chem 104a, uc, berkeley powder diffractionnanowires.berkeley.edu/teaching/104a/201425.pdf · chem...
TRANSCRIPT
![Page 1: Chem 104A, UC, Berkeley Powder diffractionnanowires.berkeley.edu/teaching/104a/201425.pdf · Chem 104A, UC, Berkeley What is the highest density for sphere packing? Chem 104A, UC,](https://reader036.vdocument.in/reader036/viewer/2022063005/5fb4df5711532f16d04263ca/html5/thumbnails/1.jpg)
1
Chem 104A, UC, Berkeley
Chem 104A, UC, BerkeleyPowder diffraction
![Page 2: Chem 104A, UC, Berkeley Powder diffractionnanowires.berkeley.edu/teaching/104a/201425.pdf · Chem 104A, UC, Berkeley What is the highest density for sphere packing? Chem 104A, UC,](https://reader036.vdocument.in/reader036/viewer/2022063005/5fb4df5711532f16d04263ca/html5/thumbnails/2.jpg)
2
Chem 104A, UC, BerkeleyCrystallographic Directions And Planes
Lattice DirectionsIndividual directions: [uvw]Symmetry-related directions: <uvw>
Miller Indices:1. Find the intercepts on the axes in terms of the lattice
constant a, b, c2. Take the reciprocals of these numbers, reduce to the
three integers having the same ratio(hkl)
Set of symmetry-related planes: {hkl}
Chem 104A, UC, Berkeley
(100) (111)
(200) (110)
![Page 3: Chem 104A, UC, Berkeley Powder diffractionnanowires.berkeley.edu/teaching/104a/201425.pdf · Chem 104A, UC, Berkeley What is the highest density for sphere packing? Chem 104A, UC,](https://reader036.vdocument.in/reader036/viewer/2022063005/5fb4df5711532f16d04263ca/html5/thumbnails/3.jpg)
3
Chem 104A, UC, Berkeley
Chem 104A, UC, BerkeleyCrystallographic Directions And Planes
Miller-Bravais indices
[uvtw], (hkil)i=-(h+l)t=-(u+v)
![Page 4: Chem 104A, UC, Berkeley Powder diffractionnanowires.berkeley.edu/teaching/104a/201425.pdf · Chem 104A, UC, Berkeley What is the highest density for sphere packing? Chem 104A, UC,](https://reader036.vdocument.in/reader036/viewer/2022063005/5fb4df5711532f16d04263ca/html5/thumbnails/4.jpg)
4
Chem 104A, UC, Berkeley
In cubic system,
[hkl] direction perpendicular to (hkl) plane
Chem 104A, UC, Berkeley
2
222
2
1
a
lkh
dhkl
For cubic system
Lattice spacing
![Page 5: Chem 104A, UC, Berkeley Powder diffractionnanowires.berkeley.edu/teaching/104a/201425.pdf · Chem 104A, UC, Berkeley What is the highest density for sphere packing? Chem 104A, UC,](https://reader036.vdocument.in/reader036/viewer/2022063005/5fb4df5711532f16d04263ca/html5/thumbnails/5.jpg)
5
Chem 104A, UC, Berkeley
Chem 104A, UC, BerkeleyPowder diffraction
2
222
2
1
a
lkh
dhkl
![Page 6: Chem 104A, UC, Berkeley Powder diffractionnanowires.berkeley.edu/teaching/104a/201425.pdf · Chem 104A, UC, Berkeley What is the highest density for sphere packing? Chem 104A, UC,](https://reader036.vdocument.in/reader036/viewer/2022063005/5fb4df5711532f16d04263ca/html5/thumbnails/6.jpg)
6
Chem 104A, UC, Berkeley
52.36%
Unit cell symmetries - cubic
6
)2
(34
%3
3
a
a
a
Chem 104A, UC, Berkeley
-Iron is body-centered cubic
68%
BCC Lattice
24
33)43
(34
2%3
3
a
a
a
![Page 7: Chem 104A, UC, Berkeley Powder diffractionnanowires.berkeley.edu/teaching/104a/201425.pdf · Chem 104A, UC, Berkeley What is the highest density for sphere packing? Chem 104A, UC,](https://reader036.vdocument.in/reader036/viewer/2022063005/5fb4df5711532f16d04263ca/html5/thumbnails/7.jpg)
7
Chem 104A, UC, Berkeley
What is the highest density for sphere packing?
