deepak nitrite ltd. -...

M/s Deepak Nitrite .Ltd

Pproposed modernization project of Synthetic Organic chemicals and allied products

aat Plot No.: 1-7 & 26-31, Dhatav MIDC, Roha, Raigad.-402116, Maharashtra Pre-Feasibility Report

PFR for M/s. Deepak Nitrite .Ltd. Prepared by Goldfinch Engineering Systems Pvt. Ltd.

DEEPAK NITRITE LTD.

PFR for Environmental Clearance (EC) of proposed expansion project of

manufacturing of Speciality Chemicals & intermediates at Plot No.: 1-7 & 26-31,

Dhatav MIDC, Roha, Raigad.-402116, Maharashtra.

© Goldfinch Environmental Engineering Systems Private Limited (‘Goldfinch’), November 2016

This report is released for the use of the M/s Deepak Nitrite Ltd. (DNL). Regulators and relevant

stakeholders solely as part of the subject EC of Proposed modernization project of

Manufacturing of Synthetic organic chemicals and allied products at existing manufacturing

facility located at plot No-1-7 & 26-31, Dhatav MIDC, Roha, Raigad.-402116, Maharashtra.

Information provided (unless attributed to referenced third parties) is otherwise copyrighted and

shall not be used for any other purpose without the written consent of Goldfinch/DNL.

QUALITY CONTROL

Name of

Publication

Deepak Nitrite Ltd Proposed modernization project of Manufacturing

Synthetic organic chemicals and allied products at Plot No-1-7 & 26-31,

Dhatav MIDC, Roha, Raigad.-402116, Maharashtra

Project Number Report

No. 1

Versio

n 1 Released

December,

2016

Prepared By Dr. Nivedita Kulkarni & Mr. Umesh Parab

Reviewed By Mr. K. N. Sharma

Released By Mr. Anand Apte

DISCLAIMER

Goldfinch has taken all reasonable precautions in the preparation of this report as per its

auditable quality plan. Goldfinch also believes that the facts presented in the report are based on

information submitted by DNL and based on the technical expertise of Goldfinch as on the date it

was written. However, it is impossible to dismiss absolutely, the possibility of errors or

omissions. Goldfinch therefore specifically disclaims any liability resulting from the use or

application of the information contained in this report. The information is not intended to serve

as legal advice related to the individual situation.





Index

EXECUTIVE SUMMARY .................................................................................................... 5

1.0 INTRODUCTION OF THE PROJECT ........................................................................... 6

1.1 Introduction of the Project ............................................................................... 6

1.2 Introduction of the Project Proponent ................................................................ 6

1.3 Brief description of nature of the project…....………………………….…………………..………..7

1.4 Need for the project and its importance to the country and or region ..................... 7

1.5 Demands-Supply Gap ...................................................................................... 8

1.6 Imports vs. Indigenous Production .................................................................... 8

1.7 Domestic /Export Markets ................................................................................ 8

1.8 Employment Generation due to the project ........................................................ 8

2.0 PROJECT DESCRIPTION ........................................................................................... 9

2.1 Type of Project ............................................................................................... 9

2.2 Project Location .............................................................................................. 9

2.3 Details of alternate sites considered and the basis of selecting the proposed site .. 12

2.4 Size or Magnitude of Operation .................................................................... 12

Size/Magnitude of Proposed By-Production Capacity ......................................... 14

2.5 PROCESS DESCRIPTION ............................................................................... 15

2.6 Raw material required along with estimated quantity, likely source, marketing area

of final Product/s, mode of transport of raw material and finished product. .......... 60

Raw Materials: ............................................................................................. 60

Source for Raw Material Procurement: ............................................................ 60

Mode of Transport of Raw Materials: ............................................................... 60

Storage at the site: ...................................................................................... 60

Raw Materials are stored in storage yard at the project site. Location of storage yard

is demarcated in Layout Plan. ........................................................................ 60

