cover meappsd.daera-ni.gov.uk/ipri/docs/p0052-04a lafarge ireland... · 2019. 4. 2. · monitoring...
TRANSCRIPT
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ISO/IEC 17025 Accredited Legal Entity, UKAS Accredited Testing Laboratory No. 4279Exova (UK) Ltd trading as Exova Catalyst & Exova Catalyst Ireland
Unit C5, Emery Court, The Embankment Business Park, Stockport, SK4 3GL
Stack Reference
Lafarge Ireland LtdCookstown Works29 Sandholes Road
CookstownBT80 9AR
Primary Site Contact: Jim Buchanan
Installation Name & Address
PPC Permit: P0052/04A/V6
EN 14181 AST Report Commissioned by
A8 - Kiln Exhaust Main Stack (Standby Analyser)
Lafarge Ireland Ltd
Exova Catalyst, 70 Montrose Avenue, Hillington Park, Glasgow, G52 4LAYour Exova Catalyst Contact: John Healey (07826 916 681)
Job Reference NumberCEK-2909
Report Approved by
Report Written by
COVER ME
Signature of Report Approver
Version 1Report Version
John Healey
29th May 2018Report Date
TE1 TE2 TE3 TE4MM 03 476
MCERTS Level 2
15th - 16th May 2018Dates of the Monitoring Campaign
Regional Manager
Deputy Regional Manager
TE1 TE2 TE3 TE4MM 04 492
MCERTS Level 2
Iain Wilkie
CAT-14181 (Version X)CEK-2909 Lafarge Ireland Ltd (Cookstown) - A8 Kiln Exhaust Main Stack - AST (Standby Analyser)
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SECTION 1A: TITLE PAGE
CONTENTS 2
SECTIONS 1B & 1C: EXECUTIVE SUMMARY
Overall Aim of the Monitoring Campaign & Special Requirements 3
AST Calibration Check Summary 3
Summary of Standard Reference Method & EN 14181 Deviations 4
Conclusions, Discussions and Actions arising from the Sampling 5
SECTION 2: INFORMATION ABOUT THE REGULATED INSTALLATION
Regulatory Information 5
Operational Information and Site Monitoring Provisions 6
Monitoring Provisions at the Installation - Periodic Monitoring 7
Continuous Emissions Monitors (CEM) at the Installation 9
SECTION 3: INFORMATION ABOUT THE MONITORING CAMPAIGN
Test Laboratory Staff 10
Standard Reference Methods (SRMs) 10
SECTION 4B: Data and Calculations - AST
SECTION 5: Results of the Functional Tests
CONTENTS
SECTION 5: Results of the Functional Tests
This test report has been written to fully comply with the requirements in EN 14181:2014 and the Environment Agency's Technical Guidance Note TGN M20, Version 3 (incorporating MID 14181 as Annex A) which was published in June 2015.
Opinions and interpretations expressed herein are outside the scope of Exova Catalyst's UKAS accreditation.
This test report shall not be reproduced, except in full, without the written approval of Exova Catalyst.
CAT-14181 (Version X)2 of 37
Lafarge Ireland LtdCookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
Job Number: CEK-2909, Version 1Sample Date/s: 15th - 16th May 2018
PPC Permit: P0052/04A/V6
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Overall Aim of the Monitoring Campaign
Special Requirements
AST CALIBRATION CHECK SUMMARY
Parameter Calibration Function as Derived from the
Previous QAL2
Result of Calibration
Test
SECTION 1B
Lafarge Ireland Ltd, Cookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
15th - 16th May 2018
Exova Catalyst were commissioned by Lafarge Ireland Ltd to carry out stack emissions testing on the A8 - Kiln Exhaust Main Stack (Standby Analyser) Stack at Cookstown Works.
There were no special requirements.
The aim of the monitoring campaign was to perform an AST Calibration Check Exercise on the Continuous Emissions Monitor (CEM), which is installed on the Plant, following the requirements of EN 14181.
Executive Summary (Page 1 of 2)
Calibration Function derived
from QAL2?
Range after AST Extension
@ REF Conditions
Calibration Function that the AST was
performed against (See Conclusion)
Result of Variability
Test
Calibration Range from
Previous QAL2 @ REF
Conditions
All calibration functions relate to mg/m³, unless otherwise stated.
y = 0.9876x + 20.5419
Ammonia Yes y = 1.1299x -1.804
Carbon Monoxide y = 1.064x -3.5405Hydrogen Chloride y = 0.991x -0.4158
Total Particulate Matter y = 0.5384x + 2.3444Total VOCs y = 0.8427x -0.7458
Pass Passy = 0.9708x -0.0951
0 to 21.80 to 16.6Water Vapour (% v/v) Yes y = 0.9708x -0.0951 Pass Pass
Oxygen (% v/v) Yes y = 1.0181x + 0.3301 y = 1.0181x + 0.3301
Pass
PassPass
PassPassPass
PassOxides of Nitrogen (as NO₂) Yes y = 0.9622x + 5.9809 Pass PassSulphur Dioxide Yes
YesYes
YesYes
0 to 60.20 to 12.1
0 to 677.50 to 976.80 to 19.10 to 30.1
Existing Range Still Valid
Existing Range Still Valid
Existing Range Still Valid
Existing Range Still Valid
Existing Range Still Valid
Existing Range Still Valid
Existing Range Still Valid
Existing Range Still Valid
Existing Range Still Validy = 0.5384x + 2.3444y = 0.8427x -0.7458y = 0.9622x + 5.9809
y = 0.9876x + 20.5419y = 1.064x -3.5405
Pass Passy = 0.991x -0.4158y = 1.1299x -1.804
Pass
PassPass0 to 544.5
The calibration functions, once applied, only remain valid as long as the QAL3 data remains within control limits, and that there are no manual adjustments made to the CEMs other than those allowed to bring the settings back within the QAL3 control limit.
CAT-14181 (Version X)3 of 37
Lafarge Ireland LtdCookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
Job Number: CEK-2909, Version 1Sample Date/s: 15th - 16th May 2018
PPC Permit: P0052/04A/V6
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Total Particulate Matter, Total VOCs, Oxides of Nitrogen, Sulphur Dioxide, Carbon Monoxide, Hydrogen Chloride, Ammonia, Water Vapour & Oxygen
15th - 16th May 2018A8 - Kiln Exhaust Main Stack (Standby Analyser)
CONCLUSIONS, DISCUSSIONS & ACTIONS FROM THE SAMPLING EXERCISE
SECTION 1C
Executive Summary (Page 2 of 2)
Lafarge Ireland Ltd, Cookstown Works
The CEM data was corrected using the calibration function derived during the most recent QAL2 campaign. The corrected values passed both the variability and calibration tests as required by EN 14181 and therefore the calibration function is deemed to be valid within the given tolerances. The calibration range derived in the previous QAL2 is still valid.
SUMMARY OF STANDARD REFERENCE METHOD & EN 14181 DEVIATIONS
Parameter Run Deviation
All Parameters All There are no deviations associated with the sampling employed
CAT-14181 (Version X)4 of 37
Lafarge Ireland LtdCookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
Job Number: CEK-2909, Version 1Sample Date/s: 15th - 16th May 2018
PPC Permit: P0052/04A/V6
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Regulated Determinands and Emission Limit Values (ELVs)
¹ TGN M20, Version 3
Date CEMs Data Obtained by Exova Catalyst 25th May 2018
Section 2: Information about the Regulated Installation
2020 ¹
Name of the Installation
Value
600
--
30
Lafarge Ireland Ltd, Cookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
15th - 16th May 2018
Short-Term ELV (mg/m³)
Daily or 48hr Average ELV (mg/m³)
Date of the Last QAL2 / AST Campaign 1st - 6th November 2017 (Gaseous AST / TPM QAL2)
Cookstown Works
Oxides of Nitrogen (as NO₂) -
--
3035
600
40Hydrogen ChlorideCarbon Monoxide
10- 50
30
Ammonia
-
Determinand
Cement & LimePermit Number P0052/04A/V6
Address of the Installation See Title PageSector of the Installation
REGULATORY INFORMATION
Parameter
800 20
Uncertainty Requirement (%)
Sulphur Dioxide
Total VOCsTotal Particulate Matter
40
¹ TGN M20, Version 3
CAT-14181 (Version X)5 of 37
Lafarge Ireland LtdCookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
Job Number: CEK-2909, Version 1Sample Date/s: 15th - 16th May 2018
PPC Permit: P0052/04A/V6
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Process Type and Variations in Emissions
Type of Fuel
Continuous
Yes
No
OPERATIONAL INFORMATION AND SITE MONITORING PROVISIONS
No
Were there any variations in emissions during the EN 14181 test (e.g. Load changes)Will these variations affect the representative nature of the collected data?
A8 - Kiln Exhaust Main Stack (Standby Analyser)15th - 16th May 2018
Are multiple calibration functions required if the emissions vary
Value
Pulverised Coal & Recyled Liquid Fuel Oil
No
Are there any factors that may affect the collected data(e.g. auto-calibrations, plant start up and shut down)
Fuel type used during the EN 14181 test(include proportions for co-incineration)
Was the CEM reading zero for any determinands, if so, was this investigated to ensure it was working?
Section 2: Information about the Regulated Installation
Continuous or batch process
No
What product was being processed during the tests? Cement
Reviewing historical Plant data, were low emissions expected for any determinands?
No
Parameter
Lafarge Ireland Ltd, Cookstown Works
Parameter Value
Abatement
due to different fuel types being used?
ESP
Parameter Value
Running Status On
Type of Abatement System
CAT-14181 (Version X)6 of 37
Lafarge Ireland LtdCookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
Job Number: CEK-2909, Version 1Sample Date/s: 15th - 16th May 2018
PPC Permit: P0052/04A/V6
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Duct Characteristics Location of Sampling Platform
Platform Details
Number of Ports - 4.0
cm 9.0Orientation of Duct - Vertical
Safe access available
YesPlatform has vertical base boards (approx. 0.25m high) Yes
Yes
No
Sufficient working area to manipulate probe and operate the measuring instruments
4" BSP
EA Technical Guidance Note M1 / EN 15259 Platform Requirements
YesYes
Platform has 2 levels of handrails (approx. 0.5m & 1.0m high)
Platform has chains / self closing gates at top of ladders
Value
Units Value General Platform Information Value
Type - Circular Permanent / Temporary Platform PermanentDepth m 4.82 Inside / Outside OutsideWidth m -Area m² 18.25Port Depth
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Section 2: Information about the Regulated Installation
MONITORING PROVISIONS AT THE INSTALLATION - PERIODIC MONITORING
Lafarge Ireland Ltd, Cookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
Sample Port Size
Access to sample ports unhindered by obstructions
15th - 16th May 2018
Parameter
(Page 1 of 2)
Sampling Location / Platform Improvement Recommendations
EN 15259 Homogeneity Test Requirements
Sampling Plane Validation Criteria (EN 15259)
-
6.0
m/s 5.22 -Highest Gas Velocity
< 15° Yes
- > 5 Pa Yes
--
Yes-
- - - -
Safe access available
Required Compliant
Lowest Differential Pressure Pa 13.5
Maximum Angle of Swirl ° -
No
The sampling location meets all the requirements specified in EA Guidance Note M1 and EN 15259, and therefore there are no improvement recommendations.
According to EN 15259, a Homogeneity Test is required on this stack, however, as far as we are aware, it has not yet been undertaken. Unless agreed otherwise with the respective regulator, we would recommend that the Homogeneity Test be undertaken prior to the next set of emissions testing on this stack, and would be happy to carry out the work. Please contact Exova Catalyst for further details.
Criteria in M1 Units
--
Ratio of Above : 1 1.20
4.85 - -
Yes
- -
Yes
4.34 -
-No Local Negative Flow -
- - -
Lowest Gas Velocity m/s
- -
Traverse 1 - - - -
< 3 : 1
Mean Velocity m/s - - - --
Easy access available Yes
- -
CAT-14181 (Version X)7 of 37
Lafarge Ireland LtdCookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
Job Number: CEK-2909, Version 1Sample Date/s: 15th - 16th May 2018
PPC Permit: P0052/04A/V6
-
Pro-forma for Site Provisions for Monitoring
Plant Photos
Yes
Compliance with MID 15259
Section 2: Information about the Regulated Installation
Requirement Notes
Photo 1 Photo 2
A safe and clean working environment with sufficient space and weather protection.
Yes
Easy and safe access to the CEM. Yes
Adequate supplies of reference materials, tools and spare parts.
