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Phase Change Material Properties NaNO3
Density (kg/m3) 2257Solid Heat Capacity (J/kg.K) 1780Liquid Heat Capacity (J/kg.K) 1610Latent Heat (J/kg) 170000Thermal Conductivity (W/m.K)Melting Point (degC) 306Solid Operating Temp (K) tsLiquid Operating Temp (K) tlMolwt 85
Cost Calculations
Heat to be stored (kWh) 100000Heat to be stored (J) 360000000000System Temperature Change (K) 90CpdtPCM 324420CpdtShell+ latent heat PTFE 148000
Packed Bed System Radius of sphere (m) 0.0137
Shell thickness 0.0004 PCM Vol 1.0765398E-05 Vol. of sphere 1.1736152E-05sphere Shell Vol 9.7075403E-07PCM Mass in each sphere 0.02429750305Shell Mass in each sphere 0.00213565886Number of sphere required 43909542.47Total PCM Required 1066892.24Total Shell Material Required 93775.80Volume occupied by N sphere 515.33Porosity of Bed 0.35Bed Volume 792.81Spacers Height 5% of total volume 39.64Total Volume of Tank 832.45Air Volume (m3) 317.13Tank Diameter assume (m) 12.00Tank Height 7.36Surface area of Tank on perimeter 277.48Roof/Floor Area of Tank 113.04Surface area with Tank shell 277.85Floor with shell 113.34Roof with shell 113.27
Note: Mp=306C, delta T below Mp = 56delta Tabove Mp = 34Latent heat of Teflon = 31 J/kg used
Property EquationsLiquid Constants Solid ConstantsA -42.4478 A 50.72389B 113.526 B 6.672267C -43.6466 C -2.517167D 5.89663 D 10.15934E 39.1386 E -0.200675F -305.561 F -427.2115G 91.0639 G 130.3973H -385.923 H -411.1203
1400.616
Tank System Components 2002 Cost
Tank Shell (Carbon Steel) ($4.4/kg) - Shell thickness 7 mm 67090.29 - Floor thickness - 8 mm 31235.21 - Roof Thickness 6 mm 23426.41Insulation ($160/m2-300mm 290C;$235/m2 500 565c - 700 mm(Diff 275C-200mm, For 850 C+ 200 mm$300/m2) 62579.37Tank Foundation - Insulating Concrete (460mm and $100/m3) 5213.72 - Concrete Installation $1.3 hr/m3 - Foam glass insulation (200 mm and $356/m3) 8069.92 - Insulating Fire Bricks (330 mm, $1 each) 20288.37 - Installation of bricks (0.1 labor hours each) - Perimeter ringwall bricks (530 mm, $1 each) - Installation of ringwall (0.33 labor hours each ) - Steel Slip Plate 6 mm, $1.3/kg - Installation of steel plate (0.022 labor hour/kg) - Foundation Cooling PipesStorage Media - Storage material ($774/tonne) Current price Assume 825774.60Fabrication of pellets (10%pcm cost) 82577.46
Shell Material -PTFE ($20/kg) Current price 1875516.07 - Cost of encapsulation (10% of shell cost) 187551.61
Labor Costs/Misc (Assume 40% of Total Tank costs) 87161.32Total Costs (USD) 3276484.34Cost per kWh 32.76
Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − HS° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + GCp = heat capacity (J/mol*K) H° = standard enthalpy (kJ/mol) S° = standard entropy (J/mol*K) t = temperature (K) / 1000.
