chem 125 lecture 3 9/9/02 projected material this material is for the exclusive use of chem 125...
Post on 22-Dec-2015
214 views
TRANSCRIPT
Chem 125 Lecture 39/9/02
Projected material
This material is for the exclusive use of Chem 125 students at Yale and may not
be copied or distributed further.
It is not readily understood without reference to notes from the lecture.
Equilibrium vs. Resonance
A B A B
Two Real SpeciesOne Real Species
Two “Reasonable”Structural Formulas
Failure of Simplistic NotationUnusually Stable
Equilibrium vs. Resonance
H CO
O
HH C
O
O H••
••••
•• ••
••
••
••
••
H CO
O
H C
O
O
••••
•• ••
••
••
•••
•
•
•
Two Species
Two SpeciesOne Species!
LORE••
H C
O
O
H C
O
O
••••
•• ••
••
••
•••
•
•
•
One Nuclear Geometry!
OCCULT CHEMISTRY
A SERIES OF
Clairvoyant Observations on theChemical Elements
BY
ANNIE BESANT, P.T.S.
AND
CHARLES W. LEADBEATER
Reprinted from the Theosophist.
THEOSOPHIST OFFICE, ADYAR, MADRAS, S.
THEOSOPHICAL PUBLISHING SOCIETY, LONDON AND BENARES CITY.
1909 (105 pp.)
1919 (123 pp.)
1951 (400 pp.)
Benzene(1924)
"each of the three valencies of each Carbon are satisfied by Hydrogen, and the fourth valency, which some have postulated as going to the interior of the molecule, does actually do so."
Mrs. AnnieBESANT
P.T.S.(1847-1933)
CuruppumullageJINARAJADASA
P.T.S.(~1877-1953)
"Bishop"Charles WebsterLEADBEATER
(1847 - 1932)
The Occult Chemists (1895-1932)
"These [1905 chemical] weights differ from those hitherto accepted, and are generally lighter than those given in earlier textbooks. It is interesting to note that our counting endorses the earlier numbers...we must wait to see if later observations will endorse the last results of orthodox chemistry, or confirm ours."
1905 International Chemical TablesOccult Anu/18
Were They Crackpots or Charlatans?
Lothar Meyer (Breslau, 1884) p. 140
Lothar Meyer (rounded values) p. 191
Exact hits on 10 of 15 elements!Chance of innocent exact hit on 10 of 60 is 1/10,000,000,000,000
For 57 elements (# of anu) / 18 = atomic weight!~
Innocent Subconscious Adjustment?
a) 4 * (4 * 15 + 8 * 3) b) 16 * (4 * 6 + 9)c) 2 * (12 * 7 + 6 * 2 +5)d) 2 * 2 * (4 * 4 + 4 * 6)
e) 2 * 12 * (28 + 4 * 11 + 3 * 3 + 6 * 2 + 4)
Innocent Subconscious Adjustment?
a) 4 * (4 * 15 + 8 * 3)
b) 16 * (4 * 6 + 9)
c) 2 * (12 * 7 + 6 * 2 +5)
d) 2 * 2 * (4 * 4 + 4 * 6)
e) 2 * 12 * (28 + 4 * 11 + 3 * 3 + 6 * 2 + 4)
Grand Total
Cantilever ChoiceOnly one of these five cantilevers is used in any one experiment. They differ in stiffness and ability to twist.
The smallest scaledivision is 20 m
Scanning Tunneling Microscopy (1999)
Geo. FlynnD. Yablon
(Columbia Univ)
Br
O
Br(CH2)11COOHon graphite