chapter 20 organic chemistry organic chemistry = the study of compounds containing carbon and their...

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Chapter 20 Organic Chemistry Organic chemistry = the study of compounds containing carbon and their properties. Carbon forms many biomolecules (molecules that maintain and reproduce life) Carbon and silicon form the basis of most natural substances.

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20.2 alkanes The simplest organic compounds are hydrocarbons, compounds containing only carbon and hydrogen. saturated hydrocarbons, hydrocarbons with only single bonds between the carbon atoms. (alkanes) unsaturated hydrocarbons, hydrocarbons that contain double or triple bonds between carbon atoms.

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Page 1: Chapter 20 Organic Chemistry Organic chemistry = the study of compounds containing carbon and their properties. Carbon forms many biomolecules (molecules

Chapter 20 Organic Chemistry Organic chemistry = the study of

compounds containing carbon and their properties.

Carbon forms many biomolecules (molecules that maintain and reproduce life)

Carbon and silicon form the basis of most natural substances.

Page 2: Chapter 20 Organic Chemistry Organic chemistry = the study of compounds containing carbon and their properties. Carbon forms many biomolecules (molecules

20.1 Carbon bonding Because carbon has four valence

electrons, it can form four covalent bonds.

A unique feature of carbon is its ability to form strong bonds with other carbons to form long chains or rings of various length.

Carbon forms single, double, and triple bonds to achieve a filled octet.

C C C C

Page 3: Chapter 20 Organic Chemistry Organic chemistry = the study of compounds containing carbon and their properties. Carbon forms many biomolecules (molecules

20.2 alkanes The simplest organic compounds are

hydrocarbons, compounds containing only carbon and hydrogen.

saturated hydrocarbons, hydrocarbons with only single bonds between the carbon atoms. (alkanes) unsaturated hydrocarbons, hydrocarbons that contain double or triple bonds between carbon atoms.

Page 4: Chapter 20 Organic Chemistry Organic chemistry = the study of compounds containing carbon and their properties. Carbon forms many biomolecules (molecules

Alkanes The alkanes are acyclic, saturated

hydrocarbons that form a homologous series of compounds, with the general formula CnH2n+2.

The simplest hydrocarbon is methane, CH4.

4CH

molecular formula structural formula

C HHH

H

Page 5: Chapter 20 Organic Chemistry Organic chemistry = the study of compounds containing carbon and their properties. Carbon forms many biomolecules (molecules

Figure 20.1: Methane is a tetrahedral molecule.

Page 6: Chapter 20 Organic Chemistry Organic chemistry = the study of compounds containing carbon and their properties. Carbon forms many biomolecules (molecules

Alkanes The structural formulas for the first four

straight-chain (or normal) alkanes are shown below. (Not really straight because of the tetrahedron shape. C-C bonds have a 109.5o angle).

methane

CC HH

HH

H

H

CCC HH

H

H

HH

H

HCCCC HH

H

H

H

H

HH

H

HC HHH

H

ethane propane butane

Page 7: Chapter 20 Organic Chemistry Organic chemistry = the study of compounds containing carbon and their properties. Carbon forms many biomolecules (molecules

Figure 20.3: Structure of propane.

Page 8: Chapter 20 Organic Chemistry Organic chemistry = the study of compounds containing carbon and their properties. Carbon forms many biomolecules (molecules

Figure 20.3: Structure of butane.

Page 9: Chapter 20 Organic Chemistry Organic chemistry = the study of compounds containing carbon and their properties. Carbon forms many biomolecules (molecules

Alkanes condensed structural formulas

methane

CC HH

HH

H

HCCC HH

H

H

HH

H

HCCCC HH

H

H

H

H

HH

H

HC HHH

Hethane propane butane

CH3CH2CH2CH3CH3CH2CH3CH3CH3CH4

Page 10: Chapter 20 Organic Chemistry Organic chemistry = the study of compounds containing carbon and their properties. Carbon forms many biomolecules (molecules

20.3 Isomers In addition to straight-chain alkanes,

branched-chain alkanes are possible.

Note that isobutane, C4H10, has the same molecular formula as normal butane.Butane and isobutane are structural isomers, compounds with the same molecular formula but different structural formulas. (Different structure means different properties.)

Page 11: Chapter 20 Organic Chemistry Organic chemistry = the study of compounds containing carbon and their properties. Carbon forms many biomolecules (molecules

Models of isobutane and butane.