15th - 16th May 2018
Yes
Compliant
MONITORING PROVISIONS AT THE INSTALLATION - PERIODIC MONITORING
Lafarge Ireland Ltd, Cookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
Facilities to introduce the reference materials for gaseous-monitoring systems, both at the inlet of the sampling line (where present), and at the inlet of the CEM.
Yes
(Page 2 of 2)
See the Sampling Plane Validation Criteria table on the previous page.
Sample Points
where = isokinetic point sampled at
= isokinetic point not sampled at
= combustion gases sample point
= non-isokinetic sample point
Line A
Line B
B1
B4
B3
B2
B6
B9
B8
B7
A8A7 A9 A10
A1 A2 A3 A4
B10
B5
A5
A6
CAT-14181 (Version X)8 of 37
Lafarge Ireland LtdCookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
Job Number: CEK-2909, Version 1Sample Date/s: 15th - 16th May 2018
PPC Permit: P0052/04A/V6
-
Type
ABB CEMAS FTIR-NT
MC 030016
Yes DURAG D-R-230
3.350294.7
3.350294.7
3.350294.7
ExtractiveExtractiveExtractive
YesExtractiveExtractiveExtractive
MC 030016MC 030016Oxygen (Wet)
3.350294.7
Ammonia 0 - 15
Cross-Duct
MC 030016MC 030016
15th - 16th May 2018
Yes
ExtractiveExtractive
ABB CEMAS FTIR-NT
FTIR
0 - 40%Water Vapour 3.350294.7
Total Particulate Matter DURAG D-R-230
Instrument Name
A0 2000 Multi FIDABB CEMAS FTIR-NT
0 - 25%
Lafarge Ireland Ltd, Cookstown Works
Extractive 3.350294.7
Nitrogen MonoxideNitrogen DioxideSulphur Dioxide
FID
Measurement Principle
Total VOCs 3.350294.73.350294.7
Optical Light Scattering
Carbon MonoxideHydrogen Chloride
QAL1 Compliant
MC 030015
MC 030016MC 030016
Certified Range (mg/m³)
0 - 7.5 MC 140253
FTIRFTIR
Zirconia
MC 030016
Pressure Yes DURAG D-R-230
ABB CEMAS FTIR-NTABB CEMAS FTIR-NT
Peripheral Determinand Recorded Instrument Name
Temperature
ABB CEMAS FTIR-NT
Main Determinand
0 - 200
Instrument Serial Number
01239225
A8 - Kiln Exhaust Main Stack (Standby Analyser)
0 - 15
MCERTS Number
FTIRFTIR
FTIRFTIR
Section 2: Information about the Regulated Installation
CONTINUOUS EMISSION MONITORs (CEMs) AT THE INSTALLATION
-0 - 750 - 750 - 15
YesYesYesYes
ABB CEMAS FTIR-NTABB CEMAS FTIR-NT
3.350294.7YesYes
YesYes
CAT-14181 (Version X)9 of 37
Lafarge Ireland LtdCookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
Job Number: CEK-2909, Version 1Sample Date/s: 15th - 16th May 2018
PPC Permit: P0052/04A/V6
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NOTE 1: Exova Catalyst hold UKAS and MCERTS Accreditation for all Standard Reference Method Tests performed.
NOTE 2: The MU specified in this column is reported as the MU at the Daily ELV (not the MU percentage of concentration measured.)
where: MST stands for Manual Sampling Train
Anthony LovellTechnician
Position Technical EndorsementsMCERTS AccreditationName
Stephen Dick MCERTS Level 2 TE1 TE2 TE3 TE4MCERTS Level 1 MM 16 1397, Expiry: 30/09/2021 None
Gasmet DX4000Total VOCs
0 - 75
Gasmet DX4000Water Vapour 0 -30%
Team Leader
MCERTS Number & Expiry Date
MM 10 1061, Expiry :30/04/2020
Operational (mg/m³)
N/A - SRM0 - 161
0 - 936.9
Instrumental Ranges
Sulphur Dioxide
EN 12619
0 - 75.9 MC 030014 TGN M22 8.1
EN 14789TGN M22FTIR
Paramagnetic CellHoriba PG-350E
0 - 15
MU ²(%)
MC 030014Gasmet DX4000
MST
FTIRFTIR
STANDARD REFERENCE METHODS (SRMs)
Total Particulate Matter
FTIRCarbon Monoxide 0 - 75
EN 13284-1
Ammonia Gasmet DX4000 FTIR N/A
0 - 15
Determinand
8.02.22.41.5
Sick Maihak 3006
Exova Catalyst hold UKAS and MCERTS Accreditation for performing QAL2 and ASTs, to EN 14181.
MCERTS Number
FTIR
0 - 200 MC 030014MC 040036MC 030014
Reference Method
0 - 1159.2TGN M22
Measurement Principle
GravimetricFID
TGN M222.28.9
Oxides of Nitrogen (as NO₂)
0 - 20%0 - 25%
Instrument Name
Certified (mg/m³)
Section 3 - Information about the Monitoring Campaign
TEST LABORATORY STAFF
MC 130223MC 030014
Oxygen (Dry) 0 - 25%
0 - 75
Hydrogen Chloride
TGN M22TGN M22
Gasmet DX4000Gasmet DX4000 MC 030014
MC 0300140 - 624.60 - 16.3
5.43.4
Servomex 4900
Oven Box (1)
Mass View (2)
CAT 13.24Umbilical (2)
Control Box DGM (1)
CAT 4.206Stack Thermocouple (1)
-Digital Temperature Meter CAT 3.34 / 3.54
Heated Probe (2) CAT 5.162 CAT 20.131
5m Heated Line (1)
CAT 12.963 CAT 4.934
Stopwatch
Oven Box (2)
CAT 25.4
Heated Probe (3) CAT 5.11 Ankersmid APP100
Box Thermocouples (2)Umbilical (1) CAT 3.57
Servomex 5200MP -Barometer
-CAT 14.53
Equipment Type Equipment I.D. Equipment Type Equipment I.D. Equipment I.D.Equipment Type
-
-CAT 10.4
Stack Thermocouple (3) CAT 4.995 / 4.0048
Heated Probe (1) CAT 5.4Bernath 3006 FID
CAT 12.721m Heated Line (2)
L-Pitot -
Mass Flow Controller (1)Mass Flow Controller (2) CAT 6.12
CAT 6.111m Heated Line (3) -
CAT 21S.28
Gasmet DX4000 CAT 19.12Stack Thermocouple (2)
Extractive Sampling Instrumental Analysers
Eco Physics CLD 822Mh
CAT 7.38 Horiba PG-350E CAT 39.7 Digital Manometer (1) CAT 3.34Control Box DGM (2)
LIST OF EQUIPMENT
- Horiba PG-250 SRM CAT 9.13 Digital Manometer (2) CAT 3.54
CAT 17.420m Heated Line (1) CAT 20.133
Box Thermocouples (1) CAT 3.57
-ABB AO2020-URAS26
Miscellaneous Items
S-Pitot (1)
CAT 8.4
-
JCT JCC P1 CoolerCAT 4.597
-
1m Heated Line (1) CAT 20.130Gasmet Sampling System
S-Pitot (2) 15m Heated Line (1) -CAT 21P.95 / 105
20m Heated Line (2) -Dual Channel Heater Controller1Kg Check Weight
Last Impinger ArmCallipersTubes Kit Thermocouple
CAT 17.4CAT 4.22 / 4.24 / 4.9993
CAT 23.22CAT 4.217
Easylogger EN-EL-12 Bit -Hioki 5043 (V) CAT 11.94
CAT 3.161Single Channel Heater Controller
500g Check WeightMass View (1) -
-Laboratory Balance CAT 1.18 / 1.18aTape Measure CAT 16.3
CAT-14181 (Version X)10 of 37
Lafarge Ireland LtdCookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
Job Number: CEK-2909, Version 1Sample Date/s: 15th - 16th May 2018
PPC Permit: P0052/04A/V6
-
Calibration Data
Outliers Data
Reason for Data Pair Removal
SELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE IN
INPUT
INPUT INPUT 0.00 0.00
5 15/05/2018 14:20 - 15:06 10.56 8.469.34
Time
8
SRM (STP, DRY,
10% O₂) mg/m³
(Page 1 of 3)
7.5612.11
x - xav(A)
y - yav(B)
13.80
12:00 - 12:45
Section 4B - Data and Calculations - AST
TOTAL PARTICULATE MATTER: AST CALCULATIONS
INPUT INPUT 0.00 0.00 INPUT
INPUT
1
-0.75
MAX SRM - MIN SRM
x, CEM (STP, ACTUAL) mg/m³
-0.39
0.00 INPUT
6
43
INPUT INPUT 0.00 0.00
0.00
0.005INPUTINPUT INPUT 0.00
2.53 2.75(DAILY) DELV (mg/m³)
30
INPUT2 INPUT INPUT
INPUT 0.00 0.00
8.08
9.01 14.15
10.65
-0.12 0.03 8.067 16/05/2018 09:00 - 09:46
10:48 - 11:34
y, SRM (STP, ACTUAL) mg/m³
(A) x (B) (x - xav)² CAL CEM (STP,
ACTUAL) mg/m³
1 15/05/2018 09:35 - 10:20 11.21 9.50 15.27 0.77 0.64 0.49 0.5915/05/2018
0.93 0.56
5.2530
95% CI MU (%)
Pair Date Time
0.59
SUM
0.16 0.09 0.34 8.2811.0317.36 -0.03 2.08 -0.07 0.00 7.95
8.382
15.46
6 15/05/2018 15:25 - 16:11 10.62 8.19 13.19
3 15/05/2018 10.41 10.93
Lafarge Ireland Ltd, Cookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
Pair Date
4 15/05/2018 13:15 - 14:02
16/05/2018 10:00 - 10:45
0.12
7.80 12.71
0.21 0.49 0.10 0.04
-1.259.69 7.61-0.66
9.36
-0.05 0.01 8.030.18
-1.08 -1.06 1.14 1.17 7.38
INPUT
x, CEM (ACTUAL)
mg/m³
y, SRM (ACTUAL)
mg/m³
Filter ID Number
(47-XXXX)
SELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE IN
INPUT
INPUT
8 INPUT INPUT 0.00 0.00
6
10
INPUT0.00 INPUT7
INPUT 0.00 0.000.00
INPUT INPUT 0.00 0.00 INPUTINPUT 0.00
Existing Calibration Function
0.00 INPUT9 INPUT
y = 0.5384x + 2.3444Source of Existing Calibration Function
INPUT INPUT
CEK-2705 Exova Catalyst QAL2
Existing Calibration Range (@ REF Conditions)0 to 30.1 mg/m³
CAT-14181 (Version X)11 of 37
Lafarge Ireland LtdCookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
Job Number: CEK-2909, Version 1Sample Date/s: 15th - 16th May 2018
PPC Permit: P0052/04A/V6
-
PLOT 1: BAR CHART FOR REFERENCE SRM vs REFERENCE CEM (STANDARDISED)
Variability Test Data where CAL = Calibrated using AST calibration functions
A8 - Kiln Exhaust Main Stack (Standby Analyser)
Date
TOTAL PARTICULATE MATTER: AST CALCULATIONS (Page 2 of 3)
Lafarge Ireland Ltd, Cookstown Works
SRMPressure
COPY CORRECT PLOT 1 BAR CHART
SRMWater
CEMOxygen
CEMOxygen
SRMOxygen
Section 4B - Data and Calculations - AST
Time CEMTemp
SRMTemp
CEMPressure
PairCAL CAL
CEMWater
CEMWater
0.0
5.0
10.0
15.0
20.0
25.0
30.0
1 2 3 4 5 6 7 8
mg/
m³ (
REF)
Pair
CEM SRM
101.7 101.7
0.0
101.7 101.7
00/01/1900
0 00/01/1900 00:00 0.0 0.0 0.0
101.7
0
0.0
0
91.9
0.0 0.0 0.0
0 00/01/1900
00:000
0.00 0.000
PressurekPa
67 16/05/2018 90.1
96.0 101.7 101.7
1 15/05/2018
94.3
Water Vapour% v/v