Chem 104A, UC, Berkeley
In 1611 the German astronomer Johannes Kepler stated that no packing could be denser than that of the face-centred cubic (f.c.c.) lattice arrangement favored by grocers for stacking oranges, which fills about 0.7405 of the available space.
It took mathematicians some 400 years to prove him right.
Kepler's Conjecture
Hales, T. C. Discrete Computational Geom. 17, 1-51 (1997); 18, 135-149 (1997).
![Page 8: Chem 104A, UC, Berkeley Powder diffractionnanowires.berkeley.edu/teaching/104a/201425.pdf · Chem 104A, UC, Berkeley What is the highest density for sphere packing? Chem 104A, UC,](https://reader036.vdocument.in/reader036/viewer/2022063005/5fb4df5711532f16d04263ca/html5/thumbnails/8.jpg)
8
Chem 104A, UC, Berkeley
Chem 104A, UC, Berkeley
Close packing structures: Cubic vs. Hexagonal
![Page 9: Chem 104A, UC, Berkeley Powder diffractionnanowires.berkeley.edu/teaching/104a/201425.pdf · Chem 104A, UC, Berkeley What is the highest density for sphere packing? Chem 104A, UC,](https://reader036.vdocument.in/reader036/viewer/2022063005/5fb4df5711532f16d04263ca/html5/thumbnails/9.jpg)
9
Chem 104A, UC, Berkeley
Chem 104A, UC, Berkeley
CN=12
(0,0,0)(1/3,2/3,1/2)
![Page 10: Chem 104A, UC, Berkeley Powder diffractionnanowires.berkeley.edu/teaching/104a/201425.pdf · Chem 104A, UC, Berkeley What is the highest density for sphere packing? Chem 104A, UC,](https://reader036.vdocument.in/reader036/viewer/2022063005/5fb4df5711532f16d04263ca/html5/thumbnails/10.jpg)
10
Chem 104A, UC, Berkeley
CN=12
%05.74)22(
33.14%
3
3
r
rFor BCC; 68.02%
Chem 104A, UC, Berkeley
![Page 11: Chem 104A, UC, Berkeley Powder diffractionnanowires.berkeley.edu/teaching/104a/201425.pdf · Chem 104A, UC, Berkeley What is the highest density for sphere packing? Chem 104A, UC,](https://reader036.vdocument.in/reader036/viewer/2022063005/5fb4df5711532f16d04263ca/html5/thumbnails/11.jpg)
11
Chem 104A, UC, Berkeley
Chem 104A, UC, Berkeley
Rare Gas: Ne, He, Ar, Kr, Xe (ccp; fcc)
Metal: Cu, Ag, Au, Ni, Pd, Pt (ccp)
Mg, Zn, Cd, Ti (hcp)
Fe, Cr, Mo (bcc)
![Page 12: Chem 104A, UC, Berkeley Powder diffractionnanowires.berkeley.edu/teaching/104a/201425.pdf · Chem 104A, UC, Berkeley What is the highest density for sphere packing? Chem 104A, UC,](https://reader036.vdocument.in/reader036/viewer/2022063005/5fb4df5711532f16d04263ca/html5/thumbnails/12.jpg)
12
Chem 104A, UC, Berkeley
Chem 104A, UC, Berkeley
Caesium Chloride (CsCl) is primitive cubic
Different atoms at corners and body center. NOT body centered, therefore.
Lattice type P
Also CuZn, CsBr, LiAg
Simple Cubic Lattice
![Page 13: Chem 104A, UC, Berkeley Powder diffractionnanowires.berkeley.edu/teaching/104a/201425.pdf · Chem 104A, UC, Berkeley What is the highest density for sphere packing? Chem 104A, UC,](https://reader036.vdocument.in/reader036/viewer/2022063005/5fb4df5711532f16d04263ca/html5/thumbnails/13.jpg)
13
Chem 104A, UC, Berkeley
Chem 104A, UC, Berkeley
![Page 14: Chem 104A, UC, Berkeley Powder diffractionnanowires.berkeley.edu/teaching/104a/201425.pdf · Chem 104A, UC, Berkeley What is the highest density for sphere packing? Chem 104A, UC,](https://reader036.vdocument.in/reader036/viewer/2022063005/5fb4df5711532f16d04263ca/html5/thumbnails/14.jpg)
14
Chem 104A, UC, Berkeley
Ionic structures:
Can be considered as close packing of large anions with Cation filling in the interstitial sites.
