chapter 2 cp
TRANSCRIPT
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Chapter 2
CHEMISTRY
OF
LIFE
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KEY CONCEPT
All living things are made of cells which are based on
atoms and their interactions.
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Cell Theory
All living things are made of cells
All cells come from other cells
The cell is the basic unit of life
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Matter is . . .
Anything that occupies space andhas mass
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Living things consist of atoms of different elements.
An atom is the smallest basic unit of matter. An element is one type of atom.
H
O
Hydrogen atom (H)
Oxygen atom (O)
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What is an element?
A substance made of only one kind of atom
Elements are listed on the periodic table
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How many elements listed on the
periodic table are actually found
in 97% of all living organisms?
10 elements
C CarbonH Hydrogen
N Nitrogen
O Oxygen
Ca Calcium
P Phosphorus
K Potassium
S Sulfur
Na Sodium
Cl Chlorine
Mg Magnesium
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The nucleus has protons and neutrons.
Electrons are in energy levels outside nucleus.
Oxygen atom (O)
Nucleus:
8 protons (+)
8 neutrons
outermost energy level:
6 electrons (-)
inner energy level:
2 electrons (-)
An atom has a nucleus and electrons.
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water (H2O) is a compound
O
HH
_
++
A compound is made of atoms of different elements
bonded together.
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carbon dioxide (CO2)
A compound is made of atoms of different elements
bonded together.
water (H2O)
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many other carbon-based compounds in living things
A compound is made of atoms of different elements
bonded together.
water (H2O)
carbon dioxide (CO2)
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Ions form when atoms gain or lose electrons.
An ion is an atom that has gained or lost one or moreelectrons.
positive ions
negative ions
Ionic bonds form between oppositely charged ions.
Sodium atom (Na) Chlorine atom (CI) Sodium ion (Na+) Chloride ion (CI-)
Na loses an
electron to CI ionic bond
gained electron
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Atoms share pairs of electrons in covalent
bonds.
A covalent bond forms when atoms share a pair ofelectrons.
covalent bonds
Oxygen atom (O) Carbon atom (C) Oxygen atom (O)
Carbon dioxide (CO2 )
multiple covalent bonds
diatomic molecules
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KEY CONCEPT
Waters unique properties allow life to exist on Earth.
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What is Osmosis?
the diffusion of water.
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HH
_
++
Life depends on hydrogen bonds in water.
Water is a polar molecule. Polar molecules have slightly charged regions.
Nonpolar molecules do not have charged regions.
Hydrogen bonds form between slightly positive
hydrogen atoms and slightly negative atoms.
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Hydrogen bonds are responsible for three important
properties of water. high specific heat
cohesion
adhesion
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Many compounds dissolve in water.
A solution is formed when one substance dissolves inanother.
A solution is a homogeneous mixture.
Solvents dissolve other substances (solvents are
greater than solutes in number) Solutes dissolve in a solvent.
solution
Solvent
Solute
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Like dissolves like.
Polar solvents dissolve polar solutes.
Nonpolar solvents dissolve nonpolar solutes.
Polar substances and nonpolar substances generally
remain separate.
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Some compounds form acids or bases.
An acid releases a hydrogen ion when it dissolves inwater.
high H+ concentration
pH less than 7
more acidic because there are more H+ ions
stomach acid pH between 1 and 3
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A base removes hydrogen ions from a solution.
low H+ concentration
pH greater than 7
bile pH between 8 and 9
more basic because there is less H+
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A neutral solution has a pH of 7. (the H+ ions are equal to
the OH- ions)pure water pH 7
H+ (+) OH- = H2O
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What would result if you added an acid to a
neutral solution?
Water is neutral H2O
Acid + neutral = Acid
pH 6 + pH7 = pH 6.5
H+ ions added to H2O = H20 + H+(shifted toward the acid end of the pH scale
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0100 (1.0)1410-14
110-1 (0.1)1310-13
210-2 (0.01)1210-12
310-3 (0.001)1110-11
410-4(0.0001)1010-10
510-5(0.00001)910-9
610-6(0.000001)810-8(0.00000001)
710-7(0.0000001)710-7(0.0000001)
810-8(0.00000001)610-6(0.000001)
910-9510-5(0.00001)
1010-10410-4(0.0001)
1110-11310-3 (0.001)
1210
-12
210
-2
(0.01)
1310-13110-1 (0.1)
1410-140100 (1.0)
MpOH[OH-]pH[H+] M
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Household ammonia has a pH of 12; household bleach
has a pH of 13. What is the difference in the number of
H+ ions in the two solutions?
The ammonia has 10 times as many H+ ions as the bleach.
pH 12 has: 1 x 10-12H+ and 1 x 10-2OH-
pH 13 has: 1 x 10-13H+ and 1 x 10-1OH-
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VOCABULARY 2.1
1. Atom
2. Element
3. Compound
4. Ion
5. Ionic bond
6. Covalent bond
7. Molecule
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VOCABULARY 2.1
Atom smallest basic unit of matter
Element one particular type of atom, cannot be brokendown into a simpler substance by ordinary chemical
means
Compound two or more atoms bonded together in a
fixed ratio Ion an atom that has gained or lost one or more
electrons
Ionic bond forms through electrical force between
oppositely charged atoms Covalent bond forms when atoms share a pair of
electrons
Molecule two or more atoms held together by covalent
bonds
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Carbon atoms have unique bonding
properties.
