chapter22 section01 organic chemistry and hydrocarbons by hamdy karim

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Page 1: Chapter22 section01 Organic Chemistry and Hydrocarbons By Hamdy Karim

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Chemistry 22.1

Page 2: Chapter22 section01 Organic Chemistry and Hydrocarbons By Hamdy Karim

© Copyright Pearson Prentice Hall

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22.1 Hydrocarbons

Gasoline, diesel fuel, and kerosene are examples of liquid fuels. A solid fuel, coal, produced the steam for the locomotives that pulled old-time trains. These fuels are mixtures of compounds called hydrocarbons. You will learn about the structure and properties of hydrocarbons.

Page 3: Chapter22 section01 Organic Chemistry and Hydrocarbons By Hamdy Karim

© Copyright Pearson Prentice Hall

Hydrocarbons >

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22.1 Organic Chemistry and Hydrocarbons

Organic Chemistry and Hydrocarbons

How is the number of valence electrons in carbon atoms related to the bonds that carbon atoms form?

Page 4: Chapter22 section01 Organic Chemistry and Hydrocarbons By Hamdy Karim

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© Copyright Pearson Prentice Hall

22.1 Hydrocarbons > Organic Chemistry and Hydrocarbons

Because carbon has four valence electrons, a carbon atom always forms four covalent bonds.

The simplest organic compounds contain only carbon and hydrogen and are called hydrocarbons.

Page 5: Chapter22 section01 Organic Chemistry and Hydrocarbons By Hamdy Karim

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© Copyright Pearson Prentice Hall

22.1 Hydrocarbons > Organic Chemistry and Hydrocarbons

One carbon atom can form a single covalent bond with four hydrogen atoms.

Page 6: Chapter22 section01 Organic Chemistry and Hydrocarbons By Hamdy Karim

© Copyright Pearson Prentice Hall

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Hydrocarbons > Organic Chemistry and Hydrocarbons

Animation 28

Get a glimpse of the staggering variety of hydrocarbon compounds.

Page 7: Chapter22 section01 Organic Chemistry and Hydrocarbons By Hamdy Karim

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© Copyright Pearson Prentice Hall

22.1 Hydrocarbons > Organic Chemistry and Hydrocarbons

Ball-and-stick model Space-filling model

Formulas and Models for Methane and Ethane

Page 8: Chapter22 section01 Organic Chemistry and Hydrocarbons By Hamdy Karim

© Copyright Pearson Prentice Hall

Hydrocarbons >

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22.1 Alkanes

Alkanes

What are two possible arrangements of carbon atoms in an alkane?

Page 9: Chapter22 section01 Organic Chemistry and Hydrocarbons By Hamdy Karim

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© Copyright Pearson Prentice Hall

22.1 Hydrocarbons > Alkanes

An alkane is a hydrocarbon in which there are only single covalent bonds.

The carbon atoms in an alkane can be arranged in a straight chain or in a chain that has branches.

Page 10: Chapter22 section01 Organic Chemistry and Hydrocarbons By Hamdy Karim

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© Copyright Pearson Prentice Hall

22.1 Hydrocarbons > Alkanes

Straight-Chain Alkanes

Ethane is the simplest of the straight-chain alkanes, which contain any number of carbon atoms, one after the other, in a chain.

Page 11: Chapter22 section01 Organic Chemistry and Hydrocarbons By Hamdy Karim

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© Copyright Pearson Prentice Hall

22.1 Hydrocarbons > Alkanes

A group of compounds forms a homologous series if there is a constant increment of change in molecular structure from one compound in the series to the next.

Page 12: Chapter22 section01 Organic Chemistry and Hydrocarbons By Hamdy Karim

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© Copyright Pearson Prentice Hall

22.1 Hydrocarbons > Alkanes

Hydrocarbons are used as fuels.

Page 13: Chapter22 section01 Organic Chemistry and Hydrocarbons By Hamdy Karim

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© Copyright Pearson Prentice Hall

22.1 Hydrocarbons > Alkanes

In a condensed structural formula, some bonds and/or atoms are left out of the structural formula. Although the bonds and atoms do not appear, they are there.

Page 14: Chapter22 section01 Organic Chemistry and Hydrocarbons By Hamdy Karim

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© Copyright Pearson Prentice Hall

22.1 Hydrocarbons > Alkanes

Page 15: Chapter22 section01 Organic Chemistry and Hydrocarbons By Hamdy Karim

© Copyright Pearson Prentice Hall

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Page 16: Chapter22 section01 Organic Chemistry and Hydrocarbons By Hamdy Karim

© Copyright Pearson Prentice Hall

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Page 17: Chapter22 section01 Organic Chemistry and Hydrocarbons By Hamdy Karim

© Copyright Pearson Prentice Hall

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Page 18: Chapter22 section01 Organic Chemistry and Hydrocarbons By Hamdy Karim

© Copyright Pearson Prentice Hall

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Practice Problems for Conceptual Problem 22.1

Problem Solving 22.1 Solve Problem 1 with the help of an interactive guided tutorial.