Oxygen (DRY)% v/v
Oxygen (DRY)% v/v
Oxygen (DRY)% v/v
15.97 15.41 14.19
0 00/01/1900
10:00 - 10:45
9.989.75 10.26 10.02
95.3
0.00
101.7 101.796.1
00/01/1900
0
9.68 10.19 10.2616.11 15.55 14.59 9.70 10.21
00/01/1900
09:35 - 10:20 93.8
00:00 0.0
90.4 93.7
13.80 0.766 15/05/2018 15:25 - 16:11
101.7
94.3 95.3
8 16/05/2018
0
0.00
0.00
0
00/01/1900
5
2
101.7
15/05/2018 10:48 - 11:34 94.3
Temp°C
0.00 0.00 0.00 0.00
2
-0.228
Filter ID Number
(47-XXXX)
47-4896847-51049
00:00MAX
0.00 0.000.0000.00 0.00
0 0.000:00 0.0
15/05/2018 10:48 - 11:34
12:00 - 12:45
Date Time CAL CEM (ACTUAL)
mg/m³
CAL CEM (STP, DRY,
10% O₂) mg/m³
000:00 0.00 0.00
15/05/2018
00:0016/05/2018
8.38 13.49 15.27 1.78
13:15 - 14:02 8.08 13.0515/05/2018 14:20 - 15:06
12.11
0.00
15.46 2.42
10:00 - 10:45 7.38 12.19
0.0 0.0
Sd 1.52
0.000 000/01/1900 00:00
09:35 - 10:20
0.00
16/05/2018
00/01/1900
0 00/01/1900 00:00 0.00 0.00 0.00 0.00 0
13.49
4
0 00/01/19000 00/01/1900 00:00
0.000.00 0.00 0.00 0.00
8.03 13.04
17.36 4.44
8.06
SRM (STP, DRY,
10% O₂) mg/m³
ys, SRM - CAL CEM
0
Pair
0
712.71 0.52
0.0 0.0
96.6 101.7 101.715/05/2018
15/05/2018 15:25 - 16:11 94.3 96.4 101.7
Temp°C
PressurekPa
13:15 - 14:0215/05/2018 101.7 101.7
4
0.0
13.04 13.19 0.15
00:00 0.0
0.753 15/05/2018 12:00 - 12:45 7.95 12.91
47-5044309:00 - 09:46 12.33
15/05/2018
0.0 0.0 0.000:00
0.0 0.010.40
0.00 0.00 0.00 0.00 0.00 0.00
0.000.00
94.3
00/01/1900
09:00 - 09:46
00:00 0.0 0.0
16.08 15.51 15.18
47-5121547-5096347-5044447-5121647-50449
1
0.00 0.00 0.00 0.00 0.00 0.00
3
7.56
5
8.28 13.40 14.15
0.0 0.0
15/05/2018 14:20 - 15:06
0.00.00.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00
Water Vapour% v/v
Water Vapour% v/v
16.09 15.52 16.98 9.68 10.19 10.2216.06 15.49 15.28 9.75 10.26 10.2615.89 15.33 16.14 9.72 10.23 10.0215.50 14.95 15.93 9.98 10.49 10.0615.51 14.96 14.80 10.10 10.61
0.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00
00/01/1900 00:00
CAT-14181 (Version X)12 of 37
Lafarge Ireland LtdCookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
Job Number: CEK-2909, Version 1Sample Date/s: 15th - 16th May 2018
PPC Permit: P0052/04A/V6
-
Test of Variability Test of Calibration (Acceptance of Calibration Function)
where N (number of samples) = 8
The variability is accepted if Sd ≤1.5 x Q₀ x Kv The calibration is accepted if D < t0.95 (N-1) x Sd / SQRT (N) + Q₀
PLOT 2: X-Y Plot - REF CAL CEM vs REF SRM Values
Standard Deviation (Sd)
4.59
Section 4B - Data and Calculations - AST
TOTAL PARTICULATE MATTER: AST CALCULATIONS
Lafarge Ireland Ltd, Cookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
Existing Range Still Valid
1.321.5 x Q₀ x Kv 6.56
Kv for 8 Pairs of Data
t0.95 (N-1)
a) Calibrated Range (10% extension) (mg/m³)
1.52 Mean Difference (D)t0.95 (N-1) x Sd / SQRT (N) + Q₀
Outcome of Variability Test Pass
Q₀ = ELV x (MU / 100) / 1.96
(Page 3 of 3)
Outcome of Calibration Test
0 to 14.8b) Calibrated Range (50% of Daily ELV) (mg/m³) 0 to 15
New range up to a maximum of 50% of the Daily ELV 0 to 14.8
1.895
5.61Pass
0.9521
Parameter Value Parameter Value
New Calibration Range (REF)
25.0
30.0
35.0 DATE/S: 15/05/2018 to 16/05/2018
COPY APPROPRIATE PLOT 2: X-Y PLOT OF REF CAL CEM vs REF SRM VALUES (choose the graph with or without the AST extension)
-5.0
0.0
5.0
10.0
15.0
20.0
25.0
-5.0 0.0 5.0 10.0 15.0 20.0 25.0 30.0 35.0
SRM
mg/
m³ (
REF)
CAL CEM mg/m³ (REF)
TPMCalibration Range
CAT-14181 (Version X)13 of 37
Lafarge Ireland LtdCookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
Job Number: CEK-2909, Version 1Sample Date/s: 15th - 16th May 2018
PPC Permit: P0052/04A/V6
-
Calibration Data
15/05/2018 -1.66 -2.01
0.00
-0.83 0.43 0.27 7.8519 15/05/2018 -1.10 -1.38 1.52 1.22
(Page 1 of 3)
8.90
11.58 13.78 0.95 9.08
0.04
6 15/05/2018 05:32 - 06:02 11.85
8.26
7.81
4 15/05/2018 03:32 - 04:02 11.84 12.105
13.26 -0.11 0.22 -0.02 0.01 8.19
15/05/2018 08:32 - 09:02
0.00 0.00 0.00 0.00 0.00
15/05/2018
0.37
11.267.42
8.64
2 15/05/2018
9.24
Section 4B - Data and Calculations - AST
8.123 15/05/2018 02:32 - 03:02 10.60 10.95
6.37
9.90 11.86 -0.52
9.23
18:32 - 19:02
21:32 - 22:02
0.00 0.00
8.9615/05/2018 10:32 - 11:02 11.66
VOLATILE ORGANIC COMPOUNDS: AST CALCULATIONS
SRM (STP, DRY,
10% O₂) mg/m³
15 15/05/2018
CAL CEM (STP, WET)
mg/m³
915/05/2018 09:32 - 10:02 11.52 12.15 15.14
1.16 0.89 0.58 8.92
10.88 13.13
8.48
1.72 2.56 2.22
10.48 12.85
11.48 11.89 14.14 0.76
10.49 12.60
0.78 0.33 0.18
8.12
(A) x (B)
14
5.17
7.35
11.96 14.13
18 15/05/2018 17:32 - 18:02
9.548
0.36 0.08
-0.03 -0.25
1.45 1.29
0.00
A8 - Kiln Exhaust Main Stack (Standby Analyser)
16 15/05/2018 15:32 - 16:02 10.95 11.08
13:32 - 14:02
13.29
130.01 0.00
1.43 1.15
0 00/01/1900 00:00
-1.85 2.62 2.01
-0.19
0.00 0.00
17 15/05/2018
0.00 0.00
22:32 - 23:020.00
-1.4219:32 - 20:02 9.69 9.32
0.24
10.66 -0.23 0.01
14.83 1.12
12.92 -0.19 0.10 -0.02 0.04
10
10.94 10.70
-0.03
8.88 10.77
0.00
15/05/201815/05/2018 20:32 - 21:02 9.30
0.15
0.65
0.74
11.33 10.85 13.35 0.61 0.13 0.08
x - xav(A)
y - yav(B)
0 00/01/1900 00:00 0.00
11
Pair Date
0.00 0.000.00 0.00
0 00/01/1900 00:00 0.00
16:32 - 17:02
0.81
20 15/05/2018
23
9.61 9.35
10.53
15/05/2018 0.911.49
7.0922 8.44
0.5406:32 - 07:02 12.20
10.719.05
1
1.2711.14
21
8.33-0.05
7 15/05/2018
Time (30-minute Average)
01:32 - 02:02 10.52 10.83
0.00
1.54
12.00
Lafarge Ireland Ltd, Cookstown Works
0.43
x, CEM (STP, WET)
mg/m³
y, SRM (STP, WET)
mg/m³
14.27 1.13 1.28
11.23 -1.02
0.00 0.00 0.000.00 0.00
00:00 0.00
9.61 -2.27 -2.92 6.64
15/05/2018 04:32 - 05:02
-1.40 1.44 1.05
(x - xav)²
07:32 - 08:02 11.45
1.37
0.00 0.00
8.72
0 00/01/1900
12 15/05/2018 11:32 - 12:02
0.00 0.00
15/05/2018 12:32 - 13:02 10.77
15/05/2018 00:32 - 01:02
0.000.00
13.29 0.23 -0.03 -0.01 0.05
1.23
14:32 - 15:02
0.85
10.20
10.69
8.24
3.33 2.75 6.88
8.800.06
11.50 13.74
0.89
10.85 12.89 0.06 0.13 0.01
12.44 14.76
0.81
8.48
Outliers Data
Reason for Data Pair Removal
SELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE IN
CEK-2320 Exova Catalyst QAL2 Report (Standby Analyser)
0.00 0.00 0.00 0.00 0.00
Existing Calibration Range (@ REF Conditions)
0.00
8
Existing Calibration Functiony = 0.8427x -0.7458
Source of Existing Calibration Function
0.00 0.00
0 to 19.1 mg/m³
SELECT or TYPE IN
00/01/1900 00:00
0 00/01/1900 00:00
0.00 0.00 0.00
INPUT 0.00 0.00
0.00 0.003 INPUT INPUT
0.00 0.00
0
Time (30-minute Average)
x, CEM (WET) mg/m³
00:00 0.00
0.00
INPUT INPUT 0.00 0.009 INPUT INPUT 0.00
0.00
5 INPUT INPUT 0.00 0.006 INPUT INPUT 0.00 0.007 INPUT
3595% CI MU (%) 30
0.000 00/01/1900
y, SRM (WET) mg/m³
0.00 0.00
1 INPUT2 INPUT INPUT
0.00 0.00
Pair Date
4 INPUT INPUT 0.00 0.00
0 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00
0.0010 INPUT INPUT 0.00 0.00
0.00MAX SRM - MIN SRM 5.53 SUM 25.72 20.65(DAILY) DELV (mg/m³)
0.00
INPUT 0.00
0.00 0.00
CAT-14181 (Version X)14 of 37
Lafarge Ireland LtdCookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
Job Number: CEK-2909, Version 1Sample Date/s: 15th - 16th May 2018
PPC Permit: P0052/04A/V6
-
PLOT 1a: GRAPH FOR STP SRM vs STP CEM (NON-STANDARDISED) (1 minute readings)
PLOT 1: GRAPH FOR REFERENCE SRM vs REFERENCE CEM (STANDARDISED) (30 minute rolling averages)
(Page 2 of 3)
Lafarge Ireland Ltd, Cookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
COPY PLOT 1: 30/60-MINUTE ROLLING AVERAGE TREND GRAPH INTO HERE
COPY PLOT 1a: 1 MINUTE TREND GRAPH INTO HERE
Section 4B - Data and Calculations - AST
VOLATILE ORGANIC COMPOUNDS: AST CALCULATIONS
0.0
5.0
10.0
15.0
20.0
25.0
30.0
35.0
00:0
0
01:0
0
02:0
0
03:0
0
04:0
0
05:0
0
06:0
0
07:0
0
08:0
0
09:0
0
10:0
0
11:0
0
12:0
0
13:0
0
14:0
0
15:0
0
16:0
0
17:0
0
18:0
0
19:0
0
20:0
0
21:0
0
22:0
0
23:0
0
mg/
m³ (
STP)
Time
VOCs (CEM - 1 min)VOCs (SRM - 1 min)
0.0
5.0
10.0
15.0
20.0
25.0
30.0
35.0
00:0
0
01:0
0
02:0
0
03:0
0
04:0
0
05:0
0
06:0
0
07:0
0
08:0
0
09:0
0
10:0
0
11:0
0
12:0
0
13:0
0
14:0
0
15:0
0
16:0
0
17:0
0
18:0
0
19:0
0
20:0
0
21:0
0
22:0
0
23:0
0
mg/
m³
Time
VOCs (CEM - 30 min)VOCs (SRM - 30 min)
Variability Test Datawhere CAL = Calibrated using AST calibration functions
MAX0.00 0.00 0.000 00/01/1900
8.48
0.61
9.06 11.23 2.18
00:00 0.00 0.00 0.00 0.00
0 00/01/1900 00:00 0.00
00:00 0.00
14 13:32 - 14:02 8.26
10.74 15.14 4.41
15/05/2018 04:32 - 05:02
08:32 - 09:02 8.92
15/05/2018 9.54
02:32 - 03:02 8.19
1 15/05/2018 00:32 - 01:02 8.12
19 15/05/2018 18:32 - 19:02 7.35
1.9422 15/05/2018 21:32 - 22:02 6.37 8.00 9.61 1.61
9.86
SRM (STP, DRY,
10% O₂) mg/m³
ys, SRM - CAL CEM