Shell Material Properties PTFE
Density (kg/m3) 2200Heat Capactiy (J/kg.K) 1300 Latent heat (j/kg K) 31000Thermal Conductivity
Referenceshttp://ed.icheme.org/costchem.htmlhttp://www.worldsteelprices.com/Brick Vol 0.0016592m3
Updated Cost Cost/KWh
80508.3537482.2628111.69 146102.30 1.46
75095.24 0.75
6256.46
9683.9124346.05 40286.42 0.40
261483.96 2.61
825774.6082577.46
908352.05 9.08
1875516.07187551.61
2063067.67 20.63
104593.58 1.053337497.27
33.37
Phase Change Material Properties NaNO3
Density (kg/m3) 2257Solid Heat Capacity (J/kg.K) 1780Liquid Heat Capacity (J/kg.K) 1610Latent Heat (J/kg) 170000Thermal Conductivity (W/m.K)Melting Point (degC) 306Solid Operating Temp (K) tsLiquid Operating Temp (K) tlMolwt 85
Cost Calculations
Heat to be stored (kWh) 100000Heat to be stored (J) 360000000000System Temperature Change (K) 90CpdtPCM 324420CpdtShell+ latent heat PTFE 148000
Packed Bed System Radius of sphere (m) 0.0137
Shell thickness 0.0004 PCM Vol 1.07654E-05 Vol. of sphere 1.173615E-05sphere Shell Vol 9.70754E-07PCM Mass in each sphere 0.024297503Shell Mass in each sphere 0.0021356589Number of sphere required 43909542.469Total PCM Required 1066892.2419Total Shell Material Required 93775.803354Volume occupied by N sphere 515.32906115Porosity of Bed 0.35Bed Volume 792.81394024Spacers Height 5% of total volume 39.640697012Total Volume of Tank 832.45463725Air Volume (m3) 317.1255761Tank Diameter assume (m) 12Tank Height 7.3642483833Surface area of Tank on perimeter 277.48487908Roof/Floor Area of Tank 113.04Surface area with Tank shell 277.85485892Floor with shell 113.34164096Roof with shell 113.26619304
Property EquationsLiquid Constants Solid ConstantsA -42.4478 A 50.72389
Cp° = A + B*t + C*t2 + D*t3 + E/t2 B 113.526 B 6.672267H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − C -43.6466 C -2.517167S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G D 5.89663 D 10.15934Cp = heat capacity (J/mol*K) E 39.1386 E -0.200675
F -305.561 F -427.2115G 91.0639 G 130.3973H -385.923 H -411.1203
1400.616
Tank System Components 2002 Cost
Tank Shell (Carbon Steel) ($4.4/kg) - Shell thickness 7 mm 67090.29 - Floor thickness - 8 mm 31235.21 - Roof Thickness 6 mm 23426.41Insulation ($160/m2-300mm 290C;$235/m2 500 565c - 700 mm(Diff 275C-200mm, For 850 C+ 200 mm$300/m2) 62579.37Tank Foundation - Insulating Concrete (460mm and $100/m3) 5213.715 - Concrete Installation $1.3 hr/m3 - Foam glass insulation (200 mm and $356/m3) 8069.925 - Insulating Fire Bricks (330 mm, $1 each) 20288.37 - Installation of bricks (0.1 labor hours each) - Perimeter ringwall bricks (530 mm, $1 each) - Installation of ringwall (0.33 labor hours each ) - Steel Slip Plate 6 mm, $1.3/kg - Installation of steel plate (0.022 labor hour/kg) - Foundation Cooling PipesStorage Media - Storage material ($774/tonne) Current price Assume 825774.6Fabrication of pellets (10%pcm cost) 82577.46
Shell Material -PTFE ($20kg) Current price 1875516Zinc coating 10% of PCM wt. @$2000/Ton 213378.4Cost of encapsulation (10% of shell cost) 208889.5
Labor Costs/Misc (Assume 40% of Total Tank costs) 87161.32Total Costs (USD) 3511201Cost per kWh 35.11201
H° = standard enthalpy (kJ/mol) S° = standard entropy (J/mol*K) t = temperature (K) / 1000.
