corrosivity at various distances

22
National Aeronautics and Space Administration John F. Kennedy Space Center MTB 099-74 REPORT ' ON RELATIVE CORROSIVITY Ok ATMOSPHERES AT VARIOUS DISTANCES FROM THE SEACOAST PREPARED BY: MALFUNCTION/MATERIALS ANALYSIS SECTION MATERIALS ANALYSIS BRANCH b FLUIDS AND ANALYSIS DIVISION TG-FLD-22, ROOM 1218, 0 & C BUILDJNG JANUARY 16, 1980 MSA I(SC FOR,., 16-12 IREV. 8/761

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Page 1: Corrosivity at Various Distances

National Aeronautics andSpace Administration

John F. Kennedy Space Center

MTB 099-74

REPORT '

ON

RELATIVE CORROSIVITY Ok ATMOSPHERES

AT VARIOUS DISTANCES FROM THE SEACOAST

PREPARED BY:MALFUNCTION/MATERIALS ANALYSIS SECTION

MATERIALS ANALYSIS BRANCH bFLUIDS AND ANALYSIS DIVISION

TG-FLD-22, ROOM 1218, 0 & C BUILDJNG

JANUARY 16, 1980

MSAI(SC FOR,., 16-12 IREV. 8/761

Page 2: Corrosivity at Various Distances

NASAMALFUNCTION/MATERIALS ANALYSIS SECTION

MATERIALS ANALYSIS BRANCHFLUIDS AND ANALYSIS DIVISION .

TC-FLD-22, ROOM 1218, O&C BUILDINGKENNEDY SPACE CENTER, FLORIDA 32899

JANUARY 17, 1980

-

MTB 099-74 .

SUBJECT: Relative Corrosivity of Atmospheres at VariousDistances from the Seacoast

1.0 FOREWORD

1.1 This i s the summary report o f an in -house invest igat iveprogram initiated by William J. Paton in 1975 and con-tinued by this organization after his reassignment.The purpose of this program was to obtain test datas p e c i f i c a l l y t o e v a l u a t e t h e e f f e c t o f d i s t a n c e f r o m *the seacoast on the rate o f corros ion o f s tee l .

1 . 2 Most of the field corrosion tests perform-ed at KSC haveu t i l i z e d a s i n g l e t e s t s i t e ,near the beach.

located.along the Cape RoadThe sample support racks are located

about 100 to 120 feet from mean high tide. This i s po -tentially a severe environment and has been used to sim-u l a t e “wars t case” field exposure of ground supportequipment (GSE) and to give a somewhat acceleratedevaluation of candidate protective coatings for CSE.For example, z i n c - r i c h c o a t i n g s f o r a p p l i c a t i o n t o s t e e ls tructures at KSC are required to protect s tee l testpanels for 18 months at th is s i te . H,owever, s u b j e c t i v eevaluat ion o f the corros ion rate o f s tee l s tructures andvarious test samples located at greater distances fromthe seacoast has indicated that the “d istance” var iablehas a pro found e f fec t on corros ion rate . I t has a lsobeen noted that atmospheric effects, such as the prolong-ed easterly winds of early autumn, and the higher rain-fall rates and higher relative humidities of summer, haved i s t i n c t s e a s o n a l e f f e c t s o n c o r r o s i o n r a t e .

1 . 3 A l t h o u g h t h e s e f a c t o r s a f f e c t i n g c o r r o s i o n r a t e c o u l dinf luence the corros ion protect ion methods se lec ted fora g i v e n i n s t a l l a t i o n , no test data were avai lable for -t h e “ d i s t a n c e e f f e c t ” o r f o r t h e v a r i a t i o n s i n c o r r o s i o nresulting from the prevail ing weather conditions whenexposure was initiated.

Page 3: Corrosivity at Various Distances

MTB 099-74 2

2.0 TEST PROCEDURES

This program was designed to obtain such data, by means ofthe Collowing corros ion exposure tests.

