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Chapter 14 Ocean Thermal Energy Conversion and Ocean Salinity Gradient Energy ©2015 Cengage Learning Engineering. All Right Reserved. 1 Sustainable Energy

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Page 1: Chapter 14 · Conversion (OTEC) ©2015 Cengage Learning Engineering. All Right Reserved. 3 A heat engine may be constructed using the temperature difference between the cold water

Chapter 14

Ocean Thermal Energy

Conversion and

Ocean Salinity Gradient Energy

©2015 Cengage Learning Engineering. All Right Reserved. 1

Sustainable Energy

Page 2: Chapter 14 · Conversion (OTEC) ©2015 Cengage Learning Engineering. All Right Reserved. 3 A heat engine may be constructed using the temperature difference between the cold water

Sustainable Energy Dunlap

Learning Objectives

©2015 Cengage Learning Engineering. All Right Reserved. 2

● The distribution of thermal energy in the oceans.● The use of a heat engine to extract energy from

the oceans and convert it into electricity.● The design of the different types of OTEC systems.● Experimental OTEC facilities and their

performance.● The basic principles of osmotic energy

production.● Experimental facilities for osmotic energy

production.

Page 3: Chapter 14 · Conversion (OTEC) ©2015 Cengage Learning Engineering. All Right Reserved. 3 A heat engine may be constructed using the temperature difference between the cold water

Sustainable Energy Dunlap

Basics of Ocean Thermal Energy Conversion (OTEC)

©2015 Cengage Learning Engineering. All Right Reserved. 3

A heat engine may be constructed using the temperature difference between the cold water deep in the ocean and the warm surface water.

Below about 1000 m depth ocean water is a fairly constant temperature of about 4 °C.

To maximize efficiency of heat engine it is necessary to maximize the temperature difference.

This means maximizing the surface temperature - so tropical regions are appropriate.

Page 4: Chapter 14 · Conversion (OTEC) ©2015 Cengage Learning Engineering. All Right Reserved. 3 A heat engine may be constructed using the temperature difference between the cold water

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Depth dependence of ocean temperature

©2015 Cengage Learning Engineering. All Right Reserved. 4

typical thermocline in tropical regions

Page 5: Chapter 14 · Conversion (OTEC) ©2015 Cengage Learning Engineering. All Right Reserved. 3 A heat engine may be constructed using the temperature difference between the cold water

Sustainable Energy Dunlap

Ocean surface temperature worldwide

©2015 Cengage Learning Engineering. All Right Reserved. 5

Page 6: Chapter 14 · Conversion (OTEC) ©2015 Cengage Learning Engineering. All Right Reserved. 3 A heat engine may be constructed using the temperature difference between the cold water

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Types of OTEC systems

©2015 Cengage Learning Engineering. All Right Reserved. 6

Three different systems designs exist

• Open cycle• Closed cycle• Hybrid systems

Page 7: Chapter 14 · Conversion (OTEC) ©2015 Cengage Learning Engineering. All Right Reserved. 3 A heat engine may be constructed using the temperature difference between the cold water

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Open cycle OTEC system design

©2015 Cengage Learning Engineering. All Right Reserved. 7

Page 8: Chapter 14 · Conversion (OTEC) ©2015 Cengage Learning Engineering. All Right Reserved. 3 A heat engine may be constructed using the temperature difference between the cold water

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Operation of an open cycle OTEC system

©2015 Cengage Learning Engineering. All Right Reserved. 8

Warm surface water is vaporized in the evaporator by lowering its vapor pressure.

The vaporized water is used to run a turbine and is then condensed by cooling it with cold sea water pumped from deep in the ocean.

Page 9: Chapter 14 · Conversion (OTEC) ©2015 Cengage Learning Engineering. All Right Reserved. 3 A heat engine may be constructed using the temperature difference between the cold water

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Phase diagram of water

©2015 Cengage Learning Engineering. All Right Reserved. 9

Above the triple point, lowering the pressure causes a transition from the liquid to gaseous state - This is what happens in the evaporator.

Lowering the temperature of a gas causes a transition back to the liquid state - This is what happen in the condenser.

Page 10: Chapter 14 · Conversion (OTEC) ©2015 Cengage Learning Engineering. All Right Reserved. 3 A heat engine may be constructed using the temperature difference between the cold water

Sustainable Energy Dunlap

Closed cycle OTEC system

©2015 Cengage Learning Engineering. All Right Reserved. 10

A closed cycle OTEC system uses a working fluid (other than water) to drive the turbine.

Heat is transferred to the working fluid by a heat exchanger (evaporator).

Heat is extracted from the working fluid by a heat exchanger.

Page 11: Chapter 14 · Conversion (OTEC) ©2015 Cengage Learning Engineering. All Right Reserved. 3 A heat engine may be constructed using the temperature difference between the cold water

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Schematic of a closed cycle OTEC system

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Page 12: Chapter 14 · Conversion (OTEC) ©2015 Cengage Learning Engineering. All Right Reserved. 3 A heat engine may be constructed using the temperature difference between the cold water

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Hybrid OTEC systems

©2015 Cengage Learning Engineering. All Right Reserved. 12

Hybrid systems vaporize both the warm sea water and the working fluid.

The vaporized working fluid is used to drive the turbine.

The vaporized sea water is condensed to provide a source of fresh water.

Page 13: Chapter 14 · Conversion (OTEC) ©2015 Cengage Learning Engineering. All Right Reserved. 3 A heat engine may be constructed using the temperature difference between the cold water

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Analysis of OTEC energy output

©2015 Cengage Learning Engineering. All Right Reserved. 13

The thermal energy available is the difference in thermal energy associated with warm water and the cold water.

