chemical kinetics

15
Chemical kinetics

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This set of powerpoint slides revolves around the topic of chemical kinetics. Are you looking for notes on factors affecting speed of reaction? Looking for foolproof ways to calculate the rate of reaction? You have come to the right place! Excellent as a chemistry study material and as an examination revision tool :) A short and sweet O level topic guide with the things you need to ace in chemical kinetics!

TRANSCRIPT

Page 1: Chemical kinetics

Chemical kinetics

Page 2: Chemical kinetics

Rate of a reaction O 1) amount of reactant used up/time

taken O 2) amount of product formed/time

takenO 3) volume of gas produced/time

taken

Page 3: Chemical kinetics

Measuring rate of reaction –volume of gas produced O Since magnesium reacts with dilute

HCl to form hydrogen gas, the speed of reaction can hence be determined by measuring the volume of hydrogen gas produced at regular time intervals.

Page 4: Chemical kinetics

Experimentation Time! O Conduct your own experiment and

sketch out your own vol. of hydrogen vs time graph!

Page 5: Chemical kinetics

Graph analysisO Gradient of graph speed of

reactionO The steeper the gradient, the faster

the speed of reaction O Decrease in steepness indicates

decreasing speed of reaction O Shape of graph

changes/consistency in speed of reaction as time passes

Page 6: Chemical kinetics

Measuring speed of reaction-changes in massO Allow gas produced to escape and

measure the loss of massO Reaction speed determined by

measuring loss of mass at regular time intervals

Page 7: Chemical kinetics

Factors affecting rate of a chemical reaction

O Summary: O Temperature O Concentration O PressureO Surface area O Presence of a catalyst

Page 8: Chemical kinetics

Collision theory O For a reaction to occur, reacting

particles must O 1) collide with each other O 2) possess activation energy

O Note: Orientation of collision must be correct as well

Page 9: Chemical kinetics

Factor 1: Temperature O Increase in temp. increase in KE

increase in no. of collisions + increase in no. of particles with greater than required amount of activation energy more particles react increase rate of reaction

Page 10: Chemical kinetics

Put on your thinking cap!

O Can you explain why food should be kept in deep-freeze compartments in order to ensure its freshness?

O (answer on next slide)

Page 11: Chemical kinetics

O Answer: O The low temperature slows down

chemical reactions which makes the food turn bad.

Page 12: Chemical kinetics

Factor 2: Concentration/Pressure O High concentration/pressure more

particles per unit volume increase in frequency of collisions rate of reaction increases

Page 13: Chemical kinetics

Factor 3: Surface area O Increase in surface area/particle size

increase in exposure to the other reactant increase in probability of collisions increase in rate of reaction

Page 14: Chemical kinetics

Factor 4: Presence of Catalyst

O Speeds up rate of reaction through lowering activation energy needed for reaction to occur

O Think: What can you infer from the above statement?

Page 15: Chemical kinetics

The end Learn through understanding,

not through memorization.