2.1,. Two types of test materials were used: AISI 1008 steel ,and AISI 4130 steel . The former is a mild steel contain-ing nominally 0.08% carbon and 0.40% manganese. ‘The4130 is a low al loy stee l ,plications,

u s e d w i d e l y f o r a i r c r a f t ap-containing nominally 0.40% carbon, 0.50%

manganese, 0.30% silicon, 1.0% chromium, and 0.20%molybdenum. With i ts content o f a l loy ing e lements , i twould be expected to be s’omewhat more resistant to at-mospheric corrosion than the 1008 steel . The test sam-ples were 4” X 6” X l/8” panels o f the two s tee ls , asr e c e i v e d i n t h e h o t - r o l l e d c o n d i t i o n . A thin layer o fmill scale was present on the samples.were weighed to the nearest 0.01

These samplesgram pr ior to test ing .

2 . 2 S i x c o r r o s i o n t e s t s i t e s , at various distances from theocean, were ut i l i zed : No . 1 (beach) 100 feet ; No . 2 (nearComplex 41 entrance) 800 feet; No. 3 (near perimeterfence, east s ide o f Complex 39A) 2500 feet ; No . 4 ( inyard of water pump station, Pad B Road), 5,200 feet;No. 5 (behind Building M7-505, Industr ia l Area) 6 mi les ;and No. 6 (Orlando Naval Training Center) 50 miles.

2 .3 ~Five test panels o f each mater ia l were p laced in east-facing support racks at each exposure site every monthfor 23 months. After 12 months, t h e f i r s t g r o u p o f 5samples of each material was removed from each site andbrought to the laboratory for analys is .month, the second group was removed.

The followingThis process con-

t inued unt i l a l l test groups at each s i te had been ex-posed for 12 months and then removed ‘for evaluation.

3.0 RESULTS

3.1 The results of the 12 month exposure tests are presentedin Tables 1 through 12, which give the weight loss fromcorros ion o f the two test mater ia ls for each o f the 23exposure periods at each of the six exposure sites.These data are summarized in Table 13, in which theaverage weight loss over the ent ire test per iod i s g ivenfor each test mater ia l at each corros ion test s i te .Figure 1 is a graphical presentation-of these data, show-ing weig.ht loss as a funct ion o f d is tance f rom the sea-coast for the two test mater ia ls . ‘The average weightloss data (from Table 13) are plotted, and the weight-loss envelopes (maximum and minimum losses) are alsoshown. The data presented in Table 13 and Figure 1 arethose accummulated dur ing the ent ire test per iod f romA p r i l , 1975 through February, 1978.

.

Page 4: Corrosivity at Various Distances

MTB 099-74 3

3 .2

3 . 3

3 .4

At the lOO-foot s i te (beach) , the AISI 1008 stee l cor -roded at a considerably higher rate than the AISI 4130(approximately 3 l/2 times, based on average data forthe ent ire program interval ) . A t t h e 8 0 0 - f o o t s i t e therate d i f ferent ia l for the two s tee ls decreased to about2:1, and, at greater d is tances f rom the seacoast thec o r r o s i o n r a t e d i f f e r e n t i a l c o n t i n u e d t o decreasi s l i g h t -l y . For the AISI 1008 steel , the corros ion rate at the800-foot site was about 1 l/2 times that at the SO-miles i t e , a r e l a t i v e l y m i n o r r a t e d i f f e r e n t i a l f o r s u c h alarge increase in d is tance f rom the seacoast . The dif-ferent ia l for the AISI 4130 stee l was even less : 6 .6grams at the 800- foot s i te versus 5 .4 grams for the 50-m i l e s i t e .

As is shown in Figure 1, the weight-loss data envelopefor the AISI 1008 stee l exposed at the 100-foot s i te i svery wide, varying by a factor o f 3 . This indicated apronounced e f fect o f seasonal var iat ions in atmot;phericconditions during the various exposure periods at thebeach s i te . The envelope is much narrower for the AISI4 1 3 0 s t e e l a t t h e lOO-foot s i t e , a n d i s r e l a t i v e l y n a r -r o w f o r b o t h s t e e l s a t t h e 800-foot s i t e a n d a l l s i t e smore remote from the seacoast.

