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Curriculum Vitae    

Francisco Rodríguez‐Reinoso University of Alicante. Alicante. Spain 

         

March 2010  

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Index                                                                    Page 

 Personal information ………………………………………………………   03 List of publications ………………………………………………………….   11 Research projects ……………………………………………………………   37 Research contracts ………………………………………………………….   45 Ph.D. thesis supervised ……………………………………………………   51 Plenary and Invited lectures …………………………………………….   57 Patents ……………………………………………………………………………   59 Presentations in congresses ……………………………………………..  64 Miscellaneos ………………………………………………………………….    65                           

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 Personal Information 

                          

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        Francisco Rodríguez­Reinoso   

HIGHLIGHTS:  

i) Research  on  a  wide  range  of  carbon materials  (structural,  porous, catalysts, etc.), 

ii) Supervisor of 46 Ph.D. thesis (18 on activated carbon/adsorption, 6 on  carbon‐related  catalysts,  9  in  structural  carbon materials,  5  on non‐carbon  catalysts,  3  on  composites  and  5  on  miscellaneous materials), 

iii) Responsible  for  a  total  of  120  research  projects  and  industrial contracts in the period 1982‐2009 at the University of Alicante: (US$ 11.132,273), 

iv) Around  300  articles  published  in  refereed  journals  (Index  h  =  39; citations: 5.500+ ), 

v) Large number of plenary and invited lectures, vi) World‐recognized  leadership  in  the  fields  of  activated  carbon  and 

adsorption, vii) Intense long‐term interaction with carbon‐related industry, viii) Steady and continuous funding from European Union projects since 

1990, ix) Editor of the journal Carbon for the last 19 years. 

  

 

      Summary of activities 

  Present position:   Professor of Inorganic Chemistry. University of Alicante (since 1981)  Education: 

1964 B.Sc. Chemistry. University of Granada 1967 Ph.D. Chemistry. University of Granada 

        (Thesis title: Preparation of activated carbons from olive stones)  Postdoctoral positions: 

1968, 1969:  Research Associate. Dept. of Physical Chemistry. University of Bristol (UK) 

 (a  total  of  21  months  research  under  the  supervision  of  Professor D.H. Everett). 

1970,  1971:  Senior    Research  Associate.  Dept.  of Materials  Science.  Penn. State (USA). 

           (a total of 21 months research under the supervision of Professor P.L.   Walker, Jr.) 

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 University appointments: 

1964‐1967 Assistant.  Department  of  Inorganic  Chemistry.  University  of Granada.Spain 

1971‐1975 Assistant  Professor.  Department  of  Inorganic  Chemistry. University of Granada. Spain 

1976‐1981 Associate  Professor.  Department  of  Inorganic  Chemistry. University of Granada. Spain 

1981…Present  Professor. Department of Inorganic Chemistry. University of Alicante. Spain 

 Research experience: 

Research  experience  is  within  the  general  area  of  Surface  Chemistry  of carbon and ceramic materials with special emphasis on: a) Activated carbon: preparation, characterization and uses. b) Carbon  molecular  sieves:  including  new  approaches  to  their 

preparation, characterization, and uses in gas separation. c) Carbons for gas storage: including the development of new carbon 

monoliths for natural gas and hydrogen storage. d) Carbons for energy storage: including carbons for supercapacitors. e) Carbon­supported catalysts: use of porous carbons as support  for 

metals  and  alloys  catalysts  in  selective  hydrogenation  of  Fine Chemicals. 

f) Mesoporous  carbons  and  carbon  foams,  from  lignocellulosic precursors. 

g) Isotropic  graphite:  development  of  binderless  polyaromatic mesophase  from  petroleum  residues  for  the  production  of  pistons, water‐pump seals, etc. 

h) Carbon­ceramic and carbon­metal composites: work based on the polyaromatic  mesophase  mentioned  above,  using  heteroatom doping/infiltration. 

i) Structural  ceramics,  ceramic­ceramic  and  metal­ceramic composites:  :Development  of  new  processes  for  the  synthesis  of  SiC, Si3N4, sialon, etc.; effect of  the carbon materials used for carbo‐reduction processes. Development  of  novel  processes  for  the  synthesis  of  advanced ceramic composites. 

              Publications: 

Around  300  papers  published  in  such  journals  as  Carbon,  J.  Phys.  Chem., Langmuir, J. Catal., Appl. Catal., Surface Sci., PCCP, etc. 

  One book, “Activated Carbon” (Elsevier).   10 chapters in books, encyclopedias and handbooks.  

 Communications: 

Over 300 presentations in international conferences, mainly in the fields of carbon and catalysis 

              Plenary and Invited Lectures: 

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  11 Plenary Lectures (outside Spain)   30+ Invited Lectures (mainly outside Spain)  Ph.D. Students: 

46 supervised research students obtained their Ph.D degree.   Research Projects:   69  research  projects  financed  by  Spanish  and  European  Union  agencies were   supervised in the period 1982‐2009.   Research Contracts: 

51 research contracts with Spanish and foreign companies were supervised in the period 1986‐2009. 

 Patents:   7 patents, 3 of which are international  Books written   1 book (“Activated Carbon”) at Elsevier, published July 2006.  Books edited:   8 books were edited or co‐edited  Congress organization:   5 international and 3 national congresses were organized   1 international Short Course (one week) on activated carbon organized.  International interactions: 

Coordinator  of  two  Iberoamerican  projects  (CYTED  Programme)  on adsorbents, involving 8 and 9 countries, respectively (1993‐1998). Coordinator  of  the  “Iberoamerican  network  on  adsorbents  for  a  cleaner environment”,  involving  73  research  groups  from  12  different  countries (CYTED Programme), 2001‐2005. Participation  in  international  projects  with  universities  and  research centres  of  France,  United  Kingdom,  Germany,  Portugal,  USA,  Chile,  Brazil, Japan, Sweden, Russia, Ukraine, Denmark. 

 Miscellaneous:   Vicepresident for Research, University of Alicante: 1983‐1985   FICIA Research Prize: 1987   Editor journal Carbon (Elsevier): since 1991   President of the Spanish Carbon Group (1991‐1999) 

Academician  Academy of Sciences of Granada: since February 2000. NATO consultant for the Science for Peace Programme, since 2001. Japan Carbon Award for Lifetime Achievement, 2008 

 Personal notes: One of  the main objectives  of  the  research  activity has been  the development  of new  materials  (a  large  proportion  of  them  from  agricultural  and  industrial  by‐

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products),  and  their  application  in  the  solution  of  industrial  and  environmental problems.  Some  of  these  materials  are  already  in  the  stage  of  industrial production, or under testing by companies to evaluate their industrial use. On the other  hand,  the  second  main  objective  of  the  research  is  the  training  of  young researchers, as shown by the 46 graduate students supervised for their Ph.D thesis Many of them are now professors at Spanish universities or researchers in public and private enterprises.  Two of the articles are among the most ever cited articles published in the journal Carbon and these are the most worlwide cited articles in Chemistry of the University of Alicante. It is to be noted that the number of citations per average article in the last ten years is 20, the total number of citations being above 5.500. The index “h” is 39 in 2009 (search at Web of Knowledge: AU=(RODRIGUEZ$REINOSO F NOT RODRIGUE F*) OR (AU=RODRIGUE.F* AND TS=(CARBON*OR PYRO*)) OR AU=(REINOSO FR) OR AU=(RODRIGUEZ-REINOSO E NOT RODRIGUE.RE) OR AU=(RODRIGUEZREINOSO R AND GUERRERORUIZ A) OR RODRIGUE.R AND MARTINRO.A). The recognized contribution to the research and development in the field of carbon materials lead to the designation of Editor of the international journal Carbon in 1991, and continues in this position since then.

 RESEARCH INTERESTS  A. CARBON MATERIALS  Porous carbons: 

The design, development and description-characterisation of porous materials,

especially activated carbons, is essential not only for the control of environmental pollution but also for satisfying the increasing demand of purity in natural and

synthetic products. The research carried out in the last years (18 Ph.D. thesis

supervised in this area), which is continued today, has permitted an in-depth

knowledge of all processes implied in the preparation of activated carbon, and this has

been used to propose new manufacturing routes, either to solve specific problems

(purification and separation of gases, removal of odors, gas storage, etc.), or to be able

to prepare materials with defined pore size distributions to be used as models for the

analysis of the adsorption process. We have developed new forms of adsorbents such as

activated carbon cloths and felts (already in industrial production in Cocentaaine, Alicante), carbon molecular sieves, or monoliths for gas storage (in the stage of

optimization for a Brasilian company). On the other hand, our studies led to the

installation of the first industry in Spain to produce activated carbon (from olive

stones, ICASA, 1997).

A new international project has been very recently awarded to Prof. Rodríguez-Reinoso

in collaboration with Prof. K. Kaneko, in Chiba (Japan) to study the use of

nanostructured carbon monoliths for the storage and conversion of methane.

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Carbon supported Catalysts:

A similar approach has been used to analyze the effect of the chemistry of the carbon

surface on the adsorption process of molecules with different properties, and this

research has open a new field of applications not considered a few years ago. One of

these applications is heterogeneous catalysis based on metal catalysts supported on

carbon. The research carried out up to now (6 Ph.D. thesis supervised in this field) has made possible to be able to establish the porosity and chemistry of the carbon

surface required for an appropriate dispersion of the active phase. Furthermore, this

has permitted the preparation of catalysts with adequate catalytic activity and

selectivity for many reactions of interest in the area of Fine Chemicals, such as the

selective hydrogenation of the carbonyl group in unsaturated aldehydes.

As from October 2004,to 2009 the research group participated as Core group in the European Network of Excellence “InsidePores”.

A good measure of the world-wide repercussion of the research carried out in these two areas is the fact that between 1999 and 2000 there were requests to write three long chapters for Encycopledias or Handbooks: The Encycolpedia of Materials: Science and Technology (Elsevier, 2001); Handbook of Surface and Interfaces of Materials (Academic Press, 2001); Handbook of Porous Solids (Wiley-VCH, 2002) and a book on “Activated Carbon”, published by Elsevier last 2006.

Other carbon materials:

A similar approach has been used for the development of other materials. An in-depth

analysis of the chemistry and kinetics of the processes has permitted a better understanding of the mechanisms involved, and this was later used for the new

developments.

In the case of non-porous carbon materials such as isotropic graphite, the main effort

was centered in reaching a better understanding of the complex mechanisms involved

in the pyrolysis of petroleum residues. The control of the carbon mesophase formation

and the subsequent separation from the isotropic phase provided the self-sintering

precursor for the isotropic graphite needed for the manufacture of pistons and seals (9

Ph.D. thesis supervised). This research resulted in the first European patent on

self-sintering mesophase for the production of isotropic graphite filed for the company

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Repsol_YPF. Furthermore, the basic knowledge of the mechanism of pyrolysis has also

been used to further improve the material via heteroatom doping. In this case, the

copyrolysis of the petroleum residue with soluble compounds of boron or silicon has

been used instead of the traditional infiltration or chemical vapour deposition

techniques. Copyrolysis resulted in a much more homogeneous distribution of the

heteroatom through the carbon matrix, thus improving the mechanical and rheological

properties of the graphite.

These last research lines have been the base of several European projects (Brite-Euram and Growth) undertaken along the last nine years, and resulted in the material used to produce pistons for vehicle engines, already under optimization and testing. This research field of the group has been awarded a European Integrated Project (ExtreMat) for the period 2005-2009. The invitation to the group to participate was based on the expertise in the field of doped carbon materials needed to build the wall of fusion reactors or as protection for re-entry of spatial vehicles.

B. OTHER NON-CARBON MATERIALS

Heterogeneous catalysis has also been studied using catalysts not supported on carbon

but on other types of support, mainly on partially reducible oxides such as CeO2, TiO2,

ZnO, etc. 5 Ph.D. thesis were supervised in this field.

In the case of structural ceramics, the research carried out has been mainly concerned

with the mechanisms of formation of silicon carbide, silicon nitride and phases such as

sialon. The research has pointed out the important role of catalysts (mainly iron, cobalt

and nickel) in the formation and growth of whiskers, of great technological importance.

The same approach has been used for the synthesis of new composite materials, and it has been possible to find new routes for the synthesis of ceramic-ceramic composites

such as SiC-MoSi2, avoiding the problems associated to previous methods. 3 Ph.D.

thesis were supervised in this area of research.

The rest of 5 Ph.D. thesis supervised correspond to a variety of materials ranging

from intercalation compounds of graphite, to graphite, use of industrial wastes , etc.

 FUNDING  The wide range of carbon materials under research by the Laboratorio de 

Materials Avanzados led by Prof. Rodríguez‐Reinoso in Alicante has attracted the 

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attention of public and private enterprises, whom have been funding this research 

since 1982, when he was incorporated to the University of Alicante.  He has been 

responsible for a large number of research projects and industrial contracts, for a 

total of US$ 11.132.273. 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

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List of Refereed Publications

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Professor Francisco Rodríguez-Reinoso

LIST OF REFEREED PUBLICATIOINS

293. E.V. Ramos-Fernández, J. Silvestre-Albero, A. Sepúlveda-Escribano, F. Rodríguez-Reinoso “Effect of metal precursor on the properties of Ru/ZnO catalysts” Appl. Catal. A., 374, 221-227 (2010) 292. M. Montiero de Castro, M. Martínez-Escandell, M. Molina-Sabio, F. Rodríguez-Reinoso “Hydrogen adsorption on KOH activated carbons from mesophase pitch containing Si, B, Ti or Fe” Carbon, 48, 636-644 (2010) 291. A. Silvestre-Albero, J-M- Ramos-Fernández, M. Martínez-Escandell, A. Sepúlveda-Escribano, J. Silvestre-Albero, F. RodríguezReinoso “High saturation capacity of activated carbon prepared from mesophase pitch in the removal of volatile organic compounds” Carbon, 48, 548-556 (2010) 290. J. Kärger, J. Caro, P. Cool, M.O. Coppens, D. Jones, F. Kapteijn, F. Rodríguez-Reinoso, M. Stocker, D. Theodorou, E.F. Vansant, J. Weitkamp. “Benefit of microscopic diffusin measurement for the characterization of nanoporous materials”. Chem. Eng. Technol., 32, 1494-1511 (2009) 289. F. Rodríguez-Reinoso, A. Sepúlveda-Escribano “Carbon as catalyst support” Carbon Materials for Catalysis. Pages-131-156. Wiley, New Jersey (USA) (2009) 288. E.V. Ramos-Fernández, J.M. Ramos-Fernández, M. Martínez-Escandell, A. Sepúveda-Escribano, F. Rdfríguez-Reinoso Selective hydrogenation of cynnamaldehyde over (111) preferentially oriented Pt particles supported on expanded graphite” Catalysis Letters, 133, 917-920 (2009 287. F. Alonso, P. Riente, F. Rodríguez-Reinoso, J. Ruiz-Martínez, A. Sepúlveda-Escribano, M. Yus “A highly reusable carbon-supported platinum catalyst for the hydrogen transfer reduction of ketones.” Chem. Cat. Chem., 1, 75-77 (2009) 286. M. Belhachemi, R.V.R.A. Riosd, F. Adoun, J. Silvestre-Albero, A. Sepúlveda-Escribano, F. Rodríguez-Reinoso, “Preparation of activated carbon from date pits. Effect of activation and liquid oxidation” J. Anal. & Appl. Pyrolysis, 86, 168-172 (2009)