2.7 Resource optimization/recycling and reuse envisaged in the project................... 61

2.8 Availability of water its source, energy/power requirement and source ................ 61

2.8.1 Water Requirement and Source ................................................................... 61

Recycled water from STP will be near about 30 CMD which will be used for

gardening, floor washing flushing, spraying on coal etc. ................................ 61

2.8.2 Power Requirement .................................................................................... 61

2.8.2.1 Emergency power ........................................................................................ 62

2.9 Quantity of wastes to be generated (liquid and solid) and scheme for their





management/disposal ................................................................................... 63

2.9.1 Gaseous Emissions ....................................................................................... 63

2.9.2 Effluent ....................................................................................................... 65

Existing treatment Scheme for Trade Effluent .................................................. 65

2.9.3 Details of Hazardous wastes ........................................................................... 67

2.10 Schematic representations of the feasibility drawing which give information of EIA

purpose.. .................................................................................................... 69

3.0 SITE ANALYSIS .......................................................................................... 70

3.1 Connectivity ................................................................................................. 70

3.2 Land Form, Land use and Land ownership ........................................................ 70

3.3 Topography ................................................................................................. 70

3.4 Existing land use pattern (agriculture, non-agriculture, forest, water bodies

(including area under CRZ)), shortest distances from the periphery of the project

to periphery of the forests, nationa park, wild life sanctuary, eco sensitive areas,

water bodies (distance from HFL of the river), CRZ. .......................................... 71

3.5 Soil classification .......................................................................................... 71

3.6 Climatic data from secondary sources ........................................................... 71

3.7 Social Infrastructure Availability .................................................................... 71

4.0 Planning In Brief ...................................................................................... 72

4.1 Planning Concept ......................................................................................... 72

4.2 Land Use Planning ........................................................................................ 72

4.3 Assessment of Infrastructure Demand (Physical & Social) ................................. 72

4.4 Amenities/Facilities ...................................................................................... 73

4.5 Population Projection .................................................................................... 73

5.0 Existing infrastructure ................................................................................... 74

5.1 Industrial area .............................................................................................. 74

5.2 Residential Area ............................................................................................ 74

5.3 Green Belt .................................................................................................... 74

5.4 Social Infrastructure ...................................................................................... 74

5.5 Connectivity ................................................................................................. 74

5.6 Drinking Water Management ......................................................................... 75

5.7 Sewage System ........................................................................................... 75

5.8 Industrial Water Management ........................................................................ 75

5.9 Solid Waste Management ............................................................................. 75





5.10 Power Requirement & Supply / source ............................................................ 75

6.0 Rehabilitation and Resettlement (R & R) Plan .......................................... 76

6.1 Policy to be adopted (Central/State) in respect of the project affected persons

including home oustees, land oustees and landless. ........................................... 76

7.0 PROJECT SCHEDULE & COST ESTIMATES ................................................. 77

7.1 Likely date of start of construction and likely date of completion .......................... 77

7.2 Estimated project cost along with analysis in terms of economic viability of the

project ......................................................................................................... 77

Economic Viability .......................................................................................... 77

8.0 ANALYSIS OF PROPOSAL (FINAL RECOMMENDATIONS) .......................... 78





EXECUTIVE SUMMARY

Deepak Nitrite is a leading supplier of organic, inorganic and fine chemicals to global

chemical majors. The Deepak Nitrite Ltd.(DNL)is a multi-division and multi-product company with

manufacturing facilities at Nandesari and Dahej in Gujarat, Roha and Taloja in Maharashtra, and

at Hyderabad in Andhra Pradesh.

Deepak Nitrite aggressively works towards adopting the principles of responsible

chemistry and stands among 18 Indian companies to be accredited with Responsible Care

certification - towards global environment, safety and health management.

