cheminform abstract: hexagonal-close-packed, hierarchical amorphous tio2 nanocolumn arrays:...

ChemInform 2009, 40, issue 06 © 2009 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim www.cheminform.wiley-vch.de Nanotechnology V 1505 Hexagonal-Close-Packed, Hierarchical Amorphous TiO2 Nanocolumn Arrays: Transferability, Enhanced Photocatalytic Activity, and Superamphiphilicity Without UV Irradiation. — The title nanocolumn array is prepared by pulsed laser deposition using a polystyrene colloidal monolayer as a template (6.7 Pa background O2 pressure) and characterized by FE-SEM, TEM, and XPS. The nanostructured TiO2 array can be transferred to almost any desired substrate during the removal of the polystyrene colloidal monolayer in an organic solution. It exhibits both enhanced superamphiphilicity without further UV irradiation and photocatalytic activity, giving the TiO2 surface an excellent self-cleaning effect. — (LI, Y.; SASAKI, T.; SHIMIZU, Y.; KOSHIZAKI*, N.; J. Am. Chem. Soc. 130 (2008) 44, 14755-14762; Nanotechnol. Res. Inst., Natl. Inst. Adv. Ind. Sci. Technol., Tsukuba, Ibaraki 305, Japan; Eng.) — W. Pewestorf 06- 225

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Page 1: ChemInform Abstract: Hexagonal-Close-Packed, Hierarchical Amorphous TiO2 Nanocolumn Arrays: Transferability, Enhanced Photocatalytic Activity, and Superamphiphilicity Without UV Irradiation

www.cheminform.wiley-vch.de

NanotechnologyV 1505 Hexagonal-Close-Packed, Hierarchical Amorphous TiO2 Nanocolumn Arrays:

Transferability, Enhanced Photocatalytic Activity, and Superamphiphilicity Without UV Irradiation. — The title nanocolumn array is prepared by pulsed laser deposition using a polystyrene colloidal monolayer as a template (6.7 Pa background O2 pressure) and characterized by FE-SEM, TEM, and XPS. The nanostructured TiO2 array can be transferred to almost any desired substrate during the removal of the poly-styrene colloidal monolayer in an organic solution. It exhibits both enhanced superam-phiphilicity without further UV irradiation and photocatalytic activity, giving the TiO2 surface an excellent self-cleaning effect. — (LI, Y.; SASAKI, T.; SHIMIZU, Y.; KOSHIZAKI*, N.; J. Am. Chem. Soc. 130 (2008) 44, 14755-14762; Nanotechnol. Res. Inst., Natl. Inst. Adv. Ind. Sci. Technol., Tsukuba, Ibaraki 305, Japan; Eng.) — W. Pewestorf

06- 225

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