chiral porous metal-organic frameworks with dual active sites for sequential asymmetric catalysis by...
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![Page 1: Chiral porous metal-organic frameworks with dual active sites for sequential asymmetric catalysis by Feijie Song, Teng Zhang, Cheng Wang, and Wenbin Lin](https://reader030.vdocument.in/reader030/viewer/2022032702/56649f425503460f94c61d21/html5/thumbnails/1.jpg)
Chiral porous metal-organic frameworks with dual active sites for sequential asymmetric catalysis
by Feijie Song, Teng Zhang, Cheng Wang, and Wenbin Lin
Proceedings AVolume 468(2143):2035-2052
July 8, 2012
©2012 by The Royal Society
![Page 2: Chiral porous metal-organic frameworks with dual active sites for sequential asymmetric catalysis by Feijie Song, Teng Zhang, Cheng Wang, and Wenbin Lin](https://reader030.vdocument.in/reader030/viewer/2022032702/56649f425503460f94c61d21/html5/thumbnails/2.jpg)
Chemical structures of Mn-salen-derived dicarboxylic acids L1-H2 to L4-H2.
Feijie Song et al. Proc. R. Soc. A 2012;468:2035-2052
©2012 by The Royal Society
![Page 3: Chiral porous metal-organic frameworks with dual active sites for sequential asymmetric catalysis by Feijie Song, Teng Zhang, Cheng Wang, and Wenbin Lin](https://reader030.vdocument.in/reader030/viewer/2022032702/56649f425503460f94c61d21/html5/thumbnails/3.jpg)
Synthesis of CMOF-1 and CMOF-2.
Feijie Song et al. Proc. R. Soc. A 2012;468:2035-2052
©2012 by The Royal Society
![Page 4: Chiral porous metal-organic frameworks with dual active sites for sequential asymmetric catalysis by Feijie Song, Teng Zhang, Cheng Wang, and Wenbin Lin](https://reader030.vdocument.in/reader030/viewer/2022032702/56649f425503460f94c61d21/html5/thumbnails/4.jpg)
Powder XRD pattern (a) and TGA curve (b) for CMOF-1.
Feijie Song et al. Proc. R. Soc. A 2012;468:2035-2052
©2012 by The Royal Society
![Page 5: Chiral porous metal-organic frameworks with dual active sites for sequential asymmetric catalysis by Feijie Song, Teng Zhang, Cheng Wang, and Wenbin Lin](https://reader030.vdocument.in/reader030/viewer/2022032702/56649f425503460f94c61d21/html5/thumbnails/5.jpg)
Space-filling models of CMOF-1 (a) and CMOF-6′ (b), viewing perpendicular to the (001) plane.
Feijie Song et al. Proc. R. Soc. A 2012;468:2035-2052
©2012 by The Royal Society
![Page 6: Chiral porous metal-organic frameworks with dual active sites for sequential asymmetric catalysis by Feijie Song, Teng Zhang, Cheng Wang, and Wenbin Lin](https://reader030.vdocument.in/reader030/viewer/2022032702/56649f425503460f94c61d21/html5/thumbnails/6.jpg)
Empirical linear relationship between the MOF void space% as calculated by PLATON and the solvent weight loss% determined by TGA. Each square represents a MOF structure published by
the Lin group from 2002 to 2011.
Feijie Song et al. Proc. R. Soc. A 2012;468:2035-2052
©2012 by The Royal Society
![Page 7: Chiral porous metal-organic frameworks with dual active sites for sequential asymmetric catalysis by Feijie Song, Teng Zhang, Cheng Wang, and Wenbin Lin](https://reader030.vdocument.in/reader030/viewer/2022032702/56649f425503460f94c61d21/html5/thumbnails/7.jpg)
(a) Photos of CMOF-1 (left) and CMOF-6′ (right).
Feijie Song et al. Proc. R. Soc. A 2012;468:2035-2052
©2012 by The Royal Society
![Page 8: Chiral porous metal-organic frameworks with dual active sites for sequential asymmetric catalysis by Feijie Song, Teng Zhang, Cheng Wang, and Wenbin Lin](https://reader030.vdocument.in/reader030/viewer/2022032702/56649f425503460f94c61d21/html5/thumbnails/8.jpg)
The coordination environment of the [Zn5(μ3-OH)2(O2CR)8] node (a) and the structure of the (L3)2 dimeric motif (b) in CMOF-2.
Feijie Song et al. Proc. R. Soc. A 2012;468:2035-2052
©2012 by The Royal Society
![Page 9: Chiral porous metal-organic frameworks with dual active sites for sequential asymmetric catalysis by Feijie Song, Teng Zhang, Cheng Wang, and Wenbin Lin](https://reader030.vdocument.in/reader030/viewer/2022032702/56649f425503460f94c61d21/html5/thumbnails/9.jpg)
A topological scheme of the threefold interpenetrated frameworks (a) and one of the frameworks (b) in CMOF-2.
Feijie Song et al. Proc. R. Soc. A 2012;468:2035-2052
©2012 by The Royal Society