The proposed products covered under application shall save $ 5 million foreign exchange

for the country since they are import substitutes and besides which some of them will generate

$10 million of exchange for our country through their export. Needless to say that these

initiatives shall be our contribution to Make in India movement and shall generate additional

profits for the company and revenue for the states.

DNL proposed modernization project of manufacturing of synthetic organic chemicals and

allied products at existing manufacturing unit at Plot No. 1-7 & 26-31, Dhatav MIDC, Roha,

Raigad.-402116, Maharashtra. The proposed project falls under classification 5(f) of schedules

listed in EIA notification SO1533 dated 14/09/2006. Its appraisal category is B-1.

Project Synopsis:

Sr.

No

Parameters Description

1. Category as per EIA Notification 5 (f ) B

2. Longitude 73.159346 N

3. Latitude 18.428720 E

4. Production Capacity after product

mix

740MT/M, and By-products 371 MT/M

5. Total Plot Area /Built up area 26624.00 sq. m./ 10331 sq. m

6. Green Belt Area 2581 sq. m.

7. Fresh Water Requirement 519 CMD

8. Effluent Quantity (Trade +

Domestic)

243 CMD + 31 CMD = 274 CMD

9.

Trade Effluent Treatment 243 CMD effluents are presently treated in ETP of

capacity 400 CMD. It is consists of primary,

secondary and tertiary treatment. Treated water

will be discharged to CETP Mahad for final disposal

into sea.

10.

Domestic Waste water Treatment 31 CMD treatment in Sewage treatment plan

having capacity 35 CMD. Treated domestic waste

will be recycle and reuse for cooling tower and

gardening

11.

Fuel requirement at full load Boiler: 8 TPH X 1 no : 32.83 TPD

(Type Fuel: Indonesian Coal)

6 TPH X 1 no : 20.53 TPD (Type Fuel:

Indonesian Coal and 9 TPD(Type Fuel: Farnese





Sr.

No

Parameters Description

Oil)

Thermopack 6 lac Kcal/hr X 1no = 1

TPD (Coal)/ 0.5 TPD (FO)

D G set = 750 KVA X 2 no

500 KVA X 1 no

Fuel Required = 6 TPD

(Type Fuel: HSDl)

12. Power Requirement 2100 KW

13. Dispersion of emission for Boiler

and Thermopac

Stack Height: 34 m stack for boiler and common

stack for boiler (6TPH) and thermo Pac 24.5m.

14. Dispersion of emission DG Sets, Stack Height : 4.5m above enclosure

15. Work Force 220no.

16. Total Capital Cost the project (Cr) Rs 38.60 Cr.

1.0 INTRODUCTION OF THE PROJECT

1.1 Introduction of the Project

Deepak Nitrite Ltd. (Hereafter being referred as DNL for brevity in this text) intends to

modernize/product mix of existing projects in the category of synthetic organic chemicals and

allied products.

The existing manufacturing unit is in MIDC Dhatav; which is approved chemical

manufacturing zone of MIDC. DNL is located at plot no- 1-7 & 26-31. Existing manufacturing

capacity of the unit is 822 MT/M along with byprodtcs 371 MT/M. With this change in product mix

the total quantities of products and by-products will becomes 740 MT/M and 371 MT/M

respectively .

As per the EIA Notification S.O. 1533 dated 14th September 2006, proposed activity is

covered under Synthetic Organic Chemical Industry 5 (f) and needs prior environmental

clearance. Further, as the proposed industry is under category B. Since it is located in a notified

industrial area the project will not need public approval and is under category B.

1.2 Introduction of the Project Proponent

List of Directors and their designations

S.No. Name Designation

1 Mr. C.K. Mehta, Chairman-Emeritus

2 Mr. Deepak C. Mehta Chairman & Managing Director

3 Mr. Ajay C. Mehta Managing Director





4 Mr. Umesh Asaikar CEO & Executive Director

5 Mr. Maulik Mehta Whole-Time Director

1.3 Brief description of nature of the project

Existing manufacturing capacity of the unit is 822 MT/M along with byprodtcs 371 MT/M.