Page 19: Chapter22 section01 Organic Chemistry and Hydrocarbons By Hamdy Karim

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© Copyright Pearson Prentice Hall

22.1 Hydrocarbons > Alkanes

Branched-Chain Alkanes

An atom or group of atoms that can take the place of a hydrogen atom on a parent hydrocarbon molecule is called a substituent.

Page 20: Chapter22 section01 Organic Chemistry and Hydrocarbons By Hamdy Karim

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© Copyright Pearson Prentice Hall

22.1 Hydrocarbons > Alkanes

• A hydrocarbon substituent is called an alkyl group.

• An alkane with one or more alkyl groups is called a branched-chain alkane.

Page 21: Chapter22 section01 Organic Chemistry and Hydrocarbons By Hamdy Karim

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© Copyright Pearson Prentice Hall

22.1 Hydrocarbons > Alkanes

Ball-and-stick and space-filling models show the arrangement of atoms in 4-ethyl-2,3-dimethylheptane.

Page 22: Chapter22 section01 Organic Chemistry and Hydrocarbons By Hamdy Karim

© Copyright Pearson Prentice Hall

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Page 23: Chapter22 section01 Organic Chemistry and Hydrocarbons By Hamdy Karim

© Copyright Pearson Prentice Hall

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Page 24: Chapter22 section01 Organic Chemistry and Hydrocarbons By Hamdy Karim

© Copyright Pearson Prentice Hall

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Page 25: Chapter22 section01 Organic Chemistry and Hydrocarbons By Hamdy Karim

© Copyright Pearson Prentice Hall

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Practice Problems for Conceptual Problem 22.2

Problem Solving 22.3 Solve Problem 3 with the help of an interactive guided tutorial.

Page 26: Chapter22 section01 Organic Chemistry and Hydrocarbons By Hamdy Karim

© Copyright Pearson Prentice Hall

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Page 27: Chapter22 section01 Organic Chemistry and Hydrocarbons By Hamdy Karim

© Copyright Pearson Prentice Hall

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Page 28: Chapter22 section01 Organic Chemistry and Hydrocarbons By Hamdy Karim

© Copyright Pearson Prentice Hall

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Page 29: Chapter22 section01 Organic Chemistry and Hydrocarbons By Hamdy Karim

© Copyright Pearson Prentice Hall

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Practice Problems for Conceptual Problem 22.3

Problem Solving 22.5 Solve Problem 5 with the help of an interactive guided tutorial.

Page 30: Chapter22 section01 Organic Chemistry and Hydrocarbons By Hamdy Karim

© Copyright Pearson Prentice Hall

Hydrocarbons >

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22.1 Properties of Alkanes

Properties of Alkanes

In terms of their polarity, what type of molecules are alkanes?

Page 31: Chapter22 section01 Organic Chemistry and Hydrocarbons By Hamdy Karim

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22.1 Hydrocarbons > Properties of Alkanes

Molecules of hydrocarbons, such as alkanes, are nonpolar molecules.

The nonpolar molecules in the oil spill are not attracted to the polar water molecules in the ocean.

Page 32: Chapter22 section01 Organic Chemistry and Hydrocarbons By Hamdy Karim

© Copyright Pearson Prentice Hall

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Section Quiz

-or-Continue to: Launch:

Assess students’ understanding of the concepts in Section

22.1 Section Quiz.

22.1.

Page 33: Chapter22 section01 Organic Chemistry and Hydrocarbons By Hamdy Karim

© Copyright Pearson Prentice Hall

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22.1 Section Quiz.

1. Choose the correct words for the spaces. Because carbon has ______ valence electrons, it can form ______________ bonds.

a. four, four covalent

b. four, four ionic

c. six, six covalent

d. six, four or fewer covalent

Page 34: Chapter22 section01 Organic Chemistry and Hydrocarbons By Hamdy Karim

© Copyright Pearson Prentice Hall

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22.1 Section Quiz.

2. Alkanes are hydrocarbons that contain only ___________ bonds.

a. carbon-carbon

b. single covalent

c. carbon-hydrogen

d. ionic

Page 35: Chapter22 section01 Organic Chemistry and Hydrocarbons By Hamdy Karim

© Copyright Pearson Prentice Hall

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22.1 Section Quiz

3. Choose the correct words for the spaces. Hydrocarbons are highly soluble in _______ solvents because they are ________ molecules.

a. nonpolar, nonpolar

b. nonpolar, polar

c. polar, nonpolar

d. polar, polar

Page 36: Chapter22 section01 Organic Chemistry and Hydrocarbons By Hamdy Karim

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