This effect of seasonal variations in weather phenomenaon corros ion rate at the lOO-foot s i te i s shown in Figure2, in which weight losses for the two s tee ls are p lot tedfor sample groups representing each of the 23 exposureper iods . There i s a general increase in weight loss forthe AISI 1008 stee l a f ter the th ird exposure per iod(samples p laced at the beach s i te in June 1975) . Thisweight loss peaked with the e leventh expo;ure-periodsamples (those exposed beginning in February, 1976).Weight losses dropped thereafter, reaching a minimumwith the thirteenth group (exposed beginning April 1976).This was followed by another increase in weight lo:s,which reached another peak with the nineteenth group(exposed beginning October, 1976). The mechanisms bywhich the combinat ions o f meteoro log ica l factors c;ntri-but ing to these wide var iat ions in corros ion rates operate ,are not known. Since each of the 23 test groups remainedat the 100-foot exposure site for 12 months it might beexpected that seasonal var iat ions in these iactors wouldlargely be compensated for. I t i s p o s s i b l e t h a t t h edetermining factor may be the prevajling conditionsimmediately following placement of the samples at theBeach Site. Certainly , h igh humidity , a ir -borne sa l tand warm temperatures would be expected to result inhigh corros ion rate .

i

the s tart o f exposure ,I f these condi t ions prevai l f romthe samples may rapidly develop

a th ick layer o f i ron corros ion product ,ly adherent and moisture absorbing.

which i s loose -Consequently, this

in i t ia l corros ion layer may tend to acce lerate ,than prevent, further corros ion .

r a t h e r

Page 5: Corrosivity at Various Distances

M’l’B 099- 74 4

3 . 5 T h e r o l e o f a i r - b o r n e s e a s a l t h a s b e e n c i t e d , a n d i swidely acknowledged, as the main factor in rapid corro-s ion o f succeptible structural mater ia ls used near theseacoast . Recent studies were conducted at KSC byManagement Services Incorporated, under TS direction,

.* to determine the concentration of air-borne sodiumchlor ide at d i f ferent d is tances f rom the seacoast . Ofseven sampling points used, six were the six corrosionexposure s i tes l i s ted in Paragraph 2 .2 , above . Ther e s u l t s o f t h e s e s t u d i e s were p u b l i s h e d i n a t e c h n i c a lreport and two addendum reports (“Local Atmosphere SaltProfi le” , Shuttle Study Task No. 0031, July 8, 1974;“Local Atmosphere Salt Pl;ofile - Addendum I”, June 2,1975; “Local Atmosphere Salt Profile - Addendum II”,October, 1976). These studies showed considerablevar iat ions in atmospher ic sa l t with prevai l ing windd i r e c t i o n , a n d , as would be expected, easterly windsproduced the h ighest average sa l t concentrat ion . Itwas also noted that samples taken during heavy fogs con-tained much higher concentration of salt than samplestaken dur ing c lear condit ions . These observations ares i g n i f i c a n t t o t h e n o t e d v a r i a t i o n s o f c o r r o s i o n r a t ewith seasonal weather changes.f icance, however,

Of more obvious signi-are the data obtained for atmospheric

salt concentrations at various distances from the seac o a s t , and the re lat ionship o f th is factor to the cor -ros ion rates o f mi ld s tee l at the same locat ions .

Figure 3 shows graphical ly the var iat ion in a ir -bornesal t ( co l lec ted by the funnel method) at the s ix corro -s ion exposure s i tes . The plotted values are averagesof biweekly samples taken over a period from April , 1975,to November, 1976. The salt concentration is shown tobe an exponential function of distance from the seacoast.( R e f e r t o o r d i n a t e a t l e f t f o r u n i t s ) . It should benoted that the se lect ion o f ord inate ’ sca les for theseplots was arbi trary ,can be demonstrated.

and no quant i tat ive re lat ionshipHowever, a s imi lar i ty in curve

shape for these two p lots i s ev ident , and the corros ionr a t e o f t h e AISI 1008 steel i s cvidcntly a l s o a n cxpo-nent ia l funct ion o f d is tance f rom the seacoast . Thesecomparative data also demonstrate the controll ing influenceon corros ion rate o f the atmospher ic sa l t concentrat ion .