14:32 - 15:02
13.78
15.86 15.30 15.54 9.78
19:32 - 20:02 7.42
16.09 15.53 15.77 9.76 10.27 10.1216.05 15.49 15.75
15/05/2018 01:32 - 02:02 8.12 9.90
11.52 14.76
10.29
Date Time (30-minute Average)
CAL CEM (STP, WET)
mg/m³
4 15/05/2018 03:32 - 04:02 9.235
15/05/2018
06:32 - 07:02
7.85
15/05/2018 8.48
2.8110.20 13.29 3.09
17:32 - 18:02
2
11:32 - 12:02 8.24
9.48
3.02
10.1616.25 15.68
16 15/05/2018
9.97
18 15/05/2018
13.26 3.15
Sd
CAL CALCEM
Water Vapour% v/v
CEMWater Vapour% v/v
10.11
10.84
Pair SRMWater Vapour% v/v
CEMOxygen (DRY)% v/v
CEMOxygen (DRY)% v/v
SRMOxygen (DRY)% v/v
16.21
11.52
17
21 15/05/2018 20:32 - 21:02 7.09 8.83 10.77
15:32 - 16:02
10.00 12.60
15/05/2018 16:32 - 17:02 13.35
15.64 15.93 10.37
8.646 15/05/2018 05:32 - 06:02 9.24
9.97 12.85 2.87
9 15/05/2018
0 00/01/1900
7
2.31
3.07
20 15/05/2018
13.74 3.25
12 15/05/201811 15/05/2018 10:32 - 11:02 9.08 10.89
8.80 10.54
12:32 - 13:02 8.33
15
2.6013 15/05/2018
3.258 15/05/2018 07:32 - 08:02 8.90 10.72 14.13 3.41
23 15/05/2018
10.27 13.29
10.45 10.2116.36 15.79 16.02 9.77
12.89
10.28 10.31
15.83 9.63 10.13 10.02
16.02 15.46 15.72 9.69 10.19 9.9516.06 15.50 15.75 9.77 10.28 10.0215.96 15.39 15.64
9.62 10.12
9.65
CAL CEM (STP, DRY,
10% O₂) mg/m³
11.25 14.83 3.58
15.98 15.42 15.67 9.72 10.23 10.00
9.96 13.13 3.1712.92 3.03
2.93
10.5011.20 14.27
15.91 9.78
2.89
15.93 15.36 15.63 9.64 10.15
10.0416.16 15.59 15.83 9.94
10.4016.01 15.44 15.61 9.73 10.23 10.13
22:32 - 23:02 6.88
14.14 3.3110 15/05/2018 09:32 - 10:02 8.96
15.90 15.34
00/01/1900 00:00 0.00 0.00 0.00 0.00
0 00/01/1900 00:00 0.00 0.00 0.00 0.0000/01/1900 00:00
3 15/05/2018
0.00 0.00 0.000 00/01/1900 00:00 0.00 0.00 0.00 0.00
15.60 9.82 10.32 8.95 11.26
10.0116.09 15.53 15.75 9.71 10.21 10.3416.06 15.50 15.74 9.75 10.25 10.49
10.18 10.70 10.46
0 0.00 0.00 0.00 0.000
8.63 10.7115.77 15.22 15.37 10.14 10.65 10.420.00 0.00 0.00
2.08
0.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00
15.93 15.37 15.65 9.79 10.30 10.0810.29 10.05
10.15 10.5416.17 15.60
15.88 15.32 15.62 9.69 10.19
0.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.00
11.8610.17
15.89 15.33 15.57 9.85 10.36 10.1915.84 15.28 15.53 10.06 10.57 10.2715.58 15.03 15.20
10.13
0.00 0.00 0.00
2.38
Time
CAT-14181 (Version X)15 of 37
Lafarge Ireland LtdCookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
Job Number: CEK-2909, Version 1Sample Date/s: 15th - 16th May 2018
PPC Permit: P0052/04A/V6
-
Test of Variability Test of Calibration (Acceptance of Calibration Function)
where N (number of samples) = 23
The variability is accepted if Sd ≤1.5 x Q₀ x Kv The calibration is accepted if D < t0.95 (N-1) x Sd / SQRT (N) + Q₀
PLOT 2: X-Y Plot - REF CAL CEM vs REF SRM Values
0.611.5 x Q₀ x Kv 7.89
1.711
Existing Range Still Valid
Outcome of Calibration Test
Standard Deviation (Sd)
PassOutcome of Variability Test
Mean Difference (D)t0.95 (N-1) x Sd / SQRT (N) + Q₀
Pass
2.885.57
0.9824
Parameter
Q₀ = ELV x (MU / 100) / 1.96 t0.95 (N-1)
Parameter ValueValue
5.36Kv for 23 Pairs of Data
Section 4B - Data and Calculations - AST
VOLATILE ORGANIC COMPOUNDS: AST CALCULATIONS(Page 3 of 3)
Lafarge Ireland Ltd, Cookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
a) Calibrated Range (10% extension) (mg/m³) 0 to 12.7b) Calibrated Range (50% of Daily ELV) (mg/m³) 0 to 17.5
New range up to a maximum of 50% of the Daily ELV 0 to 12.7
New Calibration Range (REF)
25.0
30.0
35.0
40.0 DATE/S: 15/05/2018 to 15/05/2018
COPY APPROPRIATE PLOT 2: X-Y PLOT OF REF CAL CEM vs REF SRM VALUES (choose the graph with or without the AST extension)
-10.0
-5.0
0.0
5.0
10.0
15.0
20.0
25.0
-5.0 0.0 5.0 10.0 15.0 20.0 25.0 30.0 35.0
SRM
mg/
m³ (
REF)
CAL CEM mg/m³ (REF)
VOCsCalibration Range
CAT-14181 (Version X)16 of 37
Lafarge Ireland LtdCookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
Job Number: CEK-2909, Version 1Sample Date/s: 15th - 16th May 2018
PPC Permit: P0052/04A/V6
-
Calibration Data
653.21 0.20 8.35 1.65 0.04 537.57
597.87 583.53100.25
685.46 37.39 32.10 573.3645.59
A8 - Kiln Exhaust Main Stack (Standby Analyser)
Pair (A) x (B) (x - xav)² CAL CEM (STP, WET)
mg/m³
00:32 - 01:02
6 15/05/2018 3621.36
10 15/05/2018
549.6754 15/05/2018
56.9515/05/2018 04:32 - 05:02 641.01 622.86 744.09 88.74 80.55 7147.68
3 15/05/2018 02:32 - 03:02
1 15/05/2018
706.9001:32 - 02:02
525.39 506.31
163.08
1091.18
622.76
632.69
511.51
7.85
SRM (STP, DRY,
10% O₂) mg/m³
723.08
-34.45 -31.6715/05/2018
2078.53 581.251879.34
701.17 608.74 513.64
7537.55
556.04
x - xav(A)
y - yav(B)
1200.48 1398.34
4042.94 598.567
550.16 674.04 12.77
2 15/05/2018
Date Time (30-minute Average)
15/05/2018 10:32 - 11:02 527.60
694.29 10.63 16.66
13 15/05/2018 12:32 - 13:0212
453.84
11:32 - 12:02 517.83 510.63 613.13
589.67 574.41
615.86 599.26 712.4605:32 - 06:02
09:32 - 10:02 472.88 473.56 590.06 -79.40 -68.75 5458.41 6303.709 15/05/2018 08:32 - 09:02 521.87 501.74 596.74 -30.40 -40.56
15 15/05/2018 14:32 - 15:02 562.91 558.96
567.33
628.01
634.55 -14.69 -8.15 119.73 215.78 523.25
15/05/2018 15:32 - 16:02 509.78 527.72 -42.49 -14.58
23
20:32 - 21:02 465.46 466.01
0.00
03:32 - 04:02 565.057874.01
0.00 0.00
63.58
177.09 113.04 547.6116
537.59 534.15
00/01/1900
611.17
17 15/05/2018 16:32 - 17:02 555.16 540.65 664.88 2.88 -1.65 -4.76 8.30 540.15
0.00 0.00
512.83 628.39 -26.44 -29.48 779.50 699.18 511.94
1233.24 924.38 508.13460.99
11
15/05/2018 07:32 - 08:02 571.67 550.73 650.53
-86.82 -76.30 6624.17
0.000
540.68 -105.68 -102.04 10783.54 11167.79 435.700 00/01/1900 00:00 0.00 0.00
0.00 0.000
912.36 968.96
22:32 - 23:02 446.60 440.26
00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000.00
22 15/05/2018 21:32 - 22:02 646.46
18 15/05/2018 17:32 - 18:02 668.27 654.46 784.56 116.00 112.15 13009.66 13455.66 648.9919 15/05/2018 18:32 - 19:02 583.40 571.61 687.98 31.13 29.31
0.00 0.0000:00 0.00 0.00 0.00
15/05/20188426.69 8871.60
20 15/05/2018 19:32 - 20:02 501.71 496.87 598.71 -50.56 -45.44 2297.41 2556.79 488.7321 15/05/2018
0.00 0.00 0.000.00
-35.99
631.77 777.88 94.19 89.47
513.89 611.40 -24.67 -28.42
Section 4B - Data and Calculations - AST
OXIDES OF NITROGEN (as NO₂): AST CALCULATIONS(Page 1 of 3)
Lafarge Ireland Ltd, Cookstown Works
8
x, CEM (STP, WET)
mg/m³
y, SRM (STP, WET)
mg/m³
19.39 8.42 163.35 376.15
0 00/01/1900 00:00 0.00 0.00 0.00 0.00
565.67
-26.89 967.88
41.22
619.67 1805.52 496.49
15/05/2018 06:32 - 07:02 552.47 550.66
1186.79 504.23
14 15/05/2018 13:32 - 14:02 525.83
Outliers Data
SELECT or TYPE IN
Existing Calibration Function
0.006
0.00 0.00
INPUT 0.00
Existing Calibration Range (@ REF Conditions)0 to 976.8 mg/m³
Reason for Data Pair Removal
SELECT or TYPE INSELECT or TYPE IN
INPUT
00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00
00/01/1900
0
0.004 INPUT INPUT
20
0.00 0.00 0.00 0.00 0.00 0.00
5 INPUT INPUT 0.00
x, CEM (WET) mg/m³
SELECT or TYPE IN
0 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
0
Source of Existing Calibration Function
INPUT 0.00 0.008 INPUT
0.00 0.0000:00 0.00 0.00 0.00
0.00 0.00 0.00MAX SRM - MIN SRM(DAILY) DELV (mg/m³) 80095% CI MU (%)
0.00
INPUT INPUT 0.00 0.00INPUT INPUT 0.00 0.00
2 INPUT INPUT 0.00 0.003 INPUT INPUT 0.00
243.88 SUM 67311.05 73079.91
0.00 0.00 0.000 00/01/1900 00:00 0.00 0.00
0.007 INPUT
9
Pair Date Time (30-minute Average)
0.00
y, SRM (WET) mg/m³
1 INPUT INPUT
SELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE IN10
INPUT 0.00
CEK-2320 Exova Catalyst QAL2 Report (Standby Analyser)y = 0.9622x + 5.9809
0.00
CAT-14181 (Version X)17 of 37
Lafarge Ireland LtdCookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
Job Number: CEK-2909, Version 1Sample Date/s: 15th - 16th May 2018
PPC Permit: P0052/04A/V6
-
PLOT 1: GRAPH FOR REFERENCE SRM vs REFERENCE CEM (STANDARDISED) (30 minute rolling averages)
Variability Test Datawhere CAL = Calibrated using AST calibration functions
Section 4B - Data and Calculations - AST
OXIDES OF NITROGEN (as NO₂): AST CALCULATIONS(Page 2 of 3)
Lafarge Ireland Ltd, Cookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
ys, SRM -
COPY PLOT 1: 30/60-MINUTE ROLLING AVERAGE TREND GRAPH INTO HERE
CAL CEM SRM CAL CAL
CEM CEM SRM CEM CEM SRMPair Date Time CAL CEM
0
100
200
300
400
500
600
700
800
900
00:0
0
01:0
0
02:0
0
03:0
0
04:0
0
05:0
0
06:0
0
07:0
0
08:0
0
09:0
0
10:0
0
11:0
0
12:0
0
13:0
0
14:0
0
15:0
0
16:0
0
17:0
0
18:0
0
19:0
0
20:0
0
21:0
0
22:0
0
23:0
0
mg/
m³
Time
NOx (CEM - 30 min)NOx (SRM - 30 min)
0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00
