chemistry lesson group 17

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    Group 7 Elements

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    Have you ever seen this object?When did you use it in your daily life?

    Do you know the chemical element in it?

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    Group 7 Elements

    Consists non-metals

    elements which are known as

    Halogen.

    Exist as Diatomic molecules

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    Fluorine,F

    Chlorine,Cl

    Bromine,Br

    Iodine,I

    Astatine,At

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    Exist as

    diatomic

    molecules at

    room

    conditions

    Do not

    conduct

    electricity

    Low

    Density

    Pungent

    smell and are

    poisonous

    Very low

    melting

    points and

    boiling points

    Physical Properties ofGroup 17 Elements

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    Chlorine

    Bromine

    Fluorine

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    Iodine Astatine

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    HalogenAtomic

    MassMeltingPoint

    BoilingPoint

    Electro-negativity)

    Physical stateat room

    temperature

    Fluorine 18.998 53.53 85.03 3.98 Pale yellow

    Chlorine 35.453 171.6 239.11 3.16

    Greenish-yellow

    gas

    Bromine 79.904 265.8 332.0 2.96Reddish-brown

    liquid

    Iodine 126.90 386.85 457.4 2.66Purplish-black

    solidAstatine (210) 575 610 ? 2.2

    Physical Properties of Group 17 Elements

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    Change in physical

    properties down the groupBrief explanation

    The number of shells of the atom

    increases.

    Atomic radius or atomic size

    increases down the group.

    Forces of attraction between

    particles also increases.

    More heat energy is needed to

    overcome the forces of attraction

    between these particles.

    Mass of atom increase

    Atomic size increases down the

    group

    Forces of attraction between

    molecules also increase

    Ability to receive electrons

    decreases down the group.

    Atomic radius or size of atom

    increases

    Melting point and boiling point

    of elements increases

    Density of elements increases.

    Existence of physical states ofelements which are different at

    room conditions

    Electronegativity decreases

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    Chemical Properties of Group 17 Elements

    Element Electronarrangement

    Number ofvalence

    electrons

    Fluorine 2.7 7

    Chlorine 2.8.7 7

    Bromine 2.8.18.7 7

    Iodine 2.8.8.18.7 7

    Astatine 2.8.18.32.18.7 7

    Table: Arrangement of electrons of Group 17

    elements.

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    Arrangement of electrons ofGroup 17 elements.

    2.7 2.8.7

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    2.8.18.7 2.8.18.18.7

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    2.8.18.32.18.7

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    Chemical Properties of Group 17 Elements

    Halogen elements such as chlorine, bromine and

    iodine show similar chemical properties when reacting

    with

    WaterIron

    Sodium hydroxide solution

    Because they have the same number of valenceelectrons which is 7 electrons at the outermost shell.

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    The reactivity of halogens decreases down the group

    because:

    The atomic size increases down the group

    The distance of the outermost shell becomes

    further from the nucleus

    The force of attraction of the nucleus on theelectrons of the outermost shell decreases

    The tendency of an atom to receive an electron

    to achieve an octet electron arrangement

    decreases

    F2 Cl2 Br2 I2 At2Decreasing reactivity

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    Safety precautions in handlings Group 17 elementsHalogens are elements which are very poisonous andcorrosiveChlorine gas and bromine vapour cause breathingdifficulties and death if inhaled in large quantities.Bromine vapour can cause dizziness, nausea and burns onskin.Thus, halogens must be handled with care:

    perform the experiment in a fume chamberdo not inhale halogen gas or vapourdo not touch halogens with bare hands wear gloves)wear safety goggles when handling halogens.

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