285. A. Silvestre-Albero, A. Waby, J. Silvestre-Albero, F. Rodríguez-Reinoso, W. Betz Carbon molecular sieves prepared from polymeric precursors: porous structure and hydrogen adsorption properties” Ind. Chem. Res. 48, 7125-7131 (200)

284: M. Krutyeva, F. Grinberg, F. Hurtado, P. Galvosas, J. Karger, A. Silvestre-Albero, A. Sepúlveda-Escribano, F. Rodríguez-Reinoso “Characterization of carbon materials with the help of NMR methods” Microp- Mesop. Mater. 120, 91-97 (2009)

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283. A. Silvestre-albero, J. Silvestre-Albero, A. Sepúlveda-Escribano, F. Rodríguez-Reinoso “Ethajnol removal using activated carbon:effect of porous structure and surface chemistry” Microp. Mesop. Mater., 120, 62-68 (2009) 282 N.R. Calderon, M. Martínez-Escandell, J. Narciso, F. Rodríguez-Reinoso “The role of carbon biotemplate density in mechanical propierties of biomorphic SiC” Journal of the European Ceramic Society 29, 465-472 (2009) 281 “Spectroscopic and microcalorimetric study of a TiO2-supported platinum catalyst” J. Ruiz-Martínez, A. Sepúlveda-Escribano, J.A. Anderson, F. Rodríguez-Reinoso Physical Chemistry Chemical Physics 11, 917-920 (2009) 280 A. Silvestre-Albero, E.O. Jardim, E. Brujin, V. Meynen, P. Cool, A. Sepúlveda-Escribano, J. Silvestre-Albero, F. Rodríguez-Reinoso “Is there any microporosity in ordered mesoporous silicas?” Langmuir 25, 939-943 (2009) 279 V. Ruiz, C. Blanco, R. Santamaría, J.M. Ramos-Fernández, M. Martínez-Escandell, A. Sepúlveda-Escribano, F. Rodríguez-Reinoso “An activated carbon monolito as an electrode material for supercapacitors” Carbon 47, 195-200 (2009) 278 J. Silvestre-Albero, A. Sepúlveda-Escribano, F. Rodríguez-Reinoso, V. Kouvelos, G. Pilatos, N.K. Kanellopoulos, M. Krutyeva, F. Grinberg, J. Kärger, A.I. Spjelkavik, M. Stöcker, A. Ferreira, S. Brouwer, F. Kapteijn, J. Weitkamp, S.D. Sklari, V.T. Zaspalis, D.J. Jones, L.C. de Menorval, M. Lindheimer, P. Caffarelli, E. Borsella, A.A.G. Tomlinson, M.J.G. Linders, J.L. Tempelman, E.A. Bal “Characterization measurements of common referente nanoporous materials by gas adsorption (round robin tests)” “Proceedings of the 8th International Symposium on the characterization of Porous Solids” , Pages 9-16. Royal Society of Chemistry (2009) 277 J.M. Juárez-Galán, A. Silvestre-Albero, J. Silvestre-Albero and F. Rodríguez-Reinoso “Synthesis of activated carbons with highly developed “mesoporosity”” Microporous and Mesoporous Materials 117, 1519-1521 (2009) 276 J. Silvestre-Albero and F. Rodríguez-Reinoso “Combined use of gas adsorption and inmersion calorimetry for the correct characterization of the narrow microporosity in carbon materials” Prep. Pap.-Am. Chem. Soc., Div. Fuel Chem. 53, 462-463 (2008) 275. F. Alonso, P. Riente, F. Rodríguez-Reinoso, J. Ruiz-Martínez, A. Sepúlveda-Escribano, M. Yus “Platinun nanopartiles supported on titania as an efficient hydrogen-transfer catalysts” J. Catal., 260, 113-118 (2008

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274 Diana López, Robison Buitrago, Antonio Sepúlveda-Escribano, Francisco Rodríguez-Reinoso, Fanor Mondragón “Low temperatura catalytic adsorption of SO2 on activated carbon” Journal of Physical Chemistry C 112, 15335-15340 (2008) 273 P. Carreira, J. Sánchez-Coronado, J. Narciso, M. Martínez-Escandell, F. Rodríguez-Reinoso “Preparation of graphite/nano-SiC composites by co-pyrolisis of a petroleum residue with phenylsilanes” Journal of Analytical & Applied Pyrolisis 83, 137-144 (2008) 272 E .V. Ramos-Fernández, A.F.P. Ferreira, A. Sepúlveda-Escribano, F. Kapteijn, F. Rodríguez-Reinoso “Enhancing the catalytic performance of Pt/ZnO in the selective hydrogenation of cinnamaldehyde by Cr addition to the support” Journal of Catalysis 258, 52-60 (2008) 271 J. Silvestre-Albero, J.C. Serrano-Ruiz, A. Sepúlveda-Escribano, F. Rodríguez-Reinoso “Zn-modified MCM-41 as support for Pt catalysts” Applied Catalysis A: General 351, 16-20 (2008) 270 F. Rodríguez-Reinoso, Y. Nakagawa, J. Silvestre-Albero, J.M. Juárez-Galán, M. Molina-Sabio “Correlation of methane uptake with microporosity and surface area of chemically activated carbons” Microporous and Mesoporous Materials 115, 603-608 (2008) 269 J. Llorca-Porcel, M.A. Rodríguez-Valero, M. Martínez-Escandell, F. Rodríguez-Reinoso “Sinterability enhancement in semicokes obtained by controlled pyrolisis of a petroleum residue” Journal of Analytical & Applied Pyrolisis 82, 163-169 (2008) 268 A. Rodríguez-Guerrero, J.M. Molina, F. Rodríguez-Reinoso, J. Narciso, E. Louis “Pore filling in graphite particle compacts infiltrated with Al-12wt.%Si and Al-12wt.% Cu alloys” Materials Science and Engineering 495, 276-281 (2008) 267 S.A. Sanchez, J. Narciso, E. Louis, F. Rodríguez-Reinoso, E. Saiz, A. Tomsia “Wetting and capillarity in the Sn/graphite system” Materials Science and Engineering 495, 187-191 (2008) 266 R.V.R.A. Rios, J. Silvestre-Albero, A. Sepúlveda-Escribano, F. Rodríguez-Reinoso “Liquid-phase adsorption / oxidation of sulphur-containing species by activated carbon” Recent advances in adsorption processes for enviromental protection and security, 107-118, Ed. Springer, The Netherlands (2008) 265 J.M. Ramos-Fernández, M. Martínez-Escandell, F. Rodríguez-Reinoso

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“Production of binderless activated carbon monolitos by KOH activation of carbon mesophase materials” Carbon 46, 384-386 (2008) 264 E .V. Ramos-Fernández, A. Sepúlveda-Escribano, F. Rodríguez-Reinoso “Enhancing the catalytic performance of Pt/ZnO in the vapour phase hydrogentaion of crotonaldehyde by the addition of Cr to the support” Catalysis Communication 9, 1243-1246 (2008) 263 K. De Witte, V. Meynen, M. Mertens, O.I. Lebedev, G. Van Tendeloo, A. Sepúlveda-Escribano, F. Rodríguez-Reinoso, E.F. Vansant, P Cool “Multistep loading of titania on mesoporous silica: Influence of the morphology and the porosity on the catalytic degradation of aqueous pollutants and VOC’s” Applied Catalysis B: Environmental 84, 125-132 (2008) 262 S. Urbonaite, J.M. Juárez-Galán, J. Leis, F. Rodríguez-Reinoso, G. Svensson “Porosity development along the síntesis of carbons from metal carbides” Microporous and Mesoporous Materials 113, 14-21 (2008) 261 E.V. Ramos-Ferández, B. Samaranch, P. Ramírez de la Piscina, N. Homs, J.L.G. Fierro, F. Rodríguez-Reinoso, A. Sepúlveda-Escribano “Pt/Ta2O5-ZrO2 catalysts for vapour phase selective hydrogenation of crotonaldehyde” Applied Catalysis A: General 349, 165-169 (2008) 260 J.C. Serrano-Ruiz, A. López-Cudero, J. Solla-Gullón, A. Sepúlveda-Escribano, A. Aldaz, F. Rodríguez-Reinoso “Hydrogenation of alpha,beta-unsaturated aldehydes over polycristalline, (111) and (100) preferentially oriented Pt nanoparticles supported on carbon” Journal of Catalysis 253, 159-166 (2008) 259 J. Silvestre-Albero, A. Sepúlveda-Escribano, F. Rodríguez-Reinoso “Preparation and characterization of Zn-containing MCM41 spheres” Microporous and Mesoporous Materials 113, 362-369 (2008) 258. J.C. Serrano-Ruiz, E.V. Ramos-Fernández, J. Silvestre-Albero, A. Sepúlveda-Escribano, F. Rodríguez-Reinoso “Preparation and characterization of CeO2 highly dispersed on activated carbon” Materials Research Bulletin 43, 1850-1857 (2008) 257. J. Ruiz Martìnez, F. Coloma, A. Sepúlveda Escribano, J.A. Anderson, F. Rodríguez-Reinoso Effect of tin content and reduction temperature on the catalytic behavior of PtSn/TiO2 in the vapor phase hydrogenation of crotonaldehyde. Catalysis Today 133-135, 35-41 (2008) 256. V. Ruiz, C. Blanco, R. Santamaría, J.M. Suárez Galán, A. Sepúlveda-Escribano, F. Rodríguez-Reinoso Carbon molecular sieves as model active electrode materials in supercapacitors Micropor. Mesopor. Mater. 110, 431-435 (2008) 255. J.M. Ramos Fernández, M. Martínez-Escandell, F. Rodríguez-Reinoso

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Production of binderless activated carbon monoliths by KOH activation of carbonm mesophase materials Carbon 46,384-386 (2008) 254. M. Molina-Sabio, Y. Nakagawa, F. Rodríguez-Reinoso Posible errors in microporosity in chemically activated carbon deduced from immersion calorimetry Carbon, 46, 329-334 (2008) 253. E. Ramos Fernández, J.C. Serrano Ruiz, J. Silvestre Albero, A. Sepúlveda Escribano, F. Rodríguez-Reinoso The effect of the cerium precursor and the carbon surface chemistry on the dispersion of ceria on activated carbon J. Mater. Sci. 43, 1525-1531 (2008) 252. M. Prauchner, F. Rodríguez-Reinoso Preparation of granular activated carbons for adsorption of natural gas Micropor. Mesopor. Mater. 109, 581-584 (2008) 251. A. Rodríguez Guerrero, J. Narciso, E. Louis, F. Rodríguez-Reinoso Decreasing the infiltration threshold pressure of Al-12wt% Si into alumina particle compacts by Sn or Pb layers Composite Sci. & Technol. 68, 75-79 (2008) 250. D. López, R. Buitrago, A. Sepúlveda Escriabano, F. Rodríguez-Reinoso, F. Mondragón Low temperature catalytic adsorption of NO on activated carbonnmaterials Langmuir, 23, 12131-12137 (2007) 249. J.M. Ramos-Fernandez, M. Martínez-Escandell, F.Rodríguez-Reinoso Preparation of mesophase pitch doped with TiO2 or TiC particles J. Anal. Appl. Pyrolysis 80, 477-484 (2007) 247. Francisco Rodríguez Reinoso Activated carbon, the universal adsorbent. In Sólidos porosos: preparación, caracterización y aplicaciones, Publ. Uniandes, 95-137 (2007) 246. Rachel V.R.A. Rios, J. Silvestre-Albero, A. Sepúlveda-Escribano, M. Molina-Sabio, F. Rodríguez-Reinoso Kinetic restrictions in the characterization of narrow microporosity in carbon materials J. Phys. Chem. C 111, 3803-3805 (2007) 245. Diana López, Robison Buitrago, Antonio Sepúlveda-Escribano, Francisco Rodríguez-Reinoso, Fanor Mondragón Surface complexes formed during simultaneous catalytic adsorption of NO and SO2 on activated carbons at low temperatures J. Phys. Chem.C 111, 1417-1423 (2007) 244. Rachel V.R.A. Rios, J. Silvestre-Albero, A. Sepúlveda-Escribano, F. Rodríguez-Reinoso Liquid-phase adsorption/oxidation of sulfur-containing species by activated carbon In Recent advances in adsorption processes for environmental protection and security, Springer, 107-118 (2007) 243. J. Ruiz-Martínez, A. Sepúlveda-Escribano, J.A. Anderson, F. Rodríguez-Reinoso Influence of the preparation method on the catalytic behaviour of PtSn/TiO2 catalysts

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Catal. Today 123, 235-244 (2007) 242. Y. Nakagawa, M. Molina-Sabio, F. Rodríguez-Reinoso Modification of the porous structure along the preparation of activated carbon monoliths with H3PO4 and ZnCl2 MIcropor. Mesopor. Mater. 103, 29-34 (2007) 241. J.M. Molina, A. Rodríguez-Guerrero, M.Bahraini, L. Weber, J. Narciso, F. Rodríguez-Reinoso, E. Louis, A. Mortensen Infiltration of graphite preforms with Al-Si eutectic alloy and mercury Scripta Materialia 56, 991-994 (2007) 240. J.C. Serrano-Ruiz, A. Sepúlveda-Escribano, F. Rodríguez-Reinoso, D. Duprez Pt-Sn catalysts supported on highly-dispersed ceria on carbon. Application to citral hydrogenation J. Molec. Catal. 268, 227-234 (2007) 239. Rachel V.R.A. Rios, J. Silvestre-Albero, A. Sepúlveda-Escribano, F. Rodríguez-Reinoso Liquid phase removal of propanethiol by activated carbon: Effect of porosity and functionality” Colloids & Surfaces 300, 180-190 (2007) 238. J.C. Serrano-Ruiz, A. Sepúlveda-Escribano, F. Rodríguez-Reinoso Bimetallic PtSn/C catalysts promoted by ceria: application in the nonoxidative dehydrogenation of isobutene J. Catal. 246, 158-165 (2007) 237. A.Rodríguez-Guerrero, J. Narciso, E. Louis, F. Rodríguez-Reinoso Reducing threshold pressure for infiltration of Al-12Si alloys into carbon particle compacts by placing a thin layer of Sn at the infiltration front Mater. Sci. Forum 539-543, 785-790 (2007) 236. J. Ruiz-Martínez, E.V. Ramos-Fernández, A. Sepúlveda-Escribano, F. Rodríguez-Reinoso Effect of thermal treatments on the surface chemistry of oxidized activated carbons Studies in Surf. Sci. and Catal. 160, 129-136 (2007) 235. M. Molina-Sabio, M.J. Sánchez-Montero, J.M. Juarez-Galán, F. Salvador, F. Rodríguez-Reinoso. A. Salvador Development of porosity in a char during reaction with steam and supercritical water J. Phys. Chem. B 110, 12360-12364 (2006) 234. F. Rodríguez-Reinoso Porous carbons in gas separation and storage In Combined and Hybrid Adsorbents. Springer 133-144 (2006) 233. T. López, E. Ortiz-Islas, J. Manarrez, F. Rodríguez-Reinoso, A. Sepúlveda, R.D. González. Biocompatible titania microtubes formed by nanoparticles and its application in the drug delivery of valproic acid Optical Mater. 29, 70-74 (2006) 232. J.C. Serrano-Ruiz, G.W. Huber, M.A. Sánchez-Castillo, J.A. Dumesic, A. Sepúlveda-Escribano, F. Rodríguez-Reinoso Effect of Sn addition to Pt/CeO2-Al2O3 and Pt/Al2O3 catalysts: An XPS, 119Sn Mosbauer and microcalorimetry study J. Catal. 241, 378-388 (2006)

