ceramic matrix

Page 35: Chapter 1

Polymer Matrices

Polymers

Thermosets Thermoplastics Elastomers

Non-crystalline Crystalline

Page 36: Chapter 1

Polymer Matrix Materials

• Polymers ≡(poly ≡many) (mer ≡ unit or molecule)

– Rubbers ≡ cross-linked polymers which have a semi

crystalline state well below room temperature.

• Thermoplastic ≡ resins or plastic compounds which can

be repeatedly softened by heating and hardened by

cooling,E.G., Nylon, Polyethylene, Polysulfone

• Thermosets ≡ resins which are chemically reacted until

almost all of the molecules are irreversible cross-linked

in A 3-D Net-work, E.G, Epoxies, Polyamides

Page 37: Chapter 1

Polymer systems

Page 38: Chapter 1

Thermosets

• Most of the polymer matrices are thermosets (75%)

• Thermosets are cured using curing agents or

hardeners to form a network structure (cross-linked)

• Thermosets are brittle at room temperature and

have low fracture toughness values (KIC = 0.5 -1.0

MPa m1/2)

• Thermosets are suitable for high temperature

application as they have higher softening

temperatures and better creep resistance than

thermoplastics

Page 39: Chapter 1
Page 40: Chapter 1

Polyester• Developed in 1833, consisted of unsaturated linear

polyester molecules dissolved in styrene (styrene is a cross-linking monomer).

• Curing can take place when an organic peroxide (e.g. MEKP) is added to the polyester resin. Free radicals are then created during the chemical reaction which leads to a formation of a 3-dimensional network structure.

• Polyesters are fairly easy to process as they are relatively inexpensive and have low viscosities. The shrinkage which occurs on curing is around 4-8% (pretty high).

Page 41: Chapter 1
Page 42: Chapter 1
Page 43: Chapter 1

Terminology• Shelf life or storage life – the length of time that

unmixed resins can be stored

• Pot life – resins into which the initiator has been mixed

• Inhibitor – molecules which absorb free radicals are added to resin mixture to slow down or prevent further cross-linking reaction

• A-stage – referring to resole and nonvolac resins

– Resole: a low molecular mass material, only heat is needed to covert the resin to the C-stage

– Nonvolac: hardener is needed to achieve the C-stage

• B-stage – a rubbery phase, the resin mixture is partially soluble and partially cured

– Prepreg: pre-impregnated tape (B-stage)

• C-stage – resin mixture is cured to a fully cross-linked condition

Page 44: Chapter 1

Epoxy• Developed in 1939, was mainly for coatings and

adhesives.

• Many different structures available today are derived from bisphenol acetate and epichlorohydrin.

• Epoxy is more expensive and is more viscous than the polyester resin making it very difficult to process

• A higher curing temperature (up to 180oC) with two to three stages of curing will be required.

• The shrinkage is much smaller than for polyesters (1-4%)

• In general, epoxies are stiffer and stronger, but more brittle than polyesters. Epoxies also retain their properties better in high temperatures than polyesters do.

Page 45: Chapter 1
Page 46: Chapter 1

Phenolics

• Developed in 1872, known as phenol-

formaldehyde.

• A resole is produced by reacting a phenol with an

excess amount of aldehyde in the presence of a

basic catalyst. (one-stage resin)

• A nonvolac is generated when excessive phenol is

reacting with an acid catalyst. (two-stage resin)

• Low cost, excellent heat resistance and good

balance of properties

Page 47: Chapter 1
Page 48: Chapter 1
Page 49: Chapter 1
Page 50: Chapter 1

Thermoplastics• Are linear polymers, don’t cross-link, might be branched

• Have superior toughness to thermosets

• Polypropylene and polyethylene are similar in origin and manufacture. PP is cheaper than PE. PP is harder, more rigid and has a higher stress cracking resistance than PE. Polycarbonate is an amorphous, transparent material, has good impact resistance, can be used up to 140oC.

• Polyamide (e.g. Nylon) has a high m.p. (260oC) and maintains its properties to about 150oC.

