compound identified 2.3 . 1.6 0.7 pinene, a 1 7.0 …environmental chamber, product loading: test...

01890 Final ReportJanuary 31,1996

Appendix CPage17of43

COMPOUND IDENTIFIED

Nonane, 4-methyl

Octane, 3,6-dimethyl

Pentane, 2,2,4-trimethyl (Isooctane)

Pinene, a(2,6,6-Trimethyl-bicyclo[3.1.1 Jhept-2-ene1

Styrene

Toluene (Methylbenzene)

Unidentified

Xylene (para and/or meta)

Xylene, ortho

cis-I-Ethyl-3-methykyciohexane*

1.0 6.0 24.0 48.0 72.0 96.0

1.9

.2.3

1.6 0.7

3.4

7.0 3.1 5.5 5.5 4.2 6.5

9.2 0.7

1.5

4.8

2.0

4.0

%dicates best NISTIEPANH library match only.Individual compounds and TVOC (total volatile organic compounds) are calibrated relative to toluene.TVOC detection limit: 0.9 yg/m’. Individual detection limits may vary, depending on instrument response.

.

Environmental Chamber,Product Loading:Test Conditions:

Test Period:



Cushion C

SA30.42 m2/m31.00 ACH50.0% RH f 5.0% RH23.0 degs C f 2.0 degs C06/22/95 - 06126195

CHAMBER 7VOC CONCENTRATIONS FROM 0.000 TO 96.000 HOURS

ELAPSED T v o cEXPOSURE CONCENTRATION

HOUR ug/m3

0.000 0.0

1 .ooo 915.0

6.000 826.6

24.000 265.3 .

48.000 366.9

72.000 253.1

96.000 38.8

IVOC CONCENTtiTIONS (pg/m’) FROM 0.000 TO 96.000 HOURS

COMPOUND IDENTIFIED 1.0 6.0 24.0 48.0 72.0 96.0

1,3-Dioxolan-2-one, cl-methyl’ 5.9 4.8 11.0 9.1

l-Octanol, 3,7-dimethyl* 2.0 2.4

I-Pentanol, 2-methyl-’ 1.5

I-Pentanol, 4-methyl-2-propyl- (9CI)* 3.0

2,2,7,7-Tetmmethyloctane” 15.6 5.5

2,6-Diitert-butyWmethylphenol (BHT) 66.9 106.1 31.3 82.5 72.1 38.8

2-Hexanol, 5-methyl-* 4.5

2-Propanol (Isopropanol) 2.2

-I_.-__IL-. . . ..--- - -^__-_l”^



COMPOUND IDENTIFIED 1.0 6.0 24.0 48.0 7i.o 96.0

2-Propanol, 1 ,3-dichloro- 74.8 106.3 41.6 65.2 86.3

2.Propanone, I-(dimethylamino)-* 5.6

2i-k2,4a-Methanonaphthalene, 1.6 1.3 1.0 1.7 0.81,3,4,5,6,7-hexahydro-l , I ,5,5-tetramethyl-, (2s).’

4-Octanol, 4,7-dimethyl-* 1.2

A&amide, N,N-dimethyl- (8Cl9CI) 82.0 65.0 61.8

Acetone (2.Propanone) 11.2

Benzene, I-ethyl-4-methyl 2.6(IdEthyltofuene)

Benzene, I-methyl+(1-methylethyl) 2.2(p-Cymene; 4-lsopropyltoluene)*

Benzene,(l ,I-Dimethylethyl)- . 6.8 2.0(t-Butylbenzene)*

Butane, 1.52,2’-[methylenebis(oxy)]bis[2-methyl-*

Cyclohexane, propyl 1.7

Cyclohexanone, 4-methyl-* 1.4

Cyclohexasiloxane, dodecamethyl* 8.9 9.4 3.1 1.6

Cyclopentasiloxane, decamethyl* 145.4 123.7 7.3 0.8

Cyclotetrasiloxane, octamethyl 132.3 32.1

Decane, 2,5,9-trimethyl- (9CI) 5.0 4.6 0.7

Decane, 2-methyl’ 5.1 3.4

Decane, 3-methyl 16.8 5.1

Decane, 4-methyl 10.3 6.1

Dodecane 3.4 1.2

Ethane, III, I-trkhloro 2.8

Ethane, 1,2-dichloro 1.9 .

Ethane,l ,l’oxybis[2-chloro- 1.2(s-Dichloroethyl ether)

Ethanol 10.9


Appendii CPage 20 of 43


Ethene, 1,1,2,2-tetrachloro 2.7(Tetrachloroethylene)

Fomramide, N,N-dimethyl 2.8 78.9 13.5 6.1

Hepiane, 2,2,4,6,6-pentamethyl (8Cl9CI)” 6.8 1.9

Heptane, 2.2,6,6-tetramethyl* 11.2 1.3

Heptane, 4-ethyl-2,2,6,6-tetramethyl- 18.9 7.3(9Cl)

