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Preliminary Discussion on Molecules, Covalent Bonds and Lewis Dot Diagrams

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Page 1: Chapter 5 Chemistry
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What is it? Lewis Dot Diagram. What do the dots represent? Valence electrons. Fluorine is diatomic
Page 2: Chapter 5 Chemistry
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What do you notice? Valence electrons. Who wants to get rid of electrons? Metals.
Page 3: Chapter 5 Chemistry

January 4, 2011Objectives

1. Define molecule2. Discuss the relationship of the physical and

chemical properties of the molecules to the properties of the atoms from which they are made (They’re different!)

3. Explain what covalent bonds are and why they are formed.

4. Draw a Lewis Dot diagram for any covelentmolecule, indicating the number of valence electrons on each atom in the diagram.

Page 4: Chapter 5 Chemistry

What holds molecules together?

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Caffeine and ? What holds molecules together? What’s happening with the molecules? How many valence electrons does H have? How many does O have? They are sharing. How? Where does the attractive force come from. Take hydrogen for example. 10 >-10 1 Angstrom. Nuclei to nuclei 10>-10 Closer and closer 3 angstrom move on their own .78 angstrom. There is an extra positive negative attraction in the molecule. Why did the temp increase more stable release energy.
Page 5: Chapter 5 Chemistry

Molecule: collection of atoms that are bound together

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How does this work?
Page 6: Chapter 5 Chemistry

What is a covalent bond?

• What holds a molecule together? Covalent bond

• Force of attraction that results from valence electrons being attracted to two nuclei.

• Valence electrons being shared between two nuclei

• Core electrons are not involved in bonding• Valence electrons are shared between the

two nuclei

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What holds a molecule together? Covalent bond Force of attraction that results from valence electrons being attracted to two nuclei. Valence electrons being shared between two nuclei Core electrons are not involved in bonding
Page 7: Chapter 5 Chemistry

Ways to represent shared electrons

H:H H..H H-H

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The line means two electrons!!!!!!
Page 8: Chapter 5 Chemistry

Covalent Bonds are very strong!

Page 9: Chapter 5 Chemistry

Bond formation always releases energy

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Breaking bonds always takes energy. Think about a screaming baby.
Page 10: Chapter 5 Chemistry

How many valence electrons does each molecule have?

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How many does carbon normally have?
Page 11: Chapter 5 Chemistry

Why won’t two Helium atoms form a molecule?

Page 12: Chapter 5 Chemistry

What do all elements want to be like? Why?

Page 13: Chapter 5 Chemistry

The Octet Rule

• Remember for the representative elements the Roman Numeral group number tells you the number of valence electrons.

• He is the only exception. Why?

• Formula for Water and Methane.

Page 14: Chapter 5 Chemistry

Practice

• What is the formula for ammonia?

• What is the formula for carbon and chlorine?

Page 15: Chapter 5 Chemistry

The Lewis Dot Diagram

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GN Lewis
Page 16: Chapter 5 Chemistry

Lewis Dot diagrams

• Show an atom’s valence electrons• The number of dots is equal to the group

number• Pairs of dots(electrons) are electron pairs• Single electrons are unpaired electrons

Page 17: Chapter 5 Chemistry

Metal Metalloids Nonmetals

I II III IV V VI VII VIII

Transition metals

Page 18: Chapter 5 Chemistry

Non Metals and The Dots

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H C N O F Si P S Cl Ge as Se Br
Page 19: Chapter 5 Chemistry

Electron Pairs vs. Unpaired Electron

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Fluorine and Helium Hydrogen Quick reminder about the noble gases and the octet rule. You must have 8 valence electrons to achieve stability. Fluorine is diatomic.
Page 20: Chapter 5 Chemistry

Bonding Pairs vs. Lone Pairs

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NF3 and CH4 c2H6 Line for bonding pairs Shared pairs and called bonding pairs and unshared pairs are called lone pairs. Lets try HClO, C3H8
Page 21: Chapter 5 Chemistry

Steps to drawing dot diagrams

• Count up how many valence electrons will be in the final diagram (PCl3) (CO)

• Connect the atoms with single bonds. Assume first non hydrogen atom is the central atom (PCl3)

• Put the remaining dots in as lone pairs. First on the terminal atoms then on the central atom. Don’t use more electrons then you have.

Page 22: Chapter 5 Chemistry

Steps to drawing dot diagrams

• (CO ) Remember every atom needs an octet. Lone pairs to the rescue. Only from adjacent atoms.

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Resonance forms.
Page 23: Chapter 5 Chemistry

Multiple Covalent Bonds

O2

N2

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Double Triple
Page 24: Chapter 5 Chemistry

Multiple Covalent Bonds

CO2

C2H2

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Double Triple
Page 25: Chapter 5 Chemistry