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231. F. Rodríguez-Reinoso Activated carbon Elsevier (536 pages). (2006) 230. J.C. Serrano-Ruiz, J. Luettich, A. Sepúlveda-Escribano, F. Rodríguez-Reinoso Effect of the support composition on the vapor-phase hydrogenation of crotonaldehyde over Pt/CexZr1-xO2 catalysts J. Catal. 241, 45-55 (2006) 229. E. Mora, V. Ruiz, R. Santamaría, C. Blanco, M. Granda, R. Menéndez, J.M. Juárez-Galán, F. Rodríguez-Reinoso Influence of mesophase activation conditions on the specific capacitance of the resulting carbons J. Power Sources 156, 719-724 (2006) 228. Joaquín Silvestre-Albero, Fernando Coloma, Antonio Sepúlveda-Escribano, Francisco Rodríguez-Reinoso Effect of the presence of chlorine in bimetallic PtZn/CeO2 catalysts for the vapor-phase hydrogenation of crotonaldehyde Appl. Catal.A 304, 159-167 (2006) 227. R.V.R.A. Rios, M. Martínez-Escandell, M. Molina Sabio, F. Rodríguez-Reinoso Carbon foam prepared by pyrolysis of olive stones under steam Carbon 44, 1448-1454 (2006) 226. A. Rodríguez-Guerrero, S.A. Sánchez, J. Narciso, E. Louis, F. Rodríguez-Reinoso Pressure infiltration of Al-12wt.% Si-X (X=Cu,Ti, Mg) alloys into graphite particle performs Acta Materialia 54, 1821-1831 (2006) 225. Renán Arraigada, Germán Bello, Rafael García, F. Rodríguez Reinoso, A. Sepúlveda Carbon molecular sieves from hardwood carbon pellets. The influence of carbonization temperature in gas separation properties Micropor. Mesopor. Mater. 81, 161-167 (2005) 224. F. Rodríguez Reinoso, Cristina Almansa, M. Molina Sabio Contribution to the evaluation of density of methane adsorbed on activated carbon J. Phys. Chem. B 109, 20227-20231 (2005) 223. J. Silvestre Albero, J.C. Serrano Ruiz, A. Sepúlveda Escribano, F. Rodríguez Reinoso Modification of the catalytic behaviour of platinum by zinc in crotonaldehyde hydrogenation and iso-butane dehydrogenation Appl. Catal. 292, 244-251 (2005) 222. A.. Rodríguez, S.A. Sánchez, J. Narciso, E. Louis, F. Rodríguez-Reinoso Pressure infiltration of Al-Si alloys into compacts made of carbon particles J. Mater. Sci. 40, 2519-1523 (2005) 221. Carlota Gómez de Salazar, Antonio Sepúlveda-Escribano, Francisco Rodríguez-Reinoso Preparation of carbon molecular sieves by pyrolytic carbon deposition Adsorption 11, 663-667 (2005) 220. R. Arpón, J. Narciso, F. Rodríguez-Reinoso, M. Komatsu Synthesis of mixed disilicides/SiC composites by displacement reaction between metal carbides and silicon Mater. Sci. Eng. 380, 62-66 (2004)

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219. C. Almansa, M. Molina-Sabio, F. Rodríguez-Reinoso Adsorption of methane into ZnCl2-activated carbon derived discs Micropor. Mesopor. Mater. 76, 185-191 (2004) 218. M. Molina-Sabio, F. Rodríguez-Reinoso Role of chemical activation in the development of carbon porosity Colloids & Surfaces 241, 15-25 (2004) 217. M. Molina-Sabio, C. Almansa, F. Rodríguez-Reinoso Phosphoric acid activated carbon discs for methane adsorption Carbon 41, 2113-2119 (2003) 216. Jorge Sanchez-Coronado, D.D.L. Chung, M. Martínez-Escandell, J. Narciso, F. Rodríguez-Reinoso Effect of boron carbide particle addition on the thermomechanical behavior of carbon matrix silicon carbide particle composites Carbon 41, 1096-1099 (2003) 215. J. Silvestre-Albero, A. Sepúlveda-Escribano, F. Rodríguez-Reinoso and J.A. Anderson Influence of Zn on the characteristics and catalytic behavior of TiO2-supported Pt catalysts J. Catal. 223, 179-190 (2004) 214. P. Carreira, M. Martínez-Escandell, J.M. Jiménez-Mateos, F. Rodríguez-Reinoso Chemistry of the co-pyrolysis of an aromatic petroleum residue with a pyridine-borane complex Carbon 41, 549-561 (2003) 213. M. Molina-Sabio, J.C. González, F. Rodríguez-Reinoso Adsorption of NH3 and H2S on activated carbon and activated carbon-sepiolite pellets Carbon 41, 448-450 (2003) 212. E. Bekyarova, K. Kaneko, M. Yudasaka, D. Kasuya, S. Iijima, A. Huidobro and F. Rodríguez-Reinoso Controlled opening of single-wall carbon nanohorns by heat treatment in carbon dioxide J. Phys. Chem. B 107, 4479-4474 (2003) 211. Joaquin Silvestre-Albero, A. Sepúlveda-Escribano, F. Rodríguez-Reinoso, James A. Anderson Infrared study of CO and 2-butenal co-adsortion on Zn modified Pt/CeO2-SiO2 catalysts Phys, Chem. Chem. Phys. 5, 208-216 (2003) 210. A. Huidobro, A. Sepúlveda-Escribano, F. Rodríguez-Reinoso Vapor-Phase Hydrogenation of Cronotonaldehyde on Titania-Supported Pt and PtSn SMSI Catalysts J. Catal. 212, 94-103 (2002) 209. F. Rodríguez-Reinoso Production and application of activated carbon In Handbook of Porous Solids, Wiley, Vol. 3, 1766-1827 (2002) 208. M. Martínez-Escandell, M.A. Rodríguez-Valero, J.S. Coronado, F. Rodríguez-Reinoso Modification of the Sintering Behaviour of Mesophase Powder from Petroleum Residue Carbon 40, 2843-2854 (2002)

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207. E. Ahumada, H. Lizama, F. Orellana, C. Suárez, A. Huidobro, A. Sepúlveda-Escribano, F. Rodríguez-Reinoso Catalytic Oxidation of Fe (II) by Actived Carbon in the Presence of Oxygen: Effect of the Surface Oxidation Degree on the Catalytic Activity Carbon 40, 2827-2834 (2002) 206. J. Silvestre-Albero, A. Sepúlveda-Escribano, F. Rodríguez-Reinoso Textural and Chemical Characterization of Nax Zeolite Exchanged with Zn(II) Ions Studies in Surface Sci. and Catal. 144, 107-114 (2002) 205. G. Bello, R. García, R. Arriagada, A. Sepúlveda-Escribano, F. Rodríguez-Reinoso Carbon Molecular Sieves from Eucalyptus Globulus Charcoal Micropor. Mesopor. Mater. 56, 139-145 (2002) 204. E. Bekyarova, Y. Hanzawa, K. Kaneko, J. Silvestre-Albero, A. Sepúlveda-Escribano, F. Rodríguez-Reinoso, D. Kasuya, M. Yudasaka, S. Iijima Cluster-Mediated Filling of Water Vapor in Intratube and Interstitial Nanospaces of Single-Wall Carbon Nanohorns Chem. Phys. Letters 366, 463-468 (2002) 203. M.A. Rodríguez-Valero, M. Martínez-Escandell, F. Rodríguez-Reinoso Production of High-Strength Carbon Artifacts from Petroleum Residues: Influence of the Solvent Used to Prepare Mesophase Powder Energy & Fuels 16, 1087-1094 (2002) 202. J. Silvestre-Albero, F. Rodríguez-Reinoso, Antonio Sepúlveda Escribano Improved Metal-Support Interaction in Pt/CeO2-SiO2 Catalysts after Zinc Addition J. Catal. 210, 127-136 (2002) 201. P. Pfeifer, F. Ehrburger-Dolle, T.P. Rieker, M.T. González, W.P. Hoffman, M. Molina-Sabio, F. Rodríguez-Reinoso, P.W. Schmidt, D.J. Voss Nearly Space-Filling Fractal Networks of Carbon Nanopores Physical Review Letters 88, 115502-1 115502-4 (2002) 200 Keith Lenghaus, Greg GuangHua Qiao, David H. Solomon, Carlota Gomez, F. Rodríguez Reinoso, Antonio Sepúlveda Escribano Controlling carbon microporosity: the structure of carbons obtained from different phenolic resin precursors Carbon 40, 743-749 (2002) 199. A. Huidobro, A. Sepúlveda-Escribano and F. Rodríguez-Reinoso Hydrogen spillover in Pt-Sn catalysts supported on activated carbon cloth Studies in Surface Sci. Catal. 138, 275-282 (2001) 198. J. Silvestre-Albero, F. Coloma, A. Sepúlveda-Escribano and F. Rodríguez-Reinoso Preparation and characterization of bimetallic Pt-Zn catalysts supported on zeolite NaX Studies in Surface Sci. Catal. 135, 29-P-15 (2001) 197. J.C. González, M. Molina-Sabio, F. Rodríguez-Reinoso Sepiolite-based adsorbents as humidity controller Appl. Clay Sci. 20, 111-118 (2001) 196. M. Molina-Sabio, F. Caturla, F. Rodríguez-Reinos, G.V. Kharitonova Porous structure of a sepiolite as deduced from the adsorption of N2, CO2 and H2O Micropor. Mesopor. Mater. 47, 389-396 (2001)

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195. J. Silvestre-Albero, M. A. Sánchez-Castillo, R. He, A. Sepúlveda-Escribano, F. Rodríguez-Reinoso, J.A. Dumesic Microcalorimetric, reaction kinetics and DFT studies of Pt-Zn/X-zeolite for isobutane dehydrogenation Catal. Letters 74, 17-25 (2001) 194. Narcís Homs, Jordi Llorca, Pilar Ramírez de la Piscina, Francisco Rodríguez-Reinoso, Antonio Sepúlveda-Escribano, Joaquín Silvestre-Albero Vapour phase hydrogenation of crotonaldehyde over magnesia-supported platinum-tin catalysts Phys. Chem. Chem. Phys. 3, 1782-1788 (2001) 193. F. Rodríguez-Reinoso, M. Molina-Sabio, J.C. González Preparation of activated carbon-sepiolite pellets Carbon, 39, 776-779 2001. 192. F. Rodríguez-Reinoso, A. Sepúlveda-Escribano. Porous carbons in adsorption and catalysis In Handbook of Surfaces and Interfaces of Materials. Academic Press. Vol. 1, 1018-2000 (2001) 191. J. Silvestre-Albero, A. Sepúlveda-Escribano, F. Rodríguez-Reinoso Characterization of microporous solids by immersion calorimetry Colloids & Surfaces, 187-188, 151-165 (2001) 190. M.A. Rodríguez-Valero, M. Martínez-Escandell, M. Molina-Sabio, F. Rodríguez-Reinoso CO2 activation of olive stones carbonized under pressure Carbon 39, 320-324 (2001) 189. P. Carreira, M. Martínez-Escandell, R. Santamaría and F. Rodríguez-Reinoso Co-pyrolysis of an aromatic petroleum residue with triphenylsilane Carbon 39, 1001-1011 (2001) 188. A.Huidobro, A. C. Pastor, F. Rodríguez-Reinoso Preparation of activated carbon cloth from viscous rayon. Part IV. Chemical activation Carbon 39, 389-398 (2001) 187. Francisco Rodríguez-Reinoso Activated carbons and adsorption In Encyclopedia of Materials: Science & Technology. Pergamon Vol. 1, 22-35 (2001) 186. F. Rodríguez-Reinoso, M. Martínez-Escandell, P. Torregrosa, H. Marsh, C. Gómez de Salazar, E. Romero Palazón. Pyrolysis of petroleum residues III: Kinetics of pyrolysis Carbon, 39, 61- 71 (2000) 185. C. Gómez de Salazar, A. Sepúlveda-Escribano and F. Rodríguez-Reinoso Preparation of carbon molecular sieves by controlled oxidation treatments Carbon, 38, 1889- 1892 (2000) 184. J. Narciso-Romero, R. Arpón-Carballo, F. Rodríguez-Reinoso, H. Komatsu Synthesis of a (MoSi2, Mo5Si3)/SiC Composite Using an In Situ Sokid-State Displacement Reaction between Mo2C and Si J. Ceramic Society of Japan, 108, 957-959 (2000).