4.0 CONCLUSIONS

4.1 The weight loss from atmospheric corrosion of AISI 1008stee l exposed at 6 test s i tes at var ious d is tances f romthe seacoast exceeded that of AISI 4130 steel exposedunder similar conditions, The corrosion rate of thelOO8 steel at a site 100 feet from the ocean was greaterby a factor o f 3 than was the corros ion rate o f the 4130steel. A t sites m o r e remote from the c o a s t (SO0 I’cctto 50 mi les ) , t h e c o r r o s i o n rate diffcrcntial hctwccn thetwo stee ls was less but was s igni f i cant ly greater for the1 0 0 8 .

.

Page 6: Corrosivity at Various Distances

MT13 099-74 5

4 . 2 V a r i a t i o n s i n c o r r o s i o n r a t e s , p a r t i c u l a r l y f o r t h eAlSI 1 0 0 8 s t e e l a t t h e lOO-foot s i t e ( b e a c h ) were de-monstrated with samples placed at the test site eachmonth for 23 months and exposed for a 12-month period.Variat ions in weight loss by a factor o f 3 , depending

.-upon the period of exposure, were noted. I t i s b e -lieved that this phenomenon is caused by a complexinterrelationship among prevailing winds, humidity,a n d r a i n f a l l .

4 .3 Corros ion rates for the AISI 1008 s tee l were found tobe an exponentional function of distance from the sea-c o a s t . It is noted that salt content ,in the KSC areaatmospherehas also been shown to be an exponentialfunct ion o f d is tance f rom the seacoast , and i t i s be -l i e v e d t h a t t h e c o r r o s i o n r a t e o f t h e s t e e l i s l a r g e l yinfluenced b y t h i s r e l a t i o n s h i p .

INVESTIGATOR:

APPROVED:MMAS/NASA

Page 7: Corrosivity at Various Distances

TABLE 1

AISI 1008 STEEL SAMPLES

6

1.

2.

3.

4.

5.

6.

7.

8.

9.

10.

11.

12.

13.

14.

15.

16.

17.

18.

19.

20.

21.

2 2 .

- - 23.

EXPOSED AT BEACH (100 FOOT) TEST SITE

EXPOSURE PERIOD

A p r i l ' 7 5 - A p r i l ' 7 6

May '75 - May '76

June '75 - June '76

July.'75 - J u l y ' 7 6

August '75 - August '76

September '75 - September '76

O c t o b e r ' 7 5 - O c t o b e r '76

November '75 - November '76

December '75 - December '76

January '76 - January '77

February '76 - February '77

March '76 - March '77

A p r i l ' 7 6 - A p r i l ' 7 7

May '76 - May '77

June '76 - June '77

July ' 7 6 - J u l y ' 7 7

August '76 - August '77

September '76 - September '77

October '76 - October '77

November '76 - November '77

December '76 - December '77

January '77 - January '78

February '77 - February '78

AVERAGE

WEIGHT LOSSGRAMS

35.1

36.2

35.6

53.1

47.7

70.5

63.7

64.9

69.0

90.1

95.1

74.4

33.9

42.8

49.6

72.9

82.7

79.9

87.1

62.3

47.9

54.6

56.4

. 61.1

Page 8: Corrosivity at Various Distances

--

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I,

/

I

I

,

I

/

I

I

I

I

,

I

-

1.

2.

3.

4.

5.

6.

7.

8.

9.

10.

11.

12.

13.

14,

15.

16.

17.

18.

19.

20.

21.

22.

23.

TABLE 2

AISI 4130 STEEL SAMPLES

EXPOSED AT BEACH (100 FOOT) TEST SITE

WEIGHT LOSSEXPOSURE PERIOD CRAMS

Apr'il '75 - A p r i l ' 7 6 11.8

May '75 - May '76 18.3

J u n e ' 7 5 - J u n e '76 17.2

J u l y ' 7 5 - J u l y ' 7 6 16.5

August"75 - August '76 13.2

September '75 - September '76 13.6

October '75 - October '76 12.9

November '75 - November '76 13.7

December '75 - December '76 14.4

January '76 - January '77 17.3

February '76 - February '77 21.1

March '76 - March '77 13.9

A p r i l ' 7 6 - A p r i l ' 7 7 12.0

May '76 - May '77 19.3

June '76 - June '77 20.4

J u l y ' 7 6 - J u l y ' 7 7 17.2

August '76 - August '77 19.7

September '76 - September '77 19.6

October '76 - October '77 18.5

November '76 - November '77 27.7

December '76 - December '77 17.3

January '77 - January '78 14.7

February '77 - February '78 10.2

AVEMCE 16.9

7

.

