comets & meteorites outline 1. origin and structure of comets 2. cometary composition & coma...
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COMETS & METEORITES
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Outline
1. Origin and Structure of Comets
2. Cometary Composition & Coma Chemistry
3. Origin and Composition of Meteorites
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Comets, Astronomy & Astrobiology
• Comets are the key to understanding the Solar Nebula & its evolution.
• Comets could serve as probes of chemical processes occurring in the midplanes of astronomical disks
• Comets may have provided key organic nutrients required to jump start life on Earth.
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Processes affecting ices and dust
in Protoplanetary Disks.
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Comet Reservoirs in our planetary system.
After Stern, Nature 424:639-642 (2003).
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When comets are near the Sun and active, comets have several distinct parts:
nucleus: relatively solid and stable, mostly ice and gas with a small amount of dust and other solids
coma: dense cloud of water, carbon dioxide and other neutral gases sublimed from the nucleus hydrogen cloud: huge (millions of km in diameter) but very sparse envelope of neutral hydrogen
dust tail: up to 10 million km long composed of smoke-sized dust particles driven off the nucleus by escaping gases; this is the most prominent part of a comet to the unaided eye
ion tail: as much as several hundred million km long composed of plasma interactions with the solar wind
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Major Comet Structures
COMA
ION TAIL
HI CLOUD
NUCLEUS
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COMET NUCLEUS
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Comets: Porous aggregates of ices and refractories
GIOTTO PIAVEGA-1 PUMA-1VEGA-2 PUMA-2
Time-of-flight mass spectra wererecorded during impact of dust
• 70 % of the dust grains comprise: mixed phase of organics and silicates
• 30 % of the dust grains do not contain organics
• CHON particles and silicate components are interspersed on sub-micron scales
Kissel & Krueger 1987Jessberger et al. 1988
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NUCLEUS ICE COMPOSITION FROM COMA OBSERVATIONS?
PRISTINE INTERSTELLAR MATERIAL?
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THE COMAMolecules are liberated from the nucleus by solar heating and sublimation
Molecules are destroyed by photodissociation & photoionization
H2O + h H + OHOH + h H + O
H2O + h H2O+ + e-
Nucleus molecules are referred to as the “parent molecules”
The fragments produced by the absorption of a photon are called “daughters”
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CHEMICAL REACTION PROCESSES
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Remote Sensing of Cometary Comae
Mumma et al. (2003)
R = 2000
R = 24,000
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OUTGASSING CURVES OF VOLATILES
Biver et al. 1998
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Chemical Composition of Comets
Bockelee-Morvan, Crovisier, Mumma, and Weaver (Comets II, 2003)
Abundances (%, relative to water)
(The grey bar indicates the range measured to date)
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H2O
COCO2
CH3OHNH3
CS2
HCNSO2
CH4
C2H2
C2H6
H2COOCS
MOLECULAR STRUCTURE OF THE COMA
CO+
CO2+
O+
H2O+
H3O+
OHHI
NH2
S2
CNSONSHNC?C2, C3
POM: H2CO CO
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SPECIES HM PROTOSTARS LM PROTOSTARS COMETS
H2O 100 100 100
CO 1-20 1-60 5-20
CO2 ~20 15-40 2-10
CH4 1-4 - 0.2-1.2
CH3OH 1-35 1-20 0.3-2
H2CO 3 - 0.2-1
OCS 0.05-0.18 < 0.08 0.5
NH3 < 5 - 0.6-1.8
C2H6 < 0.4 - 0-4-1.2
HCOOH 3 - 0.05
O2 < 20 - 0.5 ul
N2 ? ? ?
XCN 0.3-2.9 - -
HCN < 3 - 0.2
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Physics World, Charnley et al. 2003
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CO2+
C4H2
S2
CS2
C2H6
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COMA CHEMISTRY PROBLEMS
• Molecule formation in the collisional inner coma ?
HNC, S2, NS, C2, C3 … role of `exotic’ reactions (electrons and Hf ) ?
• Origin of extended coma sources ?
Polyoxymethylene (POM) --> H2CO, CO other complex organic polymers --> HNC, CN, OCS ?
• Cosmogonic information ? conditions in the 5-40AU region of the early Solar
System; D/H (HDO/H2O), ortho-para ratios, 14N/15N
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Fast H Atoms in the Coma
• Hf atoms created in photodissociation of water:
H2O + --> OH* + Hf
• Thermalisation of Hf atoms is the principal heat source in the inner coma.
• Possible role in driving ‘suprathermal’ chemistry (reactions with barriers or which are endoergic) ?