Hexanal (Hexaldehyde) 1.4

Hexane, 1 ,Y-Oxybis (Hexyl ether* 1.5

Hexane, 2,2,4-trimethyl 2.3

Isooctane, (ethenyloxy)- (9CI)* 1.3

Methanol 28.7 5.4

Methylene chloride (Dichloromethane) 5.1

N,N-Dimethyl-2-propenamide 5.0 100.9 70.9 126.8 82.6

Nonane 2.9

Nonane, 2,5-dimethyl-* 13.1 5.9

Nonane, 3,7-dimethyl’ 3.4

Nonane, 3-ethyl 1.9

Nonane, 3-methyl 1.5

Nonane, 4,5-dimethyl* 2.1 -

Octane, 2,2-dimethyl* 4.7

Octane, 2,3,6-trimethyl-* 2.7

Octane, 2,3-dimethyl* 2.3

Octane, 2,6-dimethyl 3.0

Oxetane, 2+dimethyl-, trans-* 5.9 1.2

Oxirane, (chloromethyl)-• 1.4

Pentane* 1.3

Pentane, 2,2,4-trimethyl (Isooctane) 9.2 1.4

Pentane, 2,3,4-trimethyl 3.4


Appendix CPage 21 of 43

.

COMPOUND IDENTIFIED

Pentane, 3-ethyl-2,2-dimethyl- (8Cl9CI)”

Phenol

Propane,? ,2,3-trichloro


Undecane

Undecane, 6-methyl-’

Unidentified


Xytene, ortho

a-Methylstyrene (iso-Propenylbenzene;(I-Methylethenyl)benzene)

1.0 6.0 24.0 48.0 72.0 96.0

2.8

.2.7 1.5 2.0

129.0 111.5 20.6 6.5

59.9 2.5

9.4 4.1

3.2 1.3

5.7 2.3

7.1

2.8

3.7 2.3

%dkates best NISTIEPAMH library match only.hdiidual compounds and TVOC (total volatile organic compounds) are calibrated relative to toluene.NDC detection limit: 0.9 pg/m’. Jndividual detection limits may vary, depending on instrument response.



Environmental Chamber.Product Loading:T& Conditions:

TestPeriod:

Cushion D

SA40 40 m2/m3I:00 ACH50.0% RH f 5.0% RH23.0 degs C f 2.0 degs C06/26/95 - 06/30/95

CHAMBERTVOCCONCENTRATIONS FROM0.000TO96.000HOURS

ELAPSED TvocEXPOSURE CONCENTRATION

HOUR (pglm3)

0.000 0.0

1 .ooo 349.0

6.000 634.9

24.000 421.6

48.000 345.8

72.000 NA*

96.000 212.0 4

‘NA: data not available due to laboratory error.

lVOCCONCENTRAT10NS(pglm3)FROM0.000T096.000HOURS

COMPOUND IDENTIFIED

l&Dimethylpiperazine

I H-Cyclopropa[a]naphthaIene,la,2,3,5,6,7,7a,7b-octahydro-1,1,7,7a-te!ramethyl-,[laR-(laa,7a,7aa,7ba)J*

1.0 6.0 24.0 48.0 96.0

58.5 319.1 71.4 55.3

1.3 1.7 1.3

2,2,7,7-Tetramethyloctane* 0.8

2,6-Di-terkbutyl4methylphenol 23.5 108.1 149.9 122.1 100.9(WIT)

2-Butenal’ 2.1



COMPOUND IDENTIFIED

2-Propanol (isopropanol)

44sobutylmorpholine*

Acetamide, N,N-dimethyl- (8Cl9CI)

Acetate, butyl

Acetic acid, hydroxy-•

Acetone (2,Propanone)

3enzene, l,2,4-trimethyl

Benzene, 1,2-dichloro

Benzene, ethyl

Benzene, propyl

Butane, 2-methyl (Isopentane)

Cyclohexasiloxane, dodecamethyl*

1.0 6.0 24.0 48.0 96.0

2.5

1.1

13.0 19.4 15.7 11.0 7.4

1.1

1.0

5.9

0.7

7.7 8.0 5.3 3.8 1.9

1.0

1.0

Ethane, 1, 1, I-trichloro

Ethanol, 2-butoxy



COMPOUND IDENTIFIED 1.0 6.0 24.0 48.0 96.0I

Octane, 2,3-dimethyl

Pentane, 2,2,4-trimethyl (Isooctane)

Pentane, 2,3,4-trimethyl’

Phenol

Pinene, a(2,6,6-Trimethyl-bicyclo[3.1.l]hept-2-ene)

Styfene

1.2

2.11

0.6

1.0

1.1

40.6 40.3 23.1 12.2 4.2

Toluene (Methylbenzene) 16.9 4.0

Undecane 1.6 1.0

Unidentified 100.8 101.2 138.2 130.4 90.7IXyiene, ortho I 1.5 I I I I

Wtkates best NISTEPAINIH library match only.Individual compounds and TVOC (total volatile organic compounds) are calibrated relative to toluene.TVOC detection limit: 0.9 pg/m’. Individual detection limits may vary, depending on instrument response.