• Polyetheretherketone (PEEK) is a semi-crystalline polymer having 20-40% crystallinity. PEEK has a high Tg (143oC) and m.p. (343oC), good toughness (6 MPa m1/2) and good solvent resistance

Page 51: Chapter 1
Page 52: Chapter 1
Page 53: Chapter 1

Elastomers• Rubber-like elasticity – can be stretched more than

200%.

• In general the suitable temperature range for an

elastomer is between -50oC and 120oC.

• Natural rubber –cis-polyisoprene

• Styrene-butadiene rubber (SBR)

• Acrylonitrile-butadiene rubber (NBR)

• Chloropreene (CR)

• Polysiloxane (Silicone)

• Vulcanization – cross-link chemical chains using

sulfur.

Page 54: Chapter 1
Page 55: Chapter 1
Page 56: Chapter 1
Page 57: Chapter 1

Laminated Composites

• Bimetals

– Thermostat

• Clad metals

– Copper-clad Aluminum wire

• Laminated glass

– Safety glass

• Plastic-Based Laminates

– Formica

Page 58: Chapter 1
Page 59: Chapter 1

Particulate Composite

• Particles and Matrix can be either metallic or nonmetallic

• Nonmetallic in Nonmetallic – Concrete

– Polycrystalline Graphite

• Metallic in Nonmetallic – Rocket propellant

– Aluminum paint

• Metallic in Metallic – Lead in copper alloys and steel

• Nonmetallic in Metallic – Cermets (Reactor control rods)

Page 60: Chapter 1

Mechanical Behavior

• Most engineering materials

– Homogeneous

Properties independent of position in Body.

– Isotropic

properties independent of orientation at a point in the body

• Composites

– Inhomogeneous (Heterogeneous)

properties depend on orientation at a point in the body

Page 61: Chapter 1

Consequences of Heterogeneity

• Study composites VIA

– Micromechanics

Interaction of constituent materials is examined on a

microscopic scale

• Macromechanics

– Composite presumed Homogenous and effects of constituent

materials are detected on an Average Macroscopic scale

Page 62: Chapter 1
Page 63: Chapter 1

Mechanical Behavior

ASTM dog-bone tension specimen

Page 64: Chapter 1

Laminated Fiber-Reinforced

composite materials

Page 65: Chapter 1

Laminated Fiber-Reinforced composite

• Also called filamentary composites

• Lamina –basic building block

– Flat (but sometime curved ) arrangement of unidirectional

or woven fibers in a matrix

• Fibers

– Load –carrying agent

• Matrix

– Support and protect fibers

– Transfer load between broken fibers

Page 66: Chapter 1

Fiber-reinforced laminae

Page 67: Chapter 1

Effect of a broken fiber

Page 68: Chapter 1

Various stress-strain behaviors

Page 69: Chapter 1

Laminate

• Laminae with various

orientations of their

principle material

directions

• Bonded with lamina

matrix as “Glue”

• Can tailor directional

dependence of laminate

stiffness and strength to

match the loading

environment

Page 70: Chapter 1

Reason for Lamination

• Must bond laminae together to achieve maximum bending stiffness

• Recall the two-beam problems from basic mechanics of materials:

Page 71: Chapter 1

Possible deformation of two bonded layers

Page 72: Chapter 1

Bimetallic Strip

Page 73: Chapter 1

Thermal stresses

in isotropic and composite material

Page 74: Chapter 1

Terminology • Lamina-singular-one layer or ply

• Laminae-plural-more than one lamina, layers ,or ply

• Laminate-collection of laminae bonded together

• Principle-A law or fact

• Principle-main

• Criterion-singular

• Criteria-plural

• Data-plural (so data are)

• Axis-singular

• Axis-plural

• Modulus-singular

• Moduli –plural

• Phenomenon –singular

• Phenomenon-Plural

Page 75: Chapter 1

Manufacturing / Fabrication of

Composites

Some slides in this section are courtesy of

Richard Chung, Chemical and Materials Engineering Dept., San Jose State University