Page 9: Corrosivity at Various Distances

1.

2.

3.

4.

5.

6.

7.

8.

9.

10.

11.

12.

13.

14.

15.

16.

17.

18.

19.

20.

21.

22.

23.

--

TABLE 3

AISI 1008 STEEL Sti1PLES

EXPOSED AT COMPLEX 41 (800 FOOT) TEST.SITE

WEIGHT LOSSEXPOSURE PERIOD GRAMS

Ap'r il '75 - A p r i l ' 7 6

May '75 - May '76

June '75 - June '76

July ' 7 5 - Ju ly ' 76

August '75 - August '76

September '75 - September '76

October '75 - October '76

November '75 - November '76

December '75 - December '76

January '76 - January '77

February '76 - February '77

March '76 - March '77

A p r i l ' 7 6 - A p r i l ' 7 7

May '76 - May '77

June '76 - June '77

Ju ly ' 76 - Ju ly ' 77

August '76 - August '77

September '76 - September '77

October '76 - October '77

November '76 - November '77

December '76 - December '77

January '77 - January '78

February '77 - February '78

AVERAGE

9.5

10.1

10.0

9 .9

11.3

11.8

12.1

12.0

14.1

12.0

11.9

11.5

8 .9

11.3

13.0

11.6

13.5

13.5

12.3

12.8

12.1

10.7

10.5

11.6

.

Page 10: Corrosivity at Various Distances

1.

2.

3.

4.

5.

6.

7.

8.

9.

10.

11.

12.

13.

14.

15.

16.

17.

18.

19.

20.

21.

22.

23.

TABLE 4

AISI 4130 STEEL SAMPLES

EXPOSED AT COMPLEX 41 (800 FOOT) TEST.SITE

9

EXPOSURE PERIOD

April ' 7 5 - A p r i l ' 7 6

May '75 - May '76

June '75 - June '76

J u l y ' 7 5 - J u l y ' 7 6

August , '75 - August '76

September '75 - September '76

October '75 - October '76

November '75 - November '76

December '75 - December '76

January '76 - January '77

February '76 - February '77

March '76 - March '77

Apr i l ' 7 6 - A p r i l ' 7 7

May '76 - May '77

June '76 - June '77

July ' 7 6 - J u l y ' 7 7

August '76 - August '77

September '76 - September '77

O c t o b e r ' 7 6 - O c t o b e r '77

November '76 - November '77

December '76 - December '77

January '77 - January '78

February '77 - February '78

AVERAGE

WEIGHT LOSSGRAMS

4 . 3

5.7

5.2

5 .6

6 .0

6 .5

7.1

6 .8

8 .5

6 .9

6 .6

7.7

3 .2

7.5

7.5

7.0

9.0

6.4

6 .1

8.7

_ 7.2

5.7

5.7

6 . 6./

/

Page 11: Corrosivity at Various Distances

1.

2.

3.

4.

5.

6.

7.

8.

9.

10.

11.- -12.

13.

14.

15.

16.

17.

18.

19.

20.

21.

22.

