LanthanumI 2700 DOI: 10.1002/chin.201151012

Hydrothermal Synthesis and Characterization of a Na+ Templated New 3-D Lan-thanum Sulfate Na[C6H14N2][La3(SO4)6(H2O)3] Constructed from La—O—S Tubes and Cubic Cages. — Title compound (III) crystallizes in the orthorhombic space group Cmca with Z = 8 (single crystal XRD). The structure consists of an unusual three-dimensional inorganic open framework constructed from LaO9 and SO4 polyhe-dra. The structure contains zigzag La—O—S chains interconnected to form one-di-mensional tubes and 8-membered rings which share edges to form a cubic cage tem-plated by diprotonated DABCO cations. — (ZHENG, L.; ZHANG, Z.; ZHU, D.; XU*, Y.; Inorg. Chem. Commun. 14 (2011) 1, 258-260, http://dx.doi.org/10.1016/j.inoche.2010.11.008 ; Coll. Chem. Chem. Eng., Nanjing Univ. Technol., Nanjing 210009, Peop. Rep. China; Eng.) — W. Pewestorf

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