Shell Material Properties PTFE
Density (kg/m3) 2200Heat Capactiy (J/kg.K) 1300 Latent heat (j/kg K) 31000Thermal Conductivity
Heat Capactiy (J/kg.K) for Zinc 388
Referenceshttp://ed.icheme.org/costchem.htmlhttp://www.worldsteelprices.com/Brick Vol 0.0016592m3
Updated Cost Cost/KWh
80508.3537482.2628111.69 146102.3 1.46
75095.24 0.75
6256.46
9683.9124346.05 40286.4152 0.40
261483.957 2.61
825774.6082577.46
908352.055 9.08
1875516.07213378.45208889.45 2297784 22.98
104593.58 1.053572213.56
35.72
Phase Change Material Properties NaNO3
Density (kg/m3) 2257Solid Heat Capacity (J/kg.K) 1780Liquid Heat Capacity (J/kg.K) 1610Latent Heat (J/kg) 170000Thermal Conductivity (W/m.K)Melting Point (degC) 306Solid Operating Temp (K) tsLiquid Operating Temp (K) tlMolwt 85
Cost Calculations
Heat to be stored (kWh) 100000Heat to be stored (J) 360000000000System Temperature Change (K) 90CpdtPCM 324420CpdtShell+ latent heat PTFE 148000
Packed Bed System Radius of sphere (m) 0.0137
Shell thickness 0.0004 PCM Vol 1.0765398E-05 Vol. of sphere 1.1736152E-05sphere Shell Vol 9.7075403E-07PCM Mass in each sphere 0.02429750305Shell Mass in each sphere 0.00213565886Number of sphere required 43909542.4691Total PCM Required 1066892.24186Total Shell Material Required 93775.8033541Volume occupied by N sphere 515.329061155Porosity of Bed 0.35Bed Volume 792.813940238Spacers Height 5% of total volume 39.6406970119Total Volume of Tank 832.45463725Air Volume (m3) 317.125576095Tank Diameter assume (m) 12Tank Height 7.36424838332Surface area of Tank on perimeter 277.484879083Roof/Floor Area of Tank 113.04Surface area with Tank shell 277.854858922Floor with shell 113.34164096Roof with shell 113.26619304
Property EquationsLiquid Constants Solid ConstantsA -42.4478 A
Cp° = A + B*t + C*t2 + D*t3 + E/t2 B 113.526 BH° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H C -43.6466 CS° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G D 5.89663 DCp = heat capacity (J/mol*K) E 39.1386 E
F -305.561 FG 91.0639 GH -385.923 H
1400.616
Tank System Components 2002 Cost
Tank Shell (Carbon Steel) ($4.4/kg) - Shell thickness 7 mm 67090.29406 - Floor thickness - 8 mm 31235.2128 - Roof Thickness 6 mm 23426.4096Insulation ($160/m2-300mm 290C;$235/m2 500 565c - 700 mm(Diff 275C-200mm, For 850 C+ 200 mm$300/m2) 62579.36831Tank Foundation - Insulating Concrete (460mm and $100/m3) 5213.715484 - Concrete Installation $1.3 hr/m3 - Foam glass insulation (200 mm and $356/m3) 8069.924836 - Insulating Fire Bricks (330 mm, $1 each) 20288.37233 - Installation of bricks (0.1 labor hours each) - Perimeter ringwall bricks (530 mm, $1 each) - Installation of ringwall (0.33 labor hours each ) - Steel Slip Plate 6 mm, $1.3/kg - Installation of steel plate (0.022 labor hour/kg) - Foundation Cooling PipesStorage Media - Storage material ($774/tonne) Current price Assume 825774.5952Fabrication of pellets (10%pcm cost) 82577.45952
Shell Material -PTFE ($3/kg) Current price 1875516.067Nickel coating 5% of PCM wt. @$15000/Ton 960203.0177Cost of encapsulation (10% of shell cost) 283571.9085
Labor Costs/Misc (Assume 40% of Total Tank costs) 87161.31897Total Costs (USD) 4332707.664Cost per kWh 43.32707664
H° = standard enthalpy (kJ/mol) S° = standard entropy (J/mol*K) t = temperature (K) / 1000.