690.49
0.00 0.00 0.00
15.22 15.37 10.14 10.420.00 0.00 0.00 0.00 0.00 0.000.00 0.000.00
-2.51
023
0.00
10.28
549.67 669.82 674.04 4.22
617.08 596.74
15/05/2018 04:32 - 05:02 622.76
00/01/1900 00:00
725.98 712.46 -13.527 15/05/2018 06:32 - 07:02
0.00
0.00 0.00 0.00
14
03:32 - 04:02
15/05/2018
669.32 650.53
15.03 15.20 10.18 10.70 10.4615.84
698.45
05:32 - 06:02756.23 744.09 -12.13
2 15/05/2018 01:32 - 02:02 573.36
15.39 15.64 9.65 10.15 10.5416.17 15.60 15.83
15.59 15.83
10.0215.96
717.87 706.90
8 15/05/2018 07:32 - 08:02
ys, SRM - CAL CEM
-20.34
0 00/01/1900 00:00 0.00 0.00 0.00 0.000
20
16
0.000
10.65
15.53 10.06
9.78 10.29 10.0515.98
9
5
35.85
1 15/05/2018 00:32 - 01:02 511.51 627.28 611.17
15/05/2018
19 15/05/2018 18:32 - 19:02 567.33
15/05/2018 10:32 - 11:02 513.64 615.86 611.40 -4.46
6 15/05/2018
9.63 10.13 10.02
13 15/05/2018 12:32 - 13:02 523.25
-10.97
-18.79
15.86 15.30 15.54
685.46 -12.993 9.94 10.45 10.21
556.04
16.36 15.79 16.02 9.77 10.28 10.3115.93
10.12626.22 634.55
415.37 15.65 9.79 10.30 10.08
15.42
784.00 784.56 0.56
649.10 653.21 4.10
511.9415.49 15.75
00/01/1900 00:00
15/05/2018 13:32 - 14:02
9.95
16.09 15.53 15.77
15.46
546.40 540.68 -5.7222:32 - 23:02 435.700.00
0.00
0.00 0.00 0.000 00/01/1900 00:00
08:32 - 09:02 508.13552.47 590.06 37.60
11
15.67 9.72 10.23 10.0016.02
537.57
15/05/2018
12 15/05/2018 11:32 - 12:02 504.23
15/05/2018 02:32 - 03:02 581.25
10 15/05/2018
CAL CEM (STP, DRY,
10% O₂) mg/m³
SRM (STP, DRY,
10% O₂) mg/m³
612.03 613.13 1.10
16.21 15.64 15.93 9.86 10.37 10.1616.25 15.68 15.91 9.78 10.29 10.0416.16
15.72 9.69 10.1916.06 15.50 15.75 9.77
09:32 - 10:02 460.99
598.56
540.15 647.00 664.88 17.8818 15/05/2018 17:32 - 18:02 648.99
CEMWater Vapour% v/v
CEMWater Vapour% v/v
SRMWater Vapour% v/v
CEMOxygen (DRY)% v/v
CEMOxygen (DRY)% v/v
SRMOxygen (DRY)% v/v
10.15 10.4016.01 15.44 15.61 9.73 10.23 10.13
-16.11
Pair Date Time (30-minute Average)
CAL CEM (STP, WET)
mg/m³
16.05 9.62 10.12
15 15/05/2018 14:32 - 15:02 547.61 663.22 694.29 31.07
9.76 10.2710.01
16.098.32
16.52
15.90 15.34 15.60 9.82 10.32 10.17
15.28
617.91 628.39
15:32 - 16:02 496.49 596.84
19:32 - 20:02 488.73 596.55 598.71 2.1521 15/05/2018 20:32 - 21:02 453.84 565.17 565.67 0.5022 15/05/2018 21:32 - 22:02 628.01 789.14 777.88 -11.26
17 15/05/2018 16:32 - 17:02
15/05/2018
687.9815.89 15.33 15.57 9.85 10.36 10.19
0.00 0.00
10.57 10.2715.58
00/01/1900 00:00 0.00
0.00 0.00 0.00 0.00
0.0015.77
15.53 15.75 9.71 10.21 10.3416.06 15.50 15.74 9.75 10.25 10.4915.88 15.32 15.62 9.69 10.19 10.1315.93 15.36 15.63 9.64
15/05/2018
0.00
0 00/01/1900 00:00 0.00 0.00 0.00 0.000 00/01/1900 00:00
0.00 0.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00
0.00 0.000.00 0.00
0.00 0.00 0.00 0.00 0.00MAX 789.14 Sd
632.69
10.48
CAT-14181 (Version X)18 of 37
Lafarge Ireland LtdCookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
Job Number: CEK-2909, Version 1Sample Date/s: 15th - 16th May 2018
PPC Permit: P0052/04A/V6
-
Test of Variability Test of Calibration (Acceptance of Calibration Function)
where N (number of samples) = 23
The variability is accepted if Sd ≤1.5 x Q₀ x Kv The calibration is accepted if D < t0.95 (N-1) x Sd / SQRT (N) + Q₀
PLOT 2: X-Y Plot - REF CAL CEM vs REF SRM Values
Kv for 23 Pairs of Data1.711
0.9824
Parameter Value Parameter Value
Section 4B - Data and Calculations - AST
OXIDES OF NITROGEN (as NO₂): AST CALCULATIONS(Page 3 of 3)
Lafarge Ireland Ltd, Cookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
Standard Deviation (Sd) 16.52 Mean Difference (D) 1.091.5 x Q₀ x Kv 120.29 t0.95 (N-1) x Sd / SQRT (N) + Q₀ 87.53Outcome of Variability Test Pass Outcome of Calibration Test Pass
Existing Range Still Valid
Q₀ = ELV x (MU / 100) / 1.96 81.63
a) Calibrated Range (10% extension) (mg/m³) 0 to 868b) Calibrated Range (50% of Daily ELV) (mg/m³) 0 to 400
New range up to a maximum of 50% of the Daily ELV 0 to 400
New Calibration Range (REF)
t0.95 (N-1)
1000
1200 DATE/S: 15/05/2018 to 15/05/2018
COPY APPROPRIATE PLOT 2: X-Y PLOT OF REF CAL CEM vs REF SRM VALUES (choose the graph with or without the AST extension)
-200
0
200
400
600
800
0 200 400 600 800 1000 1200
SRM
mg/
m³ (
REF)
CAL CEM mg/m³ (REF)
NOxCalibration Range
CAT-14181 (Version X)19 of 37
Lafarge Ireland LtdCookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
Job Number: CEK-2909, Version 1Sample Date/s: 15th - 16th May 2018
PPC Permit: P0052/04A/V6
-
Calibration Data
0.00 0.000 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.000 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00
17 15/05/2018 16:32 - 17:02 350.70 354.13 435.50 58.42 62.06 3625.54 3413.40 366.8918 15/05/2018 17:32 - 18:02 290.07 289.06 346.53 -2.20 -3.01 6.62 4.84 307.0219 15/05/2018 18:32 - 19:02 229.08 220.91 265.88 -63.19 -71.16 4496.59 3992.76 246.79
189.71 181.96 220.88 -102.57 -110.11 11293.35 10519.84 207.90
23 15/05/2018 22:32 - 23:02 187.25 177.87 218.44 -105.02 -114.20 11993.55 11029.64 205.470 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00
14 15/05/2018 13:32 - 14:02 289.21 289.63 354.90 -3.07 -2.44 7.47 9.41 306.1615 15/05/2018 14:32 - 15:02 308.49 310.26 385.37 16.22 18.19 295.02 263.16 325.2116 15/05/2018 15:32 - 16:02 327.20 330.17 395.84 34.93 38.10 1330.72 1219.85 343.68
11 15/05/2018 10:32 - 11:02 326.37 324.61 386.20 34.10 32.54 1109.42 1162.66 342.8612 15/05/2018 11:32 - 12:02 300.91 303.51 364.44 8.64 11.44 98.84 74.66 317.7213 15/05/2018 12:32 - 13:02 305.43 308.42 366.39 13.16 16.35 215.14 173.11 322.18
8 15/05/2018 07:32 - 08:02 333.53 335.15 395.89 41.26 43.08 1777.75 1702.60 349.949 15/05/2018 08:32 - 09:02 328.72 329.83 392.28 36.45 37.76 1376.16 1328.43 345.19
10 15/05/2018 09:32 - 10:02 335.86 337.01 419.92 43.59 44.94 1958.77 1899.84 352.24
326.85 400.44 35.07 34.77 1219.46 1229.71 343.825 15/05/2018 04:32 - 05:02 323.81 331.49 396.01 31.53 39.42 1242.93 994.37 340.336 15/05/2018 05:32 - 06:02 311.17 317.29 377.23 18.89 25.22 476.57 356.96 327.857 15/05/2018 06:32 - 07:02 332.46 334.33 396.59 40.18 42.26 1698.04 1614.75 348.88
(A) x (B) (x - xav)² CAL CEM (STP, WET)
mg/m³
1 15/05/2018 00:32 - 01:02 307.81 306.99 370.57 15.54 14.92 231.91 241.55 324.54
y, SRM (STP, WET)
mg/m³
SRM (STP, DRY,
10% O₂) mg/m³
x - xav(A)
y - yav(B)
550.89 409.12 329.173 15/05/2018 02:32 - 03:02 323.97 325.47 394.29 31.70 33.40 1058.77 1004.61 340.494 15/05/2018 03:32 - 04:02 327.34
Section 4B - Data and Calculations - AST
SULPHUR DIOXIDE: AST CALCULATIONS(Page 1 of 3)
Lafarge Ireland Ltd, Cookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
Pair Date Time (30-minute Average)
x, CEM (STP, WET)
mg/m³
20 15/05/2018 19:32 - 20:02 205.71 197.46 237.93 -86.56 -94.61 8190.06 7493.36 223.7021 15/05/2018 20:32 - 21:0222 15/05/2018 21:32 - 22:02 174.97 165.91 204.29 -117.30 -126.16 14798.07 13759.25 193.34
2 15/05/2018 01:32 - 02:02 312.50 319.31 381.04 20.23 27.24
Outliers Data
SELECT or TYPE INSELECT or TYPE INSELECT or TYPE IN
Reason for Data Pair Removal
SELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE IN
0 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.003 INPUT
SUM 69051.65 63897.87(DAILY) DELV (mg/m³) 60095% CI MU (%) 20
2 INPUT INPUT
4 INPUT INPUT 0.00 0.00
0 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
Pair Date Time (30-minute Average)
x, CEM (WET) mg/m³
y, SRM (WET) mg/m³
1 INPUT INPUT 0.00
INPUT 0.00 0.00
INPUT INPUT 0.00 0.009
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
MAX SRM - MIN SRM 231.21
0.00
0 00/01/1900 00:00
Existing Calibration Range (@ REF Conditions)0 to 677.5 mg/m³
5 INPUT INPUT 0.00 0.006 INPUT INPUT 0.00 0.007 INPUT INPUT 0.00 0.008
INPUT INPUT 0.00 0.0010 INPUT INPUT 0.00 0.00
Existing Calibration Function Source of Existing Calibration Functiony = 0.9876x + 20.5419 CEK-2320 Exova Catalyst QAL2 Report (Standby Analyser)
SELECT or TYPE IN
CAT-14181 (Version X)20 of 37
Lafarge Ireland LtdCookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
Job Number: CEK-2909, Version 1Sample Date/s: 15th - 16th May 2018
PPC Permit: P0052/04A/V6
-
PLOT 1: GRAPH FOR REFERENCE SRM vs REFERENCE CEM (STANDARDISED) (30 minute rolling averages)
Variability Test Datawhere CAL = Calibrated using AST calibration functions
COPY PLOT 1: 30/60-MINUTE ROLLING AVERAGE TREND GRAPH INTO HERE
Pair Date Time CAL CEM CAL CEM SRM CAL
ys, SRM - CAL
CEM CEM SRM CEM CEM SRM
Section 4B - Data and Calculations - AST
SULPHUR DIOXIDE: AST CALCULATIONS(Page 2 of 3)