Cushion E

Environmental Chamber:Product Loading:Test Conditions:

Test Period:

SA50.42 m2/m3I .OO ACH50.0% RH k 5.0% RH23.0 degs C f 2.0 degs C06/26/95 - 06/30/95

CHAMBER TVOC CONCENTRATIONS FROM 0.000 TO 96.000 HOURS

EXPOSURE CONCENTF$ATIONELH’+P;;D /;;)

0.000 0.0

1 .ooo 1447.1

6.000 1631.1

24.000 1260.0

48.000 856.1

72.900 572.9

96.000 177.7

IVOC CONCENTRATIONS &g/m’) FROM 0.000 TO 96.000 HOURS


-1,2-Propanediol (Propylene 3.1 27.1 28.1 26.8 20.2glycol)

I ,3-Butanediol’ 4.2 44.9 40.4 41.5 30.6

1,3-Cyclohexadiene, 2.5 2.2I-methyl4(+methylethyl)-• I1 $I-Cyclohexadiene, 0.8I-methyl+(‘l-methylethyl)- (9CI)

I ,4-Dimethylpiperazine 2.1

1 +Dioxane, 3.12-methyl-3-methylene-*

1-Heptanol, 6-methyl* 1.7



COMPOUND IDENTIFIED ‘1.0 6.0 24.0 48.0 72.0 96.0

IiUndecene, 8-methyl-* 6.5 5.3

2(3H)-Furanone,dihydro 3.3 3.5' 2.9 1.9(Butyrolactone)*

2,3-Butanediol 2.9 28.2 24.5 26.2 19.8

2,6-Octadien-I-01, 3,7-dimethyl-, 1.7(Z)-*

2-Butanone, 3-hydroxy-• 2.1

2-Decene, 4-methyl-, (Z)* 6.2

2-Decene, %methyl-, (Z)-” 5.7 2.7

2-Decene, 8-methyl-, (Z)-* 3.0 1.6

3-Cyclohexene-‘l-methanol, 43.7 69.1 49.8 54.7 35.7 20.2a,a,4-trimethyl-, acetate*

4-Dodecene” 8.0 6.9

4-Phenylcyclohexene 2.3 9.8 8.4 5.5 3.0 1.6

4-Undecene, (Z)-• 7.0 6.3

NJndecene, (E) 8.3 6.4

6-Dodecene, (E)- (8Cl9CI)” 3.1

Acetamide, N,N-dimethyl- 2.7 2.5 3.4 1.7(8Cl9CI)

Acetate, methyl (Acetic acid, 11.4 1.7Methyl ester)

Acetic acid 1170.4 1271.3 1004.@ 641.7 426.1 137.5

Acetic acid, phenylmethyl ester 8.4 3.9 2.1 1.2lBenzyl acetate)

Acetone (2.Propanone) 16.8 3.7

Benzaldehyde 8.1 4.1 2.8 1.7 2.2

Benzyl alcohol 7.1 4.4 6.0 3.8 1.6(Benzenemethanol)

Bicyclo[3.1 .l]heptane-2-methano 0.3I, 6,6-dimethyl-, acetate*

-“-- ..- --I-. -“.”

-_ - I . .I. --.-_l_---_l_.__ . . . _ _ _

___.



COMPOUND IDENTIFIED

Biqrclo~.2.0]undec-4-ene,4J I,1 Wimethyl-8-methylene-,[IR-(1 R@,42,9S@)]-*

Cedrene, a*

Cyclohexane, 1, I’-oxybis*

Cyclohexanol

Cyclohexanol,I-methyl4(1-methylethenyl)-,acetate*

Cyclohexene,l-methyl-4-(I-methylethylidene)-•

Cyclopentasiloxane, decamethyl*

Cyclopropane, l-ethyl-2-heptyl-(9Cl)’

Cyclotetrasiioxane, octamethyl

Decane

Ethanol

Limonene (Dipentene;

j-Methyl4( 1 -methylethyl)cyciohexene)

Methanol

Nonane, 2,6-dimethyl’

Propanoic acid


1.0 6.0 24.0 48.0 72.0 96.0

1.2 1.4 1.3

5.0 5.3 5.7 2.5 4.8 1.7

2.5 2.1 1.2

1.8

1.2 1.3 0.9

22.3 20.1 9.0 2.7 1.0 0.9

21.4 2.4

7.3 4.7

1.3

1.4 1.9

3.1 1.8

25.9 35.0 31.0 13.9 6.0 6.6

24.6

2.0

-19.6 16.8 12.3 9.5 1.5

4.8

WI --._- . -- _- -_

---*,



,1 COMPOUND IDENTIFIED 1.0 6.0 24.0 48.0 72.0 96.0

Tricyclo[5.4.0.02,8]undec-9-ene, 7.7 8.3 7.7 4.8 4.8 3.12,6,6,9-tetramethyl-•

Unidentified 14.7 4.4 5.0 1.1 1.3 0.9 4

Wckates best NISTIEPAINIH library match only.tndiiual compounds and TVOC (total volatile organic compounds) are calibrated relative to toluene.TVOC detection limit: 0.9 vg/m’. Individual detection limits may vary, depending on instrument response.