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183. F. Coloma, Jordi Llorca, Narcís Homs, Pilar Ramírez de la Piscina, Francisco Rodríguez-Reinoso and Antonio Sepúlveda-Escribano Crotonaldehyde hydrogenation over alumnina- and silica- supported Pt-s-Sn catalysts of different composition. In situ DRIFT study Phys. Chem. Chem. Phys., 2, 3063-3069 (2000) 182. C. G. de Salazar, A. Sepúlveda-Escribano and F. Rodríguez-Reinoso Use of immersion calorimetry to evaluate the separation ability of carbon molecular sieves Studies in Surface Science and Catalysis, 128, 303-312 (2000) 181. D. L. Valladares, G. Zgrablich and F. Rodríguez-Reinoso On the determination of the micropore size distribution of activated carbons from adsorption isotherms Studies in Surface Science and Catalysis, 128, 391- 400 (2000) 180. P.Torregrosa-Rodríguez, M.Martínez Escanell, F. Rodríguez-Reinoso, H.Marsh, C.G.de Salazar, E. Romero-Palazón. Pyrolysis of petroleum residues II: chemistry of pyrolysis Carbon, 38, 535- 546 (2000) 179. F.Rodríguez-Reinoso, A.C.Pastor, H. Marsh, A.Huidobro Preparation of activated carbon cloths from viscous rayon. Part III. Effect of carbonization on CO2 activation. Carbon, 38, 397- 406 (2000) 178. F.Rodríguez Reinoso, A.C. Pastor, H.Marsh and M.A. Martínez. Preparation of activated carbon cloths from viscous rayon.Part II: Physical activation processes Carbon, 38, 379- 395 (2000)

177. C.G. de Salazar, A.Sepúlveda-Escribano and F. Rodríguez-Reinoso. Use of inmersion calorimetry to evaluate the separation ability of carbon molecular sieves Studies in Surface Science and Catalysis, 128, 303- 312 (2000) 176. F.Caturla, M.Molina-Sabio, F.Rodríguez-Reinoso. Adsorption-desorption of water vapor by natural and heat-treated sepiolite in ambient air” Appl.Clay Science, 15, 367- 380 (1999) 175. F.J.Narciso-Romero, F.Rodriguez-Reinoso, M.A. Díez. Influence of the carbon material on the synthesis of silicon carbide Carbon, 37, 1771- 1778 (1999) 174. M. Martínez-Escandell, P.Carreira, M.A.Rodríguez-Valero,F.Rodríguez-Reinoso Self-sintering of carbon mesophase powders:effect of extraction/washing with solvents Carbon, 37, 1662- 1666 (1999) 173. A.G. Alvarez, M.Martínez-Escandell, M.Molina-Sabio, F.Rodríguez-Reinoso Pyrolisys of petroleum residues II. Analysis of semicokes by X-ray diffraction Carbon, 37, 1627- 1632 (1999). M.Martínez-Escandell, P.Torregrosa, H.Marsh, F.Rodríguez-Reinoso, R.Santamaría-Ramírez, 172. 172. C.Gómez de Salazar,E.Romero-Palazón Pyrolyisis of petroleum residues.I. Yields and product analyses. Carbon, 37, 1567- 1582 (1999). 171. A.C. Pastor, F. Rodríguez-Reinoso, H. Marsh and M. A. Martínez

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Preparation of activated carbon cloths from viscous rayon.part I. Carbonization procedures Carbon, 37, 1275- 1283 (1999) 170. H.Marsh, M.Martínez-Escandell,F.Rodríguez-Reinoso Semicokes frompitch pyrolysis: mechanisms and kinetics Carbon, 37, 363- 390 (1999) 169. R.Santamaría-Ramírez, E. Romero-Palazón, C.Gómez de Salazar, F. Rodríguez-Reinoso, S.Martínez-Saez, M.Martínez-Escandell, H. Marsh. Influence of pressure variations on the formation and development of mesophase in a petroleum residue Carbon, 37, 445- 455 (1999) 168. A.. Sepulveda-Escribano, F. Coloma, F. Rodríguez-Reinoso. Promoting effect of ceria on the gas phase hidrogenation of crotonaldehyde over platinum catalyst J.Catalysis, 178, 649- 657 (1998) 167. A. Sepúlveda, F.Coloma, F. Rodríguez Reinoso Platinum catalysts supported on carbon blacks with different surface chemical properties Applied Catalysis A:General, 173, 247- 257 (1998) 166. D.L. Valladares, F. Rodríguez Reinoso and G. Zgrablich Characterization of active carbons: the influence of the method in the determination of the pore size distribution Carbon, 36, 1491- 1499 (1998) 165. F. Rodríguez Reinoso, M. Molina Textural and chemical characterization of microporous carbons Advances in Colloid and Interfase Science, 76-77, 271- 294 (1998) 164. F. Coloma, J. Narciso-Romero, A. Sepúlveda-Escribano and F. Rodríguez-Reinoso Gas phase hydrogenation of crotonaldehyde over platinum supported on oxidized carbon black Carbon, 36, 1011- 1019 (1998) 163. F. Rodríguez Reinoso The role of carbon materials in heterogeneous catalysis Carbon 36, 159-175 (1998) 162. F.J. Narciso-Romero, F. Rodríguez-Reinoso, C. García-Cordovilla and E. Louis Fabrication of ceramic/ceramic composites from aluminun/ceramic composites produced by pressure infiltration Scripta Materialia, 38, 623-629 (1998) 161. A.G. Alvarez, M Molina-Sabio and F. Rodríguez-Reinoso An X-Ray scattering investigation of the carbonization of olive stone Carbon, 36, 67-70 (1998) 160. F. Rodríguez-Reinoso, P.Santana, E. Romero-Palazón, M.A. Díez and H.Marsh Delayed coking: Industrial and laboratory aspects Carbon 36, 105-116 (1998) 159. F. Ehrburger-Dolle, T. Rieker, M. T. González, M. Molina-Sabio, F. Rodríguez-Reinoso,P. Pfeifer and P.W. Schmidt. Oxidation processes and fractal properties of activated carbon In Fractals and chaos in chemical Engineering, 27-38 (1997)

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158. R. Arriagada, R. García, M. ;Molina-Sabio, F. Rodríguez-Reinoso Effect of steam activation on the porosity and chemical nature of activated carbons from Eucalyptus globulus and peach stones Microporous Materials, 8, 123-130 (1997) 157. M.T. González, F. Rodríguez-Reinoso, A. N. García and A. Marcilla CO2 activation of olive stones carbonized under different experimental conditions Carbon 35, 159-165 (1997) 156 J.C. González, A. Sepúlveda-Escribano, M.Molina-Sabio and F. Rodríguez Reinoso Micropore size distribution in carbon molecular sieves by immersion calorimetry COPS IV , Royal Soc. Chem, 9-16 (1997) 155 B. McEnaney,T. Mays, You Fa Yin, Xue Song Chen and F. Rodríguez-Reinoso Estimating the dimensions of ultramicropores using molecular probes COPS IV, Royal Soc. Chem, 125-132 (1997) 154. F. Ehrburger-Dolle, M.T. González, M. Molina Sabio and F. Rodríguez-Reinoso Determinación of the micropore size in carbons by means of experimental and calculated isotherm COPS IV, Royal Soc. Chem., 237-244 (1997) 153. F. Rodríguez-Reinoso, M. Molina-Sabio, M.T. González Effect of oxygen surface groups on the immersion enthalpy of activated carbon in liquids of different polarity Langmuir, 13, 2354-2358 (1997) 152. F. Rodríguez Reinoso Activated carbon: preparation, structure, characterization and applications In Introducción to carbon technologies, Univ. Alicante Press , 35-95 (1997) 151. R.Wolf, E Romero,C. Gómez de Salazar, P. Greiner, R. Schicktanz, F. Rodríguez-Reinoso Development of binderless carbon-mesophase for production of high strength graphites Euromat 97, Vol. 2, 341-244 (1997) 150. F. Rodríguez Reinoso Carbón activado. Estructura, preparación y aplicaciones. Canagua 97, 1-22 (1997) 149 F. Coloma, A. Sepúlveda, J.L.G. Fierro, F. Rodríguez Reinoso Gas phase hydrogenation of crotonaldehyde over Pt/activated carbon catalysts. Influence of oxygen surface groups of the support. Appl. Catal., 150, 165-183 (1997) 148. L.R. Radovic, F. Rodríguez Reinoso Carbon materials in catalysis Chem. & Phys.Carbon, 25, 243-358 (1997) 147. F. Coloma, A. Sepúlveda, J.L.G. Fierro, F. Rodríguez Reinoso Crotonaldehyde hydrogenation over bimetallic Pt-Sn catalysts supported on pregraphitized carbon black. Effect of preparation method Appl. Catal., 148, 63-80 (1996) 146. F.J. Narciso-Romero, A. Sepúlveda-Escribano, F. Rodríguez-Reinoso A new route for the synthesis of SiC-MoSi2 ceramic composite materials Chem. Comm., 14, 1667-1668 (1996)

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145. N. Setoyama, K. Kaneko, F. Rodríguez-Reinoso Ultramicropore characterization of microporous carbons by low temperature helium adsorption J. Phys. Chem. B, 100, 10331-10336 (1996) 144. F. Coloma, A. Sepúlveda, J.L.G. Fierro, F. Rodríguez Reinoso Crotonaldehyde hydrogenation over bimetallic Pt-Sn catalysts supported on pregraphitized carbon black. Effect of the Sn/Pt atomic ratio Appl. Catal., 136., 231-248 (1996) 143. M. Molina-Sabio, M.T. González, F. Rodríguez-Reinoso, A. Sepúlveda Effect of steam and carbon dioxide activation in the micropore size distribution of activated carbon Carbon, 34, 505-510 (1996) 142. M. Molina-Sabio, F. Rodríguez-Reinoso, F. Caturla, M.J. Sellés Development of porosity in combined phosphoric acid-carbon dioxide activation Carbon, 34, 457-462 (1996) 141. F.J. Narciso, F. Rodríguez Reinoso Synthesis of SiC from rice husks catalyzed by Fe, Co or Ni J. Mater. Sci., 31, 779-784 (1996) 140.M. Molina, M.A. Muñecas, F. Rodríguez-Reinoso, B. McEnaney Adsorption of CO2 and SO2 on activated carbons with a wide range of micropore size distribution Carbon 33, 1777-1782 (1995) 139. F. Caturla, F. Molina, M. Molina-Sabio, F. Rodríguez Reinoso Electroless plating of graphite with copper and nickel J. Electrochem. Soc. 142, 4084-4090 (1995) 138. F.J. Narciso, F. Rodríguez Reinoso, M.A. Díez Petroleum and coal derived cokes in the synthesis of SiC Coal Sci., 1, 11185-1168 (1995) 137. M. Martínez, F. Rodríguez Reinoso, P. Torregrosa, E. Romero, R. Santamaría A new parameter relating the properties of semicokes and the resulting sintered carbons Carbon 33, 1182-1184 (1995) 136. M. Molina-Sabio, F. Caturla, F. Rodríguez Reinoso Influence of the atmosphere used in the carbonization of phosphoric acid impregnated peach stones. Carbon 33, 1180-1182 (1995) 135. J.C. González, M.T. González, M. Molina-Sabio, F. Rodríguez Reinoso, A. Sepúlveda Porosity of activated carbons prepared from different lignocellulosic materials Carbon 33, 1175-1178 (1995) 134. M. Molina-Sabio, F. Rodríguez Reinoso, F. Caturla, M.J. Sellés Porosity in granular carbons activated with phosphoric acid Carbon 33, 1105-1113 (1995) 133. F. Coloma, A. Sepúlveda, F. Rodríguez Reinoso Heat treated carbon blacks as support for platinum catalysts

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J. Catal., 154, 299-305 (1995) 132. M.T. González, A. Sepúlveda, M. Molina-Sabio, F. Rodríguez Reinoso Correlation between surface areas and micropore volumes of activated carbons obtained from physical adsorption and immersion microcalorimetry. Langmuir 11, 2151-2155 (1995) 131. F. Coloma, A. Sepúlveda, F. Rodríguez Reinoso Improvement of the selectivity to crotyl alcohol in the gas-phase hydrogenation of crotonaldehyde over platinum/activated carbon catalysts. Appl. Catal. 123, L1-L5 (1995) 130. F.J. Narciso, A. Linares, F. Rodríguez Reinoso Synthesis of beta-sialon from coals and graphite. J. Mater. Res. 10, 727-735 (1995) 129. F. J. Narciso, F. Rodríguez Reinoso Synthesis of SiC and Si3 N4 : An overview. Advan. Mater. 7, 209-211 (1995) 128. F. Rodríguez Reinoso, M. Molina , M.T. González, The use of steam and CO2 as activating agents in the preparation of activated carbons Carbon 33, 15-23 (1995) 127. F. Rodríguez Reinoso Carbon as Catalyst Support In Porosity in Carbons. Edward Arnold, 253-290 (1995) 126. M.T. González, M. Molina, F. Rodríguez Reinoso Steam activation of olive stone chars. Development of porosity. Carbon 32, 1407-1413 (1994) 125. M. Molina, V. Pérez, F. Rodríguez Reinoso Impregnation of activated carbon with chromium and copper salts. Effect of porosity and metal content Carbon 32, 1259-1265 (1994) 124. F.J. Narciso Romero, F. Rodríguez Reinoso Synthesis of b-sialon from clays. Effect of starting materials J. Mater. Chem. 4, 1137-1141 (1994) 123. M. Molina Sabio, F. Rodríguez Reinoso, R. Torregrosa, D, Valladares, G. Zgrablich A lattice-gas model for adsorption in microporous solids Adv. Surface Sci. Catal., 87, 573-581 (1994) 122. A. Sepúlveda Escribano, F. Rodríguez Reinoso Mo-promoted Fe/activated carbon catalysts for CO hydrogenation J. Molecular. Catal. 90, 291-301 (1994) 121. F. Coloma, A. Sepúlveda Escribano, J.L.G. Fierro, F. Rodríguez Reinoso Preparation of platinum supported on pre-graphitized carbon blacks. Langmuir, 10, 750-755 (1994) 120. A. Martín Gullón, C. Prado Burguete, F. Rodríguez-Reinoso

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Effect of carbon properties on the preparation and activity of carbon-supported MoS2 catalysts Carbon 31, 1099-1105 (1993) 119. F. Coloma, C. Prado-Burguete, F. Rodríguez Reinoso Pt-C interaction in catalysts supported on carbon black subjected to different heat treatments New Frontiers in Catalysis, 2103-3106 (1993) 118. .M. Martín Martínez, F. Rodríguez Reinoso Evolution of surface homogeneity in cadmium halides upon heat treatment Langmuir 9, 568-573 (1993) 117. F.J. Narciso, F. Rodríguez Reinoso Catalytic effect of Fe, Co and Ni in the síntesis of SiC from rice husks Symp. Iberoam. Catal., 1, 511-514 (1992) 116. A. Martín, C. Prado, F. Rodríguez Reinoso Influence of preparation and sulfurization methods in Mo/C, CO/C y MoCo/C catalysts Symp. Iberoam. Catal., 1, 507-5510 (1992) 115. F. Rodríguez Reinoso, M. Molina Sabio Activated carbons from lignocellulosic materials by chemical and/or physical activation: An overview Carbon 30, 1111-1118 (1992) 114. E. Esteban, F. Rodríguez Reinoso, A. González, M. Molina, F. Caturla, A. Rodríguez Treatment and conditioning of radioactive graphite from nuclear installations Nuclear and Hazard Waste Management, 908-913 (1992) 113. F. Rodríguez Reinoso, M. Molina Sabio, M.A. Muñecas Effect of microporosity and oxygen surface groups of activated carbon in the adsorption of molecules of different polarity. J. Phys. Chem B 96, 2707-2713 (1992) 112. F. Rodríguez Reinoso, F.J. Narciso Romero Suynthesis fo Sic and Si3N4 from rice husks. An. Quim. 87, 788-794 (1991) 111. A.C. Orgilés, M.A. Martínez, F. Rodríguez, J.M. Martín, E. Sánchez, J.C. Jarque Chrome leather waste addition on ceramic paste AQEIC, XLII, 67-78 (1991) 110. F. Rodríguez Reinoso, A. Sepúlveda Effect of chromium addition on the behaviour of iron/activated carbon catalysts for carbon monoxide hydrogenation Appl. Catal. 77, 95-108 (1991) 109. F. Caturla, M. Molina Sabio, F. Rodríguez Reinoso Preparation of activated carbons by chemical activation with ZnCl2 Carbon 29, 999-1007 (1991) 108. M. Jaroniec, J. Choma, F. Rodríguez Reinoso and J.M. Martín Martínez Comparative studies of the microporous structure parameters evaluated from the adsorption isotherms of various adsorbates on activated carbons

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Studies Surf. Sci. and Catal, 62, 449-457 (1991) 107. M.A. Martínez Sánchez, J.M. Martín, A.C. Orgiles, F. Rodríguez Reinoso and M.J. Sellés Evaluation of microporosity in activated carbons with high as (Cr2O3) conten Studies Surf. Sci. and Catal, 62, 469-476 (1991) 106. F. Rodríguez Reinoso, J.M. Martín Martínez, A. Linares Solano and R. Torregrosa Further comments on low pressure hysteresis in activated carbons: effect of preparation method. Studies Surf. Sci. and Catal, 62, 419-4276 (1991) 105. M. Molina Sabio, M.A. Muñecas Vidal and F. Rodríguez Reinoso Modification in porous texture and oxygen surface groups of activated carbons by oxidation Studies Surf. Sci. and Catal, 62, 329-339 (1991) 104. J.M. Martín Martínez, F. Rodríguez Reinoso, Y. Grillet, F. Rouqerol, J. Rouquerol Characterization of microporosity and surface homogeneity by the study of argon and nitrogen isotherms crossing and measurement of differential enthalpies of adsorption. Studies Surf. Sci. and Catal, 62, 311-317 (1991) 103. C. Prado Burguete, A. Linares Solano, F.Rodríguez Reinoso and C. Salinas Effect of carbon support and mean Pt particles size on hydrogen chemisorption by carbon-supported Pt catalysts. J. Catal. 128, 397-404 (1991) 102. F. Rodríguez Reinoso Controlled gasification of carbon and pore structure development. In NATO ASI Series, 192, 533-571 (1991) 101. F. Rodríguez Reinoso and R. Torregrosa Continuous versus static automatic mode of gas adsorption on porous carbons Langmuir, 7, 350-353 (1991) 100. A.C. Orgilés, M.A. Martínez, M.J. Pérez, F. Rodríguez Reinoso, J.M. Martín Alternative to the controlled elimination of leather waste ANQUE, 3, 493-502 (1990) 99. Choma, M. Jaroniec, F.Rodríguez Reinoso, M. Molina Sabio and R. Torregrosa Charakterystyka mikroporowatej struktury wegli aktywnych na podstawie adsorpeji substancji organicznych i nieorganicznych z fazy gazowej Przem. Chem. 69, 275-279 (1990) 98. F. Rodríguez Reinoso, C.Salinas Martínez de Lecea, A Sepúlveda and J.D. López González Effect of support porosity in the preparation and catalytic activity for CO hydrogenation of carbon-supported Catal. Today 7, 287-298 (1990) 97. J:M: Martín Martínez, F. Rodríguez, M.A. Martínez, A.C. Orgilés Role of chromium oxide in the texture of carbons from leather Pyrolysis.& Gasification, 452-456 (1989) 96. M.A. Martínez, A.C. Orgilés, J.M. Martín Martínez, F. Rodríguez Reinoso Activated carbons from chromium-tanned leather waste

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Pyrolysis & Gasification, 439-443 (1989) 95. F. Rodríguez Reinoso An overview of methods for the characterization of activated carbons. Pure & Appl. Chem. 61, 1859-1866 (1989) 94. M. Jaroniec, J. Choma, F. Rodríguez Reinoso, J.M. Martín Martínez and M. Molina Sabio Parameters of microporous structure of carbonaceous adsorbents gasfied with air or carbon dioxide J. Chem. Soc., Faraday Trans. I 85, 3125-3134 (1989) 93. J.M. Martín Martínez, F. Rodríguez Reinoso and M.A. Vannice Carbon-supported, (Alkali Metal)(Fe2Mn(CO)12)-Derived catalysts. Adsorption properties and catalytic behavior in carbon monoxide hydrogenation Appl. Catal. 51, 93-112 (1989) 92. F. Rodríguez Reinoso, I. Bautista, J. Rivera Utrilla and J.D. López González Localized adsorption of N2 on graphites with different degrees of surface homogeneity. An. Quim. 85, 5-9 (1989) 91. F. Rodríguez Reinoso International Committee for characterization and terminilogy of carbon. Publication of 73 terms Carbon 27, 305-312 (1989) 90. F. Rodríguez Reinoso, J.M. Martín Martínez, B. McEnaney A comparison of two reference materials for adsorption of nitrogen on activated carbons Carbon 27, 297-299 (1989) 89. F. Rodríguez Reinoso, P. Santana, E. Romero, M.A. Diez, H. Marsh Mechanism for carbonization of petroleum residues FONM 9, 175-182 (1989) 88. J:M. Martín Martínez, M. Molina Sabio, F. Rodríguez Reinoso and R. Torregrosa Application of a reference material to the characterization of porous carbons. Fuel 68, 204-208 (1989) 87. F. Rodríguez Reinoso, J. Garrido, J.M. Martín Martínez, M. Molina, R. Torregrosa The combined use of different approaches in the characterization of microporous carbons. Carbon 27, 23-32 (1989) 86. J. Choma, M. Jaroniec, M. Molina, F. Rodríguez-Reinoso, R. Torregrosa Efektyne i rzeczywiste parametry struktury mikropowatej wegli aktwnych Chem. Stosow 33, 447-456 (1989) 85. C. Prado Burguete, A. Linares Solano, F. Rodríguez Reinoso, C. Salinas Martínez de Lecea The effect of oxygen surface groups of the support on platinum dispersion in Pt/ Carbon catalysts J. Catal. 115, 98-106 (1989) 84. F. Rodríguez Reinoso, A. Linares Solano Microporous structure of activated carbons as revealed by adsorption methods Chem. & Phys. Carbon, 21, 1-146 (1989)

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83. I. Rodríguez Ramos y F. Rodríguez Reinoso The adsorption of N2 and CO2 on PAN carbons. Carbon 26, 905-906 (1988) 82. J.M. Martín Martínez, F. Rodríguez Reinoso y M.A. Vannice Hydrogenation of CO over alkali metal-Fe2Mn clusters on carbon Proc. 9th Int. Cong. Catal. 666-673 (1988) 81. A. Guerrero, I. Rodríguez Ramos, F.Rodríguez Reinoso, C.Moreno y J.D. López González The role of nitrogen and oxygen surface groups in the behavior of carbon-supported iron and ruthenium catalysts Carbon 26, 417-123 (1988) 80.F. Caturla, J.M. Martín, M. Molina, F. Rodríguez Reinoso y R. Torregrosa Adsorption of substituted phenols on activated carbons J. Colloid & Interf. Sci. 124, 528-534 (1988) 79. C. Salinas, A. Linares Solano, F. Rodríguez Reinoso y A. Sepúlveda Carbon dioxide subtraction (CDS) method applied to a wide range of porous carbons Studies Surface Sci. and Catal. 39,173-182 (1988) 78. J.D. López González, I. Bautista y F. Rodríguez Reinoso Preparation and study of the surface in first stage grafito/CdCl2 intercallation compounds An. Quim. 84, 15-20 (1988) 77. F. Rodríguez Reinoso, I.Rodríguez Ramos, C.Moreno, A. Guerrero y J.D. López González Platinum catalysts supported on activated carbons. II. Isomerization and hydrogenolysis of n-butane. J. Catal. 107, 1-7 (1987) 76. J.Garrido, A.Linares Solano, J.M.Martín, M.Molina, F.Rodríguez Reinoso y R. Torregrosa The effect of gasification by air or CO2 in the development of microporosity in activated carbons. J. Chem. Soc., Faraday Trans. I 83, 1081-1088 (1987) F. Rodríguez Reinoso, J.M. Martín Martínez, C. Prado Burguete and B. McEnaney A standard adsorption isotherm for the characterization of activated carbons. J. Phys. Chem. 91, 515-516 (1987) 75. J. Garrido, A. Linares Solano, J.M. Martín, M. Molina, F. Rodríguez Reinoso and R. Torregrosa Use of N2 vs. CO2 in the characterization of Activated Carbons Langmuir 3, 76-81 (1987) 74. A. Linares Solano, C. Salinas Martínez de Lecea, F. Rodríguez Reinoso and M. Almela Alarcón Anomalous increase in CO2 reactivity, relative to steam and air on acid treatment of coals Fuel 65, 1345-1348 (1986) 73. F. Rodríguez Reinoso, A. Guerrero-Ruiz, C. Moreno, I. Rodríguez and J.D. López Gonzalez Effect of hydrogen reduction on the surface characteristics of carbon-supported iron and Ruthenium catalysts Appl. Catal. 23, 299-307 (1986) 72. J.D. López González, F. Rodríguez Reinoso, I. Bautista Toledo

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Second stage graphite//CdCL2 intercalation compounds from different types of graphite An. Quim. 82, 246-251 (1986) 71. F. Rodríguez Reinoso Preparation and characterization of activated carbons NATO.ASI 105, 601-644 (1986) 70. A. Marcilla, M. Molina Sabio y F. Rodríguez Reinoso A new working procedure to calculate pore size distributions. J. Catal. 99, 226-230 (1986) 69. J.A. Garrido, J.M. Martín Martínez, M. Molina Sabio, F. Rodríguez Reinoso, R. Torregrosa Adsorption of hydrocarbons on CO2-reacted activated carbons Carbon 24, 469-475 (1986) 68. J.M. Martín Martínez, B. McEnaney, M. Molina Sabio y F. Rodríguez Reinoso Application of the isotherm subtraction and preadsorption methods to activated carbons Carbon 24, 255-259 (1986) 67. F.Rodríguez Reinoso, I.Rodríguez Ramos, C.Moreno Castilla, A.Guerrero, J.D.López González Pt catalysts supported on activated carbons. I. Preparation and characterization J. Catal. 99, 171-183 (1986) 66. A. Guerrero Ruiz, J.D. López González, I. Rodríguez Ramos, F. Rodríguez Reinoso he hydrogenation of CO2 on Fe/carbon catalysts. React. Kinet. Catal. Lett. 31, 349-354 (1986) 65. F. Rodríguez Reinoso, A. Guerrero, J.D. López González The hydrogenation of CO on carbon supported Fe catalysts prepared from Fe(CO)5 Appl. Catal. 21, 251-261 (1986) 64. I. Rodríguez Ramos, F. Rodríguez Reinoso, A. Guerrero, J.D. López González Hydrogenation of CO and CO2 on carbon black supported Ru catalysts J. Chem. Techn. Biotechnol. 36, 67-73 (1986) 63. F. Rodríguez Reinoso Activated carbon with molecular sieving properties Interfaces et Transport de Materie, 431-464 (1985) 62. F. Rodríguez Reinoso, J.M.Martín Martínez, M. Molina, R. Torregrosa Maciá y J. Garrido Evaluation of the microporosity in activated carbons by n-nonane preadsorption. J. Colloid & Interf. Sci. 106, 315-323 (1985) 61. F. Rodríguez Reinoso, C. Moreno, A. Guerrero Ruiz, I. Rodríguez Ramos y J.D. López González The effect of inorganic constituents of the support on the characteristics of carbon-supported platinum catalysts. Appl. Catal. 15, 293-300 (1985) 60. Rodríguez Reinoso, J.M. Martín Martínez, M. Molina, I. Pérez Lledó y C. Prado Burguete A comparison of the porous texture of two CO2 activated botanic materials. Carbon 23, 19-24 (1985) 59. M. Molina Sabio, C. Salinas, F. Rodríguez Reinoso, C. Puente Ruiz, A. Linares Solano

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A comparison of different tests to evaluate the apparent surface area of activated carbons Carbon 23, 91-96 (1985) 58. A. Linares Solano, F. Rodríguez Reinoso, J.M. Martín Martínez, J.D. López González Adsorption of hydrocarbons on air-reacted activated carbons. II. High and low pressure hysteresis Ads. Sci. & Technol. 1, 317-327 (1984) 57. F.Rodríguez Reinoso, J.D.López González, C.Moreno Castilla, A.Guerrero I. Rodríguez Porous carbon as support for iron and rethenium catalysts Fuel 63, 1089-1094 (1984) 56. A. Linares Solano, J.D. López González, J.M. Martín Martínez y F. Rodríguez Reinoso The two-stage air CO2 activation in the preparation of activated carbons. II. Characterization by adsorption from solution Ads. Sci. & Technol. 1, 223-234 (1984) 55. F. Rodríguez Reinoso, A. Linares Solano, M. Molina Sabio, J.D. López González The two-stage air-CO2 activation in the preparation of activated carbons. I. Characterization by gas adsorption. Ads. Sci. & Technol. 1, 211-222 (1984) 54. J.M. Martín Martínez, A. Linares, F. Rodríguez Reinoso, J.D. López González Adsorption of hydrocarbons on air-reacted activated carbons. I. Adsorption isotherms. Ads. Sci. & Technol. 1, 195-204 (1984) 53. A. Linares Solano, J.D. López González, J.M. Martín Martínez y F. Rodríguez Reinoso The n-nonane preadsorption method applied to activated carbons Ads. Sci. & Technol. 1, 123-132 (1984) 52. F. Rodríguez Reinoso, A. Linares Solano, J.M. Martín Martínez The controlled reaction of active carbons with air at 350°C. II. Evolution of microporosity Carbon 22, 123-130 (1984) 51. F. Rodríguez Reinoso, F.J. López Gzarzón, C. Moreno Castilla. A. Guerrero, J.D. López González High temperature adsorption of hydrocarbons by activated carbons prepared from olive stones Ads. Sci. & Technol. 1, 133-109 (1984) 50. F. Rodríguez Reinoso, J.D. López González, C. Berenguer Activated carbons from almond shells. II. Characterization ot the pore structure Carbon 22, 13-18 (1984) 49. F. Rodríguez Reinoso, J.D. López González, C. Berenguer Activated carbons from almond shells. I. Preparation and characterization by nitrogen adsorption. Carbon 20, 513-518 (1982) 48. F. Rodríguez Reinoso, J.D. López González, J. Rivera Utrilla The adsorption of N2 and Ar on samples of CdCl2 with different degree of surface homogeneity Surface Sci.120, 431-440 (1982) 47. J.D. López González, C. Moreno Castilla, A. Guerrero, F. Rodríguez Reinoso Effect of carbon-oxygen and carbon-sulphur surface complexes on the adsorption of mercuric chloride in aqueous solution by activated carbons J.Chem. Techn. Biotechnol 32, 575-579 (1982)

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46. F. Rodríguez Reinoso Les agregats metalliques sur support dan la catalyse heterogene In Entre l'atome et le crystal: les agregats", 475-486 (1982) 45. F.Rodríguez Reinoso, J.D.López González, I.Bautista, Y.Grillet, J.Rouquerol and F. Rouquerol Seeking for a possible correlation between the existence of a crossing point of the adsorption isotherms and the state... nitride system. Studies Surface Sci. and Catal., 10, 495-501 (1982) 44. J.D. López González, F. Rodríguez Reinoso The crossing isotherms at different temperatures in relation to the surface homogeneity of solids Studies Surface Sci. and Catal., 10, 479-488 (1982) 43. A. Linares, F. Rodríguez Reinoso, A. Garrido Torres-Puchol y J.D. López González Carbons from copolymer Saran. III. Hg prosiemtry and adsorption of phenol and methylene blue An. Quim. 78, 263-269 (1982) 42. J:D. López González, F. Rodríguez Reinoso, A. Linares Solano, A. Garrido Torres-Puchol Carbons from copolymer Saran. II. Adsorption of CO2 and n-C4H10 at 273K An. Quim. 78, 173-178 (1982) 41. F.Rodríguez Reinoso, A. Linares Solano, A. Garrido Torres-Puchol y J.D. López González Carbons from copolymer Saran. I. Preparation and adsorption of N2 at 77 K An. Quim. 78, 166-172 (1982) 40. F. Rodríguez Reinoso, J.D. López González, J. Rivera Utrilla The crossing of N2 adsorption isotherms on CdCl2 Surface Sci.114, 7-9 (1982) 39. R.G. Jenkins, A. Linares Solano, F. Rodríguez Reinoso, C. Salinas, P.L. Walker, Jr. Platinum catalysts supported on graphitized carbon black. II. Characterization of the platinum by small-agle X-ray scattering and transmision electron microscopy Carbon 20, 185-189 (1982) 38 A. Linares Solano, P. Mahajan, F. Rodríguez Reinoso, C. Salinas, P. Walker, Jr. Platinum catalysts supported on graphitized carbon black. I. Characterization of the platium by titrations and differential calorimetry. Carbon 20, 177-184 (1982) 37 F. Rodríguez, A.Ramírez, J.D. López , C. Valenzuela , L. Zurita Activation of a sepiolite with diluted solutions of HNO3, and subsequent heat treatments. III. Development of porosity Clay Minerals 16, 315-323 (1981) 36 F. Rodríguez Reinoso, J.D. López González y C. Moreno Castilla Adsorptive behaviour of an exfoliated graphite. An. Quim. 77, 16-18 (1981) 35. C. Salinas, A. Linares Solano, J.D. López González, F. Rodríguez Reinoso Development of porosity and surface heterogeneity upon air activation of graphitized carbon black. Carbon, 19, 65-70 (1981) 34. J. Bonilla, J.D. López González, A. Ramírez, F. Rodríguez Reinoso

34

Activation of a sepiolite with diluted solutions of HNO3 and subsequent heat treatments. II. Determination of surface acid centers. Clay Minerals 16, 173-179 (1981) 33. J.D. López González, A. Ramírez, F. Rodríguez Reinoso, C. Valenzuela Activation of a sepiolite with diluid solutions of HNO3 and heat treatment. I. Study of the surface area. Clay Minerals 16, 103-113 (1981) 32. J.D. López González, F. Martínez Vilchez, F. Rodríguez Reinoso Preparation and characterization of active carbons from olive stones. Carbon 18, 413-418 (1980) 31. J.D. López González, A. Martín Pozuelo, F. Rodríguez Reinoso Adsorption of methanol and ethanol on graphite oxides An. Quim. 76, 329-336 (1980) 30. J.D. López González, L. Ramírez, F. Rodríguez Reinoso, C. Valenzuela Acid and termal activation of vermiculite from Benahavis. II. Evolution of surface area. An. Quim. 76, 43-47 (1980) 29. J.D. López González, L. Ramiréz Pérez, F. Rodríguez Reinoso y C. Valenzuela Acid and termal activation of vermiculite from Benahavis. I. Evolution of textura and surface activity An. Quim. 76, 27-32 (1980) 28. A. Linares Solano, J.D. López González, M. Molina Sabio, F. Rodríguez Reinoso Active carbons from almond shells as adsorbents in gas and liquid phases J. Chem. Techn. Biotechnol. 30, 65-72 (1980) 27. F. Rodríguez Reinoso, J.D. López González Applications de la chimisorption a la caracterisation de catalyseurs In Etats de surface et la liaison Chimique III.5, 1-39 (1979) 26. P. González Vilchez, A. Linares Solano, J.D. López González y F. Rodríguez Reinoso The controlled reaction of active carbons with air at 350°C. I Reactivity and changes in surface area. Carbon 17, 441-446 (1979) 25. F. Rodríguez Reinoso, J.D. López González y A. Martín Pozuelo Adsorption-desorptionn of ethylene glycol on graphite oxides from diferent graphites An. Quim. 75, 452-454 (1979) 24. F. Rodríguez Reinoso, A. Martín Pozuelo, J.D. López González, A. Martín Rodríguez Characterization of graphite oxides from different graphites An. Quim. 75, 448-451 (1979) 23. A. Jiménez López, J. Saez, F. Rodríguez Reinoso y C. Valenzuela Evolution of surface area in a sepiolite as a function of acid and heat treatment. Clay Minerals 13, 375-385 (1978) 22. A. Linares Solano, J.D. López González, C. Moreno Castilla y F. Rodríguez Reinoso Changes in surface homogeneity of a graphite upon gasification Carbon 16, 397-401 (1978) 21. J.D. López González, C.Valenzuela, A Jiménez López, A. Ramirez y F. Rodríguez Reinoso

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Retention of n-butylamine on an activated sepiolite. II. Isotherms An. Quim. 74, 220-224 (1978) 20. J.D. López González, F. Rodríguez Reinoso, L. Zurita Herrera Electron microscopy study of the carbon-oxygen reaction on pyrolitic carbon An. Quim. 73, 1460-1463 /1977) 19. J.D. López González, F. Rodríguez Reinoso, L. Zurita Herrera Topografic análisis of the carbon-oxygen reaction on pyrolitic carbon An. Quim. 73, 1447-1454 81977) 18. J.D. López González, F. Rodríguez Reinoso, L. Zurita Herrera Anisotropy in the carbon-oxygen reaction on pyrolitic carbon An. Quim. 73, 1432-1436 (1977) 17. J.D. López González, F. Rodríguez Reinoso, L. Zurita Herrera Kinetics of the carbon-oxygen reaction on pyrolitic carbon An. Quim. 73, 661-666 (1977) 16. J.D. López González, F. Rodríguez Reinoso, C. Moreno Castilla Thermodynamics of monolayer formation of adsorbed gas on homogeneous carbon surfaces An. Quim. 73, 497-503 (1977) 15. J.D. López González, F. Rodríguez Reinoso, M.A. Bañares, C. Moreno Castilla Evolution of surface area of graphite when oxidised to graphite oxide An. Quim. 72, 759-767 (1976) 14. F. Rodríguez Reinoso, J.D. López González, A. Linares Solano Transformations in the surface of graphite alter reaction with oxygen at 600°C. An. Quim. 73, 491-496 (1977) 13, J.D. López González, F. Rodríguez Reinoso, M.A. Bañares Muñoz y C. Moreno Castilla Surface area of an artificial graphite by gas adsorption An. Quim. 72, 643-650 (1976) 12. J.D. López González, F. Rodríguez Reinoso, M.A. Bañares Muñoz y C. Moreno Castilla Thermodynamics of nitrogen and argon adsorption on mineral graphite An. Quim. 72, 637-642 (1976) 11. J.D. López González, F. Rodríguez Reinoso, M.A. Bañares y A. Linares Solano Nitrogen adsorption isotherms on a mineral graphite An. Quim. 72, 441-449 (1986) 10. E.L. Evans, J.D. López González, A. Martín Rodríguez y F. Rodríguez Reinoso Kinetics of the formation of graphite oxide Carbon 13, 461-464 (1975) 9. A. Martín Rodríguez, F. Rodríguez Reinoso, J.D. López González y A. Martín Pozuelo Oxidation of pyrolitic graphite. Microscopic study An. Quim. 71, 488-484 (1975) 8. G.R. Rellick, F. Rodríguez Reinoso, P.A. Thrower, P.L. Walker Transient rates in the reaction of CO2 with highly oriented pyrolytic graphite Carbon 13, 81-82 (1975) 7. F. Rodríguez Reinoso, P.L. Walker, Jr.

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Reaction of glassy carbon with oxygen Carbon 13, 7-10 (1975) 6. F. Rodríguez Reinoso, P.A. Thrower Microscopic studies of oxidized highly oriented pyrolytic graphites. Carbon 12, 269-279 (1974) 5. F. Rodríguez Reinoso, P.A. Thrower and P.L. Walker Jr. Kinetic studies of the oxidation of highly oriented pyrolytic graphites Carbon 12, 63-70 (1974) 4. .J. Cole, D.J.Everett, C.T. Marshall, A.R. Paniego, J.C. Powl y F. Rodríguez Reinoso Thermodynamics of the high temperature adsorption of some permanent gases by porous carbons. J. Chem. Soc. Faraday Trans. 70, 2154-2169 (1973) 3. M. Iley, H. Harsh y F. Rodríguez Reinoso The adsorptive properties of carbonized olive stones Carbon 11, 633-638 (1973) 2. J.D. López González y F. Rodríguez Reinoso Preparation of activated carbon from olive stones. II. Activation and surface area An. Quim. 68, 977-987 (1972) 1. J.D. López González y F. Rodríguez Reinoso Preparation of activated carbon from olive stones. I. Carbonization and characterization of products An. Quim, 68, 135-140 (1972)                       

37

                             

Research Projects                            

38

     

Research Projetcs  

  

1. Preparation of activated carbons from agricultural by-products CAICYT 795/81         From: 1982    until: 1985          €  111.079,06 IP  

2. Creation of Centro de Adsorción y Catálisis Caja de Ahorros Provincial de Alicante   From 1983    until: 1993          €   91.353,84 IP  

3. Adsorption on microporous solids Acción Integrada Hispano‐Británica 2/59 y 3/3 Universidad de Alicante y University of Bath From: 1984    until: 1986          €  3.000 IP  

4. Supported metallic catalysts. Characterization and catalytic activity. CAICYT 996/84 From:1985    until: 1988          €  26.444,53 IP  

5. Bimetallic Fe clusters supported on carbon as catalysts for the synthesis of elefines from syn gas. C.C. Hispano-Norteamericano CBS-8504030 Universidad de Alicante y Pennsylvania State University From: 1986    until: 1987          €   15.025,30 IP  

6. Catalytic activity and selectivity of bimetallyc catalysts supported on carbon. CICYT PB86/279 From: 1987    until: 1990          €   58.298,17 IP  

7. Agricultural and industrial application of almond shells. Consellería de Agricultura y Pesca. Generalitat Valenciana From: 1998    until: 1989          €  11.419,23 IP  

8. Infrastructure Consellería de Educación y Ciencia. Generalitat Valenciana (GV‐IN97‐0356)        From:   1988    until: 1988          €   48.080,97 IP  

9. Infrastructure DGICYT (INF97‐0356MAT)     From: 1988    until: 1988          €   78.131,57 IP  

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10. Treatment and conditioning of radioactive graphite from nuclear reactors. European Comission F1.20.0017.ES(JR)     From: 1990    until: 1993          €   100.970,03 IP  

11. Development of industrial adsorbents CYTED‐D. Subprograma V, Proyecto V.2 Several countries in Iberoamérica From: 1990    until: 1993          €  155.000. IP  

12. Monte Carlo SIMULATION OF adsorption on microporous solids Generalidad Valenciana/Estancia Prof. Zgrablich From: 1992    until: 1992          €    4.808,10 IP  

13. Porosity in activated carbon. Advance in its design and characterization  DGICYT. PB91‐0747 From: 1992    until: 1995          €   112.990,28 IP  

14. Preparation and characterization of special ativated carbons. Generalitat Valenciana/Visit Prof. B. McEnaney From: 1992    until: 1992          €  4.500 IP  

15. Support to the research on carbon materials   Fundación Cultural CAM  From: 1993    until: 1996          €  81.000 IP  

16. Development of binderless carbon-mesophase for production of high strength graphites European Comission BRITE‐EURAM (BRE2.CT94.0901)  From: 01/04/1994  until: 30/03/1997          €  239.637,77 IP  

17. Development of new types of active carbons, inorganic oxides and phosphates as selective adsorbents and carriers for catalysts and their application in industry European Comission INTAS (93‐2725)  From: 01/01/1994  until: 31/12/1997          €  4.000 IP  

18. Development of carbon mesophase for production of high strength raphites (supplementary) DGICYT, CE94‐0029 From: 1995    until: 1996          €   21.035,42 IP  

19. Development of adsorbent for gas separation CYTED. Subprograma V. Project V.3   Several groups in Iberoamérica From: 01/01/1995  until: 31/12/1998          €   168.283,38 IP  

20. Development of carbon mesophase for production of high strength graphites (complementary) MEC, SAB95‐0086. Sabattical Professor H. Marsh   

40

From: 01/01/1995  until: 31/08/1997          €   32.003,89 IP  

21. Preparation of activated carbons for gas separation/storage DGICYT, PB 94‐1500   From: 01/08/1995  until: 01/08/1998           €   55.293,11 IP   

22. Preparation of carbon molecular sieves for the separation of nitrogen from air MEC-I. Coop. Iberoamericana

Universidad de Alicante; CINDECA (La Plata, Argentina) From: 01/01/1995  until: 31/12/1997          €   10.818,22 IP   

23. Preparation and characterization of composites ceramic-ceramic and metal-ceramic CICYT, MAT96‐1048   From: 01/07/1996  until: 30/06/1999          €   51.687,04 IP  

24. Certification of pore size reference materials SMT4‐CT95‐2025 (European Union)   From: 01/01/1997  until: 31/12/1997          €   3.800,00 IP  

25. Study of catalysts supported on carbon molecular sieves MEC‐ I. Cooperación Iberoamericana  Universidad de Alicante; Universidad de La Habana (Cuba) From: 01/01/1997  until: 31/12/1998          €   11.419,23 IP  

26. Removal  of  common  environmental  pollutants  from  gas  and  liquid  phase  using  catalytic  systems  supported  on  surface modified adsorbents C.E.E. INTAS (95‐1041)   From: 01/01/1996  until:31/12/1998          €   4.000,00 IP  

27. Infrastructur (XPS) (IN97‐0356MAT) DIGICYT   From: 1997    until: 1997          €   126.212,54 IP  

28. Infrastructure (XPS) (IN97‐0356) COMPLEMENTARY Genaralitat Valenciana   From: 1997    until: 1997          €   42.070,85 IP  

29. Automotive components made out of high strength isotropic graphite by a cost‐effective technology U.E., BRITE‐EURAM (BRPR‐CT97‐0482)    From: 01/01/1998  until: 31/12/2001          €   246.414,96 

41

IP  

30. Formation  and development of microporosity  in precursors  and polymer‐pyrolysed  activated  carbons with  regard  to  the separation, concentration and storage of methane C.E.E. INTAS (96‐1023)   From: 01/01/1998  until: 31/12/1999          €   4.000,00 IP  

31. Separation and purification of iso‐butane from refinery and petrochemial efluents CICYT. QUI98‐0663    From: 01/09/1998  until: 31/08/2000          €   82.759,37 IP  

32. Synthesis  and  processing  of mesophase  carbon microspheres  (MMC)  for  the  preparation  of  high density graphite CICYT‐PETRI 95‐0267‐OP    From: 20/11/1998  until: 20/11/2000          €   87.146,76 IP  

33. Synthesis of pieces and components with high resistance to abrasion from aluminium composites UE. Fondos Feder    From: 1999    until: 31/12/2001          €  224.478,02   

34. Infrastructure High resolution TEM (INF99‐15‐1129). Generalitat Valenciana    From: 1999    until: 1999          €   270.455,45 IP 

 35. Development of a series of adsorbents based on sepiolite as humidity controllers 

CICYT (PTR1995‐0429‐OP)    From: 07/04/2000  until: 06/04/2001          €   42.671,86 IP  

36. Support for Research Groups Generalitat Valenciana (GR00‐224)   From: 01/01/2000  until: 31/12/2000          €   9.015,18 IP  

37. Support for research groups. Desulfurization of gasoline  Universidad de Alicante    From: 01/01/2000  until: 31/12/2000          €   18.921,85 IP  