Page 76: Chapter 1

Initial Forms of Composite Materials

• Fibers

– Individual

– Roving

– Tow

– Unidirectional

– Woven

• Matrix

– Resin

– Metal

– Carbon

– Ceramic

• Preimpregnated fiber systems

– Tape

– Cloth

– Braid

Page 77: Chapter 1

Woven roving composite

Page 78: Chapter 1

2-D woven Fabrics

Page 79: Chapter 1

Thermosetting Resin Matrix• Hand lay-up

• Hand spray-up

• Vacuum bag/ Autoclave molding

• Match-die molding

• Resin transfer molding

• Filament winding

• Pultrusion

• Braiding

• Preform/molding compounds(SMC, BMC)

Page 80: Chapter 1
Page 81: Chapter 1
Page 82: Chapter 1

Laminate

Page 83: Chapter 1

Hand Lay-up

Page 84: Chapter 1

Hand Spray-up

Page 85: Chapter 1

Vacuum Bag/ Autoclave Molding

Page 86: Chapter 1

Autoclaves

Page 87: Chapter 1

Match-die Molding

Page 88: Chapter 1

Resin Transfer Molding

Page 89: Chapter 1

Filament Winding

Page 90: Chapter 1

Pultrusion

Page 91: Chapter 1

Braiding

• Advantage of Joint-Braiding Composite

• Seamless, thickness uniformity, fiber

density uniformity

• Angle of braiding yarn can be controlled

from 10 to 80 degree

• Multi-node complicated jointing composite

(Max. 10 layers by our experience)

• Various kind of application of joint part

Page 92: Chapter 1
Page 93: Chapter 1
Page 94: Chapter 1

Preform/Molding

Compounds(SMC, BMC)

Page 95: Chapter 1

Sandwich Structure

Page 96: Chapter 1

Thermoplastic Resin Matrix

• Fibers

• Tapes

• Electrostatic charge

• Powder

• Stamping

Page 97: Chapter 1

Metal Matrix

• Powder metallurgy

• Metal processing methods

– Rolling

– Forging

– Extrusion

– Drawing

– Die casting

Page 98: Chapter 1

Ceramic Matrix• Glass forming

– Pressing

– Sintering

– Drawing

• Particulate forming

– Powder pressing

– Hydroplastic forming

– Tape casting

• Cementation

• Drying/Firing

Page 99: Chapter 1

Manufacturing steps

1. Lay up

• Arranging of fibers in laminae and laminae in laminates

2. Curing

• Drying or polymerization of thermoset-matrix material

• Unaided

• Heat and/or pressure

• Consolidation of thermoplastic-matrix material

3. Machining

4. Assembly

Page 100: Chapter 1

Laminate Layup

Page 101: Chapter 1

Laminate layup Procedures

• Layup of tape and/or cloth– Hand

– Automated

• Filament winding

• Molding – Male and female

– Injection

• Roll forming

• Pultrusion

Page 102: Chapter 1

Composite tape layup methods

Page 103: Chapter 1

Hand layup of Boron-epoxy layer

The most basic fabrication method for thermoset composites is hand layup, which

typically involves laying dry plies or prepreg plies by hand onto a tool to form a laminate

stack. Here, technicians at Liberty Aerospace (Melbourne, Fla.) hand lay carbon/epoxy

prepreg for a general aviation part. Source: Liberty Aerospace

Source:http://www.compositesworld.com/cdn/cms/SB09_compositesthematerials_h.jpg

Page 104: Chapter 1

Automatic Tape-laying operation

• This automated fiber placement (AFP) machine, developed by Ingersoll Machine Tools

(Rockford, Ill.), is used by Goodrich Aerostructures (Chula Vista, Calif.) to produce the

inner fixed structures for the new GEnx jet engines that will power Boeing 787 passenger

jets. It replaces much slower manually intensive hand-layup techniques used previously

(see photo below). Source: Goodrich Aerostructures

• Source: http://www.compositesworld.com/cdn/cms/SB09_compositesthematerials_n.jpg