23.._-

TABLE 5

AISI 1008 STEEL SAMPLES

EXPOSED AT COMPLEX 39A (2500 FOOT) TEST. SITE

EXPOSURE PERIOD

Ap;‘.il ' 7 5 - A p r i l ' 7 6

May '75 - May '76

J u n e ' 7 5 - J u n e '76

J u l y ' 7 5 - J u l y ' 7 6

August '75 - August '76

September '75 - September '76

October '75 - O c t o b e r '76

November '75 - November '76

December '75 - December '76

January '76 - January '77

February '76 - February '77

March '76 - March '77 _

A p r i l '76 - A p r i l ' 7 7

May '76 - May '77

June '76 - June '77

J u l y ' 7 6 - J u l y ' 7 7

August '76 - August '77

September '76 - September '77

O c t o b e r '76 - O c t o b e r ' 7 7

November '76 - November '77

December '76 - December 177

January '77 - January '78

February '77 - February '78

AVERAGE

WEIGHT LOSSGRAMS

9.4

10.2

9.7

9.1

10.9

12.5

12.5

12.1

12.3

12.1

12.3

12.0

7.3

10.9

. 13.5

11.5

13.5

13.7

13.0

13.0

- 11.5

10.6

9 .5

11.4

Page 12: Corrosivity at Various Distances

1.

2.

3.

4.

5.

6.

7.

8.

9.

10.

11.

12.

13.

14. May '76 - May '77

Apri l '75 - A p r i l '76

May '75 - May '76

June '75 - J u n e ' 7 6

July ' 7 5 - J u l y ' 7 6

August"75 - August '76

September '75 - September '76

O c t o b e r ' 7 5 - O c t o b e r '76

November '75 - November '76

December '75 - December '76

January '76 - January '77

February '76 - February '77

March '76 - March '77

Apr i l '76 - A p r i l ' 7 7

TABLE 6

AISI 4130 STEEL SAMPLES

EXPOSED AT COMPLEX 39A (2500 FOOT) TEST SITE

EXPOSURE PERIOD- -,I

15.

16.

17.

18.

19.

20.

21.

22.

23.

J u n e '76 - J u n e '77

Ju ly ' 76 - Ju ly ' 77

August '76 - August '77

September '76 - September '77

O c t o b e r ‘76 - O c t o b e r ‘77

November '76 - November '77

December '76 - December ‘77

January ‘77 - January ‘78

February ‘77 - February ‘78

AVERAGE

WEIGHT LOSSGRAMS

5.0

5 .9

3.7

5.5

5.6

8 .0

9.1

7.1

6 .6

7.3

7 .0

7 .3

3.1

6.8

7 .6

7 .0

8 .1

8.2

5.9

8 .5

7 .6

5.7

4 .9

6 .6

11

Page 13: Corrosivity at Various Distances

1.

2.

3.

4.

5.

6.

7.

8.

9.

10.

11.

12.

13.

14:

15.

16.

17.

18.

19.

20.

21.

22.

23.

TABLE 7

AISI 1008 STEEL SAMPLES

EXPOSED AT PUMP HOUSE (5200 FOOT) TEST SITE

EXPOSURE PERIOD

Apr'il '75 - A p r i l ' 7 6

May '75 - May '76

J u n e ' 7 5 - J u n e '76

WEIGHT LOSSGRAMS

6.9

7.9

6 .6

J u l y ' 7 5 - J u l y ' 7 6 6 . 5

August '75 - August '76 8.1

September '75 - September '76 9.2

October ' 7 5 - O c t o b e r '76 10.5

November '75 - November '76

December '75 - December '76

January '76 - January '77

9 .3

8.7

9.4

February '76 - F e b r u a r y '77

March '76 - M a r c h '77

Apr i l '76 - A p r i l ' 7 7

May '76 - May '77

J u n e '76 - J u n e '77

July '76 - July '77

August '76 - August '77

September '76 - -September '77

O c t o b e r ' 7 6 - O c t o b e r '77

November '76 - November '77

December '76 - December '77

January '77 - January '78

February '77 - February '78

AVERAGE

8.7

8.4

5.3

8.6

9.9

9.2

9 .5

10.5

10.7

9.7

9.3

9.4

8.0

8.7

12

Page 14: Corrosivity at Various Distances

TABLE 813

-

1.

2.

3.

4.

5.

6.

7.

8.

9.

10.

11.

12.

13.I 14.

15.

16., 17.I

18.

19.1 20./

21.I 22.

