cheminform abstract: reactions of dibromotetrafluorobenzene derivatives with sodium phenoxide salts....
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Phenol ethersQ 0270 DOI: 10.1002/chin.201038069
Reactions of Dibromotetrafluorobenzene Derivatives with Sodium Phenoxide Salts. Competing Hydrodebromination and SNAr Processes. — Fluorinated diphe-nyl ether systems are synthesized starting from 1,2- and 1,3-dibromotetrafluorobenzene with high regioselectivity. In contrast, 1,4-dibromotetrafluorobenzene (X) is less reac-tive and gives only low yields. — (BANKS, B.; CARGILL, M. R.; SANDFORD*, G.; TADEUSIAK, A. J.; WESTEMEIER, H.; YUFIT, D. S.; HOWARD, J. A. K.; KILICKIRAN, P.; NELLES, G.; J. Fluorine Chem. 131 (2010) 5, 627-634, DOI:10.1016/j.jfluchem.2010.02.005 ; Dep. Chem., Univ. Durham, Durham DH1 3LE, UK; Eng.) — R. Langenstrassen
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ChemInform 2010, 41, issue 38 © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim