crude assay report
TRANSCRIPT
With complimentsIntertek Caleb Brett, Fujairah
Crude Assay Report
on
Crude Oil sample marked
"AL SHAHEEN CRUDE OIL"
On Behalf Of
Maersk Oil Qatar AS
dated 10th April 2006
Caleb Brett Fujairah Fujairah Free Zone, Phase II , P.O. Box 1307, Fujairah, United Arab Emirates
Tel: (971)(9) 2228124, Fax: 2228125 Web: http://www.intertek.com
Sl.No. Page No.
1 Description of sample 1
2 Summary and comments 2
3 Detailed Assay Base Cuts Overview 3
4 Whole Crude Characteristics 4
5 True Boiling Point Distillation data 5
6 True Boiling Point Distillation data - Graph 6
7 Summary of Product / Residue cut points & Yield 7
8 Properties of Cuts- C5 - 65°C 8
9 65 - 150°C 9
10 150 - 200°C 10
11 200 - 250°C 11
12 250 - 300°C 12
13 300 - 350°C 13
14 350 - 420°C 14
15 420 - 560°C 15
16 560°C + 16
17 Distilation data per fractions 17
18 Fractions Mid B.P. Vs. Density - Chart 18
19 Fractions Mid B.P. Vs. Sulphur Content - Chart 19
20 Fractions Mid B.P. Vs. Nitrogen Content - Chart 20
21 Fractions Mid B.P. Vs. Aniline Point - Chart 21
"AL SHAHEEN CRUDE OIL" ASSAY
INDEX
Description
Date:
Maersk Oil Qatar AsP.O.Box 22050DohaQatar
For the Attention of : Mr. Michael D. Pedersen
Sample(s) received from : Maersk Oil Qatar As
Sample(s) submitted as : Crude Oil - 3 x 20 Ltrs IATA Cans - 2 x 10 Ltrs IATA Cans
Description(s) on Label(s) :
Work Order No. : CWO-14064
Seals on Sample(s) : 042351, 042666, 042100, 042548, 042052
Sample(s) received on :
Please refer attached sheet for analytical results.
LABORATORY REPORT NO. - FUJ/FCA1025/06
June 5, 2006
The above sample(s) was/were examined as detailed below and the following results obtained:
Al Shaheen Crude Oil Ex Qatar sampled on 10th April 2006.
May 2, 2006
Page 1
General:
Appearance & Initial Examination:
Distillation and Analysis:
LABORATORY REPORT NO. - FUJ/FCA1025/06
SUMMARY & COMMENTS
Please do not hesitate to contact us for any additional information or clarifications that you may require on this analysis.
The sample observed to be liquid at room temperature with good flow properties. After cooling (to Zero degree centigrade) and homogenization of the sample. H2S content on the vapour phase of the samples within the original containers were measured and noted to be in the range of 3000-1400 ppm within the containers. A representative portion of the sample was drawn and tested for API and Water contents. API observed to be 27.97°API and the Water content as 0.18% Vol. The Dry API of the sample was calculated and observed to be 28.03° API.
The Al Shaheen Crude Oil samples were received from Intertek Caleb Brett Qatar Branch on May 02, 2006. The samples were in 3 x 20 Ltrs & 2 x 10 Ltrs IATA Cans. The labels indicated that the samples were drawn on 10th April 2006.
The distillation of the sample was carried out in two major steps as per ASTM D 2892 (15 Theoretical plate column) & ASTM D 5236 (Vacuum potstill) methods. The yield pattern of each fraction collected are tabulated in percentage weight and percentage volume and in graphical form.
Results of the analysis carried on the various fractions are shown in pages 8-17. Some of the properties are also presented in chart form in pages 18-21.
Page 2
1 2 3 4 5 6 7 8 9 10
LIG
HT
END
S -
C4-
C5
- 65°
C
65 -
150°
C
150
- 200
°C
200
- 250
°C
250
- 300
°C
300
- 350
°C
350
- 420
°C
420
- 560
°C
560°
C +
Distillation of Crude Oil (15 plate)
Yield % Wt. 1.28 2.70 7.23 6.39 7.65 9.27 9.37 12.03 21.10 22.98
Yield % Vol. 2.00 3.70 8.77 7.19 8.23 9.59 9.44 11.77 19.81 19.50
Cum. Yield % Wt. 1.28 3.98 11.21 17.60 25.25 34.52 43.89 55.92 77.02 100.00
Cum. Yield % Vol. 2.00 5.70 14.47 21.66 29.89 39.48 48.92 60.69 80.50 100.00
Density @ 15°C kg/L ASTM D 5002 / IP 365 / IP 190 0.8868 0.6464 0.7316 0.7897 0.8250 0.8578 0.8803 0.9052 0.9449 1.0250
Specific Gravity @ 60/60° F Conversion 0.8873 0.6465 0.7318 0.7901 0.8254 0.8583 0.8808 0.9057 0.9455 1.0257
API Gravity @ 60° F Calculated 27.97 87.37 61.86 47.59 39.93 33.36 29.15 24.73 18.16 6.45
Density @ 15°C (dry) kg/L Calculated 0.8865
Specific Gravity @ 60/60° F (dry) Conversion 0.8870
API Gravity @ 60° F (dry) Calculated 28.03
Water Content % Vol. ASTM D 4298 0.18
Light Ends
methane 0.000
ethane 0.039
propane 0.309
i-butane 0.260
n-butane 0.811
Total C1-C4 1.419
i-pentane 0.950
n-pentane 0.633
Sulphur Content % mass ASTM D 4294 2.37 0.043 0.066 0.180 0.356 1.04 1.88 2.41 2.86 5.00
Mercaptan Sulphur mg/kg ASTM D 3227 235 314 225 103 54
Mercaptan Sulphur mg/kg UOP 163 339
Total Nitrogen % mass ASTM D 5291 (Mod) 0.15 < 0.05 < 0.05 0.08 0.15 0.37
Research Octane Number *** ASTM D 2699 74.2 57.0
Motor Octane Number *** ASTM D 2700 71.0 55.0
PIONA analysis
Total paraffins 95.32 61.63 33.72
Total olefins < 0.01 < 0.01 < 0.01
Total napthenes 4.65 36.24 23.61
Total aromatics 0.03 2.13 18.23
> 200° C & Unidentified < 0.01 < 0.01 24.44
Poly-N < 0.01 < 0.01 5.97
Aniline Point ° C ASTM D 611 55.2 58.4 60.4 68.6 73.0 84.6
Smoke Point mm IP 57 27.0 21.0
Naphthalene content %Vol. ASTM D 1840 0.17
Vanadium (V) 112
Nickel (Ni) 38
Iron (Fe) 15
Nickel / Vanadium Ratio 0.34
Freeze Point ° C ASTM D 2386 Below -70.0 - 52.5
Cloud Point ° C ASTM D 2500 Below -42 - 29 - 4 + 18 ##
Pour Point (upper) ° C ASTM D 5853 / D97 Below -45 - 30 - 6 + 15 + 42 + 51
Pour Point (lower) ° C ASTM D 5853 / D97 Below -45
Kinematic Viscosity @ 20° C 44.06
Kinematic Viscosity @ 40° C 13.32 1.670 3.069 6.438 16.23
Kinematic Viscosity @ 50° C 10.21 1.443 2.531 4.977 11.46 74.55
Kinematic Viscosity @ 80° C 1.629 2.640 5.068 21.06
Kinematic Viscosity @ 100° C 11.53 3013
Kinematic Viscosity @ 150° C 193.9
Distillation ° C ASTM D 86 See page 17 See page 17 See page 17 *
Cetane Index ASTM D 976 43.3 45.8 46.8 *
Refractive Index @ 20° C ASTM D 1218 1.4578 1.4771 1.4893
Refractive Index @ 70° C ASTM D 1218 1.5008
Micro Carbon Residue % mass ASTM D 4530 0.60 23.3
Asphaltene % mass IP 143 1.70 9.02
Total Acid Number mgKOH/g ASTM D 664 0.329
Benzene Content % mass GLC < 0.01
Salt Content PTB ASTM D 3230 46.3
Salt Content as NaCl mg/L IP 265 145.8
Salt Content mg/kg IP 265 149.0
Flash Point ° C ASTM D 93 (Mod.) Below -5
Sediment by Extraction % mass ASTM D 473 0.01
Reid Vapour Pressure @ 100° F psi ASTM D 323 6.4
Hydrogen Sulphide mg/kg UOP 163 < 1
Mercury mg/kg Cold Vapor < 1
Lead mg/kg ASTM D 5863 / AAS < 0.1
Wax Content prec. At -30° C % mass UOP 46 1.0
*** Samples were blended with ASTM grade Iso Octane, and results were caluclated from the blend's result. ## Unable to test due to the dark colour of the fraction.
Note: * Unable to perform test due to the heavy nature of the fraction.
mm2/S ASTM D 445
% Vol GC
mg/kg IP 470 ( AAS )
LABORATORY REPORT NO. - FUJ/FCA1025/06
CRUDE OIL - DETAILED ASSAY ALL CUTS OVERVIEW
TEST UNIT METHOD
Who
le C
rude
CUT RANGE
Al Shaheen Crude Oil Ex Qatar sampled on 10th April 2006.
ASTM D 2892 & ASTM D 5236
ASTM D 2892 & ASTM D 5236
% mass GC
Page 3
Sample Descriptions / Label : Al Shaheen Crude Oil Ex Qatar sampled on 10th April 2006.
Density @ 15°C kg/L ASTM D 5002 0.8868
Specific Gravity @ 60/60° F Calculated 0.8873
API Gravity @ 60° F Conversion 27.97
Density @ 15°C (dry) kg/L Calculated 0.8865
Specific Gravity @ 60/60° F (dry) Conversion 0.8870
API Gravity @ 60° F (dry) Calculated 28.03
Water Content % Vol. ASTM D 4298 0.18
Light Ends
methane 0.000
ethane 0.039
propane 0.309
i-butane 0.260
n-butane 0.811
Total C1-C4 1.419
i-pentane 0.950
n-pentane 0.633
Sulphur Content % mass ASTM D 4294 2.37
Mercaptan Sulphur mg/kg UOP 163 339
Total Nitrogen % mass ASTM D 5291 (Mod) 0.15
Pour Point (upper) ° C ASTM D 5853 Below -45
Pour Point (lower) ° C ASTM D 5853 Below -45
Kinematic Viscosity @ 20° C 44.06
Kinematic Viscosity @ 40° C 13.32
Kinematic Viscosity @ 50° C 10.21
Refractive Index @ 70° C ASTM D 1218 1.5008
Asphaltene % mass IP 143 1.70
Total Acid Number mgKOH/g ASTM D 664 0.329
Benzene Content % mass GLC < 0.01
Salt Content PTB ASTM D 3230 46.3
Salt Content as NaCl mg/L IP 265 145.8
Salt Content mg/kg ASTM D 3230 149.0
Flash Point ° C ASTM D 93( Mod) Below -5
Sediment by Extraction % mass ASTM D 473 0.01
Reid Vapour Pressure @ 100° F psi ASTM D 323 6.4
Hydrogen Sulphide mg/kg UOP 163 < 1
Mercury mg/kg Cold Vapor < 1
Lead mg/kg ASTM D 5863 / AAS < 0.1
Wax Content prec. at -30° C % mass UOP 46 1.0
mm2/S ASTM D 445
% mass GC
LABORATORY REPORT NO. - FUJ/FCA1025/06 SUMMARY OF WHOLE CRUDE CHARACTERISTICS
TEST UNIT METHOD Whole Crude
Page 4
Sample Descriptions / Label : Al Shaheen Crude Oil Ex Qatar sampled on 10th April 2006.
Sl. No. % Weight % Volume
1 1.28 2.00
2 15 - 40 1.35 1.90
3 40 - 65 1.35 1.80
4 65 - 100 2.57 3.22
5 100 - 125 2.19 2.64
6 125 - 150 2.47 2.91
7 150 - 175 3.16 3.61
8 175 - 200 3.23 3.58
9 200 - 225 3.64 3.95
10 225 - 250 4.01 4.28
11 250 - 275 4.49 4.69
12 275 - 300 4.78 4.90
13 300 - 325 4.63 4.73
14 325 - 350 4.74 4.71
15 350 - 375 4.74 4.65
16 375 - 400 4.56 4.47
17 400 - 420 2.73 2.65
18 420 - 450 3.65 3.50
19 450 - 475 5.37 5.11
20 475 - 500 4.15 3.91
21 500 - 520 2.71 2.52
22 520 - 540 2.53 2.33
23 540 - 560 2.69 2.44
24 560 + Residue 22.98 19.50
TRUE BOILING POINT DISTILLATION DATA (ASTM D 2892 & ASTM D 5236)
77.02 80.50
Cumulative % Weight
Cumulative % Volume
Gas 1.28 2.00
Vapour Temperature °C
2.63 3.90
3.98 5.70
6.55 8.92
8.74 11.56
11.21 14.47
14.37 18.08
17.60 21.66
21.24 25.61
25.25 29.89
29.74 34.58
34.52 39.48
39.15 44.21
43.89 48.92
48.63 53.57
53.19 58.04
55.92 60.69
75.73
59.57 64.19
64.94 69.30
LABORATORY REPORT NO. - FUJ/FCA1025/06
74.33 78.06
100.00 100.00
69.09 73.21
71.80
Page 5
LABORATORY REPORT NO. FUJ/FCA1025/06
Page 6
0
20
40
60
80
100
120
140
160
180
200
220
240
260
280
300
320
340
360
380
400
420
440
460
480
500
520
540
560
580
0.0 10.0 20.0 30.0 40.0 50.0 60.0 70.0 80.0 90.0Recovery %
Tem
pera
ture
°C
% Weight % Volume
TRUE BOILING POINT DISTILLATION CURVE(ASTM D 2892 & ASTM D 5236)
AL SHAHEEN CRUDE OIL Ex Qatar sampled on 10th April 2006
Sample Descriptions / Label :
Cut Points
(° C) Weight % Volume %
IBP - 65 2.70 3.70
65 - 150 7.23 8.77
150 - 200 6.39 7.19
200 - 250 7.65 8.23
250 - 300 9.27 9.59
300 - 350 9.37 9.44
350 - 420 12.03 11.77
420 - 560 21.10 19.81
560 + 22.98 19.50
Al Shaheen Crude Oil Ex Qatar sampled on 10th April 2006.
LABORATORY REPORT NO. - FUJ/FCA1025/06
SUMMARY OF PRODUCT / RESIDUE CUT POINTS AND YIELDS
Yield %
Al Shaheen Crude Oil Ex Qatar sampled on 10th April 2006.
Page 7
Sample Descriptions / Label :
CUT RANGE
2
C5 - 65°C
Distillation of Crude Oil
Yield % Wt. 2.70
Yield % Vol. 3.70
Cum. Yield % Wt. 3.98
Cum. Yield % Vol. 5.70
Density @ 15°C kg/L IP 365 0.6464
Specific Gravity @ 60/60° F Conversion 0.6465
API Gravity @ 60° F Calculated 87.37
Sulphur Content % mass ASTM D 4294 0.043
Mercaptan Sulphur mg/kg ASTM D 3227 235
Research Octane Number *** ASTM D 2699 74.2
Motor Octane Number *** ASTM D 2700 71.0
PIONA analysis
Total Paraffins 95.32
Olefins < 0.01
Napthenes 4.65
Aromatics 0.03
> 200° C & Unidentified < 0.01
Poly-Naphthenes < 0.01
Note: *** Samples were blended with ASTM grade Iso Octane, and results were caluclated from the blend's result.
% Vol GC
ASTM D 2892
ASTM D 2892
UNIT METHODTEST
LABORATORY REPORT NO. - FUJ/FCA1025/06
CUT RANGE - C5 - 65°C
Al Shaheen Crude Oil Ex Qatar sampled on 10th April 2006.
Page 8
Sample Descriptions / Label : Al Shaheen Crude Oil Ex Qatar sampled on 10th April 2006.
CUT RANGE
3
65 -150°C
Distillation of Crude Oil
Yield % Wt. 7.23
Yield % Vol. 8.77
Cum. Yield % Wt. 11.21
Cum. Yield % Vol. 14.47
Density @ 15°C kg/L IP 365 0.7316
Specific Gravity @ 60/60° F Conversion 0.7318
API Gravity @ 60° F Calculated 61.86
Sulphur Content % mass ASTM D 4294 0.066
Mercaptan Sulphur mg/kg ASTM D 3227 314
Research Octane Number *** ASTM D 2699 57
Motor Octane Number *** ASTM D 2700 55
PIONA analysis
Total Paraffins 61.63
Olefins < 0.01
Napthenes 36.24
Aromatics 2.13
> 200° C & Unidentified < 0.01
Poly-Naphthenes < 0.01
Note: *** Samples were blended with ASTM grade Iso Octane, and results were caluclated from the blend's result.
LABORATORY REPORT NO. - FUJ/FCA1025/06
CUT RANGE - 65 - 150°C
% Vol GC
ASTM D 2892
ASTM D 2892
TEST UNIT METHOD
Page 9
Sample Descriptions / Label : Al Shaheen Crude Oil Ex Qatar sampled on 10th April 2006.
CUT RANGE
4
150 - 200°C
Distillation of Crude Oil
Yield % Wt. 6.39
Yield % Vol. 7.19
Cum. Yield % Wt. 17.60
Cum. Yield % Vol. 21.66
Density @ 15°C kg/L IP 365 0.7897
Specific Gravity @ 60/60° F Conversion 0.7901
API Gravity @ 60° F Calculated 47.59
Sulphur Content % mass ASTM D 4294 0.180
Mercaptan Sulphur mg/kg ASTM D 3227 225
PIONA analysis
Total Paraffins 33.72
Olefins < 0.01
Napthenes 23.61
Aromatics 18.23
> 200° C & Unidentified 24.44
Poly-Naphthenes 5.97
Aniline Point ° C ASTM D 611 55.2
Smoke Point mm IP 57 27.0
Naphthalene content %Vol. ASTM D 1840 0.17
Freeze Point ° C ASTM D 2386 Below -70.0
% Vol GC
ASTM D 2892
ASTM D 2892
TEST UNIT METHOD
LABORATORY REPORT NO. - FUJ/FCA1025/06
CUT RANGE - 150 - 200°C
Page 10
Sample Descriptions / Label : Al Shaheen Crude Oil Ex Qatar sampled on 10th April 2006.
CUT RANGE
5
200 - 250°C
Distillation of Crude Oil
Yield % Wt. 7.65
Yield % Vol. 8.23
Cum. Yield % Wt. 25.25
Cum. Yield % Vol. 29.89
Density @ 15°C kg/L IP 365 0.8250
Specific Gravity @ 60/60° F Conversion 0.8254
API Gravity @ 60° F Calculated 39.93
Sulphur Content % mass ASTM D 4294 0.356
Mercaptan Sulphur mg/kg ASTM D 3227 103
Aniline Point ° C ASTM D 611 58.4
Smoke Point mm IP 57 21.0
Freeze Point ° C ASTM D 2386 - 52.5
Cloud Point ° C ASTM D 2500 Below -42
Kinematic Viscosity @ 40° C 1.670
Kinematic Viscosity @ 50° C 1.443
Distillation ASTM D 86 See page 17
Cetane Index ASTM D 976 43.3
Refractive Index @ 20° C ASTM D 1218 1.4578
mm2/S ASTM D 445
ASTM D 2892
ASTM D 2892
LABORATORY REPORT NO. - FUJ/FCA1025/06
TEST UNIT METHOD
CUT RANGE - 200 - 250°C
Page 11
Sample Descriptions / Label : Al Shaheen Crude Oil Ex Qatar sampled on 10th April 2006.
CUT RANGE
6
250 - 300°C
Distillation of Crude Oil
Yield % Wt. 9.27
Yield % Vol. 9.59
Cum. Yield % Wt. 34.52
Cum. Yield % Vol. 39.48
Density @ 15°C kg/L IP 365 0.8578
Specific Gravity @ 60/60° F Conversion 0.8583
API Gravity @ 60° F Calculated 33.36
Sulphur Content % mass ASTM D 4294 1.04
Mercaptan Sulphur mg/kg ASTM D 3227 54
Total Nitrogen % mass ASTM D 5291 (Mod) < 0.05
Aniline Point ° C ASTM D 611 60.4
Cloud Point ° C ASTM D 2500 - 29
Pour Point (upper) ° C ASTM D 97 - 30
Kinematic Viscosity @ 40° C 3.069
Kinematic Viscosity @ 50° C 2.531
Kinematic Viscosity @ 80° C 1.629
Distillation ASTM D 86 See page 17
Cetane Index ASTM D 976 45.8
Refractive Index @ 20° C ASTM D 1218 1.4771
mm2/S ASTM D 445
ASTM D 2892
ASTM D 2892
LABORATORY REPORT NO. - FUJ/FCA1025/06
TEST UNIT METHOD
CUT RANGE - 250 - 300°C
Page 12
Sample Descriptions / Label : Al Shaheen Crude Oil Ex Qatar sampled on 10th April 2006.
