cold gas dynamic spray

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    Cold Spray

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    Spraying of Composites

    Zhou coated a carbon fibre polymer matrix composite with pure

    Al and Al/Cu bi-metallic (with Al as a binding layer)

    Copper, zinc, tin was also tried but unsuccessfully deposited

    Found that gas heating softened the substratebetter bonding

    Parameters for spraying pure Al:

    standoff distance 20mm

    Nitrogen gas = 1.2MPa

    temperature of 300C

    Parameters for spraying Cu: standoff distance 15mm

    pressure 1.9 MPa

    temperature 450 C

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    Spraying of Plastic Substrate

    Zhang investigated the effects of spraying Al powder onto

    plastic (ABS).

    Coating was thin and not continuous and that only relatively

    small particles adhered to the surface.

    Heavy erosion of the plastic substrate was also reported.

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    Spraying of Plastic Substrate

    Lupoi experimented using low density powder so as to reduce

    erosion

    Experimented with Al, Cu and tin

    Al: slight erosion, no deposition

    Cu: heavy erosion

    Found that tin was most suitable for spraying a variety of

    plastics (ABS, polypropylene, polystyrene)

    Use of tin proved successful in reducing erosion

    Parameters for spraying Tin:

    pressure 5-30 bar, air

    standoff distance: 103 mm

    temperature not stated

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    Carbon Nanotubes (CNT)

    Why? Improved strength, toughness, conductivity

    CNT Composites:

    CNT/aluminium

    CNT/polymer: improves matrix tensile strength

    CNT/silica: improved bending strength and fracture toughness

    CNT/copper: improved yield strength, tensile strength

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    Dispersing CNT

    Blending/mixing

    Spray drying

    Ball milling

    Turbula mixer

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    Cold Sprayed CNT

    Bakshi prepared (spray drying):

    Al-CNT

    Al-Si-CNT

    5% CNT in Al-Si eutectic powder

    Mixed with pure Al in proportions of 10wt% and 20wt%

    Substrate 6061 Al alloy

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    CNT - Bakshi

    Parameters: Temperature not stated but below 600K

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    CNT - Bakshi

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    CNT/Cu (Used Sintering & hot

    pressing processes) Used to enhance the strength of CNTs (carbon nanotubes)

    with reinforced Al matrix composites by introducing Cu into

    the composite material

    The nano-sized Cu powder and CNTs were mixed into

    composite powder through high energy ball milling process Used sintering and hot extrusion process

    The weight percent of CNT is 1.0 for 5 vol.% of CNT/Cu

    nanocomposite and 2.2 for 10 vol.% of CNT/Cu

    nanocomposites

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    Measurement Methods

    Density measurement (water displacement)

    Optical microscopy (microstructure)

    Scanning Electron Microscope (morphology, particle size

    distribution, fracture surfaces)

    Microhardness

    Nanoindentation

    Tensile testing

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    Possible ideas:

    Glass fibre substrate

    Al powder

    Cu powder

    tin

    Why? Applications for structural, electronic or thermalconductivity.

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    Carbon nanotubes

    Al powder (perhaps Al-Si)

    Cu powder (hasnt been done before using cold spray process)

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    Plastic powders

    Used in South Africa: Nylon and polyethelene

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    Metallic Powder Properties

    Aluminium

    Relatively low density, good electrical conductor and thermal

    conductor, corrosion resistant, high yield strength

    Zinc

    Corrosion resistant, thermal conductor

    Copper

    Good electrical conductor and thermal conductor, corrosion

    resistant, ductile, non magnetic

    Tin Good electrical conductor and thermal conductor, corrosion

    resistant

    Nickel

    Corrosion resistant, easily magnetised