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Destruction of Methanol
1) Photodissociation:
CH3OH + --> CH3O + H (~60%)
CH3OH + --> H2CO + 2H (~40%)
2) Hf Reactions:
CH3OH + Hf --> CH2OH + H2
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Coma Chemistry in Hale-Bopp
w/out Hf reactions with Hf reactions
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Deuterium Chemistry in Hale-Bopp
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mumma_JWST_051203.27
New, LP, & Halley-type (HTCs)5 - 40 AU
Oort cloud
1P/Halley 19P/Borrelly
Chemical differences betweentwo dynamical comet families
Type:Formed:Reservoir:Orbit:
Giotto.HMC.MPAE DS-1.JPL.NASA
Jupiter-family (JFCs)> 40 AU
Kuiper belt
mumma.061203.27
CARBON-DEPLETED?OH, C2, C3, CN, NH
ENRICHED IN C2H6 & CH3CCH?
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Nuclear Spin Temperatures in Oort Cloud Comets.
mumma_100903.28Mumma et al. 1987; 1989; 1993
I = 1 I = 0
2I +1 = 3, ortho = 1, para
OPR = 3 e-E/kT
E = 24 cm-1
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Nuclear Spin Temperatures in Oort Cloud Comets.
mumma_100903.29After Kawakita et al. Ap. J. (in press, 2003)
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14N/15N~140IDPs
ISM DEPLETION CORES 14NH3/15NH3~140
NITROGEN ISOTOPE RATIOS
COMETS:
HC14N/HC15N~400
C14N/C15N~140
(TERRESTRIAL 14N/15N~270)
PROTOSOLAR 14N/15N~400
PROCESSING ISM TO ORGANIC POLYMERS ?
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Parent Body EvolutionD. Cruikshank, in From Stardust to Planetesimals, ASP Conference Series 122, 315 (1997)
Interstellar MediumInterstellar Medium
Solar NebulaSolar Nebula
PlanetesimalsPlanetesimals
Kuiper Belt ObjectsKuiper Belt ObjectsPerturbedOutwards
PerturbedInwards
Incorporated intoPlanets
and Asteroids
heat
Parent Bodies ofMeteorites
Collide withPlanets
Oort Cloud
Long-PeriodComets
Ejected from Chaotic Orbits toEncounters with Neptune
Perturbed Inward toPlanet-Crossing
Orbits
Short-Period Comets
Ejected
Collide/Ejected
109 yr 20 % 80 %109 yr
106 yr
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Asteroids
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Asteroids are classified into a number of types according to their spectra (and hence their chemical composition) and albedo: C-type, includes more than 75% of known asteroids: extremely dark (albedo 0.03); similar to carbonaceous chondrite meteorites; approximately the same chemical composition as the Sun minus hydrogen, helium and other volatiles S-type, 17%: relatively bright (albedo .10-.22); metallic nickel-iron mixed with iron- and magnesium-silicates M-type, most of the rest: bright (albedo .10-.18); pure nickel-iron
There are also a dozen or so other rare types
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Asteroids are also categorized by their position in the solar system:
Main Belt: located between Mars and Jupiter roughly 2 - 4 AU from the Sun; further divided into subgroups: Hungarias, Floras, Phocaea, Koronis, Eos, Themis, Cybeles and Hildas
Near-Earth Asteroids (NEAs): ones that closely approach the Earth
Atens: semimajor axes less than 1.0 AU and aphelion distances greater than 0.983 AU;
Apollos: semimajor axes greater than 1.0 AU and perihelion distances less than 1.017 AU
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Meteorites
Murchison
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Iron
primarily iron and nickel;similar to type M asteroids
Stony Iron
mixtures of iron and stony material like type S asteroids
Chondrite
by far the largest number of meteorites fall into this class;similar in composition to the mantles and crusts of the terrestrial planets
Five Meteorite Types
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Carbonaceous Chondrite
very similar in composition to the Sun less volatiles;similar to type C asteroids
Achondrite
similar to terrestrial basalts;the meteorites believed to have originated on the Moon and Mars are achondrites
Meteorite Types
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TYPES OF METEORITES
TYPE SUBTYPE FREQUENCY COMPOSITION FORMATION
Stones Carbonaceous 5 % Water, carbon Primitive Chondrites silicates, metals
Chondrites 81 % Silicates Heated underpressure
Achondrites 8 % Silicates Heated
Stony irons 1 % 50 % silicates, Differentiated 50 % free metal
Irons 5 % 90 % iron Differentiated 10 % nickel
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Parent Bodies
Energy sources: • Radiocactive decay processes• Low-energy impacts• Irradiation processes
Parent Body Processing:
Organic compounds are converted into secondary products e.g. amino acids
HeatLiquid water
+Asteroids
Comets
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Carbonaceous Chondrites (CC)
Stony meteorites; classified into CM, CI, CV and CO, based on chemical dissimilarities.
are the most primitive meteorites in terms of their elemental composition.
have experienced different degrees of aqueous alteration of their original anhydrous silicate matrix.
are rich in organic matter (C content of > 3%).