23.--

AISI 4130 STEEL SAMPLES

EXPOSED AT PUMP HOUSE (5200 FOOT) TEST SITE

WEIGHT LOSSEXPOSURE PERIOD GRAMS

Ap$il ' 7 5 - A p r i l '76 3.9

May '75 - May '76 4.7

J u n e '75 - J u n e '76 3.3

July ' 7 5 - Ju ly ' 76 3 .6

August '75 - August '76 4 .9

September '75 - September '76 6.1

O c t o b e r ' 7 5 - O c t o b e r '76 7.8

November '75 - November '76 5.9

December '75 - December '76 5.5

January '76 - January '77 5.5

February '76 - February '77 4 . 9

March '76 - March '77 5.9

A p r i l '76 - A p r i l '77 1.7

May '76 - May '77 5.3

June '76 - June '77 5.8

July '7 .6 - July '77 5.4

August '76 - August '77 6 .2

September '76 - September '77 6.2

O c t o b e r ' 7 6 - O c t o b e r '77 4.9

November '76 - November '77 6.5

December '76 - December '77 6 .0

January '77 - January '78 4.3

February '77 - February '78 4.7

AVEIWCE 5.2

.

Page 15: Corrosivity at Various Distances

TABLE 9 14

AISI 1008 STEEL SAMPLES

EXPOSED AT INDUSTRIAL AREA (6 MILE) TEST SITE

WEIGHT LOSSEXPOSURE PERIOD-.. GRAMS

,I1. April ' 75 - April '76 8 .1

2. May '75 - May '76 8 .1

3. June '75 - J u n e '76 6.9

4. July ' 7 5 - J u l y ' 7 6 7 . 6

5.

6.

7.

8.

9.

10.

11._-_

12.

13.

14.

15.

16.

17.

18.

19.

20.

21.

22.

23.J'

August '75 - August '76

September '75 - S e p t e m b e r '76

O c t o b e r '75 - O c t o b e r '76

November '75 - November '76

December '75 - December '76

January '76 - January '77

February '76 - February '77

March '76 - March '77

A p r i l '76 - A p r i l ' 7 7

May '76 - May '77

June '76 - June '77

J u l y ' 7 6 - J u l y ' 7 7

August '76 - August '77

September '76 - September '77

O c t o b e r ' 7 6 - O c t o b e r '77

November '76 - November '77

December '76 - December '77

January '77 - January '78

February '77 - February '78

AVERAGE

7.7

9 .0

8 .5

8 .9

9 .2

9 .2

8 .9

7 .6

6 .3

8 . 0

9 .2

8 . 6

9 .2

10.9

10.8

9 .7

8 .9

9 .9

8 .4

8 .7

.

Page 16: Corrosivity at Various Distances

1.

2.

3.

4.

5.

6.

7.

8.

9.

1 0 .

11.

12.

13.

14;

15.16.

17.

18.

19.

20.

21.

22.

23.

TABLE 1015

AISI 4130 STEEL SAMPLE

EXPOSED AT INDUSTRIAL AREA (6 MILE) TEST'SITE

EXPOSURE PERIODWEIGHT LOSS

GRAMS,-

A p r i l ' 7 5 - A p r i l ' 7 6

May '75 - May '76

J u n e '75 - J u n e '76

J u l y ' 7 5 - J u l y ' 7 6

5.1

5 .1

4 . 3

4 .1

A u g u s t " 7 5 - A u g u s t ' 7 6

September '75 - September '76

October ' 7 5 - O c t o b e r '76

November '75 - November '76

December '75 - December '76

January ' 7 6 - J a n u a r y ' 7 7

February ' 7 6 - F e b r u a r y '77

5.0

6.1

6 .0

6 .3

5.8

5.1

6 .4

5 .5March '76 - March '77

Apr i l ' 7 6 - A p r i l '77

May '76 - May '77

June '76 - J u n e '77

J u l y ' 7 6 - J u l y ' 7 7

August '76 - August '77

September '76 - September '77

O c t o b e r '76 - O c t o b e r '77

November '76 - November '77

December '76 - December '77

January '77 - January '78

February '77 - February '78

AVERAGE

1.6

4 .8

6 .0

5 .6

6 .6

7 .6

7 .3

6 . 9

6 .4

4 . 3

5.2

5.5

Page 17: Corrosivity at Various Distances

1.