Carbon forms covalent bonds with up to four other atoms,including other carbon atoms.
Carbon-based molecules have three general types of
structures.
straight chain branched chain
ring
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Many carbon-based molecules are made of many small
subunits bonded together.
Monomers are the individual subunits.
Polymers are made of many monomers.
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Four main types of carbon-based molecules are found in
living things.
Carbohydrates
Proteins
Lipids
Nucleic Acids
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What property of carbon makes it
perfect for the building block of
life?
Carbon forms covalent bonds
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Four main types of carbon-based molecules are found in
living things.
Carbohydrates are made of carbon, hydrogen, and
oxygen.
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Four main types of carbon-based molecules are found in
living things.
Carbohydrates are made of carbon, hydrogen, and
oxygen.
Carbohydrates include
sugars and starches. Monosaccharides are
simple sugars.
Polysaccharides include
starches, cellulose, andglycogen.
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Carbohydrates can be broken down to provide
energy for cells.
Some carbohydrates are part of cell structure.
Polymer (starch)
Starch is a polymer of
glucose monomers that
often has a branched
structure.
Polymer (cellulose)
Cellulose is a polymer
of glucose monomers
that has a straight, rigid
structure
monomer
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Many contain carbon chains called fatty acids.
Fats and oils contain fatty acids bonded to glycerol.
Lipids are nonpolar molecules that include fats, oils, and
cholesterol.
Triglyceride
Four main types of carbon-based molecules are found in
living things.
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Lipids have several different functions.
broken down as a source of energy
make up cell membranes
used to make hormones
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Phospholipids make up all cell membranes.
Polar phosphate head
Nonpolar fatty acid tails
Phospholipid
Phospholipids have
KINKY tails!
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Proteins are polymers of amino acid monomers.
Twenty different amino acids are used to build
proteins in organisms.
Four main types of carbon-based molecules are found in
living things.
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Amino acids differ in side groups, or R groups.
Proteins are polymers of amino acid monomers.
Twenty different amino acids are used to build
proteins in organisms.
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Amino acids are linked by peptide bonds.
Proteins are polymers of amino acid monomers.
Amino acids differ in side groups, or R groups.
Twenty different amino acids are used to build
proteins in organisms.
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Proteins differ in the number and order of amino acids.
Amino acids interact to give a protein its shape.
Incorrect amino acids change a proteins structure
and function.
hydrogen bond
Hemoglobi
n
Four main types of carbon based molecules are found in
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Nucleic acids are polymers of monomers called
nucleotides.
Four main types of carbon-based molecules are found in
living things.
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Nucleotides are made of a sugar, phosphate
group, and a nitrogen base.
A phosphate group nitrogen-containing molecule,called a base
deoxyribose (sugar)
Nucleic acids are polymers of monomers called
nucleotides.
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DNA stores genetic
information.
Nucleic acids are polymers of monomers called
nucleotides.
Nucleotides are made of a sugar, phosphate
group, and a nitrogen base.
RNA builds proteins.
DNA
RNA
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Where do most of a cells chemical
reactions (metabolism) occur?
The liquid part of a cell called the
cytoplasm
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Four main types of carbon-based molecules are found in
living things.
Carbohydrates
Proteins
Lipids
Nucleic Acids
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KEY CONCEPT
Life depends on chemical reactions.
B d b k d f d i h i l
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Bonds break and form during chemical
reactions.
Chemical reactions change substances into different onesby breaking and forming chemical bonds.
Reactants are changed during a chemical reaction.
Products are made by a chemical reaction.
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A reaction is at equilibrium when reactants and products
form at the same rate.
CO2 + H2O H2CO3
Bond energy is the amount of energy that breaks a bond.
Energy is added to break bonds.
Energy is released when bonds form.
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Chemical reactions release or absorb energy.
Activation energy is the amount of energy that needsto be absorbed to start a chemical reaction.
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Endothermic reactions absorb more energy than they
release.
Reactants have lower bond energies than products.
Energy is absorbed by the reaction to make up the
difference.
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KEY CONCEPT
Enzymes are catalysts for chemical reactions in livingthings.
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A catalyst lowers activation energy.
Catalysts are substances that speed up chemicalreactions.
decrease activation energy
increase reaction rate (reactions happen faster at lower
energy levels)
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Enzymes allow chemical reactions to occur under tightly
controlled conditions.
Enzymes are catalysts in living things.
Enzymes are needed for almost all processes.
Most enzymes are proteins.
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Disruptions in homeostasis can prevent enzymes from
functioning. Enzymes function best in a small range of conditions.
Changes in temperature and pH can break hydrogen
bonds.
An enzymes function depends on its structure.
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An enzymes structure allows only certain reactants to
bind to the enzyme. substrates
active site
substrates
(reactants)
enzyme
Substrates bind to an
enzyme at certain places
called active sites.
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The lock-and-key model helps illustrate how enzymes
function. substrates brought together
bonds in substrates weakened, new bonds formed
which creates a new substance
Substrates bind to an
enzyme at certain places
called active sites.
The enzyme brings
substrates together,
forms new bonds,
which forms a new
The catalyzed reaction forms
a product that is released
from the enzyme.