creation of nanowires for energy saving applications university of wisconsin-eau claire caramon...

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Creation of Nanowires for Energy Saving Applications University of Wisconsin-Eau Claire Caramon Ives, Jason Leicht, Bret Meier Dr. Doug Dunham and Dr. Marc McEllistrem The Issue With nearly everything we use in modern society being electronic, energy consumption is a high cost factor. Most electronics draw small amounts of power when plugged in. This is because transistors have on and off states corresponding to smaller electric currents. This smaller current still exists when the device is “off”. Finding some way to reduce this drain would save money and reduce wasted energy. Possible Solution Mechanical (light) switches completely sever the flow of charge to the object. Nanoswitches work in the same manner on a smaller scale. SiC (silicon carbide) is a semiconductor that has been proven to be a viable option for the construction of nanoswitches because of its unique electrical properties. Challenges The formation of SiC nanowires is particularly difficult because of the unique environment needed to stimulate their growth. High temperatures and an oxygen depleted environment are crucial for their synthesis. Due to the scale of these objects, the characterization process presents many challenges. Samples were prepared from a FeSi mixture on a graphite planchet. A wide range of weight ratios were used. The planchet rested in an alumina crucible that was able to reach temperatures of over 1600ºC. The crucible was placed into a furnace that was able to reach 1600ºC. Normally the temperature was held constant at 1600ºC for 6-12 hrs. During the heating process a steady flow of argon through the furnace ensured an oxygen depleted environment needed for our synthesis. There were two primary methods of analysis: the SEM (Scanning Electron Microscope) and the Auger electron microscope. The SEM was used for quick analysis of the samples to get an overview of the composition and topography; whereas the Auger was used to obtain a higher resolution analysis of areas of interest identified by the SEM. Elemental categorization on right. The image to the left is an illustration of a series of scans on one of the samples of nanowires. The right image is the elemental analysis of the corresponding points on the graph at left. There are identifiable Carbon and Silicon peaks in the sample. Oxygen is known to 200 400 600 800 1000 1200 1400 1600 1800 2000 2200 -2 0 2 4 6 8 10 12 14 x 10 4 636.spe Kinetic Energy (eV) c/s O2 O1 Si4 Si2 C1 Si3 Si1 Al3 Al1 1000 X 10.0 keV F 344 7/1/2011 1 2 3 20.0 µm Today’s switches are manufactured primarily of Silicon. The above images are scans done of wires we have created in lab. Fabricated Silicon Carbide wires would drastically lengthen longevity as well as remain efficient at high temperatures. The images to the left are an example of Silicon Carbide nanowires which we have already grown. For further application we would need only to control the growth Analysis Furnace Process Conclusion The above picture was taken on an SEM at 20,000x magnification Further Examination Acknowledgments: Dr. Wagner, Dr. Ferguson , and Differential Tuition

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Page 1: Creation of Nanowires for Energy Saving Applications University of Wisconsin-Eau Claire Caramon Ives, Jason Leicht, Bret Meier Dr. Doug Dunham and Dr

Creation of Nanowires for Energy Saving Applications University of Wisconsin-Eau Claire

Caramon Ives, Jason Leicht, Bret MeierDr. Doug Dunham and Dr. Marc McEllistrem

The Issue With nearly everything we use in modern society being electronic, energy consumption is a high cost factor. Most electronics draw small amounts of power when plugged in. This is because transistors have on and off states corresponding to smaller electric currents. This smaller current still exists when the device is “off”. Finding some way to reduce this drain would save money and reduce wasted energy.

Possible Solution Mechanical (light) switches completely sever the flow of charge to the object. Nanoswitches work in the same manner on a smaller scale. SiC (silicon carbide) is a semiconductor that has been proven to be a viable option for the construction of nanoswitches because of its unique electrical properties.

ChallengesThe formation of SiC nanowires is particularly difficult because of the unique environment needed to stimulate their growth. High temperatures and an oxygen depleted environment are crucial for their synthesis. Due to the scale of these objects, the characterization process presents many challenges.

Samples were prepared from a FeSi mixture on a graphite planchet. A wide range of weight ratios were used. The planchet rested in an alumina crucible that was able to reach temperatures of over 1600ºC.

The crucible was placed into a furnace that was able to reach 1600ºC. Normally the temperature was held constant at 1600ºC for 6-12 hrs. During the heating process a steady flow of argon through the furnace ensured an oxygen depleted environment needed for our synthesis.

There were two primary methods of analysis: the SEM (Scanning Electron Microscope) and the Auger electron microscope. The SEM was used for quick analysis of the samples to get an overview of the composition and topography; whereas the Auger was used to obtain a higher resolution analysis of areas of interest identified by the SEM. Elemental categorization on right.

The image to the left is an illustration of a series of scans on one of the samples of nanowires.

The right image is the elemental analysis of the corresponding points on the graph at left. There are identifiable Carbon and Silicon peaks in the sample. Oxygen is known to be measured in all samples on Auger, hence the strong peak.

636.spe: F8 Company Name

2011 Jul 1 10.0 kV 0 nA FRR 1.5734e+005 max 18.42 min

Sur1/Area1/3 (S9d5)

200 400 600 800 1000 1200 1400 1600 1800 2000 2200

-2

0

2

4

6

8

10

12

14

x 104 636.spe

Kinetic Energy (eV)

c/s

O2

O1

Si4 Si2

C1

Si3 Si1

Al3 Al1

1000 X 10.0 keV

F 344 7/1/2011

1

2

3

20.0 µm

Today’s switches are manufactured primarily of Silicon. The above images are scans done of wires we have created in lab. Fabricated Silicon Carbide wires would drastically lengthen longevity as well as remain efficient at high temperatures.

The images to the left are an example of Silicon Carbide nanowires which we have already grown. For further application we would need only to control the growth location of the wires and continue to improve our consistency of synthesis.

AnalysisFurnace Process

Conclusion

The above picture was taken on an SEM at 20,000x magnification

Further Examination

Acknowledgments: Dr. Wagner, Dr. Ferguson , and Differential Tuition