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2000 alcohols alcohols (benzene compounds) Q 0230 46 - 094 Enantioselective Hydroboration of Olefins Catalyzed by Cationic Rhodium Complexes of 2-Phenylquinazolin-4-yl-2- (diphenylphosphino)naphthalene. — Cationic rhodium complexes of 2-phenylquinazolin-4-yl-2-(diphenylphosphino)naphthalene catalyze the hydroboration of indene (VIa), dihydronaphthalene (VIb), and a range of styrenes in high yields, regioselectivities, and with enantiomeric excesses of up to 97%. — (MCCARTHY, MARY; HOOPER, MARKW.; GUIRY, PATRICK J.; Chem. Commun. (Cambridge) (2000) 14, 1333-1334; Dep. Chem., Univ. Coll., Belfield, Dublin 4, Ire.; EN) 1

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Page 1: ChemInform Abstract: Enantioselective Hydroboration of Olefins Catalyzed by Cationic Rhodium Complexes of 2-Phenylquinazolin-4-yl-2-(diphenylphosphino)naphthalene

2000 alcohols

alcohols (benzene compounds)Q 0230

46 - 094Enantioselective Hydroboration of Olefins Catalyzed byCationic Rhodium Complexes of 2-Phenylquinazolin-4-yl-2-(diphenylphosphino)naphthalene. — Cationic rhodium complexesof 2-phenylquinazolin-4-yl-2-(diphenylphosphino)naphthalene catalyze thehydroboration of indene (VIa), dihydronaphthalene (VIb), and a range ofstyrenes in high yields, regioselectivities, and with enantiomeric excesses of upto 97%. — (MCCARTHY, MARY; HOOPER, MARK W.; GUIRY, PATRICKJ.; Chem. Commun. (Cambridge) (2000) 14, 1333-1334; Dep. Chem., Univ.Coll., Belfield, Dublin 4, Ire.; EN)

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