Lafarge Ireland Ltd, Cookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
0
50
100
150
200
250
300
350
400
450
500
00:0
0
01:0
0
02:0
0
03:0
0
04:0
0
05:0
0
06:0
0
07:0
0
08:0
0
09:0
0
10:0
0
11:0
0
12:0
0
13:0
0
14:0
0
15:0
0
16:0
0
17:0
0
18:0
0
19:0
0
20:0
0
21:0
0
22:0
0
23:0
0
mg/
m³
Time
SO₂ (CEM - 30 min)SO₂ (SRM - 30 min)
0.00 0.00
207.90 258.89 220.88 -38.0222 15/05/2018 21:32 - 22:02 193.34
257.67 218.44 -39.240 00/01/1900 00:00 0.00
20 15/05/2018 19:32 - 20:02 223.70 273.05 237.93 -35.1221 15/05/2018 20:32 - 21:02
00/01/1900 00:00 0.00
15.89 15.33
0 00/01/1900 00:00 0.00 0.00 0.00 0.00
10.70 10.4615.77 15.22 15.37 10.14 10.65 10.42
0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00
0 00/01/1900 00:00 0.00
17 15/05/2018 16:32 - 17:02 366.89 439.47 435.50 -3.9718 15/05/2018 17:32 - 18:02 307.02
15.58 15.03 15.20 10.18
00/01/1900 00:00 0.00 0.00 0.00 0.00
23 15/05/2018 22:32 - 23:02 205.47
0 00/01/1900
370.88 346.53 -24.3619 15/05/2018 18:32 - 19:02 246.79 300.36 265.88 -34.48
15.93 15.36 15.63 9.64 10.15 10.4016.01 15.44 15.61 9.73 10.23 10.1315.90 15.34 15.60 9.82 10.32 10.17
0 00/01/1900
12 15/05/2018 11:32 - 12:02 317.72 385.65 364.44 -21.2113 15/05/2018 12:32 - 13:02 322.18 385.59 366.39 -19.20
16.09 15.53 15.77 9.76 10.27 10.1216.05 15.49 15.75 9.62 10.12 10.01
-17.30
16.09 15.53 15.75 9.71 10.21 10.3416.06 15.50 15.74 9.75 10.25 10.4915.88 15.32 15.62 9.69 10.19 10.13
09:32 - 10:02 352.24 422.14 419.92 -2.2111 15/05/2018 10:32 - 11:02 342.86 411.10 386.20 -24.89
16.02 9.77 10.28 10.3115.93 15.37 15.65 9.79 10.30 10.0815.86 15.30 15.54 9.78 10.29 10.05
2 15/05/2018 01:32 - 02:02 329.17 400.98 381.04 -19.94
Pair Date Time (30-minute Average)
CAL CEM (STP, WET)
mg/m³
CAL CEM (STP, DRY,
10% O₂) mg/m³
SRM (STP, DRY,
10% O₂) mg/m³
ys, SRM - CAL CEM
398.00 370.57 -27.42
15.98 15.42 15.67 9.72 10.23 10.00
413.27 396.01 -17.266 15/05/2018 05:32 - 06:02 327.85 397.64 377.23 -20.41
CEMWater Vapour% v/v
CEMWater Vapour% v/v
SRMWater Vapour% v/v
CEMOxygen (DRY)% v/v
CEMOxygen (DRY)% v/v
SRMOxygen (DRY)% v/v
16.21 15.64 15.93 9.86 10.37 10.1616.25 15.68 15.91 9.78 10.29 10.0416.16 15.59 15.83 9.94 10.45 10.2116.36 15.79
1 15/05/2018 00:32 - 01:02 324.54
3 15/05/2018 02:32 - 03:02 340.49 420.53 394.29 -26.244 15/05/2018 03:32 - 04:02 343.82 418.98 400.44 -18.535 15/05/2018 04:32 - 05:02 340.33
242.95 204.29 -38.67
8 15/05/2018 07:32 - 08:02 349.94
15/05/2018
14 15/05/2018 13:32 - 14:02 306.16 369.54 354.90 -14.6315 15/05/2018 14:32 - 15:02 325.21 393.87 385.37 -8.5016 15/05/2018 15:32 - 16:02 343.68 413.14 395.84
421.23 395.89 -25.349 15/05/2018 08:32 - 09:02 345.19 419.20 392.28 -26.93
10
7 15/05/2018 06:32 - 07:02 348.88 421.26 396.59 -24.67
0.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00
0.00 0.000.00 0.00 0.00 0.00 0.00 0.00
00:00 0.00 0.00 0.00 0.000
0.000.00 0.00 0.00
000:00 0.00 0.00 0.00 0.00
0.00 0.00 0.00MAX 439.47 Sd 10.15
16.02 15.46 15.72 9.69 10.19 9.9516.06 15.50 15.75 9.77 10.28 10.0215.96 15.39 15.64 9.65 10.15 10.5416.17 15.60 15.83 9.63 10.13 10.02
15.57 9.85 10.36 10.1915.84 15.28 15.53 10.06 10.57 10.27
CAT-14181 (Version X)21 of 37
Lafarge Ireland LtdCookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
Job Number: CEK-2909, Version 1Sample Date/s: 15th - 16th May 2018
PPC Permit: P0052/04A/V6
-
Test of Variability Test of Calibration (Acceptance of Calibration Function)
where N (number of samples) = 23
The variability is accepted if Sd ≤1.5 x Q₀ x Kv The calibration is accepted if D < t0.95 (N-1) x Sd / SQRT (N) + Q₀
PLOT 2: X-Y Plot - REF CAL CEM vs REF SRM Values
Section 4B - Data and Calculations - AST
SULPHUR DIOXIDE: AST CALCULATIONS(Page 3 of 3)
Lafarge Ireland Ltd, Cookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
Outcome of Variability Test Pass Outcome of Calibration Test Pass
Existing Range Still Valid
Value Parameter ValueStandard Deviation (Sd) 10.15 Mean Difference (D) 22.981.5 x Q₀ x Kv 90.22 t0.95 (N-1) x Sd / SQRT (N) + Q₀ 64.85
Q₀ = ELV x (MU / 100) / 1.96 61.22 t0.95 (N-1) 1.711Kv for 23 Pairs of Data 0.9824
Parameter
a) Calibrated Range (10% extension) (mg/m³) 0 to 483.4b) Calibrated Range (50% of Daily ELV) (mg/m³) 0 to 300
New range up to a maximum of 50% of the Daily ELV 0 to 300
New Calibration Range (REF)
700
800 DATE/S: 15/05/2018 to 15/05/2018
COPY APPROPRIATE PLOT 2: X-Y PLOT OF REF CAL CEM vs REF SRM VALUES (choose the graph with or without the AST extension)
-100
0
100
200
300
400
500
600
0 100 200 300 400 500 600 700 800
SRM
mg/
m³ (
REF)
CAL CEM mg/m³ (REF)
SO₂Calibration Range
CAT-14181 (Version X)22 of 37
Lafarge Ireland LtdCookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
Job Number: CEK-2909, Version 1Sample Date/s: 15th - 16th May 2018
PPC Permit: P0052/04A/V6
-
Calibration Data
21 15/05/2018 20:32 - 21:02 284.76 280.59 340.60 -54.90 -46.25 2539.32 3014.43 299.4422 15/05/2018 21:32 - 22:02 280.92 274.96 338.55 -58.74 -51.88 3047.87
359.0215 15/05/2018 14:32 - 15:02 347.08 333.22 413.90 7.42 6.38 47.35 55.09
0.00 0.00 0.00
0 00/01/1900 00:00
305.4300:00 0.00
0.00 0.00 0.00 0.00 0.00 0.00
23 15/05/2018 22:32 - 23:02 2144.90 2428.273450.89 295.35
0.00 0.00
15/05/2018 13:32 - 14:02 340.76 328.32 402.31 1.10 1.47 1.61 1.20365.75
16 15/05/2018 15:32 - 16:02 354.32 339.65 407.21 14.66 12.81 187.75 214.94 373.46
286.04 344.67 -46.23 -40.80 1886.56 2137.67 308.66
18 15/05/2018 17:32 - 18:02 316.58 305.34 366.04 -23.08 -21.50 496.25 532.73 333.3019 15/05/2018 18:32 - 19:02 301.14 292.09 351.55 -38.52 -34.7520 15/05/2018 19:32 - 20:02 293.42
316.88
17 15/05/2018 16:32 - 17:02 353.77 372.88
0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.000
0.00 0.00
15/05/2018 10:32 - 11:02 352.98 338.40 402.61 13.32 11.55 153.85 177.33 372.0312 15/05/2018 11:32 - 12:02 339.61 326.19 391.67 -0.05 -0.65 0.03 0.00 357.8013 15/05/2018 12:32 - 13:02 346.01 331.98 394.38 6.35 5.14 32.64 40.33 364.61
0.00 0.000.00 0.00 0.00 0.00
0 00/01/1900
0 00/01/1900 00:00
14.71 18.44 362.4311
Pair Date Time (30-minute Average)
x, CEM (STP, WET)
mg/m³
y, SRM (STP, WET)
mg/m³
SRM (STP, DRY,
10% O₂) mg/m³
x - xav(A)
y - yav(B)
(A) x (B) (x - xav)² CAL CEM (STP, WET)
mg/m³
360.75 346.75 420.06 21.09 19.91 419.77 444.68 380.29
1 15/05/2018 00:32 - 01:02 366.94 348.94 421.21 27.28 22.10 602.96 744.41 386.892 15/05/2018 01:32 - 02:02 363.00 346.00 412.89 23.34 19.15 447.03 544.76 382.69
Section 4B - Data and Calculations - AST
CARBON MONOXIDE: AST CALCULATIONS
15/05/2018 06:32 - 07:02 355.50 339.76 403.03 15.84 12.91 204.50
367.64 349.81 417.90 27.98 22.97 642.59 782.86 387.63
250.80 374.718 15/05/2018 07:32 - 08:02 356.32 341.08 402.89 16.66 14.24 237.16 277.51 375.589 15/05/2018 08:32 - 09:02 351.75 338.15 402.18 12.09 11.31 136.70 146.11 370.72
10
14
15/05/2018 09:32 - 10:02 343.95 330.27 411.53 4.29 3.43
338.92 416.79 14.11 12.07 170.41 199.23
00/01/1900 0.00 0.00
1338.48 1483.56
4 15/05/2018 03:32 - 04:02 383.01 372.30 456.13 43.35 45.46 1970.67 1879.49 403.995 15/05/2018 04:32 - 05:026 15/05/2018 05:32 - 06:02 361.59 345.32 410.55 21.93 405.15 480.83 381.19
3 15/05/2018 02:32 - 03:02
(Page 1 of 3)
Lafarge Ireland Ltd, Cookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
718.48
00:00 0.00 0.00
290.38 283.32 347.94 -49.28 -43.53
Outliers Data
0.00 0.00 0.00 0.00
Pair Date Time (30-minute Average)
x, CEM (WET) mg/m³
y, SRM (WET) mg/m³
1 INPUT INPUT 0.00 0.00
0.00 0.00
INPUT INPUT 0.00 0.00
19305.57
Reason for Data Pair Removal
SELECT or TYPE INSELECT or TYPE IN
(DAILY) DELV (mg/m³)
0.00 0.000.00 0.00
10 INPUT INPUT 0.00 0.00
60095% CI MU (%) 20
2 INPUT INPUT 0.00 0.00
Existing Calibration Function Source of Existing Calibration Functiony = 1.064x -3.5405 CEK-2320 Exova Catalyst QAL2 Report (Standby Analyser)
7 INPUT INPUT6 INPUT INPUT 0.00 0.00
0.00
0 00/01/1900 0.00 0.00 0.000 00/01/1900 00:000 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.008 INPUT INPUT 0.00 0.00
SELECT or TYPE ININPUT INPUT 0.00 0.009
SELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE IN
3
00:00
MAX SRM - MIN SRM 117.59 SUM 17128.26
0.00 0.00 0.00 0.00 0.00 0.000.00 0.000 00/01/1900 00:00
Existing Calibration Range (@ REF Conditions)
0.00 0.00 0.00
0 to 544.5 mg/m³
4 INPUT INPUT 0.00 0.005 INPUT INPUT 0.00
CAT-14181 (Version X)23 of 37
Lafarge Ireland LtdCookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
Job Number: CEK-2909, Version 1Sample Date/s: 15th - 16th May 2018
PPC Permit: P0052/04A/V6