Page 105: Chapter 1

Fiber or Tape Placement

• http://www.compositesworld.com/cdn/cms/fraunhofer_fiber_placement_web.jpg

Page 106: Chapter 1

Unidirectional Tape problem areas

Page 107: Chapter 1

Filament Winding

http://www.freepatentsonline.com/7124797-0-large.jpg

http://i.ytimg.com/vi/NxspMPEsIk8/0.jpg

Page 108: Chapter 1

Compression Molding

Page 109: Chapter 1

Compression Molded Aerospace Part

• The Airbus A380 leading

wing edge is compression-

molded using a Ticona-

supplied thermoplastic CFRP.

http://www.sae.org/dlymagazineimages/8547_9499_ART.jpg

Page 110: Chapter 1

Continuous-belt,

chopped fiberglass roving, smc machine

Page 111: Chapter 1

Roll-Forming Process

for structural shapes

Page 112: Chapter 1

Pultrusion

Page 113: Chapter 1

Combination of manufacturing processes

Page 114: Chapter 1

Fabrication methods: relative costs and rates

Page 115: Chapter 1

Curing

Page 116: Chapter 1

Curing

• Thermoset-matrix materials

– Add heat to speed the natural chemical reaction of

polymerization with heat (catalyst) and pressure

– Volatiles usually given off during curing

– Chemical hardeners are used with some epoxy resins

• Thermoplastic –matrix materials

– Add heat to fuse constituents

– No volatiles because no chemical reaction

– Add pressure to consolidate constituents

• Cocuring is curing of two or more parts simultaneously

and in contact to fasten them together permanently

Page 117: Chapter 1

Polymer systems

Page 118: Chapter 1

Curing of thermoset-matrix composites

• Generally, the higher the temperature, the shorter the cure

time

• Heat required because:

– Some catalysts and/or hardeners do not react below a critical

temperature

– Molecular mobility necessary for contact of reactive groups

– Drives off solvent (volatiles) and water

• Otherwise, voids occur

• Must do before pressure applied

– Must resin flow to obtain uniform distribution

• Pressure required to:

– Consolidate (debulk) fiber and matrix system

– Squeeze out excess resin

Page 119: Chapter 1

Curing cycle

Page 120: Chapter 1

Resin behavior during curing

• Before curing

– Initial form of composite laminate is laminae laid adjacently in

A B-staged condition (partially cured to reduce resin flow during

laminating or molding)

– Resin is semi-sold with negligible strength and stiffness

• Gradually increase temperature

– Resin cross-linking begins and is significant by the gel

temperature (temperature at which viscosity is so high that no

further dimensional change occurs)

– Progressive cross-linking causes solidification

– However , elevated temperature lowers stiffness

Page 121: Chapter 1

Matrix cross-linking Vs. Temperature

Page 122: Chapter 1

Resin behavior during curing, continued

• At highest temperature

– Cross-linking is nearly complete

– Resin is solidified but of low stiffness because of temperature

• During subsequent temperature excursions

– No further cross-linking unless pervious maximum temperature

is exceeded

Page 123: Chapter 1

Autoclave for rocket motor cases

Page 124: Chapter 1

Rocket motor case

Page 125: Chapter 1

Manufacturing defects

• Interlaminar voids (air, no resin , delaminating)

• Excess matrix voids and porosity

• Inclusion of foreign matter

• Excess resin between layers

• Incomplete curing of resin

• Damaged fibers

• Incorrect orientation of laminae directions

• Wrinkles or ridges (improper compaction)

• Unacceptable joints in layers

• Variation in thickness

Page 126: Chapter 1

The why

Why are composite materials used instead of

metals ?