2.

3.

4.

5.

6.

7.

8.

9.

10.

11.

12.

13.

14..

15.

16.

17.

18.

19.

20.

21.

22.

23.

TABLE 11

AISI 1008 STEEL SAMPLES

EXPOSED AT ORLANDO (50 MILE) TEST SITE

EXPOSURE PERIOD

A p r i l ' 7 5 - A p r i l '76.

May '75 - May '76

J u n e ' 7 5 - J u n e '76

J u l y ' 7 5 - J u l y ' 7 6

August ' 7 5 - August '76

September '75 - September '76

O c t o b e r ' 7 5 - O c t o b e r '76

November '75 - November '76

December '75 - December '76

January '76 - January '77

February '76 - February '77

March '76 - March '77

I Apr i l '76 - A p r i l '77

May '76 - May '77

J u n e '76 - J u n e '77

Ju ly ' 76 - Ju ly ' 77

August '76 - August '77

September '76 - September '77

October '76 - O c t o b e r '77

November '76 - November '77

December '76 - December '77

January '77 - January '78

February '77 - February '78

AVERAGE

WEIGHT LOSSGRAMS

6 . 9

7 . 5 .

6.5

5.9

7.4

8 .3

7.7

7.6

10.9

7.1

7 .3

6.8

4 .4

7.1

8 .5

7 .5

8 .2

9.7

6 .9

8 .9

8.7

8.7

7.3

7 .6

16

Page 18: Corrosivity at Various Distances

TABLE 12 17

1.

2.

3.

4. J u l y ' 7 5 - J u l y ' 7 6 4 .1

5. August '75 - August '76

6. September '75 - September '76

O c t o b e r ' 7 5 - O c t o b e r '76

November '75 - November '76

December '75 - December '76

January '76 - January '77

February '76 - February '77

March '76 - March '77

A p r i l ' 7 6 - A p r i l ' 7 7

May '76 - May '77

J u n e '76 1 J u n e '77

Ju ly ' 76 - Ju ly ' 77

August '76 - August '77

September '76 - September '77

O c t o b e r '76 - O c t o b e r '77

November '76 - November '77

7.

8.

9.

10.

11.

12.

13.

14..

15.

16.

17.

18.

19.

20.

21.

22.

23.

AISI 4130 STEEL SAMPLES

EXPOSED AT ORLANDO (50 MILE) TEST SiTE

EXPOSURE PERIOD,-

A p r i l ' 7 5 - A p r i l ' 7 6

May '75 - May '76

WEIGHT LOSS ,GRAMS

4.7

4 .9

June '75 - J u n e ' 7 6 4 .7

5.0

6 .3

5.8

5.8

7.4

4 . 5

5.0

5.7

2.8

4 . 5

6 .5

4 .6

6 . 3

7 .3

4.8

6 .3

December '76 - December '77 6 .9

January '77 - January '78 6.0

February '77 - February '78 4 . 0

AVERAGE 5.4

.

Page 19: Corrosivity at Various Distances

18

,-

TABLE 13 .

AVERAGE WEIGHT LOSS FOR ALL EXPOSURE PERIODS

WEIGHT LOSS, GRAMS

CORROSIONTEST SITE

1

2

3

4

5 6 miles

6 50 miles

DISTANCEFROM SEACOAST

100 feet

800 feet

2500 feet

5200 feet

TEST MATERIALAISI 1008 AISI 4130

61.1 '16.9

11.6 6.6

11.4 6.6

8 .7 5.2

8.7 5.5

7 .6 5.4

-

Page 20: Corrosivity at Various Distances

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Page 21: Corrosivity at Various Distances

go0G 900-Y: 804

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50

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lo"

1 2 3 4 5 6

FIGURE 2

CORROSION RATES FOR 2 STEELS EXPOSED AT BEACH (100 FT) SITE

FOR 1 YEAR, DURING PROGRM INTERVAL,

APRIL 1975 THROUGH FE-BRUkRY.'1978.

X- AISI 1008

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Page 22: Corrosivity at Various Distances

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