Carpet B at Elevated Conditions (70 “C, 8% RH, high loading)

Environmentalchamber:Product Loading:Test Conditions:

TestPeriod:

SC41.64 m2/m3l.OOACH8.0% RH f 2.0% RH70.0 degsCk5.0degsC06121/95 - 06/21/95

CHAMBERTVOCCONCENTRATlONSFROM0.000TO99.000HOURS

t

ELAPSED T v o cEXPOSURE CONCENTRATION

HOUR @g/m3

-J

lVOCCONCENTRAT10NS(~g/m3)FROM 0.000T06.000 HOURS

COMPOUND IDENTIFIED 0.0 1.0 6.0

1,2-Ethanediol (Ethylene glycol) 98.3 466.0

1,3-Butanediol, (S)-' 4.3

l+Pentadien-3-01' 36.3 7.9

I-Butanol (N-Butylalcohol) 165.1 12.3

A-Decanol (N-Decyl alcohol) 60.6 21.6

I-Decene, 8-methyl 292.6 92.5

I-Dodecanol 766.5 63.4

I-Dodecene* i 51.8 17.5

'I-Heptanol,6-methyl* 1163.7 288.2

1-Hexene 4.5

I-Octanol, 2-butyl-(8Cl9CI)* 7.1 178.7

I-Octene, 2.6-dimethyl-* 74.6 22.5



COMPOUND IDENTIFIED

I-Propanol (Propyl alcohol)

I-Propanol, 2-(2-hydroxypropoxy)*

1-Propene, 3-chloro-2-methyl-*

I-Tetradecanol’

2(1 i-i)-Naphthalenone,octahydro4a,7,74rimethyl-,trans-•

0.0 1.0 6.0

57.7 13.3

405.1 371.5

9.1 2.9

468.6 13.8

142.4 9.1

2,2/LTrimethyl-1,3-pentanediolmonoisobutyrate (Texanol)

2,2-Dimethyl-I-isopropyl-1,3-propanediol monoisobutyrate(Texanol)

2,6-Diitert-butyl+methyIphenolNJ-l

2,6-Octadien-l-01, 3,7-dimethyl-,acetate, (2).•

2,6-Octadien-1-ol,3,7-dimethyl, (E)- (Geraniol)’

2-Butanone (Methyl ethyl ketone,MEK)

2-Butenal, 2-ethenyf-•

2-Cyclohexen-l-one,2-methyl-5-( 1 -methylethenyl)-*

2-Decene, g-methyl-, (2).•

2-Decene, (Z)-•

2-Decene, 3-methyl-, (Z)-•

2-Decene, 5-methyt-, (Z)-*

2-Decene, 7-methyl-, (2)’

2-Dodecen-l-yl(-)succinicanhydride*

2-Dodecene, (E)’

’2-Naphthalenemethanol,a-meth+, (.+I-J-•

267.2 33.7

137.3 29.0

2351.0 328.3

78.8 6.3

* 10.4 6.4

5.0

2.4

14.3 6.9

217.8 44.4

327.7 79.0

387.6 173.0

220.0 35.8

1090.4

322.3

6.3



COMPOUND IDENTIFIED

2-Octene, (E)-*

2-Octene, (z)-•

2-Octene, 4-ethyL*

2-Pentanone, 4hydroxy4methyl-(m9cI)*

2-Pentanone, 4-methyl (Methylisobutyl ketone, MIBK)*

2-Propanol (lsopropanol)

2-Propen-l-01, 2-methyl

2-Propenal’

2-Propenoic acid, methyl ester*

2 - U n d e c e n e , 2,5-dimethyl-”

2l-LBenzocyclohepten-2-one,decahydro-4a-methyl-, trans-•

3,5-Cyclohexadiene-I ,2-dione,3,5-bis(1, I-dimethyfethyl)-•

3-Buten-2-ol*

3-Cyclohexene-l-methanol,a,a,4-trimethyl-*

3Cyclohexene+methanol,a,a,lltrimethyl-, acetate*

3-Decene*

SDecene, 2-methyl-, (Z)-•

3-Dodecene, (E)*

SDodecene, (Z)- (8Cl9Cl)*

3-Ethyl-2-methyl-I-heptene’

3-Octene, 2,6-dimethyl-•

3-Undecene, 2-methyl-, (E)-•

IdDecene, 3-methyl-, (E)-•

4-Dodecene*

0.0 1.0 6.0

12.6

8.7

96.7

64.6 4.9

5.2

21.1 4.1

6.0 0.8

3.9

37.6 13.6

500.0 172.2

1214.1

11.5

3.9

82.8 29.5

61.5 9.4

273.3 106.1

985.6 281.6

527.3 158.6

63.6

3.1

99.1 18.2

1660.4 469.6

697.0

521.5 152.5



COMPOUND IDENTIFIED 0.0 1.0 6.0.

