cheminform abstract: silicon tethered alkenyl transfer and type i ene reactions
TRANSCRIPT
2001 organo-silicon compounds
organo-silicon compoundsS 0060
09 - 152Silicon Tethered Alkenyl Transfer and Type I Ene Reactions. —A range of vinyl silanes are prepared and their application in ene cyclizationreactions is investigated. The investigations show that ene cyclization of vinylsilane precursors is not a viable process, but desilylative alkenyl transfer isthe preferred reaction mode. However, type I ene cyclizations are found tobe successful for allylsilane precursors like (IX) and (XII) resulting in thestereoselective formation of silacyclohexanols. — (ROBERTSON, JEREMY;O’CONNOR, GARRY; RINGROSE, CAROLINE L.; MIDDLETON, DONALDS.; Tetrahedron 56 (2000) 42, 8321-8333; Dyson Perrins Lab., Dep. Chem.,Univ. Oxford, Oxford OX1 3QY, UK; EN)
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