construction of two-dimensional pore with fluorinated alkyl groups
DESCRIPTION
Construction of Two-Dimensional Pore with Fluorinated Alkyl Groups. Tobe Lab. Keisuke Katayama. Contents. Introduction top down approach and bottom up approach 2D molecular network and guest coadsorption Previous Work about dehydrobenzo[12]annulene (DBA) Purpose of this Work - PowerPoint PPT PresentationTRANSCRIPT
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Construction of Two-Dimensional Pore with Fluorinated Alkyl Groups
Tobe Lab. Keisuke Katayama
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Contents
Introduction top down approach and bottom up approach 2D molecular network and guest coadsorption Previous Work about dehydrobenzo[12]annulene (DBA) Purpose of this Work
Experiment and discussion Molecular Design Scanning Tunneling Microscopy Experimental Result
Conclusion
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Creation of surface nanopattern
3Photolithography technique
encounters physical limitation.
= molecules
Smaller geometries than photolithography can be constructed.
= substrate
= photoresist
= substrate
light
self-assembly : 自己集合
Top-down approach (photolithography)
Bottom-up approach (molecular self-assembly)
Self-assembly
A few 10 nm scale 1~10 nm scale
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2D Self Assembly via Hydrogen Bonding
NHHN
O
O
O
O
N N
N NH2H2N
NH2
N. Champness. et al. Nature 2003, 424, 1029.
Perylenediimide(PDI)
Melanine
Network model
Hydrogen Bonding
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2D Host-Guest Interaction
N. Champness. et al. Nature 2003, 424, 1029.
C60
Two-component network
Three-component network!
Bright spots are adsorbed fullerene heptamer
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R
R R
R
DBAOC10: R = OC10H21DBAOC12: R = OC12H25DBAOC14: R = OC24H29DBAOC16: R = OC16H33DBAOC18: R = OC18H37DBAOC20: R = OC20H41
R
R
An STM Image of Honeycomb structure of DBAOC20
Tobe, Y. et al. Chem. Commun. 2010, 46, 8507-8525.
Alkyl Chain Interdigitation
DBA
Honeycomb Networks of DBA Derivatives
=
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Guest Adsorption at Pores Formed by DBAs
=
DBAOC16 and NG DBAOC18 and NG DBAOC20 and NG
Nanographene (NG)
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・ The construction of the 2D porous networks with functionalized pores formed by DBAs.・ Investigation of their unique capability to host guest molecules via specific interaction between them. ・ We focus on fluorophilic interaction for specific 2D host-guest system.
Purpose of This Work
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OR2R1O
R2O
R1O OR2
OR1
R1 = C14H29
R2 = C10H20OR
ODBAOC14RF: R =
DBAOC14RH : R =O
F F
FF
F F
FF
F F
FF
F FFFF
Molecular Design
Fluorophilic 2D nano pores
FF
F
FF
F
F
FF
FF
F
FF
F
F
FF
Hexakis(phenylethynyl)benzene(HPEB)
18F-HPEB
GuestHost
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Scanning Tunneling Microscopy (STM)
Conditions・ Constant current mode
・ Negative sample bias
・ Room temperature
・ Solvent : 1-Phenyloctane
・ Substrate : Graphite
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STM Images of Monolayer Formed by DBAOC14RF and DBAOC14RH at the 1-Phenyloctane/Gaphite Interface
DBAOC14RF (4.4 × 10–6 M) DBAOC14RH (7.0 × 10–6 M)
・ In the both images, the fluorinated alkyl chains or alkyl chains were observed at the rim of the pores as designed, respectively. ・ The 2D porous networks with functionalized pores can be constructed.
=
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Co-Adsorption of HPEB and 18F-HPEB at the Pore of Honeycomb Structure of DBAOC14RF
DBAOC14RF (4.0 × 10–6 M) and HPEB (4.1 × 10–4 M)
DBAOC14RF (3.7 × 10–6 M) and 18F-HPEB (4.0 × 10–4 M)
In all images we observed the guest molecules located in the pores. (left) HPEB was observed at 94% of the pores formed by DBAOC14RF. (right) 18F-HPEB was observed at 97% of the pores formed by DBAOC14RF.