For every anion, there are
1 Octahedral site2 tetrahedral sites.
Chem 104A, UC, Berkeley
![Page 15: Chem 104A, UC, Berkeley Powder diffractionnanowires.berkeley.edu/teaching/104a/201425.pdf · Chem 104A, UC, Berkeley What is the highest density for sphere packing? Chem 104A, UC,](https://reader036.vdocument.in/reader036/viewer/2022063005/5fb4df5711532f16d04263ca/html5/thumbnails/15.jpg)
15
Chem 104A, UC, Berkeley
What's the Numerical Value of a specific Ionic Radius?
High resolution X-Ray Diffraction
Chem 104A, UC, BerkeleyRadiusRatioRule
Red line:Contacting
![Page 16: Chem 104A, UC, Berkeley Powder diffractionnanowires.berkeley.edu/teaching/104a/201425.pdf · Chem 104A, UC, Berkeley What is the highest density for sphere packing? Chem 104A, UC,](https://reader036.vdocument.in/reader036/viewer/2022063005/5fb4df5711532f16d04263ca/html5/thumbnails/16.jpg)
16
Chem 104A, UC, Berkeley
Chem 104A, UC, Berkeley
![Page 17: Chem 104A, UC, Berkeley Powder diffractionnanowires.berkeley.edu/teaching/104a/201425.pdf · Chem 104A, UC, Berkeley What is the highest density for sphere packing? Chem 104A, UC,](https://reader036.vdocument.in/reader036/viewer/2022063005/5fb4df5711532f16d04263ca/html5/thumbnails/17.jpg)
17
Chem 104A, UC, Berkeley
Chem 104A, UC, Berkeley
Limiting Radius Ratios - anions in the coordination polyhedron of cation are in contact with the cation and with each other
Radius Ratio Coordination no. Binary (AB) Structure-type
r+/r- = 1 12 none known
1 > r+/r- > 0.732 8 CsCl
0.732 > r+/r- > 0.414 6 NaCl
0.414 > r+/r- > 0.225 4 ZnS
![Page 18: Chem 104A, UC, Berkeley Powder diffractionnanowires.berkeley.edu/teaching/104a/201425.pdf · Chem 104A, UC, Berkeley What is the highest density for sphere packing? Chem 104A, UC,](https://reader036.vdocument.in/reader036/viewer/2022063005/5fb4df5711532f16d04263ca/html5/thumbnails/18.jpg)
18
Chem 104A, UC, Berkeley
Applicable to ionic solidNot covalent solid
Many exceptions!
ZnS:r+/r-=0.88/1.70=0.5Expect CN=6
Chem 104A, UC, Berkeley
Cs (0,0,0)Cl (½, ½, ½)
![Page 19: Chem 104A, UC, Berkeley Powder diffractionnanowires.berkeley.edu/teaching/104a/201425.pdf · Chem 104A, UC, Berkeley What is the highest density for sphere packing? Chem 104A, UC,](https://reader036.vdocument.in/reader036/viewer/2022063005/5fb4df5711532f16d04263ca/html5/thumbnails/19.jpg)
19
Chem 104A, UC, BerkeleyRadiusRatioRule
Red line:Contacting
Chem 104A, UC, Berkeley•Motif: Cl at (0,0,0); Cs at (1/2,
1/2,1/2)
•1 CsCl in unit cell •Coordination: 8:8 (cubic)•Adoption by chlorides, bromides and iodides of larger cations, •e.g. Cs+, Tl+, NH4
+ x
y
![Page 20: Chem 104A, UC, Berkeley Powder diffractionnanowires.berkeley.edu/teaching/104a/201425.pdf · Chem 104A, UC, Berkeley What is the highest density for sphere packing? Chem 104A, UC,](https://reader036.vdocument.in/reader036/viewer/2022063005/5fb4df5711532f16d04263ca/html5/thumbnails/20.jpg)
20
Chem 104A, UC, Berkeley
NaCl; ccp, O sites: 100%
Chem 104A, UC, Berkeley
•CCP Ca2+ with F- in all Tetrahedral holes •Lattice: fcc •Motif: Ca2+ at (0,0,0); 2F- at (1/4,
1/4,1/4) & (3/4,
3/4,3/4)