Page 127: Chapter 1

The why

Advantages

• Strength and stiffness

• Cost

• Weight

• General

Page 128: Chapter 1

Strength and

stiffness advantages

Page 129: Chapter 1

Advantages of

Fiber-reinforced composites

• Strength and stiffness

– Specific strength =

– Specific modulus=

• Cost

– Better in weight –sensitive applications

– Better in usual high scrap page applications

(double tapered wing spar with holes)

– Easier fabrication

– Going down with higher production and new technology

density

strength

Density

ModulusElastic

Page 130: Chapter 1

Translation form

constituents to lamina to laminate

Page 131: Chapter 1

Comparison of composite forms

Page 132: Chapter 1

Tensile strength and stiffness

Page 133: Chapter 1

Stiffness versus strength

• Stiffness is often equally important and

sometimes even more important than strength

Page 134: Chapter 1

Cost Advantages

Page 135: Chapter 1

Predicted cost of fiber

Page 136: Chapter 1

Cost versus pounds used

Page 137: Chapter 1

Composites down metals up

Page 138: Chapter 1

Elements of cost

• Raw material cost

• Design cost

• Fabrication cost

• Assemble cost

• Operating cost

• Maintenance cost

• Salvage value

Initial cost

Life-cycle cost

Page 139: Chapter 1

Materials utilization factor

• M.U.F = Amount of raw material

Amount of material in final part

• Metals : up to 15 to 25

• composite: 1.2 to 1.3

Page 140: Chapter 1

Doubly tapered wing spar

Raw Material cost

Machining cost

Scrappage

Layup cost

Titanium

High

Very high

Very high

None

Graphite- epoxy

High

Very low

Very low

Moderate

Page 141: Chapter 1

Fundamental fabrication difference

between composite and metal structures

Page 142: Chapter 1

Tooling

• CTE of tool need Not match part

– Both must be known and predictable

– Tool must be dimensionally compensated

• For great precision, but few parts

N-C machined Aluminum

• For great precision, but few parts

N-C machined Steel

• For good accuracy with many parts electro-formed

Nickel

• For rapid fabrication and few parts graphite-epoxy

Page 143: Chapter 1

Advantages of composite tooling

over metal tooling

(High-Temperature fiberglass – reinforced plastic tooling)

• Shorter fabrication time

• Weight 25% less

• Faster cure times (less mass to heat)

• Coefficient of thermal expansion of tool matches part

• Easier to repair (but less durable)

• Suitable for low-volume production runs

• Suitable for prototyping stage where shape changes are

common

Page 144: Chapter 1

Composite Tooling

• Graphite-epoxy tooling

– Susceptible to

• Surface damage (more than fiberglass)

• Penetration of release agents

• Delamination

– Too porous- leaks

• Ceramic tooling

– For low CTE

– Not porous

– Costs less than graphite for tool itself, but more for other

equipment

Page 145: Chapter 1

The How

How are composite material used

in structural application

Page 146: Chapter 1

The How

important Applications

• Replacement pieces

• Military Aircraft

• Civil Aircraft

• Space

• Automotive

• Commercial

Page 147: Chapter 1

Applications of composites

Hierarchy of development

• Demonstration pieces

• Replacement pieces

• Production pieces

• All –composite Airplane

Page 148: Chapter 1

Lockheed composite work in the 1920’s

Wooden Aircraft fuselages via molded sheets of

Glue-coated plywood in concrete tube with inflated rubber Bags

Page 149: Chapter 1

Replacement pieces

• Boron-Epoxy

– F-111 Stabilizer

– F-111 Fuselage

• Graphite- Epoxy

– F-5 Fuselage

– A-7 Access door

– A-7 Speed Brake

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Military Aircraft Applications