Solid Constants Shell Material Properties PTFE50.723896.672267 Density (kg/m3) 2200
-2.517167 Heat Capactiy (J/kg.K) 1300 Latent heat (j/kg K) 3100010.15934 Thermal Conductivity
-0.200675-427.2115 Heat Capactiy (J/kg.K) for Nickel 445130.3973
-411.1203 Referenceshttp://ed.icheme.org/costchem.htmlhttp://www.worldsteelprices.com/Brick Vol 0.0016592m3
Updated Cost Cost/KWh
80508.3537482.2628111.69 146102.30 1.46
75095.24 0.75
6256.46
9683.9124346.05 40286.42 0.40
261483.96 2.61
825774.6082577.46
908352.05 9.08
1875516.07960203.02283571.91 3119290.99 31.19
104593.58 1.054393720.59
43.94
Phase Change Material Properties NaNO3
Density (kg/m3) 2257Solid Heat Capacity (J/kg.K) 1780Liquid Heat Capacity (J/kg.K) 1610Latent Heat (J/kg) 172000Thermal Conductivity (W/m.K)Melting Point (degC) 306Solid Operating Temp (K) tsLiquid Operating Temp (K) tlMolwt 85
Cost Calculations
Heat to be stored (kWh) 100000Heat to be stored (J) 360000000000System Temperature Change (K) 90CpdtPCM 326420CpdtShell+ latent heat PTFE 117000
Packed Bed System Radius of sphere (m) 0.0137
Shell thickness 0.0004 PCM Vol 1.07653979E-05 Vol. of sphere 1.17361519E-05sphere Shell Vol 9.70754027E-07PCM Mass in each sphere 0.02429750305Shell Mass in each sphere 0.00213565886Number of sphere required 44004061.4109Total PCM Required 1069188.81613Total Shell Material Required 93977.6635694Volume occupied by N sphere 516.438349815Porosity of Bed 0.35Bed Volume 794.520538177Spacers Height 5% of total volume 39.7260269088Total Volume of Tank 834.246565085Air Volume (m3) 317.808215271Tank Diameter assume (m) 12Tank Height 7.38010054039Surface area of Tank on perimeter 278.082188362Roof/Floor Area of Tank 113.04Surface area with Tank shell 278.452964613Floor with shell 113.34164096Roof with shell 113.26619304
Property EquationsLiquid Constants Solid ConstantsA -42.4478 A
Cp° = A + B*t + C*t2 + D*t3 + E/t2 B 113.526 BH° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F C -43.6466 CS° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G D 5.89663 DCp = heat capacity (J/mol*K) E 39.1386 E
F -305.561 FG 91.0639 GH -385.923 H
1400.616
Tank System Components 2002 Cost
Tank Shell (Carbon Steel) ($4.4/kg) - Shell thickness 7 mm 67234.71150212 - Floor thickness - 8 mm 31235.2128 - Roof Thickness 6 mm 23426.4096Insulation ($160/m2-300mm 290C;$235/m2 500 565c - 700 mm(Diff 275C-200mm, For 850 C+ 200 mm$300/m2) 62675.065224474Tank Foundation - Insulating Concrete (460mm and $100/m3) 5213.71548416 - Concrete Installation $1.3 hr/m3 - Foam glass insulation (200 mm and $356/m3) 8069.924836352 - Insulating Fire Bricks (330 mm, $1 each) 20288.372327097 - Installation of bricks (0.1 labor hours each) - Perimeter ringwall bricks (530 mm, $1 each) - Installation of ringwall (0.33 labor hours each ) - Steel Slip Plate 6 mm, $1.3/kg - Installation of steel plate (0.022 labor hour/kg) - Foundation Cooling PipesStorage Media - Storage material ($774/tonne) Current price Assume 827552.14368753Fabrication of pellets (10%pcm cost) 82755.214368753
Shell Material -PTFE ($3/kg) Current price 1879553.2713881Nickel coating 5% of PCM wt. @$15000/Ton 962269.93452038Cost of encapsulation (10% of shell cost) 284182.32059084
Labor Costs/Misc (Assume 40% of Total Tank costs) 87257.364709681Total Costs (USD) 4341713.6610395Cost per kWh 43.417136610395
H° = standard enthalpy (kJ/mol) S° = standard entropy (J/mol*K) t = temperature (K) / 1000.
Solid Constants Shell Material Properties PTFE50.723896.672267 Density (kg/m3) 2200
-2.517167 Heat Capactiy (J/kg.K) 130010.15934 Thermal Conductivity
-0.200675-427.2115 Heat Capactiy (J/kg.K) for Nickel 445130.3973
-411.1203 Referenceshttp://ed.icheme.org/costchem.htmlhttp://www.worldsteelprices.com/Brick Vol 0.0016592m3
Updated Cost
80681.6537482.2628111.69 146275.60
75210.08
6256.46
9683.9124346.05 40286.42
261772.09
827552.1482755.21
910307.36
1879553.27962269.93284182.32 3126005.53
104708.844402793.82
44.03
Latent heat (j/kg K)
Cost/KWh
1.46
0.75
0.40
2.62
9.10
31.26
1.05