4-Isobutylmorpholine > 1317.7** 547.3

4-Nonene, 3-methyl, (2) .551.7 126.6

4-Nonene, 5-methyl-* 56.0 34.0

4-Octene, (E)’ 35.0

4-Octene, 2,3&trimethyl-• 130.5

4-Phenylcyclohexene 58.7 10.2

4-Piperidinecarboxylic acid, 633.1 26.24-phenyl-, ethyl ester*

4-tert-Butylcyclohexyl acetate* 3.3

5-Dodecene, (E)* 191.6 49.5

5-Undecene, (E)” 1045.9 331 .I

5-Undecene, (z)- (8C19CI)’ 1789.0 403.0

6-Dodecene, (E)- (BCl9Cl) 816.4 348.0

A&amide, N,N-dimethyl- 404.3 60.5(BCl9Cl)

Acetamide, 264.1 28.2N-methyl-N-[4-[4-methoxy-I-hexahydropyridyll-2-butynyi]-•

Acetate, ethyl 4.0

Acetic acid 0.9 153.3

Acetone (2.Propanone) 78.0 23.1

Azulene, 7-ethyl-1,4-dimethyl-* 8.1

Benzene, I-ethyM-methyl 43.1(4-Ethyltoluene) .Benzene, ethyl 23.4

Benzene.1 ,I’-Oxybis- (Diphenyl 126.4 10.3ether)’

Benzoic acid, 2-hydroxy-, I - 399.7 53.63-methylbutyl ester”

Benzoic acid, 2-hydroxy-, pentyl 333.3 * 10.1ester*




Benzoic acid, 138.0 4.73-(5-hydroxy-I-pentenyl)-, methylester, (E)-*

Benzothiatole 8.8

Butane 6.7

Butanoic acid 10.3

Caryophyllene oxide* 464.7

Cyclohexane, (I-methylpropyl)-* 44.1 4.2

Cyclohexane, 1,1,2-trimethyl* 11.6 1.2

Cyclohexane, 278.0 163.01 ,I-dimethyl-Z-propyl-”

Cyclohexane, 2.0I-ethenyM-methylene-5-(l-propenylidene)-*

Cyclohexane, I-ethyl-2-methyl-, 17.5 3.9cis- (8Cl9CI)”

Cyclohexane, methyl 5.2

Cyclohexane, octyl’ 33.6

Cyclohexane, propyl 61.0

Cyclohexane, t-I-ethyM-methyl* 32.8

’Cyclohexanol, 52.6 15.1Z-methylene-3-(I-methylethyl)-, -acetate, cis-•

Cyclopentane, 1,2,4-trimethyl, 11.0 1.7(1 a,2&4a)*

Cyclopentasiloxane, decamethyl’ 99.5 25.9

Decane 910.6 . 46.7

Decane, 6-ethyl-2-methyl- (9CI)* 12.1

Dipropylene glycol 229.4 23.7

Disiloxane, pentamethyl-• 4.1 ‘

Dodecane 122.8 11.2




Ethane, 1 , 1,l -trichloro 4.7

Ethanol 210.4 4.7

Ethanol, 2-(2-butoxyethoxy) 224.8 105.2

Ethanol, 2-butoxy 35.6 3.7

Ethanol, 2-phenoxy- 84.4 36.6

Furantetrahydro; THF 2.0

Heptadecane* 2.4

Heptanal (Heptaldehyde)* 2.8

Heptane 15.6

Heptane, 2,4-dimethyl 25.0

Heptane, 2,5-dimethyl* 13.6

Heptane, 3-methyl 10.9

Heptane, 3-methylene- (9Cl)” 16.6

Heptane, 4-methyl 12.4

Hexadecane (Cetane) 235.7 10.5

Hexadecane, 2,6,10-trimethyl-* 10.0

Hexane, 2,2,5-trimethyl- (8Cl9CI)* 126.6 5.2

Hexane, 2,2-dimethyl 67.5

Hexane, 3-methyl 15.8

Hexanoic acid 77.6 66.4

lsobomyl acetate* 363.5

Methanesulfonyl chloride* 1.9

Morpholine, LGmethyl 6.6 3.4

Naphthalene 69.7 22.3

Naphthalene, 1,2-dimethyl-* 79.8 3.4

Naphthalene, t ,4,6-trimethyl* 120.2 8.2

Naphthalene, 1 +dimethyl’ 193.8 5.2

Naphthalene, 1,6-dimethyl* 199.9 10.7



COMPOUND IDENTIFIED

Naphthalene,1,6-dimethyl(l-methylethyl)-’

Naphthalene, l-methyl

Naphthalene, 2,3,6-trimethyl-(8Cl9CI)*

Naphthalene, 2,7-dimethyl*

Naphthalene, 2-methyl

Naphthalene,6(3-ethylpropyl)-1,2,3,4-tetrahydrol

0.0 1.0 6.0

436.3

23.5 5.3

18.5

96.0 3.8

28.3 10.8

123.9 9.3

Naphthalene, 298.7 12.4decahydro-4a-methyl-l -methylene-7+methylethylidene)- (4aR-bans)-*

Nonane 84.8 2.0

Nonane, 3-methyl 73.1

Nonane, 4-methyl 31.7 3.3

Octane 23.1

Octane, 2,6-dimethyl 121.1 15.6

Octane, 2-methyl 17.7

Octane, 3-methyl 43.6 14.4

Octane, Idethyl* 75.8

Pentadecane, 469.92,6,10,14-tetramethyl-• aPentane, 2,2,4&imethyl 560.7(Isooctane)

Pentane, 2,3,4-trimethyl 61.6

Pentane, 2,3-dimethyl (8C19CI)* 11.8

Pentane, 2+dimethyl* 8.4

Pentanoic acid (Valeric acid) 30.1 20.2

Phenol 183.4 68.7



COMPOUND IDENTIFIED

Phenol,4,6-di(l ,I-dimethylethyt)-2-methyl-l

0.0 1.0 6.0

79.6 2.0

Phenol, bis(1 ,l-dimethylethyI)-(9Cl)’