-
PLOT 1a: GRAPH FOR STP SRM vs STP CEM (NON-STANDARDISED) (1 minute readings)
PLOT 1: GRAPH FOR REFERENCE SRM vs REFERENCE CEM (STANDARDISED) (30 minute rolling averages)
COPY PLOT 1a: 1 MINUTE TREND GRAPH INTO HERE
COPY PLOT 1: 30/60-MINUTE ROLLING AVERAGE TREND GRAPH INTO HERE
Section 4B - Data and Calculations - AST
CARBON MONOXIDE: AST CALCULATIONS(Page 2 of 3)
Lafarge Ireland Ltd, Cookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
0
100
200
300
400
500
600
00:0
0
01:0
0
02:0
0
03:0
0
04:0
0
05:0
0
06:0
0
07:0
0
08:0
0
09:0
0
10:0
0
11:0
0
12:0
0
13:0
0
14:0
0
15:0
0
16:0
0
17:0
0
18:0
0
19:0
0
20:0
0
21:0
0
22:0
0
23:0
0
mg/
m³ (
STP)
Time
CO (CEM - 30 min)CO (SRM - 30 min)
0
100
200
300
400
500
00:0
0
01:0
0
02:0
0
03:0
0
04:0
0
05:0
0
06:0
0
07:0
0
08:0
0
09:0
0
10:0
0
11:0
0
12:0
0
13:0
0
14:0
0
15:0
0
16:0
0
17:0
0
18:0
0
19:0
0
20:0
0
21:0
0
22:0
0
23:0
0
mg/
m³
Time
CO (CEM - 30 min)CO (SRM - 30 min)
Variability Test Datawhere CAL = Calibrated using AST calibration functions
0.00 0.00 0.00
15.44 15.61 9.73 10.23 10.1315.90 15.34 15.60 9.82 10.32 10.1715.89 15.33 15.57 9.85 10.36 10.19 -32.10
00:00
Sd 9.210 00/01/1900 00:00 0.00 0.00 0.00 0.00
20 15/05/2018 19:32 - 20:02 308.66 376.76
-32.5823 15/05/2018 22:32 - 23:02 305.43 383.03
17 15/05/2018 16:32 - 17:02
21 15/05/2018 20:32 - 21:02 299.44 372.89 340.60 -32.29
0 00/01/1900 00:00 0.000
00:00
16.06 15.50 15.74 9.75 10.25 10.4915.88 15.32 15.62 9.69 10.19 10.1315.93 15.36 15.63 9.64 10.15 10.4016.01 402.63 366.04 -36.59
19 15/05/2018
0.00 0.00
0.000 00/01/1900 00:00 0.00 0.00 0.00
15.77
0.000 00/01/1900 00:00 0.00 0.00 0.00 0.00
22 15/05/2018 21:32 - 22:02 295.35 371.13 338.55
15/05/2018 05:32 - 06:02
18:32 - 19:02 316.88 385.66 351.55 -34.11
362.43 434.35 411.53 -22.8211 15/05/2018 10:32 - 11:02 372.03 446.06 402.61 -43.4512 15/05/2018 11:32 - 12:02 357.80 434.30 391.67 -42.6313 15/05/2018 12:32 - 13:02 364.61
-36.16
15.91 9.78 10.29 10.04
15/05/2018 15:32 - 16:02 373.46 448.93 407.21 -41.72
436.37 394.38 -41.99
10 15/05/2018 09:32 - 10:02
9.77 10.28 10.3115.93 15.37
-29.8518 15/05/2018 17:32 - 18:02 333.30
14
9.69
-29.0716
374.71 452.45 403.03 -49.42
16.16 15.5915.79 16.02
15.83 9.94 10.45 10.2116.36
SRMWater Vapour% v/v
CEMOxygen (DRY)% v/v
CEMOxygen (DRY)% v/v
SRMOxygen (DRY)% v/v
2 15/05/2018380.29 469.68 420.06 -49.62
4 15/05/2018 03:32 - 04:02
01:32 - 02:02 382.69 466.18 412.89 -53.2910.16
16.25 15.68
Pair Date Time (30-minute Average)
CAL CEM (STP, WET)
mg/m³
CAL CEM (STP, DRY,
10% O₂) mg/m³
SRM (STP, DRY,
10% O₂) mg/m³
ys, SRM - CAL CEM
CAL CALCEM
Water Vapour% v/v
CEMWater Vapour% v/v
15.65 9.79 10.30 10.08
8
15/05/2018
15/05/2018 07:32 - 08:02 375.58 452.10 402.89 -49.209 15/05/2018 08:32 - 09:02 370.72 450.21 402.18 -48.03
1 15/05/2018 00:32 - 01:02 386.89 474.46 421.21 -53.24
13:32 - 14:02 359.02 433.34 402.31 -31.04
10.19 9.9516.06 15.50 15.75 9.77 10.28 10.0215.96 15.39 15.64 9.65 10.15 10.5416.17 15.60 15.83 9.63 10.13 10.0216.09 15.53 15.77 9.76 10.27 10.12
403.99 492.29 456.13470.70 417.90 -52.80
6
10.37
3 15/05/2018 02:32 - 03:02
347.94 -35.090 00/01/1900 00:00 0.00
0.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.00
0.00
00/01/1900
15.22 15.37 10.14 10.65 10.420.00
0.00
0 00/01/1900
381.19 462.33 410.55 -51.787 15/05/2018 06:32 - 07:02
0.00 0.00 0.00
344.67
442.97 413.90
15.86 15.30 15.54 9.78 10.29 10.0515.98 15.42 15.67 9.72 10.23 10.0016.02 15.46 15.72
5 15/05/2018 04:32 - 05:02 387.63
16.21 15.64 15.93 9.86
16.05 15.49 15.75 9.62 10.12 10.0116.09 15.53 15.75 9.71 10.21 10.34
15.84 15.28 15.53 10.06 10.57 10.2715.58 15.03 15.20 10.18 10.70 10.46
0.00 0.000.00 0.00 0.00 0.00 0.00 0.00
0.00 0.000.00 0.00
0.00 0.00 0.00
0.00 0.00
0.00
15 15/05/2018 14:32 - 15:02 365.75
372.88 446.64 416.79
0.000.000.00 0.00 0.00 0.00 0.00 0.00
MAX 492.29
Time
CAT-14181 (Version X)24 of 37
Lafarge Ireland LtdCookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
Job Number: CEK-2909, Version 1Sample Date/s: 15th - 16th May 2018
PPC Permit: P0052/04A/V6
-
Test of Variability Test of Calibration (Acceptance of Calibration Function)
where N (number of samples) = 23
The variability is accepted if Sd ≤1.5 x Q₀ x Kv The calibration is accepted if D < t0.95 (N-1) x Sd / SQRT (N) + Q₀
PLOT 2: X-Y Plot - REF CAL CEM vs REF SRM Values
0 to 300
New Calibration Range (REF)
Parameter Value Parameter Value
a) Calibrated Range (10% extension) (mg/m³)
Pass Outcome of Calibration Test
0 to 541.5b) Calibrated Range (50% of Daily ELV) (mg/m³) 0 to 300
New range up to a maximum of 50% of the Daily ELV
CARBON MONOXIDE: AST CALCULATIONS(Page 3 of 3)
Lafarge Ireland Ltd, Cookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
Q₀ = ELV x (MU / 100) / 1.96 61.22 1.711Kv for 23 Pairs of Data 0.9824
Standard Deviation (Sd) 9.21 Mean Difference (D) 40.391.5 x Q₀ x Kv 90.22 t0.95 (N-1) x Sd / SQRT (N) + Q₀ 64.51Outcome of Variability Test Pass
Existing Range Still Valid
t0.95 (N-1)
Section 4B - Data and Calculations - AST
600
700
800 DATE/S: 15/05/2018 to 15/05/2018
COPY APPROPRIATE PLOT 2: X-Y PLOT OF REF CAL CEM vs REF SRM VALUES (choose the graph with or without the AST extension)
-100
0
100
200
300
400
500
600
-100 0 100 200 300 400 500 600 700
SRM
mg/
m³ (
REF)
CAL CEM mg/m³ (REF)
COCalibration Range
CAT-14181 (Version X)25 of 37
Lafarge Ireland LtdCookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
Job Number: CEK-2909, Version 1Sample Date/s: 15th - 16th May 2018
PPC Permit: P0052/04A/V6
-
Calibration Data
0.00
(x - xav)² CAL CEM (STP, WET)
mg/m³
8.54
00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.000.00
0.00 0.00
0
00/01/1900 00:00 0.00 0.00
0.00 0.00
0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00
0.00
0 00/01/1900
0.00
00/01/1900 00:00 0.00 0.00 0.00
0 00/01/1900 00:00 0.00 0.00
00:00 0.00 0.00 0.00 0.00
0.000.00 0.00
0 00/01/1900 00:00 0.00 0.00
0.000.00
0.00 0.00 0.000.00
0 00/01/1900 00:00
0.00
0
5 15/05/2018 04:32 - 05:02
0.53 8.28
0.70 6.72
0.000 00/01/1900 00:00
1 15/05/2018 00:32 - 01:02 8.07 6.13 7.40 0.02 -0.70 -0.02
0.00 0.00 0.00
0.00
0.00
0.00 0.00 0.00 0.000 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00
0.000
0 00/01/1900
0.99
-0.29
0.98
0.00
00/01/1900 00:00 0.00
0 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.000.00
2 15/05/2018
0.00
0 00/01/1900 00:00 0.00 0.00 0.00
0.34 6.9802:32 - 03:02 8.77 7.37 8.93 0.73 0.54 0.39
0.00 0.00 0.00
0.00
0 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00
03:32 - 04:02 7.46 7.33
8.19 -0.84 0.06 -0.05
0.00 0.00 0.00 0.000 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000 00/01/1900 00:00 0.00
0 00/01/1900 00:00 0.00 0.00 0.00 0.00
0 00/01/1900 00:00 0.00 0.00 0.00 0.00
0.00 0.00 0.00
0.00
y - yav(B)
(A) x (B)
4 15/05/2018
0.00 0.00 0.000
15/05/2018 05:32 - 06:02 7.20 6.89
8.98
Section 4B - Data and Calculations - AST
HYDROGEN CHLORIDE: AST CALCULATIONS(Page 1 of 3)
Lafarge Ireland Ltd, Cookstown Works
3 15/05/2018
A8 - Kiln Exhaust Main Stack (Standby Analyser)
Pair Date Time (30-minute Average)
x, CEM (STP, WET)
mg/m³
y, SRM (STP, WET)
mg/m³
SRM (STP, DRY,
10% O₂) mg/m³
x - xav(A)
-0.58 0.49
01:32 - 02:02 9.04 5.96 7.117.58
7.72 7.32 8.74 -0.32 0.48 -0.16 0.10 7.236
0.00
0.00 0.00 0.00 0.00 0.00 0.00 0.000 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
0.000 00/01/1900 00:00 0.00 0.00 0.00
0.00 0.00 0.000.00 0.00
0.00 0.00 0.00 0.00
-0.87 -0.87
0.00
0 00/01/1900 00:00
Outliers Data
0.0000:00 0.00 0.00 0.00
Existing Calibration Range (@ REF Conditions)0 to 12.1 mg/m³
0.00 0.00 0.00 0.00 0.00
40
Pair Date
2
0.00
INPUT
INPUT 0.00
INPUT
0.00 0.00 0.00 0.00
INPUT
0.00
INPUT
INPUT
SELECT or TYPE INSELECT or TYPE INSELECT or TYPE IN
Existing Calibration Function Source of Existing Calibration Functiony = 0.991x -0.4158 CEK-2320 Exova Catalyst QAL2 Report (Standby Analyser)
0.00 0.00
0.00 0.003 INPUT INPUT 0.00
8 INPUT INPUT 0.00 0.009 0.00 0.00
10 INPUT INPUT 0.00 0.00
0.00 0.00 0.00
7 INPUT INPUT 0.00 0.00
5
0.000 00/01/1900 00:00 0.00 0.00 0.00
SELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE IN
6 INPUT INPUT
INPUT INPUT 0.00 0.00
0.0000/01/1900
Reason for Data Pair Removal
SELECT or TYPE IN
MAX SRM - MIN SRM 1.86 SUM -0.98 2.67(DAILY) DELV (mg/m³) 1095% CI MU (%)
0 00/01/1900
SELECT or TYPE IN
00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.000.00
0 0.00 0.000
00/01/190000:00
0.004 INPUT INPUT 0.00 0.00
Time (30-minute Average)
x, CEM (WET) mg/m³
y, SRM (WET) mg/m³