of composite material

Production pieces • Boron-Epoxy

• F-111 wing pivot fitting doubler

• F-14 Horizontal Stabilizers

• F-15 Horizontal & vertical stabilizers

• Graphite- Epoxy • S-3A Spoilers

• F-16 horizontal & vertical stabilizers

• Space shuttle payload bay doors

• F-18

• Harrier

• Kevlar –Epoxy • spirit

Page 157: Chapter 1

Wing pivot Fitting

boron-epoxy doubler

Page 158: Chapter 1

Wing pivot fitting modification

cost comparison-new Aircraft

Page 159: Chapter 1

Wing pivot fitting modification

cost comparison-new Aircraft

Page 160: Chapter 1
Page 161: Chapter 1

F-14 Horizontal stabilizer

Page 162: Chapter 1

F-15 Horizontal and

vertical stabilizers

Page 163: Chapter 1

S-3A Graphite Spoiler

Page 164: Chapter 1

S-3A Metal Spoiler

Page 165: Chapter 1

S-3A Graphite Spoiler

Page 166: Chapter 1

Limited production S-3 spoiler

weight summary

Page 167: Chapter 1

F-16 Stabilizer

Page 168: Chapter 1

F-18 composite materials Applications

Page 169: Chapter 1

Deo RB, Starnes IHJR, Holzwart RC, Low-Cost Composite materials and

Structures for Aircraft application. NATO RTO AVT Panel spring symposium and

specialists' meeting Loen, NORWAY, 2001.

Page 170: Chapter 1

F-18 Graphite-epoxy usage

Page 171: Chapter 1

AV-8B Harrier

Page 172: Chapter 1
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Civil Aircraft Applications

of Composite materials

Page 174: Chapter 1

Commercial Aviation Applications

• Boeing 737 spoilers

• L-1011 vertical fin

• McDonnell Douglas Dc-10 vertical stabilizer

• Boeing 757

• Boeing 767

• McDonnell Douglas MD-11

• Boeing 7J7

Page 175: Chapter 1

Composites Applications

• High percentage of composite in Airplane necessary to

realize potential

– Pyramiding

– Weight reductions

• Structure ≈ 30% total weight

• Payload ≈ 10% total weight

Stiffer& stronger materials yield

• Larger Payload

• Longer range

• Higher fuel efficiency

Page 176: Chapter 1

737 spoilers flight hours

Page 177: Chapter 1

747 seat strut

• Aluminum forging

– 7075-T73 $8/Ib(1980)

• Injection molded lexan

– Glass fibers in polycarbonate matrix

– 2 to 2-1/2 mm diameter pellets $ 1.45/Ib (1980)

– Less raw material cost

– Less fabrication cost

– Lower weight

– 2/3 minute per strut

– 40 KSI strength

Page 178: Chapter 1

L-1011 vertical fin

Page 179: Chapter 1

L-1011 vertical fin

Aluminum versus graphite –epoxy

Page 180: Chapter 1
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DC-10 Vertical Stabilizer

• Primary structure

• FAA certification

• Flight evaluation (kc-10 and DC-10)

• Interchangeable with metal fin

• Carbon-epoxy spar box structure

• 187 Ibs. Less than 1,006 Ib. metal structure (30-45%

more weight savings if not interchangeable)

• Area 10 SQ. FT. less than Av-8B wing

• 60 components autoclave cured to form main pieces

• Heater bars used to final assembly

• Aluminum sprayed on outer surface for lightning

protection and antenna ground plane

Page 182: Chapter 1

Boeing 757 use of composites

Page 183: Chapter 1

Boeing 767 use of composites

Page 184: Chapter 1

MD-11 COMPOSITES USE

• Redesigned DC-10

• More composites, but still primarily metal

• Kevlar wing-to-fuselage fillet

• Graphite-epoxy parts (-2,500 Ib):– Elevators

– Center engine inlet duct

– Outboard flaps

– Wing trailing edges

– Horizontal stabilizer

– Winglets

– Tail cone

– Ailerons

• Some Aluminum-lithium floor beams (-340 Ib)

Page 185: Chapter 1
Page 186: Chapter 1

All-composite Aircraft

• Mosquito

• WinDecker eagle

• Lear fan 2100

• Beech starship

• Rutan voyager

• Avtek 400

• Piaggio p-188

• Williams V-Jet

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Starship use of composites

• Essentially an all-composite Aircraft

• Graphite –epoxy sandwich with nomex honeycomb core

• Fuselage

• Wing

– For separate airfoil shapers for efficiency

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Spaceship One