1998 photochemistry, radiation chemistry, chemoluminescence

photochemistry, radiation chemistry, chemoluminescenceO 0160

07 - 077Facile Ring Opening of Tertiary Aminocyclopropanes by Photooxi-dation. — Deuterium labeling experiments of the photosensitized oxidativering opening of tert. aminocyclopropanes such as (I) and (III) reveal that itoccurs via cyclopropylamine cation radical formation followed by 1,5-hydrogenshift. — (LEE, J.; U, J. S.; BLACKSTOCK, S. C.; CHA, J. K.; J. Am. Chem.Soc. 119 (1997) 42, 10241-10242; Dep. Chem., Univ. Ala., Tuscaloosa, AL35487, USA; EN)

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