Most important CC’s: Murchison, Murray, Orgueil.
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Meteorites represent the only extraterrestrial material which can be studied on Earth.
Volatile fraction:
Insoluble C-fraction:60-80 % aromatic carbonhighly substituted smallaromatic moieties branchedby aliphatic chains
Murchison
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Fullerenes in Carbonaceous Chondrites
Becker et al. 2000
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Organics Found in Meteorites
Total Carbon Content: > 3% (by weight); Soluble Fraction: < 30% of total C
COMPONENTS:ACIDS:
Amino acidsCarboxylic acidsHydroxycarboxylic acidsDicarboxylic acidsHydroxydicarboxylic acidsSulfonic acidsPhosphonic acids
FULLERENES:
C60, C70
He@C60
Higher Fullerenes
HYDROCARBONS:
non-volatile: aliphaticaromatic (PAH)polar
volatile
OTHERS:
N-HeterocyclesAmidesAmines AlcoholsCarbonyl compounds
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1 D-Aspartic Acid
2 L-Aspartic Acid
3 L-Glutamic Acid
4 D-Glutamic Acid
5 D,L-Serine
6 Glycine
7 -Alanine
8 -Amino-n-butyric Acid (g-ABA)
9 D,L-b-Aminoisobutyric Acid (b-AIB)
10 D-Alanine
11 L-Alanine
12 D,L--Amino-n-butyric Acid (b-ABA)
13 -Aminoisobutyric Acid (AIB)
14 D,L--Amino-n-butyric Acid (a-ABA)
15 D,L-Isovaline
16 L-Valine
17 D-Valine
X: unknown
Chromatograms of Meteorite Extracts
Ehrenfreund et al., 2001
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ISOTOPIC RATIOS FOR “C” AND “H”
Irvine 1998
Terr.ocean= D= O Cosmic D/H ratio ~ 0.8-2x10-5
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Amino Acids in Carbonaceous Chondrites
Amino acids are readily synthesized under a variety of plausible prebiotic conditions (e.g. in the Miller-Urey Experiment).
Amino acids are the building blocks of proteins and enzymes in life on Earth.
Chirality (handedness) can be used to distinguish biotic vs. abiotic origins.
Most of the amino acids found in meteorites are very rare on Earth (AIB, isovaline).
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What is Chirality?
• Left- and right-handed mirror molecules are called enantiomers.
Enantiomers possess identical physical properties (melting point etc.).
They rotate the plane of planar-polarized light in opposite directions.
They cannot be chromatographically separated on a non-chiral column.
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Separation on chiral column
or
Derivatization to form diastereoisomers, separation on non-chiral column
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Enantiomeric Excesses in Meteoritic Amino Acids
Pizzarello and Cronin, Geochim. Cosmochim. Acta 64, 329-338 (2000)
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imet
hyl
-p
enta
no
ic a
cid2S
,3S
/2R
,3R
2S,3
R/2
R,3
S
Iso
valin
e
-M
eth
yln
orv
alin
e
-M
eth
ylva
line
-M
eth
yln
orl
euci
ne
-M
eth
yl-n
-bu
tyri
c ac
id
No
rval
ine
Ala
nin
e
Val
ine
Mechanisms?Racemization?Amplification?
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Nucleobases in Carbonaceous Chondrites
are very important in the replicating system of all known
terrestrial organisms (in DNA and RNA)
have been detected in Murchison, Murray and Orgueil
meteorites at the 200-500 ppb level
(Schwartz and coworkers, 1979-1982)
various other (non-biogenic) N-heterocycles, including a
variety of alkylated pyridines, were found in meteorites
no isotopic measurements have been reported
N
NHN
NH
O
Hypoxanthine
N
NN
NH
NH2
Adenine Guanine Xanthine
N
NHN
NH
O
NH2 NH
NHN
NH
O
O
NH
NH
O
O
Uracil
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Summary
- Comets are a mixture of pristine ISM & nebular materials
- Coma chemistry constrains nucleus composition
- Comets preserve record of the early Solar System
- Meteorites are highly processed nebular material
- Meteorites are very rich in organics