•4 CaF2 in unit cell •Coordination: Ca2+ 8 (cubic) : F- 4 (tetrahedral) •In the related Anti-Fluorite structure Cation and Anion positions are reversed
CaF2
![Page 21: Chem 104A, UC, Berkeley Powder diffractionnanowires.berkeley.edu/teaching/104a/201425.pdf · Chem 104A, UC, Berkeley What is the highest density for sphere packing? Chem 104A, UC,](https://reader036.vdocument.in/reader036/viewer/2022063005/5fb4df5711532f16d04263ca/html5/thumbnails/21.jpg)
21
Chem 104A, UC, Berkeley
Chem 104A, UC, Berkeley
![Page 22: Chem 104A, UC, Berkeley Powder diffractionnanowires.berkeley.edu/teaching/104a/201425.pdf · Chem 104A, UC, Berkeley What is the highest density for sphere packing? Chem 104A, UC,](https://reader036.vdocument.in/reader036/viewer/2022063005/5fb4df5711532f16d04263ca/html5/thumbnails/22.jpg)
22
Chem 104A, UC, Berkeley
Zinc Blende
Chem 104A, UC, Berkeley
•CCP S2- with Zn2+ in half Tetrahedral holes (only T+ {or T-} filled)
•Lattice: fcc
•4 ZnS in unit cell
•Motif: S at (0,0,0); Zn at (1/4,1/4,
1/4)
•Coordination: 4:4 (tetrahedral)
Zinc Blende: ZnS
![Page 23: Chem 104A, UC, Berkeley Powder diffractionnanowires.berkeley.edu/teaching/104a/201425.pdf · Chem 104A, UC, Berkeley What is the highest density for sphere packing? Chem 104A, UC,](https://reader036.vdocument.in/reader036/viewer/2022063005/5fb4df5711532f16d04263ca/html5/thumbnails/23.jpg)
23
Chem 104A, UC, Berkeley
NaCl•Very common (inc. 'ionics', 'covalents' & 'intermetallics' ) •Most alkali halides (CsCl, CsBr, CsI excepted) •Most oxides / chalcogenides of alkaline earths •Many nitrides, carbides, hydrides (e.g. ZrN, TiC, NaH)
CaF2 (Fluorite)•Fluorides of large divalent cations, chlorides of Sr, Ba •Oxides of large quadrivalent cations (Zr, Hf, Ce, Th, U)
Na2O (Anti-Fluorite)•Oxides /chalcogenides of alkali metals
ZnS (Zinc Blende/Sphalerite)•Formed from Polarizing Cations (Cu+, Ag+, Cd2+, Ga3+...)
and Polarizable Anions (I-, S2-, P3-, ...); •e.g. Cu(F,Cl,Br,I), AgI, Zn(S,Se,Te), Ga(P,As), Hg(S,Se,Te)
Chem 104A, UC, Berkeley
All T
All O
Half T
All O & T
? ?
? ?
![Page 24: Chem 104A, UC, Berkeley Powder diffractionnanowires.berkeley.edu/teaching/104a/201425.pdf · Chem 104A, UC, Berkeley What is the highest density for sphere packing? Chem 104A, UC,](https://reader036.vdocument.in/reader036/viewer/2022063005/5fb4df5711532f16d04263ca/html5/thumbnails/24.jpg)
24
Chem 104A, UC, Berkeley
Chem 104A, UC, Berkeley
![Page 25: Chem 104A, UC, Berkeley Powder diffractionnanowires.berkeley.edu/teaching/104a/201425.pdf · Chem 104A, UC, Berkeley What is the highest density for sphere packing? Chem 104A, UC,](https://reader036.vdocument.in/reader036/viewer/2022063005/5fb4df5711532f16d04263ca/html5/thumbnails/25.jpg)
25
Chem 104A, UC, Berkeley
Chem 104A, UC, Berkeley
![Page 26: Chem 104A, UC, Berkeley Powder diffractionnanowires.berkeley.edu/teaching/104a/201425.pdf · Chem 104A, UC, Berkeley What is the highest density for sphere packing? Chem 104A, UC,](https://reader036.vdocument.in/reader036/viewer/2022063005/5fb4df5711532f16d04263ca/html5/thumbnails/26.jpg)
26
Chem 104A, UC, Berkeley