38. Catalysts with strong metal‐support interaction fir the selective hydrogenation of unsaturated  MEC (BQU2000‐0467)   From 01/10/2000   until 30/9/2003         €   144.723,71 IP  

39. Infrastructure. Adsorption microcalorimter Generalitat Valenciana (INFO1‐28)    From: 2001    until: 2001          €   78.131,57 

42

IP  

40. Optimization of sintering of carbon mesophase for special graphites MEC (PTR1995‐0551‐OP) From: 02/10/2001  until: 30/09/2003          €  96.161,94 IP  

41. Iberoamerican network for environmental protection CYTED (Red V.F.: Coordinador Internacional)    From: September 2001    until: Augost 2005 (US$ 40.000/year)    €   176.000,00 IP  

42. Pt‐Sn y Pt‐Zn catalyst supported on carbon and zeolites for dehydrogenation of light alkanes Generalitat Valenciana  (GV01‐346)    From: 2002    until: 2003          €  13.815,18   

43. Advanced lightweight graphite based composite components for  low emisión combustión engines (ALICE) U.E. (G3RD‐CT‐2002‐00799. V Programa)    From: July 2002   until: July 2007          €   339.121,00 IP  

44. Organization of Congress International COPS ‐ VI MEC (BQU2001‐4359‐E)     From:   2002      until:  2002        €   3.005,06 IP  

45. Organization of Congress International COPS – VI (complementary) Generalitat Valenciana (CTCOOR/2002/71)     From:   2002    until:  2002          €   3.000,06 IP  

46. Organizatio of Congress International COPS – VI (supplementary) Fundación BANCAJA‐U. ALICANTE      From:   2002    until:  2002          €   3.606,07 IP  

47. Removal of VOCs by adsorption and catalysis Generalitat Valenciana (CTIDIB/2002/161)     From:  January 2002    hasta: December 2003      €   35.000,00 IP  

48. Support for hte research group LMA Universidad de Alicante  From: January 2003  hasta: December 2007        €   79.562,89 IP 

 49. Manufacture of metal‐ceramic coposites with low thermal expansion coefficient 

MEC            From:   2002    until: 2004           €   71.881,05   

50. PtSn y RuSn catalysts supported on partically reducible ocides for selective hydrogenation MCyT (BQU2003‐6150)           From: November 2003  until: October 2006         €   140.000,00 IP 

43

 51. Programa Senior, Prof. H. Marsh 

Universidad de Alicante         From: Septembre 2003    hasta: March 2004       €   18.000,00 IP  

52. Support for group LMA. Generalitat Valenciana Generalitat Valenciana (GRUPOS03/212)  From: December 2003  until: Diecember 2003         €  38.773,86 IP  

53. Special support CICYT. (BQU 2002‐10448‐E)         From: March 2004  until: December 2004         €  21.000,00 IP  

54. Materials for Extreme Environments (Extremat) UE (NMP3‐CT‐2004‐500253)   From: Novembre 2004    until: October 2008        €  398.000,00 IP  

55. In‐situ Study and Development of Processes Involving Nano‐porous Solids. INSIDE‐PORES Network of Excellence Insidepores UE (NMP3‐CT‐2004‐500895)     From: October 2004  until: September 2008        €  450.000,00 IP  

56. Nanoporous carbon materials for gas storage MEC (MAT 2004‐03480‐CO2‐02)      From: 13/12/2004  until: 12/12/2007        €  69.000,00  

 57. Infrastructure 

MEC (FEDER)         From: 01/07/2005  until: 30/06/2006        €  52.214,49 IP 

 58. Development of nanoporous material for environmental catalysis 

MEC  NAN2004‐09267‐CO3       From: 31/12/2005  until: 31/12/2008        €  69.000,00   

59. Carbon monoliths for the removal from residual water Ministerio de Asuntos Exteriores y de Cooperación (Marroco)          From: 24/01/2006  until: 24/01/2007        €  10.748,00   

60. Infraestructure: graphitization furnace MEC. MAT2006‐26552‐E         From: 01/10/2006  until: 31/12/2007        €  75.000,00 IP  

61. New carbon‐supported catalysts for preferential CO oxidation in fuel cell technology Ministerio de Educación y Ciencia (Acciones Integradas España‐Austria, HU2006‐0002)      From: 01/01/2007  until: 31/12/2008        €  9.800,00 IP  

44

62. Development  of  catalysts  supported  on  carbon  materials  for  the  preferential  oxidation  of  CO (PROX) Ministerio de Educación y Ciencia. RyC 2137/06 From: 01/12/2006  until: 30/11/2011        €  15.000,00 IP  

63. In  situ  study  and  development  of  processes  involving  nanoporous  solids  (INSIDEPORES) (complementary) Generalitat Valenciana. ACOMP/2007/049 From: 01/01/2007  until: 31/12/2007        €  20.000,00 IP  

64. Development of new nanomaterials for production, purification and storage of biohydrogen Ministerio de Educación y Ciencia. MAT2007‐61734 From:  01/10/2007  until: 30/09/2010         €  471.900,00  

65. Development  of  catalysts  supported  on  nanostructured  carbon  materials  for  environmental applications Ministerio de Educación y Ciencia (Acciones Integradas España‐Portugal) From:  01/01/2008  until: 31/12/2009         €  8.000,00    

66. Advanced First Response Respiratory Protection. FRESP. Contract 218138. UE Contract 218138 From:  01/06/2008  until: 30/11/2011         €  367.000,00  IP 

 67. Catalysts for the catalytic oxidation of phenolic compounds in industrial efluents 

Agencia Española de Cooperación Internacional From:  01/01/2008  until: 31/12/2008         €  7.000,00    

68. Development of nanomaterials for energetic and environmental applications PROMETEO/209/002 From:  01/01/2009  until: 31/12/2009         €  47.500,00    

69. Título del proyecto: Nanostructured carbon monoliths for storage and conversion of methane. Japan‐Spain (PLE 2009‐0052) From:  01/11/2009  until: 31/10/2012         €  225.400,00  IP 

Total in projects (1982­2009): € 6.211.653 (US$ 9.192,246)             

45

                     

Research Contracts                    

46

   

Research Contracts  

1. Reduced vapour pressure storage Shell International From:1986 until: 1989 € 126.212,54 IP 2. Analysis of coke calcination Repsol Petróleo, S.A. From: 1987 until: 1987 € 5.709,61 IP

3. Analysis of coke calcination (II) Repsol Petróleo, S.A. From:1988 until: 1989 € 35.459,71 IP 4. Carbon-supported catalysts Repsol Petróleo, S.A. From: 1988 until: 1988 € 8.654,57 IP 5. Preparation of SiC and SiC/Al composites INESPAL From: 1988 until: 1988 € 6.010,12 IP 6. Carbon supported catalysts: hydrotreating reactions Repsol Petróleo, S.A. From:1989 until: 1990 € 21.035,42 IP

7. Reactivity of petroleum coke in air and CO2 Repsol Petróleo, S.A. From: 1989 hasta: 1991 € 24.040,48 Investigador responsable: F. Rodríguez Reinoso Número de Investigadores participantes: 2   8. Production of mesocarbon microbeads Repsol Petróleo, S.A. From: 1990 until: 1991 € 69.116,39 IP 9. Preparation (laboratory and pilot plant) of activated carbon from olive pits ICASA, S.A. From: 1991 until: 1992 € 38.197,62 IP 10. Activated carbon for NBC applications Filtros y Energía, S.A. From: 1991 until: 1992 € 41.135,67 IP

47

11. Manufacture of fibres and carbon cloth from viscous rayon. INESCOP From: 1991 until: 1992 € 20.826,27 IP 12. Graphitization of microspheres, characterization and applications Repsol Petróleo, S.A. From: 1991 until: 1992 € 69.116,39 IP

13. Development of new carbon materials from petroleum residues Repsol Petróleo, S.A. From: 1992 until: 1994 € 94.459,02 IP 14. Disign, construction and optimization of a plant fro the production of MMC Repsol Petróleo, S.A. From: 1993 until: 1995 € 79333 IP 15. Adsortptiver properties of sepiolite and smectite for gases and liquids TOLSA From: 1994 until 1994 € 4607 IP 16. Design and construction of a pilot plant for the production of activated carbon cloth. TEXTIFLOK From: 1995 until: 1996 € 18030 IP 17. Characterization of activated carbons Canales del Taibilla From: 1995 until: 1995 € 1051 IP 18. Analisis of feasibility of using sepiolite in industrial adsorption processes TOLSA From: 1995 until: 1996 # 31997 IP

19. Preparation and control of activated carbons ICASA From: 1996 until: 1997 € 17.816,00 IP 20. Study of sepiolite and sepiolite-carbon as industrial adsorbents (I) TOLSA From: 1997 until: 1997 € 37.515,18 IP 21. Manufacture of activated carbon for NBC clothing. F.N. La Marañosa From: 1997 until: 1997 € 26.841,20 IP 22. Analysis of the variables of extraction and sintering of MMC. Repsol Petróleo S.A . From:1997 until:1997 € 10.121,04

48

IP 23. Carbonization of two petroleum residues at two different temperatures. The Carbide/Graphite Group`, INC . From:1998 until:1998 € 4.014,76 IP 24. Study of sepiolite and sepiolite-carbon as industrial adsorbents (II) TOLSA From: 1998 until: 1998 € 18.300,82 IP 25. Fabrication of a special activated carbon material (I) Fabrica Nacional de la Marañosa From: 1998 until: 1998 € 18.030,36 IP 26. Study of sepiolite and sepiolite-carbon as industrial adsorbents .(III) TOLSA From: 1998 until: 1998 € 10.229,23 IP 27. Separation and purification of iso-butane in refinery and petrochemical efluents 28. REPSOL, Petróleo. From: 1998 until: 1998 € 20.915,22 IP 29. Fabrication of a special activated carbon material (II) Fabrica Nacional “La Marañosa”. From: 1999 until 1999 € 18.030 IP 30. Determination of isotherms at high pressure in samples supplied by air liquide Air Liquide, S.A. From: 2000 until: 2000 € 1.995,36 IP 31. Analysis of the feasibilty of deslphurization of gasoline with activated carbon. Repsol Petróleo, S.A. From: 01/05/2000 until: 01/08/2000 € 12.050,29 IP 32. Optimization of the carbonization of peroleum residues Repsol Petróleo, S.A. From: 01/10/2000 until: 31/01/2001 € 21.035,42 IP 33. The development of activated carbon for use in cigarette filters Carbon Limited From: 19/01/2001 until: 18/07/2001 € 20.000,00 IP 34. Development of adsorbents based on sepiolite as humidity controllers Tolsa, S.A. From: 01/07/2000 until: 30/06/2001 € 18.030,36 IP 35. Optimization of the sintering of mesophase for the fabrication of graphites.

49

Repsol Petroleo, S.A. From: /2001 until: /2002 IP 36. Chemical surface análisis by titrtion, TPD and XPS of samples of carbon black. BOREALIS AB. From: /2001 until: /2002 € 1.880,00 IP 37. Carbonization of aramyde fibres and felts Dupont Ibérica, S.L. From: 2002 until: 2003 € 8.000,00 IP 38. Characterization of special activated carbon samples prepared for adsorption purposes Carbon Limited From: 2003 until: 2003 € 5.000,00 IP 39. Treatment of activated carnpn cloth CARBONGEN From: March 2003 until: February 2004 € 38.860,00 IP 40. Monoliths preparation using Brazilian coconut shels, as precursor. Testing the monoliths PETROBRAS (Petroleo Brasileiro, S.A.) From: 2003 until: 2003 € 3.300,00 IP 41. Development of activated carbon for special purposes Carbon Limited From: 01/07/2003 until: 30/06/2004 € 60.000,00 IP 42. Preparation of activated carbon for natural gas storage PETROBRAS (Petroleo Brasileiro, S.A.) From: 13/12/2004 until: 12/12/2005 € 48.000,00 IP 43. The further development of activated carbon for use in cigarette filters Carbon Limited From: 01/09/2004 until: 30/11/2004 € 15.000,00 IP 44. Preparation in pilot plant of two activated carbons, desorption under vacuum of loaded activated carbon

Carbon Limited From: november 2004 until: october 2005 € 8.000,00 IP 45. Activated carbon cloth Carbongen, S.A. Work to be carried out in 2005 € 2.900,00 IP 46. Optimization of the synthesis of activated carbon for natural gas storage

PETROBRAS (Petroleo Brasileiro, S.A.) From: January 2007 until: July 2007 € 30.000,00 IP

50

47. Removal of hydrogen sulphide and syloxanes from biogas. Phase I

URBASER, S.A. From: october 2007 hasta: march2008 € 27.840,00 IP 48. Preliminary study of the treatment of residual waters in olives tteatment

BIOPARTNER, S.L. From: october 2007 until: marcg 2008 € 19.140,00 49. Carbonization of olive stones in a rotary kiln

REPSOL YPF, S.A. From: 03/04/2008 until: 20/04/2008 € 4.640,00 IP

50. Preparation of a carbpn material equivalent to petroleum coke. REPSOL YPF, S.A. From: 01/05/2008 until: 30/04/2009 € 41.760,00 IP 51. Removal of hydrogen sulphide and syloxanes from biogas. Phase II

URBASER, S.A. From: 01/10/2008 until: 30/09/2009 € 56.000,00 IP 52. Improvement in the manufacture of activated carbon from peanut shells

Consulting COTAGRO (Argentina). From: 01/04/2009 until: indefinido € variable IP Total industrial contracts (1986-2009): € 1.321,133 (US$ 1.940, 478)                   

51

                          

Ph.D. Supervised               

52

     

Ph.D. Supervised  

1. Title: Surface area and porosity of a mineral graphite Ph.D. student: Angel Linares Solano

University: Granada Year: 1974

2. Title: Analysis of the surface of an artifical graphite and its oxidation product Ph.D. student: Carlos Moreno Castilla

University: Granada Year: 1975

3. Title: Kinetic study of the reaction carbon-oxygen on higly oriented pyrolytic graphites. Ph.D. student: Luis Zurita Herrera University: Granada Year: 1977

4. Title: Formation of graphite oxide as a function of the crystaline perfection of the graphite. Ph.D. student: Antonina Martín Pozuelo University: Granada Year: 1977    

5. Title: Carbonization and activation of olive stones and the effect on the texture and adsorptive capacity of the resulting activated carbons.

Ph.D. student: Francisco Javier Martínez Vilchez University: Granada Year: 1978

6. Title: Characterization of platinum on catlysts supported on carbon. Ph.D. student: Concepción Salinas Martínez de Lecea

University: Granada Year: 1979

7. Title: Preparation and characterization of activated carbons from almond shells. Ph.D. student: Carmen Berenguer Melero University: Granada Year: 1980

8. Title: Sudy of the surface of some metl valides with layered structure. Ph.D. student: José Rivera Utrilla University: Granada Year: 1980

9. Title: Characterization of the porous texture of activated carbons using adsorbates with different molecular dimenssion.