1
CAT-14181 (Version X)26 of 37
Lafarge Ireland LtdCookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
Job Number: CEK-2909, Version 1Sample Date/s: 15th - 16th May 2018
PPC Permit: P0052/04A/V6
-
PLOT 1: GRAPH FOR REFERENCE SRM vs REFERENCE CEM (STANDARDISED) (30 minute rolling averages)
Variability Test Datawhere CAL = Calibrated using AST calibration functions
HYDROGEN CHLORIDE: AST CALCULATIONS(Page 2 of 3)
CAL CEM SRM ys, SRM - Pair Date Time
COPY PLOT 1: 30/60-MINUTE ROLLING AVERAGE TREND GRAPH INTO HERE
Lafarge Ireland Ltd, Cookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
CAL CALCAL CEM
Section 4B - Data and Calculations - AST
CEM CEM SRM CEM CEM SRM
0.0
2.0
4.0
6.0
8.0
10.0
12.0
14.0
16.0
18.0
20.0
00:0
0
00:3
0
01:0
0
01:3
0
02:0
0
02:3
0
03:0
0
03:3
0
04:0
0
04:3
0
05:0
0
05:3
0
mg/
m³
Time
HCl (CEM - 30 min)HCl (SRM - 30 min)
0.00 0.00 0.00
0.00
00:00 0.000.00 0.000.00 0.00
15/05/2018 00:32 - 01:02 7.58
16.36 15.7910.22 8.93
0.00
00:00
00:00 0.00
00/01/19000.00
0 00/01/1900
0.00
00/01/1900
00/01/1900 00:00 0.00
0.00 0.00 0.000 00/01/1900
00/01/1900 00:00 0.00 0.00 0.00
0.00
0.000.00
0.00 0.000 00/01/1900 00:00 0.00
0
00:00 0.00
0.00 0.0000/01/1900 00:00 0.00
0
0 00/01/1900
0.00
0.00
0.00 0.00
0.00
00.00
0.00
0.00 0.00 0.00 0.00
-1.294 15/05/2018 03:32 - 04:02 6.98 8.50 8.98
15.86
0.00
00:00
00:00
00/01/1900
CAL CEM (STP, DRY,
10% O₂) mg/m³
SRM (STP, DRY,
10% O₂) mg/m³
ys, SRM - CAL CEM
Pair Date Time (30-minute Average)
0.00
0.00 0.00 0.00 0.00 0.00 0.000.00
10.40 7.11 -3.293
00.00 0.00 0.00
0
15/05/2018 02:32 - 03:02 8.28
15.93 15.37 15.65 9.79 10.30 10.08
10.1615.64
0.00 0.00 0.00
1 15.93 9.86 10.37
0 00/01/1900 00:00 0.00 0.00 0.00 0.00
0.00 0.00
15.30 15.54 9.78
CAL CEM (STP, WET)
mg/m³
9.29
MAX 10.40 Sd 1.43
00:00 0.00
16.25 15.68 15.91 9.78
0.00 0.00 0.00 0.00 0.00 0.00
6 15/05/2018 05:32 - 06:02 6.72 8.15
7.40 -1.892 15/05/2018 01:32 - 02:02 8.54
0 00/01/1900 00:00 0.00
0.00 0.00 0.00 0.00 0.00 0.00
0.00
10.0416.16 15.59 15.83 9.94 10.45 10.21
16.02 9.77 10.28 10.31
0.00 0.00 0.00
8.19 0.04
0.47
0
00/01/1900 00:00 0.00
0.000 00/01/1900
0
5
00/01/1900 00:00 0.00 0.00 0.00 0.00
15/05/2018 04:32 - 05:02 7.23 8.78 8.74 -0.05
0 00/01/1900 0.0000:00 0.00 0.00 0.00
0
0 00/01/1900 0.00
00:00 0.00 0.00
0.000 00/01/1900 00:00 0.00 0.00 0.00
0.00 0.00
10.29
0.00 0.0000/01/1900 00:00
0 00/01/1900 00:00 0.00
0 00/01/1900 00:00 0.00 0.00 0.00 0.00
0 00/01/1900 00:00 0.00 0.00 0.00 0.000 00/01/1900 00:00 0.00 0.00 0.00 0.000 00:0000/01/1900 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00
0.00
10.29 10.05
0.00 0.000
0.00 0.00 0.00
0.00 0.00 0.00 0.00
0.00
0.00 0.00
CEMWater Vapour% v/v
CEMWater Vapour% v/v
SRMWater Vapour% v/v
CEMOxygen (DRY)% v/v
CEMOxygen (DRY)% v/v
SRMOxygen (DRY)% v/v
16.21
0.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00 0.00 0.00
0.00
0.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00
CAT-14181 (Version X)27 of 37
Lafarge Ireland LtdCookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
Job Number: CEK-2909, Version 1Sample Date/s: 15th - 16th May 2018
PPC Permit: P0052/04A/V6
-
Test of Variability Test of Calibration (Acceptance of Calibration Function)
where N (number of samples) = 6
The variability is accepted if Sd ≤1.5 x Q₀ x Kv The calibration is accepted if D < t0.95 (N-1) x Sd / SQRT (N) + Q₀
PLOT 2: X-Y Plot - REF CAL CEM vs REF SRM Values
Value Parameter ValueStandard Deviation (Sd) 1.43 Mean Difference (D)
t0.95 (N-1) x Sd / SQRT (N) + Q₀2.86
2.015Kv for 6 Pairs of Data 0.9329
Parameter
Q₀ = ELV x (MU / 100) / 1.96 2.04 t0.95 (N-1)
Outcome of Calibration Test Pass
Existing Range Still Valid
1.001.5 x Q₀ x Kv 3.22Outcome of Variability Test Pass
Section 4B - Data and Calculations - AST
HYDROGEN CHLORIDE: AST CALCULATIONS(Page 3 of 3)
Lafarge Ireland Ltd, Cookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
a) Calibrated Range (10% extension) (mg/m³) 0 to 11.4b) Calibrated Range (50% of Daily ELV) (mg/m³) 0 to 5
New range up to a maximum of 50% of the Daily ELV 0 to 5
New Calibration Range (REF)
12.0
14.0
16.0 DATE/S: 15/05/2018 to 15/05/2018
COPY APPROPRIATE PLOT 2: X-Y PLOT OF REF CAL CEM vs REF SRM VALUES (choose the graph with or without the AST extension)
-4.0
-2.0
0.0
2.0
4.0
6.0
8.0
10.0
12.0
-2.0 0.0 2.0 4.0 6.0 8.0 10.0 12.0 14.0 16.0
SRM
mg/
m³ (
REF)
CAL CEM mg/m³ (REF)
HClCalibration Range
CAT-14181 (Version X)28 of 37
Lafarge Ireland LtdCookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
Job Number: CEK-2909, Version 1Sample Date/s: 15th - 16th May 2018
PPC Permit: P0052/04A/V6
-
Calibration Data
32.71
0.00
-3.17
15:32 - 16:02 29.03 28.11 33.70 -1.61 -1.98 3.19 2.59 30.99
0.08
15/05/2018 07:32 - 08:02 32.89
00/01/1900 00:00
34.14
0.00 0.00 0.00 0.00 0.00
29.50 30.31 36.04 -1.14 0.22 -0.25 1.30 31.52
00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000 00/01/1900
15/05/2018 03:32 - 04:02 30.55 31.16 38.18 -0.09 1.07 0.01
15/05/2018 05:32 - 06:02
33.1213 15/05/2018 12:32 - 13:02 31.82 30.72 36.50
69.06 8.72 36.15
09:32 - 10:02 32.2533.97 32.86 39.10 3.34 2.77 9.24 11.13 36.58
12 15/05/2018
31.90
0.00 0.00 0.00 0.00
0.00
-0.57 -1.05 0.32
36.47 -1.06 -0.40 0.4215/05/2018 22:32 - 23:02 29.57 29.69
0.0000/01/1900 00:00 0.00
00:00
1415
15/05/2018 18:32 - 19:02
1.13 31.610
15/05/2018
0.000.00 0.00
39.62 2.29
0 0.00
25.90
1.81 4.09 5.08
2.76 3.66
22 15/05/2018 21:32 - 22:02 25.47
1.80 4.13 5.23 35.40
01:32 - 02:02 25.84
(Page 1 of 3)
Lafarge Ireland Ltd, Cookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
Pair Date
15/05/2018 00:32 - 01:02 28.68 28.24 34.0916.24 14.58
y, SRM (STP, WET)
mg/m³
SRM (STP, DRY,
10% O₂) mg/m³
15/05/2018
30.07 29.05 34.96 0.60
-4.19 21.65 26.64 26.9823
17
7 15/05/2018 06:32 - 07:02 33.59
0
18 15/05/2018 17:32 - 18:02 30.19 29.37
31.89 -5.16
0.00 0.000.00
34.4221 15/05/2018 20:32 - 21:02 31.51 31.10 37.75 0.87 1.00 0.88 0.76 33.80
33.16
0.74
38.04 1.43 1.48 2.11 2.03
10 15/05/2018
15/05/2018 13:32 - 14:02 32.55
1.61 0.61 0.98 2.60
15/05/2018
2.25
5
11 15/05/2018 10:32 - 11:02
31.91
11:32 - 12:02 30.91
14:32 - 15:02 32.92
30.43 36.54 0.28
32.3119
31.53
8 37.69 35.369 15/05/2018 08:32 - 09:02 33.83
16
Section 4B - Data and Calculations - AST
AMMONIA: AST CALCULATIONS
29.23
6.62
26.823.81 30.61
4 -0.0933.70 -3.52 -1.88 12.39 28.8315/05/2018
3.61
3 15/05/2018 02:32 - 03:02 27.4728.50
x - xav(A)
y - yav(B)
(A) x (B) (x - xav)² CAL CEM (STP, WET)
mg/m³
130.83 -3.82 -4.252 15/05/2018
Time (30-minute Average)
x, CEM (STP, WET)
mg/m³
6.75 10.02
20 15/05/2018 19:32 - 20:02 32.06 31.57
16:32 - 17:02 31.86 30.92 38.02 1.22 0.82 1.00 1.49
34.97
34.19
39.34 2.95 3.07
0.00 0.00
36.42
27.96 33.87
28.21
-1.95 -1.85
0.00
0.34
0.32 0.20
4.46 10.2231.49 37.45 3.20 1.40
35.21 -0.45 -0.73
30.70 38.26
1.91 1.44
-2.13
1.18 0.63
34.63
1.3938.64
0.09
32.17
04:32 - 05:02 27.12
0.00
Daily
Outliers Data
INPUT INPUT 0.00
SELECT or TYPE INSELECT or TYPE IN
INPUT 0.00 0.00
00:00 0.00
98.60
00/01/1900 00:00
0.003 INPUT
0.00 0.00
00/01/19000.00 0.00 0.00 0.00
INPUT
00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000 00/01/1900
0.00
8 INPUTINPUT
1
SELECT or TYPE INSELECT or TYPE IN
Reason for Data Pair Removal
SELECT or TYPE INSELECT or TYPE IN
0.00
9 INPUT 0.00 0.0010 INPUT INPUT 0.00 0.00
0.00INPUT 0.00
0
SELECT or TYPE IN
0
00/01/1900
0.00 0.000.00
0.00 0.00 0.00 0.00
0
00:00 0.00
7 INPUT6 INPUT INPUT 0.00 0.00
4 INPUT INPUT5 INPUT INPUT 0.00 0.00
INPUT 0.00 0.00
125.39ELV (mg/m³) 5095% CI MU (%) 40
Existing Calibration Function Source of Existing Calibration Functiony = 1.1299x -1.804 CEK-2320 Exova Catalyst QAL2 Report (Standby Analyser)
Existing Calibration Range (@ REF Conditions)0 to 60.2 mg/m³
0.00 0.00 0.00 0.00 0.00
x, CEM (WET) mg/m³
y, SRM (WET) mg/m³
0.00 0.00
Pair Date Time (30-minute Average)
SELECT or TYPE IN
SELECT or TYPE INSELECT or TYPE IN
MAX SRM - MIN SRM 8.78 SUM
0.00 0.000.00 0.00
2INPUT
CAT-14181 (Version X)29 of 37
Lafarge Ireland LtdCookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)
Job Number: CEK-2909, Version 1Sample Date/s: 15th - 16th May 2018
PPC Permit: P0052/04A/V6
-
PLOT 1: GRAPH FOR REFERENCE SRM vs REFERENCE CEM (STANDARDISED) (30 minute rolling averages)
Variability Test Datawhere CAL = Calibrated using AST calibration functionsCAL
COPY PLOT 1: 30/60-MINUTE ROLLING AVERAGE TREND GRAPH INTO HERE
(Page 2 of 3)
Time CAL CEM CAL
CEM CEM
AMMONIA: AST CALCULATIONS
Pair Date
Section 4B - Data and Calculat