The mechanical energy is the available thermal energy times the Carnot efficiency of the heat engine.

The Carnot efficiency is determined by the absolute temperature difference between the evaporator and condenser.

The electrical energy is the mechanical energy times the efficiency of the generator (high).

Page 14: Chapter 14 · Conversion (OTEC) ©2015 Cengage Learning Engineering. All Right Reserved. 3 A heat engine may be constructed using the temperature difference between the cold water

Sustainable Energy Dunlap

Comparison with coal fired generating station

©2015 Cengage Learning Engineering. All Right Reserved. 14

The thermal energy available in a coal fired generating station is the energy produced by the combustion of the coal.

The mechanical energy is the available thermal energy times the Carnot efficiency of the heat engine.

The Carnot efficiency is determined by the absolute temperature difference between the boiler and the cold reservoir.

The electrical energy is the mechanical energy times the efficiency of the generator (high).

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Limitations of OTEC

©2015 Cengage Learning Engineering. All Right Reserved. 15

Compared to the coal generating station the energy output of the OTEC system is affected by the following factors:

• Small available energy due to small temperature differences between the warm and cold seawater

• Low Carnot efficiencies due to small temperature differences between evaporator and condenser

• Net energy also reduced because of large amount of energy needed to pump seawater from deep in the ocean

Page 16: Chapter 14 · Conversion (OTEC) ©2015 Cengage Learning Engineering. All Right Reserved. 3 A heat engine may be constructed using the temperature difference between the cold water

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An experimental OTEC facility

©2015 Cengage Learning Engineering. All Right Reserved. 16

Keahole Point, Hawaii

Page 17: Chapter 14 · Conversion (OTEC) ©2015 Cengage Learning Engineering. All Right Reserved. 3 A heat engine may be constructed using the temperature difference between the cold water

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OTEC facility locations

©2015 Cengage Learning Engineering. All Right Reserved. 17

Facilities may be

• on (or near) shore in which case cold water will need to be pumped onshore

• offshore in which case electricity will need to be transported onshore

Success limited by

• Low efficiencies• Complications due to adverse marine environment• Transport of electricity to users

Page 18: Chapter 14 · Conversion (OTEC) ©2015 Cengage Learning Engineering. All Right Reserved. 3 A heat engine may be constructed using the temperature difference between the cold water

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1980 prediction of OTEC capacity

©2015 Cengage Learning Engineering. All Right Reserved. 18

Page 19: Chapter 14 · Conversion (OTEC) ©2015 Cengage Learning Engineering. All Right Reserved. 3 A heat engine may be constructed using the temperature difference between the cold water

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Actual OTEC capacity

©2015 Cengage Learning Engineering. All Right Reserved. 19

No current commercial OTEC energy production

May be most useful as a source of

• fresh water for domestic use• cold water to replace air conditioning

Page 20: Chapter 14 · Conversion (OTEC) ©2015 Cengage Learning Engineering. All Right Reserved. 3 A heat engine may be constructed using the temperature difference between the cold water

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Ocean salinity gradient energy

©2015 Cengage Learning Engineering. All Right Reserved. 20

Two solutions (i.e. salt water and fresh water) are separated by a membrane that allows the flow of water but not the solutes.

Driving force tries to equals concentration gradients by allowing water to flow from the concentrated side to the dilute side.

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Osmotic cell

©2015 Cengage Learning Engineering. All Right Reserved. 21

Driving force cases height difference on the two sides of the membrane

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Osmotic pressure

©2015 Cengage Learning Engineering. All Right Reserved. 22

The osmotic pressure is

i = solute dependent constant (2.0 for NaCl)R = gas constantM = molarityT = temperature

Pressure is related to gravitational force due to height difference (d) across the membrane is

Page 23: Chapter 14 · Conversion (OTEC) ©2015 Cengage Learning Engineering. All Right Reserved. 3 A heat engine may be constructed using the temperature difference between the cold water

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Production of electricity from osmotic pressure

©2015 Cengage Learning Engineering. All Right Reserved. 23

Two approaches:

• pressure retarded osmosis (PRO)

• reverse electrodialysis (RED)

Page 24: Chapter 14 · Conversion (OTEC) ©2015 Cengage Learning Engineering. All Right Reserved. 3 A heat engine may be constructed using the temperature difference between the cold water

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Pressure retarded osmosis

©2015 Cengage Learning Engineering. All Right Reserved. 24

Water flowing across the membrane is used to drive turbines (to generate electricity) so as to keep the height on both sides of the membrane approximately equal.

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Reverse electrodialysis

©2015 Cengage Learning Engineering. All Right Reserved. 25

Charges associated with the dissolved ions contribute directly to the flow of current

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Applications of osmotic energy

©2015 Cengage Learning Engineering. All Right Reserved. 26

Potential viability where sources of seawater (ocean) and fresh water are in proximity

(i.e. mouths of large rivers that empty into the sea)

No commercial applications at present

Economic viability remains to be determined

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Sustainable Energy Dunlap

Pilot PRO facility in Norway

©2015 Cengage Learning Engineering. All Right Reserved. 27

Page 28: Chapter 14 · Conversion (OTEC) ©2015 Cengage Learning Engineering. All Right Reserved. 3 A heat engine may be constructed using the temperature difference between the cold water

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Summary

©2015 Cengage Learning Engineering. All Right Reserved. 28

• Energy can be obtained from the temperature gradients in the oceans and converted into electricity

• The small temperature difference combined with low Carnot efficiency make this approach difficult.

• Ocean salinity gradient available where large rivers empty into the ocean.

• Two approaches: o Pressure retarded osmosiso Reverse electrodialysis

• Viability of both OTEC and salinity gradient technologies needs to be established