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Organic ChemistryTRANSCRIPT
Quiz 1 This activity contains 12 questions.
What is the general molecular formula for a cyclic alkene?
CnH2n
CnH2n+4
CnH2n+2
CnH2n+6
CnH2n–2
What is the molecular formula for a hydrocarbon with two pi bonds and one ring?
CnH2n–1
CnH2n–4
CnH2n–2
CnH2n–3
CnH2n–5
Name the hydrocarbon CH3-CH=CH-CH2CH2CH3 using systematic nomenclature.
2-hexane
hexene-2
2-hexene
1-hexene
2-pentene
What is the systematic name for allyl chloride?
2-chloropropene
bromoethene
1-chloropropene
4-chlorobutene
3-chloropropene
Which of the following is 2-bromo-4-ethyl-7-methyl-4-octene?
(CH3)2CH-CH2CH2CH(C2H5)CH2CHBrCH3
(CH3)2CH-CH2CH=CHCH2CHBrCH3
(CH3)2CHCH2CH2C=C(C2H5)CH2CHBrCH3
(CH3)2CHCH=CHCH(C2H5)CH2CHBrCH3
(CH3)2CHCH2CH=C(C2H5)CH2CHBr-CH3
Which of the following compounds cannot exist as cis/trans isomers?
H2C=CH-C2H5
Cl-CH=CHCH3
Cl-CH=CH-Br
CH3CH=CH-C2H5
Cl-CH=CH-Cl
Referring to E/Z nomenclature, which of the following statements is not correct?
trichloromethyl priority > iodine priority
bromine priority > chlorine priority
isopropyl priority > methyl priority
deuterium priority > hydrogen priority
ethyl priority > methyl priority
Referring to E/Z nomenclature, which of the following priority rules is not correct?
If two substituents are attached by the same atom (a tie), you should compare the priority of the atoms attached to the tied atoms.
If an atom is doubly bonded to another atom, it should be treated as two single bonds to that atom.
Atoms with higher atomic numbers have higher priority.
The priority of isotopes is determined by their natural abundance.
Which of the following reagents is not a nucleophile?
methylamine
water
bromide ion
hydroxide ion
bromine atom
Which of the following does not use curved arrows correctly?
Which statement about curved arrows is not correct?
Curved arrows are drawn to indicate the movements of electrons.
Curved arrows always start at an atom.
Arrows are drawn away from negative charges and/or toward positive charges.
Several curved arrows might have to be used to describe one reaction.
The arrow is drawn in the direction of the electron flow.
Which statement is not true?
In the transition state, the bonds that break and form are partially broken or partially formed, respectively.
The structure of the transition state is between the structures of the reactants and products.
The activation energy for a reaction is equal to the energy difference between the energy of the reactants and the energy of the transition state.
The transition state is more similar in structure to the species that it is closer to energetically.
The transition state structure always resembles the starting materials more closely than it resembles the products.
Quiz 2 This activity contains 12 questions.
How many degrees of unsaturation would there be in a molecule with molecular formula C8H12?
0
1
2
3
4
What is the correct name for the following
compound?
3-bromo-4-cyclohex-1-ene
6-bromo-5-methylcyclohexene
3-bromo-4-methylcyclohexene
4-methyl-3-bromocyclohexene
1-bromo-6-methylcyclohex-2-ene
Which of the following statements is not true?
The bond angles of the alkene carbons are 109.5 degrees.
The p orbitals of the pi bond are perpendicular to the plane of the atoms attached to the alkene.
All atoms attached to the alkene carbons are in the same plane.
The carbons of an alkene are sp
2 hybridized.
Which of the following are not two appropriate names for the same compound?
propene and propylene
ethene and ethylene
allyl bromide and 2-bromopropene
vinyl chloride and chloroethene
isobutylene and 2-methylpropene
Referring to E/Z nomenclature, which of the priority orders below is incorrect?
Br < I
D > H
-OCH3 > -OH
-CH2OH > -CH=O
-OH > -CH3
Which of the following describes a reaction with a negative G?
The products are more stable than the reactants.
The products are more stable than the transition state.
The reaction is exothermic.
The reaction occurs rapidly.
The reaction is endergonic.
Which of the following is not a nucleophile?
ethylene
Br
-
BH3
water
NH3
Which is a correct name?
2-methylpentene
5-bromo-2-pentene
4-hexene
1-ethyl-1-pentene
5-chloro-3-hexene
Which of the following is an appropriate name?
5-chloro-3-hexene
2-vinylpentane
5-bromo-2-pentene
5-ethylcyclohexene
2-ethyl-2-butene
Which statement is not correct?
The methyl groups in (E)-2-methyl-2-pentene are on the same side of the double bond.
(E)-2-pentene can be called trans-2-pentene.
(Z)-4-methyl-2-pentene can be called cis-4-methyl-2-pentene.
(E)-2-butene can be called trans-2-butene.
The methyl groups in (E)-3-methyl-2-pentene are on opposite sides of the double bond.
Which of the following is not a true statement?
The more stable the alkene, the larger the cis substituents.
The more stable the alkene, the fewer the number of hydrogens bonded to thesp
2 carbons.
trans-2-Butene is more stable than cis-2-butene.
The more stable the alkene, the greater the number of alkyl substituents.
Which of the following alkenes would be least polar?
1,1,2-trichloroethene
E-1,2-dichloroethene
chloroethene
Z-1,2-dichloroethene
1,1-dichloroethene