CUT RANGE
7
300 - 350°C
Distillation of Crude Oil
Yield % Wt. 9.37
Yield % Vol. 9.44
Cum. Yield % Wt. 43.89
Cum. Yield % Vol. 48.92
Density @ 15°C kg/L IP 365 0.8803
Specific Gravity @ 60/60° F Conversion 0.8808
API Gravity @ 60° F Calculated 29.15
Sulphur Content % mass ASTM D 4294 1.88
Total Nitrogen % mass ASTM D 5291 (Mod) < 0.05
Aniline Point ° C ASTM D 611 68.6
Cloud Point ° C ASTM D 2500 - 4
Pour Point (upper) ° C ASTM D 97 - 6
Kinematic Viscosity @ 40° C 6.438
Kinematic Viscosity @ 50° C 4.977
Kinematic Viscosity @ 80° C 2.640
Distillation ASTM D 86 See page 17
Cetane Index ASTM D 976 46.8
Refractive Index @ 20° C ASTM D 1218 1.4893
mm2/S ASTM D 445
ASTM D 2892
ASTM D 2892
LABORATORY REPORT NO. - FUJ/FCA1025/06
CUT RANGE - 300 - 350°C
TEST UNIT METHOD
Page 13
Sample Descriptions / Label : Al Shaheen Crude Oil Ex Qatar sampled on 10th April 2006.
CUT RANGE
8
350 - 420°C
Distillation of Crude Oil
Yield % Wt. 12.03
Yield % Vol. 11.77
Cum. Yield % Wt. 55.92
Cum. Yield % Vol. 60.69
Density @ 15°C kg/L IP 365 0.9052
Specific Gravity @ 60/60° F Conversion 0.9057
API Gravity @ 60° F Calculated 24.73
Sulphur Content % mass ASTM D 4294 2.41
Total Nitrogen % mass ASTM D 5291 (Mod) 0.08
Aniline Point ° C ASTM D 611 73.0
Cloud Point ° C ASTM D 2500 + 18
Pour Point (upper) ° C ASTM D 97 + 15
Kinematic Viscosity @ 40° C 16.23
Kinematic Viscosity @ 50° C 11.46
Kinematic Viscosity @ 80° C 5.068
Distillation ASTM D 86 *
Cetane Index ASTM D 976 *
Note: * Unable to perform test due to the heavy nature of the fraction.
LABORATORY REPORT NO. - FUJ/FCA1025/06
TEST UNIT METHOD
CUT RANGE - 350 - 420°C
mm2/S ASTM D 445
ASTM D 5236
ASTM D 2892 / ASTM D 5236
Page 14
Sample Descriptions / Label : Al Shaheen Crude Oil Ex Qatar sampled on 10th April 2006.
CUT RANGE
9
420 - 560°C
Distillation of Crude Oil
Yield % Wt. 21.10
Yield % Vol. 19.81
Cum. Yield % Wt. 77.02
Cum. Yield % Vol. 80.50
Density @ 15°C kg/L IP 365 0.9449
Specific Gravity @ 60/60° F Conversion 0.9455
API Gravity @ 60° F Calculated 18.16
Sulphur Content % mass ASTM D 4294 2.86
Total Nitrogen % mass ASTM D 5291 (Mod) 0.15
Aniline Point ° C ASTM D 611 84.6
Cloud Point ° C ASTM D 2500 ##
Pour Point (upper) ° C ASTM D 97 + 42
Kinematic Viscosity @ 50° C 74.55
Kinematic Viscosity @ 80° C 21.06
Kinematic Viscosity @ 100° C 11.53
Micro Carbon Residue % mass ASTM D 4530 0.60
Note: ## Unable to test due to the dark colour of the fraction.
mm2/S ASTM D 445
ASTM D 5236
ASTM D 2892 / ASTM D 5236
TEST UNIT METHOD
LABORATORY REPORT NO. - FUJ/FCA1025/06
CUT RANGE - 420 - 560°C
Page 15
Sample Descriptions / Label : Al Shaheen Crude Oil Ex Qatar sampled on 10th April 2006.