Ph.D. student: José Miguel Martín Martínez University: Granada Year: 1981

10. Title: Comparison of different method of prepareation of activated carbon from agricultural by-products.

53

Ph.D. student: Miguel Molina Sabio University: Granada Year: 1981

11. Title: Carbon-supported catalysts of Fe and Ru for the hydrogenation of carbon monoxide. Ph.D. student: Antonio Guerrero Ruiz University: Granada Year 1983

12. Title: Sudy of the surface and porous texture of intercalation compounds graphite/cadmium halide. Ph.D. student: Isadora Bautista Toledo University: Granada Year: 1983

13. Title: Preparation and characterization of carbon supported platinum catalysts for the reaction of hydrogen withcN-C4H10

Ph.D. student: Inmaculada Rodríguez Ramos University: Granada Year: 1984

14. Title: Activated carbon from almond shells: effect of continuous activation with CO2 on the development of microporosity.

Ph.D. student: Rosa Torregrosa Maciá University: Alicante Year: 1984

15. Title: Characterization of the porous texture of activated carbon: anlysis of different experimental and theoretical methods.

Ph.D. student: Julian Garrido Segovia University: Alicante Year 1984

16. Title: Carbon-supported platinum catalysts. Effect of the nature of the support on the activity of the catalyst. Ph.D. student: Celia Ana Prado Burguete University: Alicante Year: 1987

17. Title: Comparative study of steam and carbon dioxide activation in the epreparation of activated carbon. Ph.D. student: Itziar Pérez Lledó University: Alicante Year: 1988

18. Title: Contribution to the use of leather waste Ph.D. student: A. Cesar Orgiles Barceló University: Alicante Year: 1988

19. Title: Porous structure of activqted carbons prepared from residues of leather waste with high content in Cr(III).

Ph.D. student: Miguel Angel Martínez Sánchez University: Alicante Year: 1988

20. Title: Fe catalysts supported on activated carbon for the hydrogenation of CO. Ph.D. student: Antonio Sepúlveda Escribano University: Alicante Year: 1989

21. Title: Adsorption of molecules of different polarity on activated carbon. Effect of porosity and surface

54

oxidation. Ph.D. student: Miguel Angel Muñecas Vidal University: Alicante Year: 1989

22. Title: Carbonization of petroleum residues. Mechanism and control. Ph.D. student: Eduardo Romero Palazón University: Alicante Year: 1990

23. Title: Effect of preparation conditions and additional treatments on the porosity of activated carbon. Ph.D. student: Ana María Gutierrez León University: Alicante Year: 1992

24. Title: Reactivity of petroleum coke. Ph.D. student: María Piedad Santana Blasco University: Alicante Year: 1992

25. Title: Interpretation of the process of petroleum residues carbonization. Ph.D. student: Ricardo Santamaría Ramírez University: Alicante Year: 1993

26. Title: Synthesis of structural ceramics (SiC, Si3N4, SiAlON) Ph.D. student: Francisco Javier Narciso Romero University: Alicante Year: 1993

27. Title: Comparative análisis of the activation with CO2 and H2O. Ph.D. student: Mª Teresa González Planelles University: Alicante Year: 1996

28. Title: Preparation of Pt/C catalysts for the selective hydrogenation of crotonaldehyde. Ph.D. student: Fernando Coloma Pacual University: Alicante Year: 1996

29. Title: Preparation of activated carbon cloth from viscose rayon. Ph.D. student: Angeles Carmen Pastor Amorós University: Alicante Year: 1997

30. Title: Kinetics of the carbonization process of petroleum residue. Ph.D. student: Manuel Martínez Escandell University: Alicante Year: 1997

31. Títle: Development of carbon molecular sieves for gas separation. Ph.D. student: Carlota Gómez de Salazar Catarineu University: Alicante Year: 2000

32. Títle: Production of special graphite by co-pyrolysis of petroleum residue and boron or Silicon compounds. Ph.D. student: Patricia Carreira Antón University: Alicante

55

Year: 2002 33. Títle: Bimetallic Pt-Zn catalysts in fine Chemicals síntesis.

PH.d. student: Joaquín Silvestre Albero University: Alicante Year: 2003

34. Títle: Activated carbon cloth as support for Pt-Sn catalysts. Promoter effect of TiO2. Ph.D. student: Ana Huidobro Pahissa Universidad: Alicante Facultad/ Escuela: Ciencias Año: 2003

35. Título: Preparación y caracterización de carbones y grafitos reforzados con carburo de silicio Doctorando: Jorge Sánchez Coronado University: Alicante Year : 2004

36. Títle: Preparation of activated carbon discs for the storage of methane. Ph.D. student: Cristina Almansa Carrascosa University: Alicante Year: 2004

37. Títle: Preparation of Silicon carbide pieces reinforced with refractory silicides by reactive infiltration. Ph.D. student: Roberto Arpón Carballo University: Alicante Year: 2006

38. Títle: Pt y Pt-Sn catalysts supported on material based on CeO2. Application to the selective hydrogenation of unsaturaded aldehydes.

Ph.D. student: Juan Carlos Serrano Ruiz University: Alicante Year: 2006

39. Títle: Preparation of composites by infiltration of graphite with light alloys. Ph.D. student: Segundo Antonio Sánchez Martínez University: Alicante Year: 2007

40. Títle: Use of activated carbon in the renoval of propanethyol and benzothyophene. Ph.D. student: Rachel Vieira Ribeiro Azzi Rios University: Alicante Year: 2008

41. Títle: Adsorption of methane on ZnCl2 and H3PO4 activated carbons Ph.D. student: Yoshiteru Nakagawa University: Alicante Year: 2008

42. Títle: Catalysts based on ZnO for the selective hydrogenation of α, β-unsaturated aldehydes. Ph.D. student: Enrique Vicente Ramos Fernández University: Alicante Year: 2008

43. Títle: Development of graphites doped with metals for application under extreme conditions. Ph.D. student: José Manuel Ramos Fernández University: Alicante Year: 2009

56

44. Títle: Pt y Sn catalysts supported on titanium oxide for the selective hydrogenation of unsaturated aldehydes and production of hydrogen from alcohols.

Ph.D. student: Javier Ruiz Martínez University: Alicante Year: 2009

45. Títle: Silicon carbide by reactive infiltration: mechanism and new sythesis routes Ph.D. student: Noelia Rojo Calderón

University: Alicante Year: 2009

46. Títle: Production of special graphites from self-sintering carbon materials Ph.D. student: Julio Llorca Pocel

University: Alicante Year: 2009

                               

57

                           

Patents              

58

     

Patents  

1. López González, J.D., Rodríguez Reinoso, F., Martínez Vilchez Preparation of activted carbon form olive Stones and olive oil resdues Nº : Spanish 426439 Year:1974 Propietary: Universidad de Granada Countries: Soain

2. Rodríguez Reinoso, F., Molina Sabio, M., Caturla, F., Buss, G.Y. Process for the preparation of activated carbon Nº GB 8803404 y EP 0329251 Year:1989 Propietary: Shell International Research Countries: Most of the world

3. C. Gómez, E. Romero, F, Rodríguez Reinoso, R. Santamaría Procedure for producing carbon mesophase microspheres and the corresponding carbon artifacts. Nº Spanish P 920143 Year:1993 Propietary: Repsol Petróleo Countries: Spain

4. A.C. Orgilés, M.A. Martínez, F. Rodríguez Reinoso, V. Valero. Preparation of activated carbon cloth and its application in shoe industry. Nº : P2023773 (1992) Year: 1993 Propietary : Inescop. Countries: Spain

5. A. Linares, J. Narciso, F. Rodríguez Reinoso Procedure for the shyntesis of sialon by nitriding Spanish coal and graphites. Nº : P9101586 (1995) Year: 1995 Propietary : Universidad de Alicante Countries: Spain  

6. C. Gómez de Salazar, E. Romero, R. Santamaría y F. Rodríguez Reinoso Process for producing carbon mesophase and the corresponding carbon artefacts Nº EP0585193B1 Year: 1997 Propietary: Repsol Petróleo Countries: Europe  

7. F. Rodríguez Reinoso, M. Molina Sabio, C. Almansa Carrascosa

Procedure for producing activated carbon monolitos and its applications. Nº : Spanish P009902459 AÑO: 2003 Propietary: Universidad de Alicante Countries: Spain

59

                            

Plenary and invited Lectures               

60

      

Plenary and Invited Lectures  1985 Invited lecture Preparation and characterization of activated carbons NATO's Carbon and Coal Gasification Alvor (Portugal)                             1986 Conference The use of carbon as catalyst support Bergbau‐Forschung Essen (Alemania)         1989 Plnary lecture An overview of methods for the characterization of activated carbon  IUPAC Symposium on  Adsoprption and Chromatography Moscow (URSS)    1991 Invited lecture Controlled gasification and pore structure development NATO's Fundamental Issues on Control of Carbon Gasification Reactivity Cadarache (France)      1991 Plenary lecture Characterization of microporous carbons Russian Meeting on Adsorption (Dubinin's Meeting)  Moscow (URSS)        1991 Invited lecture Chemical  and/or  thermal  activation  of  lignocellulosic materials:  effect  on  adsorptive  properties  of carbons. Workshop on Adsorbent Carbon Center for Applied Energy Research, Lexington, Kentucky (USA)     1991 Plenary lecture1991 Carbon molecuar sieves I Taller Iberoamericano de Tamices Moleculares Caracas (Venezuela)          1991 Plenary lecture Recent advances in the technology of activated carbon XIX Jornadas Chilenas de Química Concepción (Chile)       1991 Invited lectue The control of chemical and/or physical activation in the preparation of activated carbon Materiaux Adsorbant Carbonees Vert le Petit, Paris (France)      1992 Invited lecture Present and future of activated carbon 

61

Colombian Seminar on Activated Carbon Medellín (Colombia)         1992 Invited lecture Carbon as catalyst support II Taller Iberoamericano sobre Tamices Moleculares   Oaxaca (Mexico)             1992 Invited lecture Adsorption of CO2 on Porous and Non‐porous carbons Workshop on Fractal and Physically Adsorbed Molecular States Chiba (Japón)        1993 Invited lecture Advanced structural ceramics UNED summer courses Avila  (Spain)        1993 Invited lecture Steam activation of lignocellulosic materials Workshop on Adsorbent Carbons Center for Applied Energy Research, Lexington, Kentucky (USA)      1993 Invited lecture Activated carbon: structure, characterization, preparation and applications Short Course on Carbon Technology Buffalo (USA)        1994 Plenary Lecture Activated carbon; a versatile material CYTED 94 Caracas (Venezuela)           1995 Invited lecture Carbon molecular sieves ACTO: Course UNIDO "Procesos catalíticos en refinación y petroquímica Caracas (Venezuela)           1996 Invited lecture New carbon/graphite materials Cycle “Research in Inorganic Chemistry in Spain” University of Madrid, Spain   1997 Plenary lecture The role of carbon materials in heterogeneous catalysis Carbon’97 Pennsylvania State University (USA)   1997 Invited lecture Textural and chemical characterization of porous carbons Workshop “From anstroms to millimeter” Princeton University (USA)   1999 Invited lecture Heterogeneus catalysts based on carbon Hispano‐French Meeting on catalysis de Catálisis Barcelona    

62

2000 Invited lecture Development of activated charcoal cloth at pilot plant scale Conference of European Ministries of Defenseia  Madrid (Spain)   2000 Invited lecture Use of activated carbon in water treatment Congress on Environmental Catalysis Huelva (Spain)                                        2000 Invited lecture Characterization of microporous solids by immersion calorimetry TRI/ Princeton Workshop Princeton (USA)                                         2001 Plenary lecture Activated carbon: structure, properties and applications Carbón activado: estructura, preparación y aplicaciones XXII Congress AMIDIR Mazatlán (México) 2001 Plenary lecture Agricultural by-products as precursors for new materials XXI Congress Colombian Chemcial Engineering Bogotá (Colombia) 2003 Invited lecture Role of chemical activation in the development of carbon porosity Princeton Workshop Princeton (USA) 2005 Plenary lecture The uniqueness of activated carbon for gas separation and storage Carbon 2005 Gyeongju (Korea)   2005 Plenary lecture Gas separation and storage  on microporous carbons XXX Biennial Congressa Spanish Royal Society of Chemistry Lugo (Spain) 2005 Invited lecture Porous carbons in gas separation and storage NATO Advanced Research Workshop Kiev (Ukraine)   2005 Invited lecture Carbon Materials in Heterogeneus Catalysis Gordon Research Conference Hydroicarbon Resources Ventura. California (USA)    2006 Invited lecture Role of porosity and functionality of activated carbon in adsorption processes 4th Pacific Basin Adsorption Science and Technology Tianjin (China)    

63

2006 Invited lecture Role of porosity and functionality in the removal of sulfur‐containing compounds in fuels by activated carbon TRI Princeton Workshop Princeton (USA)   2006 Invited lecture Liquid phase adsorption/oxidation of sulphur containing species by acrivated carbon NATO Advanced Research Workshop Kiev (Ukraine)    2007 Invited lecture Recent advances in the development of activated carbon American University in el Cairo Cairo (Egipt)    2007 Invited lecture Principles of adsorption III Insidepores Workshop Thessaloniki (Grecia))  2007 Invited lecture Synthesis of adsorbents Nanomempro Woprkshop EFI Zaragoza (España)    2008 Invited lecture Self‐sintering carbon discs for sustainable chemistry Future Challenges for Carbon‐based Nanoporous Materials Chiba (Japón)    2009 Plenary lecture Actual challenges in the technology of activated carbon I symposium of adsorption, adsorbents and applications San Luis (Argentina) 2009 Invited lecture CO2 adsorption/storage on activated carbon Advanced porous materials for CO2 adsorption Liblice (República Checa) 2009 Invited lecture Common problems in the characterization of microporous carbons by gas adsorption CPM‐5 Rutgers University (USA)     

 

  

64

            

Presentations in Congresses      

300+ in International congresses 350+ in Spanish congresses 

     

65

          

Miscellaneous                       

66

Miscellaneous  

  Editorial Board of "Adsorption Science and Technology", since 1983.   Advisory Editorial Board of "Carbon", from 1984 to 1990.   Vicepresident for research, Universidad de Alicante, 1984 & 1985.   Research Award  FICIA, 1987.   Editor of Carbon, since 1991   President of the Spanish Carbon Group , 1991‐1999.   International coordinator of the project INTAS 93‐2725, 1994‐1997   International coordinator of the Iberoamerican project V.3  CYTED, 1995‐1998   International Coordinator of the Iberoamerican Network of Adsorents for a clean 

Environment, 200‐2005   Member of the Academy of Science of Granada, since 1999   Editor of the books:   "Characterization of Porous Solids II", Elsevier (1991)   "Characterization of Porous Solids III", Elsevier (1994)   "Science and Technology of Activated Carbon", Fundación CAM (1994)   "Introduction to Carbon Tecnology", Universidad de Alicante (1996)   “Characterization of Porous Solids IV”, The Royal Society, U.K. (1997)   “Characterization of Porous Solids VI”. Elsevier (2000)   “Characterization of Porous Solids VII” Elsevier (2004)   “Characterization of Porous Solids VIII”. Royal Society of Chemistry (2008)  Professorship Sanford (Universidad de los Andes, Bogotá), since 2001  Visiting Profesor  (Center    for  Frontier Electronics  and Photonics – Universidad  

Chiba, Japón) Oct‐Nov 2001  Consultant for NATO “Science for Peace”, since 2002  Japan Carbon Award, 2008