chemistry i honors history the electron cloud shells and orbitals
DESCRIPTION
Sub-Atomic Particles J.J. Thomson discovers the electron while experimenting with the cathode ray tube. Shortly after, the proton is identified.TRANSCRIPT
Chemistry I Honors
HistoryThe Electron CloudShells and Orbitals
Some History…
• Remember that John Dalton described the atom as a tiny, indivisible particles in his “Atomic Theorie”.
• His paper did not include any mention of “sub-atomic particles” – they had not been discovered at that time.
Sub-Atomic Particles
• J.J. Thomson discovers the electron while experimenting with the cathode ray tube.
• Shortly after, the proton is identified.
Atoms have a Nucleus
• Ernest Rutherford discovers that the atom has a small, dense center structure that contains all of the protons.
• He calls this structure the “nucleus” - (undoubtedly borrowed from Biology).
• This changes the “vision” of the atom into an idea one that has a positively charged nucleus (because of the protons) and an “electron cloud” where the electrons exist.
Gold Foil Experiment
The Next Question
• Science found itself trying to answer the following question:
• “If the nucleus has a positive charge (protons) and the electrons are negatively charged, why don’t the electrons “fall into” the nucleus?”
The Birth of Quantum Mechanics
• Bohr proposed that the electrons actually move around the nucleus in fixed, circular orbits.
• Borrowing from astronomy, this became the “solar-system” model of the atom.
Not Just Circular Motion…
• Bohr’s colleague, Max Planck determines that the electrons can actually move into paths that are farther away from the nucleus – and they can also move into “orbits” that are closer to the nucleus.
Combining Thoughts
• Together, Bohr and Planck arrive at a conclusion that the electron cloud can be thought of as having different “layers” in which the electrons move.
• The electrons in these layers have specific energies.
Review of the Atom
• We have learned that the atom has a structure that contains a nucleus in the middle that is surrounded by an electron cloud.
• We are able to use the Atomic Number to determine the number of protons in the nucleus and the number of electrons in the electron cloud.
Now for a Focus on the Electron Cloud
• Chemistry views the electron cloud as having layers – we call these layers SHELLS.
• We name these SHELLS with a single letter – starting with the SHELL that is closest to the nucleus.
• Shells:• K (closest to nucleus)• L• M• N• O• P• Q (farthest from nucleus)
More on Shells
• Electrons in these shells have certain energies associated with their distance from the nucleus. (they have energy because they are moving)
• So, electrons in the K Shell have less energy that the electrons in the other shells.
• And… electrons in the Q Shell have more energy that any other electrons.
Shells and Energy
Electrons closer to the nucleus have less energy than electrons farther away from the nucleus.
Jumping Shells
• It is possible for electrons to jump from a closer shell to one that is farther away.
• The electron must absorb energy from some source – like heat, or light, or electricity.
Nucleus
Electron gains energy from some outside source and moves farther away from the nucleus.
And falling…
• It is also possible for an electron to “fall” from a far-away shell to one that is closer to the nucleus.
• When this happens, the electron gives off energy as light, or X-rays, or radio waves, or a number of other types of energy.
nucleus
Electron will give off energy as it falls to a closer shell.
State Expectation
The state NCFE is going to expect you to be able to determine which form of electromagnetic energy will be given off as a specific transition occurs.
So let’s Review:
• Seven SHELLS that are like layers make up the electron cloud.
• They are K , L , M , N , O , P , and Q
• K shell is closest to the nucleus and its electrons have the lowest energy.
• Q shell is farthest from the nucleus and its electrons have the most energy.
• Electrons can gain or lose energy and move from shell to shell.
Now for Orbitals…
• Starting with the L shell (the 2nd shell from the nucleus), the shells are sub-divided into regions called orbitals.
• Depending on the shell, there may be four different “types” of orbitals.
• The 1st shell (K shell) only has one region because it is the closest to the nucleus.
• The entire shell is that single region.
Orbital Types
• The first type of orbital is called an “s” orbital.
• Each of the shells has one of these “s” orbitals.
• This region can “hold” two electrons.
• The next type of orbital is called a “p” orbital.
• Nature actually establishes 3 of these orbitals in each shell - starting with the 2nd shell (the L-Shell)
• Each of the individual p-orbitals can hold 2 electrons – so the set of them can hold a total of 6 electrons.
Continuing…
• The third type of orbital is called the “d-orbital”.
• This type occurs in sets of 5 regions starting with the 3rd shell (the M-Shell).
• Each of the individual d-orbitals can hold 2 electrons for a total of 10 electrons.
• The last of the orbital types is called the “f-orbital”.
• This type occurs in sets of 7 regions starting with the 4th shell (the N-shell).
• Each of the individual orbitals can hold 2 electrons for a total of 14 electrons
First Task:
• Use the information presented so far to answer the questions and fill in the chart on Electron Cloud Structure.
Next Focus – Shell Capacities
• Because the shells contain different numbers of orbitals, they can hold different numbers of electrons.
• This is important – any single orbital can hold 2 electrons.
– This means that an “s” orbital can hold 2 electrons.
– But, a set of “p” orbitals can hold a total of 6 electrons.
– A set of “d” orbitals can hold a total of 10 electrons.
– And a set of “f” orbitals can hold a total of 14 electrons.
Capacities – continued…
s
p
d
f
Each region can hold 2 electrons
Task #2
• Now use the new information along with the previous table to fill in Table #2 on the worksheet.