CUT RANGE
10
560° C +
Distillation of Crude Oil
Yield % Wt. 22.98
Yield % Vol. 19.50
Cum. Yield % Wt. 100.00
Cum. Yield % Vol. 100.00
Density @ 15°C kg/L IP 190 1.0250
Specific Gravity @ 60/60° F Conversion 1.0257
API Gravity @ 60° F Calculated 6.45
Sulphur Content % mass ASTM D 4294 5.00
Total Nitrogen % mass ASTM D 5291 (Mod) 0.37
Vanadium (V) 112
Nickel (Ni) 38
Iron (Fe) 15
Nickel / Vanadium Ratio Calculated 0.34
Pour Point (upper) ° C ASTM D 97 + 51
Kinematic Viscosity @ 100° C 3013
Kinematic Viscosity @ 150° C 193.9
Micro Carbon Residue % mass ASTM D 4530 23.3
Asphaltene % mass IP 143 9.02
mm2/S ASTM D 445
ASTM D 5236
ASTM D 2892 / ASTM D 5236
METHOD
LABORATORY REPORT NO. - FUJ/FCA1025/06
mg/kg IP 470 ( AAS )
CUT RANGE - 560 + °C
TEST UNIT
Page 16
Sample Descriptions / Label : Al Shaheen Crude Oil Ex Qatar sampled on 10th April 2006.
° C 200 - 250 250 - 300 300 - 350 350 - 420
Wt. % 7.65 9.27 9.37 12.03
Vol.% 8.23 9.59 9.44 11.77
Initial boiling point ° C 213.0 264.0 310.0 **
10% recovered ° C 216.0 266.5 314.0 **
20% recovered ° C 217.5 267.5 315.5 **
30% recovered ° C 219.0 269.0 317.0 **
40% recovered ° C 220.0 270.0 319.0 **
50% recovered ° C 222.0 272.0 321.0 **
60% recovered ° C 224.0 274.0 324.0 **
70% recovered ° C 226.5 275.5 326.0 **
80% recovered ° C 230.0 278.5 329.5 **
90% recovered ° C 235.0 284.0 337.5 **
Final Boiling Point ° C 243.0 290.5 345.1 **
Volume recovered % Vol. 97.0 97.5 98.5 **
Residue % Vol. 1.3 1.3 1.0 **
Loss % Vol. 1.7 1.2 0.5 **
Note: ** Unable to perform ASTM Distillation due to the heavy nature of the fraction.
Boiling range
Yield on whole crude
LABORATORY REPORT NO. - FUJ/FCA1025/06
ASTM 86 - DISTILLATION DATA PER FRACTIONS
Page 17
LABORATORY REPORT NO. FCA/1025/06Sample ID - Al Shaheen Crude Oil Ex Qatar sampled on 10th April 2006
Page 18
0.5500
0.6000
0.6500
0.7000
0.7500
0.8000
0.8500
0.9000
0.9500
1.0000
1.0500
Den
sity
- (k
g/L)
Fraction
Fraction's Mid B.P. Vs Density
Density @ 15° C 0.7316 0.7897 0.8250 0.8578 0.8803 0.9052 0.9449 1.0250
C5 - 65°C 65 - 150°C 150 - 200°C 200 - 250°C 250 - 300°C 300 - 350°C 350 - 420°C 420 - 560°C
LABORATORY REPORT NO. FCA/1025/06Sample ID - Al Shaheen Crude Oil Ex Qatar sampled on 10th April 2006
Page 19
0.000
1.000
2.000
3.000
4.000
5.000
Sulp
hur
% m
ass
Fraction
Fraction's Mid B.P. Vs Sulphur Content
Sulphur 0.043 0.066 0.180 0.356 1.04 1.88 2.41 2.86 5.00
C5 - 65°C 65 - 150°C 150 - 200°C 200 - 250°C 250 - 300°C 300 - 350°C 350 - 420°C 420 - 560°C 560+°C
LABORATORY REPORT NO. FCA/1025/06Sample ID - Al Shaheen Crude Oil Ex Qatar sampled on 10th April 2006
Page 20
0.000
0.050
0.100
0.150
0.200
0.250
0.300
0.350
0.400
0.450
0.500
Nitr
ogen
Con
tent
- %
mas
s
Fraction
Fraction's Mid B.P. Vs Nitrogen Content
Nitrogen 0.080 0.150 0.370
350 - 420°C 420 - 560°C 560+°C
LABORATORY REPORT NO. FCA/1025/06Sample ID - Al Shaheen Crude Oil Ex Qatar sampled on 10th April 2006
Page 21
0.6
10.6
20.6
30.6
40.6
50.6
60.6
70.6
80.6
90.6
Ani
line
Poin
t - °
C
Fraction
Fraction's Mid B.P. Vs Aniline Point
Aniline Point 55.2 58.4 60.4 68.6 73.0 84.6
150 - 200°C 200 - 250°C 250 - 300°C 300 - 350°C 350 - 420°C 420 - 560°C