Propanedioic acid, diproyl-, diethylester*

8.0

747.7 59.4

Pyridine,l,2,3,6-tetrahydro-4~[4,5-dihydroxypheny!]-1 -methyl-*

TXIB(2,2,4-TrimethyI-1,3-pentanedioldiisobutyrate)

Terbutol*

Tetradecane


Tridecane

Trimethylamine(methanamine,N,N-dimethyl)*

Unidentified


52.5

- 324.8 19.2

66.5

110.0 3.4

289.2

22.8

0.6

1840.9 30.8

52.9

‘Mites best NISTIEPAINIH library match only.“Values marked with l >. symbol were outside linear range of detector. Concentration value is a lower bound only.Individual compounds and TVOC (total volatile organic compounds) are calibrated relative to toluene.TVOC detection limit: 0.9 vg/rn’. Individual detection limits may vary, depending on insbument response.

I I.--“-^“.“l ̂ -e-P.-- _- -

- . . ..----.



Cushion B at Elevated Conditions (70 “C, 8% RH, high loading)

Environmental Chamber:Product Loading:Test Conditions:

SC51.65 m2/m31.00 ACH8.0% RH f 2.0% RH

Test Period:70.0 degs C f 2.0 degs C06/21/95 - 06/21/95

CHAMBER IVOC CONCENTRATIONS FROM 0.000 TO 6.000 HOURS

ELAPSED T v o cEXPOSURE CONCENTl$ATION

HOtJR

p?jEzyj

IVOC CONCENTRATICNS (pg/m3) FROM 0.000 TO 6.000 HOURS

COMPOUND IDENTIFIED 1.0 6.0

(tert-Butoxymethyl)oxirane* 37.2

1,2-Ethanediol (Ethylene glycol) 30.9 39.4

1,2-Propanediol (Propylene glycol) 37.2 42.6

1 +Dimethylpiperatine 9.5

I-Acetoxy-2-propanol* 23.9

I-Butanol (N-Butyl alcohol) 471 .o 134.8

I-Dodecene 29.3

I-Hexanol, 2-ethyl 71.4 80.7

l-Nonene, 4,6&trimethyl- (9CI)* 8.8 8.0

I-Octanot 11.0

I-Octanol, 2-butyl- (8Cl9Cl) 14.7

I-Octene, 3-ethyl-* 26.5 4.9

- _ ^I--~P - .-...



COMPOUND IDENTIFIED

I-Pentanol, 3-methyl

l-Phenyl-l-propyne

?-Propane! (PropyI alcohol)

l-Tetradecene

A-Undecene

I H-lndene,2,3-dihydro-I,? ,3-trimethyl-*

1 H-lndene,2,3-dihydro-l,2-dimethyl-”

1 H-lndene,2,3-dihydro-1,3-dimethyl*

1 H-lndene,2,3-dihydro-4,7-dimethyl-*

I H-lndene, 2,3-dihydro+methyl*

1 H-Phenanthro[9,10-dlimidazol-2-amine+

2,2,4&Tetramethyioctane*

2.2,~Trimethyl- ,3-pentanediolmonoisobutyrate (Texanol)

2,2-Dimethyl-l-isopropyl-1,3-propanediol monoisobutyrate (Texanol)

2,5-Cyclohexadiene-1 +dione,2,6-bis(1 ,I-dimethylethyl)- (9’

2,6-Di-tert-butyI4methylphenol(BHT)

2-Ethylhexanoic acid

2-Pentanone, 4-hydroxy4methyk(8C[9Cl)*

2-Pentanone, LGmethyI (Methylisobutyl ketone, MIBK)

2-Propanol (Isopropanol)

2-Propanol, 1,3=dichloro-

1.0 6.0

8.3 4.9

13.5

118.9 19.2

7.6

35.3

7.9

28.1 48.9

46.8 41.0

29.5 25.0

69.4 59.5

81.1 119.1

58.0 95.9

34.2 41.9

90.7 - 134.4

1823.6 2585.8

664.5 1210.1

447.3 303.9

13.7

7.7

53.9 41.3



COMPOUND IDENTIFIED

2-Propanol,I-II-methyl-2-(2-propenyloxy)ethoxy

1.0 6.0

* 29.0

2-Propenal’

2-Propenal, 2-methyl*

2-Pyrrolidinone, l-methyl

2H-2,4a-Methanonaphthalene,I ,3,4,5,6,7-hexahydro-I, 1,5,5-tetramethyl-, (2S)-•

3-Carene”

3-Pentanol*

3-Penten-2-one, 4-methyl- (8Cl9CI)*

4kobutylmorpholine

Acetamide, N,N-dimethyl- (8Cl9CI)

Acetate, butyl

Acetic acid

Acetic acid, 2-ethylbutyl ester’

Acetic acid, phenylmethyl ester

Acetone (2-Propanone)

Benzaldehyde

Benzene, 1,2,4,5-tetramethyl*

Benzene, 1,2&trimethyl

Benzene, 1,4-dichloro

Benzene, I-ethyl-2,4-dimethyl-*

Benzene, I-ethyl-2-methyl(2.Ethyltoluene)

