cheminform abstract: highly efficient and enantioselective iridium-catalyzed asymmetric...

ChemInform 2010, 41, issue 17 © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim www.cheminform.wiley-vch.de Amines Q 0120 DOI: 10.1002/chin.201017069 Highly Efficient and Enantioselective Iridium-Catalyzed Asymmetric Hydroge- nation of N-Arylimines. — A new cationic iridium-(SP ,RC)-DuanPhos complex effec- tively catalyzes the enantioselective hydrogenation of acyclic N-arylimines with high turnover numbers (up to 10000) and excellent enantioselectivities (up to 98% e.e.). — (LI, W.; HOU, G.; CHANG, M.; ZHANG*, X.; Adv. Synth. Catal. 351 (2009) 18, 3123-3127; Dep. Chem. Chem. Biol., Rutgers State Univ. N. J., Piscataway, NJ 08854, USA; Eng.) — S. Adam 17- 069

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Page 1: ChemInform Abstract: Highly Efficient and Enantioselective Iridium-Catalyzed Asymmetric Hydrogenation of N-Arylimines

www.cheminform.wiley-vch.de

AminesQ 0120 DOI: 10.1002/chin.201017069

Highly Efficient and Enantioselective Iridium-Catalyzed Asymmetric Hydroge-nation of N-Arylimines. — A new cationic iridium-(SP,RC)-DuanPhos complex effec-tively catalyzes the enantioselective hydrogenation of acyclic N-arylimines with high turnover numbers (up to 10000) and excellent enantioselectivities (up to 98% e.e.). — (LI, W.; HOU, G.; CHANG, M.; ZHANG*, X.; Adv. Synth. Catal. 351 (2009) 18, 3123-3127; Dep. Chem. Chem. Biol., Rutgers State Univ. N. J., Piscataway, NJ 08854, USA; Eng.) — S. Adam

17- 069

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