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Co-Adsorption of HPEB and 18F-HPEB at the Pore of Honeycomb Structure of DBAOC14RH
DBAOC14RH (4.5 × 10–6 M) and HPEB (4.5 × 10–4 M)
DBAOC14RH (3.2 × 10–6 M) and 18F-HPEB (3.8 × 10–4 M)
(left) HPEB was observed at 69% of the pores formed by DBAOC14RH. Anisotropic distribution of HPEB was observed in the honeycomb network of DBAOC14RH.(right) 18F-HPEB was observed at 98% of the pores formed by DBAOC14RH.
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Changes in Number of Filled Pore by Guest Molecules at Different Guest Concentration
Compound Host Concentration
Guest Concentration
Number of All Pores
Number of Pores Filled with Guest
Occupancy (%)
DBAOC14RF
and HPEB 4.0 × 10–6 M 4.1 × 10–4 M 216 202 94%
3.9 × 10–6 M 1.2 × 10–7 M 396 179 45%
DBAOC14RF
and 18F-HPEB 3.7 × 10–6 M 4.0 × 10–4 M 278 271 97%
3.8 × 10–6 M 1.2 × 10–7 M 355 178 50%
DBAOC14RH
and HPEB 4.5 × 10–6 M 4.5 × 10–4 M 474 326 69%
DBAOC14RH
and 18F-HPEB 3.2 × 10–6 M 3.8 × 10–4 M 292 287 98%
3.8 × 10–6 M 1.2 × 10–7 M 482 60 12%
(Blue) Anisotropic distribution of HPEB was observed in the honeycomb network of DBAOC14RH.
(Red) 18FHPEB and HPEB are favorably adsorbed at the pore of DBAOC14RF.
Compound Host Concentration
Guest Concentration
Number of All Pores
Number of Pores Filled with Guest
Occupancy (%)
DBAOC14RF
and HPEB 4.0 × 10–6 M 4.1 × 10–4 M 216 202 94%
DBAOC14RF
and 18F-HPEB 3.7 × 10–6 M 4.0 × 10–4 M 278 271 97%
DBAOC14RH
and HPEB 4.5 × 10–6 M 4.5 × 10–4 M 474 326 69%
DBAOC14RH
and 18F-HPEB 3.2 × 10–6 M 3.8 × 10–4 M 292 287 98%
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Monolayer Formed from Two Combinations, DBAOC14RH, HPEB, and 18FHPEB and DBAOC14RF, HPEB, and 18FHPEB
DBAOC14RF (3.5 × 10–6 M), 18F-HPEB (1.8 × 10–7 M), and HPEB (1.9 × 10–7 M)
DBAOC14RH (3.5 × 10–6 M), 18F-HPEB (1.9 × 10–7 M), and HPEB (1.9 × 10–7 M)
Red: Pores with 18F-HPEB, Green: Pores with HPEB, Blue: Free Pores. 18F-HPEB and HPEB can be distinguished by different image contrast.
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Changes in Number of Filled Pore by Guest Molecules at Different Guest Concentration
Compound Host Concentration
Guest Concentration
Number of All Pores
Number of Pores Filled with Guest
Occupancy (%)
DBAOC14RF, 18F-HPEB, and HPEB
3.5 × 10–6 M
18F-HPEB1.8 × 10–7 M
508284 56%
HPEB1.9 × 10–7 M 185 39%
DBAOC14RH, 18F-HPEB, and HPEB
3.5 × 10–6 M
18F-HPEB1.9 × 10–7 M
497158 32%
HPEB1.9 × 10–7 M 78 16%
·Guest occupancy is higher for DBAOC14RF compared with that of DBAOC14RH.
·The host-guest combination of DBAOC14RF and 18F-HPEB exhibits the highest guest occupancy, most likely due to the fluorophilic interactions.
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・ The formation of 2D porous networks with fluorinated pores was confirmed by STM.
・ Co-adsorptions of 18F-HPEB and HPEB at the functionalized pores formed by DBAOC14RF were observed.
・ It seems 18F-HPEB are preferably adsorbed at the pore formed by DBAOC14RF, most likely due to the fluorophilic interactions.
Conclusion