Benzene,l-methyl4(l-methylethyl)(p-Cymene; 4lsopropyltoluene)

Benzene, 4-ethyl-l &dimethyl*

Benzene, ethyl

12.3

4.5

14.4

40.1 37.9

63.4

6.8

18.0 13.9

> 1135.3** > 1534.1”’

337.8 362.7

10.2

69.7

14.8 11.7

39.8

226.4 94.5

20.0 10.6

37.3

90.9 35.4

37.2 24.5

48.9 34.5

38.9 9.5

48.6 22.0

21.6

9.8



COMPOUND IDENTIFIED

Butanal (Butyraldehyde)

Butanoic acid

Camphene

Cedrene, a*

Cyclohexane, hexyl’

Cyclohexanone

Cyclohexene,3-methyl-6-(I-methylethylidene)-•

Cyclohexene, 4-(1 ,I-dimethylethyl)*

Cyclopentane,1 -methyl-3-(29methylpropyl)-•

Cyclopentanone’

Cyclopentasiloxane, decamethyl*

Decane

Decane, 2,2,4-trimethyl-’

Decane, 2,6,6-trimethyl-*

Decane, 2-methyl

Decane, 3,8-dimethyl

Decane, S-methyl*

Dodecane

.Dodecane, 2,6, IO-trimethyl-*

Dcdecane, 3-methyl- (8Cl9CI)

Ethane, 1 , 1, I-trichlom

Ethane, 1,2-dichloro

Ethanol

Ethanol, 2-(2.butoxyethoxy)

Ethanol, 2-butoxy

Ethanol, 2-chloro-•*

1.0 6.0

5.2

8.5

81.4 23.9

16.0 12.8

42.4 35.5

8.9 7.2

91.6 91.0

51.4

15.6

11.7 16.6

77.2 34.4

114.1 18.0

37.7

43.2

40.8

35.0

73.2

80.0 - 57.4

10.6

17.5 17.2

3.1

4.6 5.5

36.3 6.3

46.3

33.4 23.2

2.8



COMPOUND IDENTIFIED

Ethene, 1 ,I ,2,2-tetrachloro(Tetrachloroethylene)

EthylI-methylcyclopropanecarboxylate*

Heptane, 2,2,6+tetramethyl

Heptane, 2,4,6-trimethyl

Hexane, 2,2,5-trimethyl- (8Cl9CI)’

Hexanoic acid

lsobomyl acetate*

Limonene (Dipentene;I-Methyl+ 1 -methylethyl)cyclohexene)

LinalooP

Morpholine, 4-ethyl-’

N,N-Dimethyl-2-propenamide

Naphthalene

Naphthalene,-l,2,3,5,6,8a-hexahydro-4,7-dimethyl-I-(I-methylethyl)-, (IS-cis)-*

Naphthalene, 1,4,6-trimethyl*

Naphthalene, ‘l,4-dimethyl

Naphthalene, 1 J-dimethyl-(8Cl9CI)’

Naphthalene,I$-dimethyl4(?-methylethyl)-*

Naphthalene, I-(2.propenyl)*

Naphthalene, I-methi

Naphthalene, 2,3,6-trimethyl-(8Cl9CI)’

Naphthalene, 2,6-dimethyl-*

Naphthalene, 2-ethyl*

1.0 6.0

6.0

60.2

8.1

8.9

10.2

27.5

848.2 906.5

224.6 75.9

71.2

18.0

12.3 14.4

115.0 95.3

13.8

52.4

10.5 10.2

-6.6

11.6

3.4 3.0 -

21.8 24.9

50.5

9.5

5.9

.- 1-..



.

COMPOUND IDENTIFIED

Naphthalene, 2-methyl

Naphthalene,G-(1 ,l-dimethylethyl)-1,2,3+tetrahydro-*

Nonane

Nonane, 3,7-dimethyl’

Nonane, 3-methyl-5-propyl-•

Nonane, 4,5-dimethyl*

Nonane, 4-methyl

Octane, 2,2,6-trimethyl*

Octane, 3-ethyl-2,7-dimethyl- (9CI)”

Pentanal (Valeraldehyde)

Pentane, 2,2+trimethyl (Isooctane)

Phenol

Phenol,2,6-bis(1 ,I-dimethylethyl)+ethyl*

Phenol, 4-t-butyl(4-(1 ,I-Dimethylethyl)phenol)*

Pinene, a(2,6,6-Trimethyl-bicycloI3.1 .A Jhept-2-ene)

Propane, 2-methyl-2-nitro*

Propanoic acid

Propanoic acid, 2,2-dimethyl-’

Propanoic acid, 2-methyl- (9CI)*

Propanoic acid,2-methyl-2-f(trimethylsilyl)oxy]-,trimethyp

Styrene

Styrene, 2,5-dimethyl*

Tetradecane

1.0 6.0

63.4 69.7

.36.4

14.4

96.5 24.1

33.0

140.6

32.0

50.9 11.8

118.8

4.1

2.7

165.1 168.3

34.6

10.4

21.7

7.3

12.4

8.1

6.1

10.1 8.2

19.4 5.5

31.5 28.9

15.3 5.8



COMPOUND IDENTIFIED 1.0 6.0

Thiophene, 17.12-buty&(2-methylpropg)- (9CI)’ 1 I~;~?fJlethylbenzene) / XL; 1 7.8

14.3

Undecane I 186.1 I 96.4I

Undecane, 2,3-dimethyl-’ - 34.1 25.5

Undecane, 2-methyl 27.6

Undecane, 3,9-dimethyl- (8CI)*

Undecane, 5-methyl- (8dl9Cl)*

42.8 I 42.0

30.6

Unidentified 374.8 503.3

Xylene (para and/or meta) 40.8

Xylene, ortho 28.9 9.4

‘Indicates best NISTEPANIH library match only.“Values marked with “pa symbol were outside Gnear range of detector. Concentration value is a lower bound only.Individual compounds and TVOC (total volatile organic, compounds) are calibrated relative to toluene.IVOC detection liiit: 0.9 yg/m’. Individual detection limits may vary, depending on instrument response.

-.----__ _-- - . ---_ _

APPENDIX D

INDIVIDUAL VOC CONCENTRAIIONS DURING EXPOSURESTO SYNTHESIZED MIXTURES

----_ .” - ---~.

61890 Flnet ReportJanuary 31,1996

Appendix 0Page 1 of 37

TABLE D-l

CONCENTRATION DATA FOR EXPOSURE TOPRIME URETHANE “A” TEST MIXTURE

Compound Concentration (mg/m3) Mean PrecisionConcentration

Sample 1 Sample 2 Sample(% RSD)

3(first IO minutes jmliidle IO minutes (!ast 90 minutes of

h4Jm

of exposure) of exposure) exposure)

2,6-Di-tert-butyl-4- 6.2 12.3 12.1 10.2 33.9methylphenol

1,4=Dimethylpiperarine 11.1 16.2 17.2 14.8 21.9

1 , 1, I -Trichloroethane 6.8 7.0 7.2’ 7.0 2.4

Adiponitrile 0.3 0.5 5.8 2.2 143

.Styrene 5.6 6.1 6.1 5.9 4.2

Octamethylcyclotetrasiloxane 3.0 3.2 3.3 3.2 3.5

Ether 0.8 1.3

Ethyl acetate* 0.5 0.8

Methanonaphthalene* 0.2 0.3 0.3

Isooctane* 0.2 0.2

Methanol* 0.1 0.2

Oi 890 FM RepotIJanuary 31,1996

Appendix DPage 2 of 37

Compound

HexaM

1 ,I-Dichloroethene’

Hexamethylcyclotetrasiloxane*

Benzene*

Concentration (mg/m3) Mean PrecisionConcentration

Sample 1 Sample 2 Sample 3(% RSD)

(first 10 minutes (mlddle 10 minutes (last 10 minutes of h4m3)

of exposure) of exposure) exposure)

0.1 < 0.1

0.1

0.1.

Wuantftatfon felath to toluene response only.

.



TABLE D-2

CONCENTRATION DATA FOR EXPOSURE TO. PRIME URETHANE “A” TEST MIXTURE WITH BHT REMOVEDI

Precision(% RSD)

Compound Concentration (mg/m’)

piz-I (first 10 minutes

of exposure)

Mean

Sample 2(middle IO minutes

of exposure)

- - C o n c e n t r a t i o nSample 3

(last 10 minutes of I Wm3)

exposure) I

nd ndnd2,6-Di-tert-butyl-4-methylphenol

1.4.Dimethylpiperazine

nd

13.8

--

15.8 I- 16.3 16.819.2

10.08.6 I 9.710.5I, I, I-Trichloroethane 10.0

Adiponitrile nd 1320.2 1.1 0.4

6.7 6.5 ' 4.4~~

6.7Styrene I 6.2

4.6 I 4.44.3 3.4Octamethylcyclotetrasiloxane

Methanol*

4.4

4.5 3.1 1.9

0.30.2Pyrazine*

Ether*

0.1

3.5 I1.7 I

--I ,I-Dkhloroethene”

Isooctane* 0.6 I

01890 Final ReportJanuary 3 1,1998


Concentration

Ethyl acetate*

Acetone*

Hexane*

Benzene*

Qmtitatfon telative to toluene response onty,

61890 FM ReportJanuary 31,1996


TABLE D-3

CONCENTRATION DATA FOR EXPOSURE TOPRIME URETHANE “A” TEST MIXTURE

WITH BHT AND 1,4=DIMETHYLPIPERAZINE REMOVED

TTCompound Concentration (mglm’) MeanConcentration

hm3;

Precision(% RSD)I

Sample 1 Sampie 2 ISampie 3

(first 10 (IO-30 (30 - 50mlnutes of minutes of minutes ofexposure) exposure) exposure)

Sample 4(last 10

minutes ofexposure)

ndI

ndI

nd nd nd

nd I nd I nd nd nd

2.9 I 2.7 I 2.5 2.5 2.7 8.0I, 1, I-Trichloroethane

Adiponitrile 6.4 3.3 89

4.9 4.7 7.6Styrene

1.4 0.9 51Octamethylcyclotetrasiloxane

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compound identified 2.3 . 1.6 0.7 pinene, a 1 7.0 …environmental chamber, product loading: test...

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