With this change in product mix the total quantities of products and by-products will becomes

740 MT/M and 371 MT/M respectively .

DNL have included all these products in four groups like Nitration/Hydrogenation based

products, Amine based products, Speciality products and Synthetic organic chemicals.

However, we have added new by-product 2NBTF(2 Nitro BTF) /2ABTF(2 Amino

BTF)/4ABTF(4 Amino BTF) (Qty.-41 MT/M which is generated from the existing product 3 Amino

BTF ) and OHBTF/OABTF (Qty.-20 MT/M) generated from TFMAP and increased the quantity of

existing by- product OT by 5 MT/M and decreased the quantity of existing by-product PPO(Poly

Phenylene Oxide) by 66 MT/M, The quantity of By-products Ortho Nitro Cumene (Qty.-150

MT/M) remains same as per existing consent.

1.4 Need for the project and its importance to the country and or

region

A global supplier of choice DNL build enduring relationships with leading chemical majors

offering a spectrum of ingredients used for multiple applications and in multiple

geographies.Capabilities include manufacturing of high-value synthetic organic chemicals and

allied products either based on our own end products or developed especially for users.


for the country since they are import substitutes and besides which some of them will generate

$10 million of exchange for our country through their export. Needless to say that these

initiatives shall be our contribution to Make in India movement and shall generate additional

profits for the company and revenue for the states.

Trusted supplier for leading global companies across more than 20 countries. DNL is a

global supplier of varieties of chemical Intermediates which are used in Agrochemicals,

Pharmaceuticals and other chemical industries. These products will serve to cut the supply of

imports from foreign countries thus saving currency and at the same time will earn valuable

foreign currency by export of the proposed products





1.5 Demands-Supply Gap

Competition in the Indian Chemical market swelled in recent years, with increasing

generic penetration. This had many companies opting out of low-margin segments, as

competition resulted in lower prices. This created a gap between demand and supply. Such

unusual price hikes take place when there is withdrawal of some of the key competitors, which

leads to demand override and as a consequence prices start soaring in a free-pricing market.

1.6 Imports vs. Indigenous Production

The proposed products including production of speciality chemicals having high in demand

in the export market. Also their demand is increasing in the domestic market. Production of these

products are domestically reduces the need to import these in future along with significant scope

for export in these products.

1.7 Domestic /Export Markets

The finished goods will be sold in domestic market and would be largely exported to the

Regulated International Market as per demand all over the world.

1.8 Employment Generation due to the project

Existing emplyopes are 220 no and are sufficient .





2.0 PROJECT DESCRIPTION

2.1 Type of Project

Proposed project is a modernization/product mix of existing products in the category of

synthetic organic chemicals and allied projects in existing manufacturing facility located at MIDC

Dhatav, Roha. It is included in category 5(f) B of EIA notification 2006.

2.2 Project Location

Existing manufacturing unit is located at Plot No. 1-7 & 26-31, Dhatav MIDC, Roha,

Raigad.-402116, State-Maharashtra. Major factories adjacent to the manufacturing unit are

Valentine Agro located on west side and Kores on south side, Sudarshan Chemicals Ltd is located

on east side there is. The site is well connected by road to Mumbai by Mumbai Goa (NH-66)

National Highway at 9 Km. It connects Panvel (south of Mumbai city) to Kanyakumari, passing

through the states of Maharashtra, Goa, Karnataka, Kerala and Tamil Nadu. Maharashtra State

Road Transport Corporation has a Bus Depot at Roha for public transport. Nearest railway station

is at Roha which is 7 Km away from site. The nearest airport is at Mumbai 117 km and Pune at

125 km.

Figure 2-1 : Google Image of the Site

Corner Latitude Longitude

A 18.429616 73.159346

B 18.428858 73.161322

C 18.428316 73.161098

D 18.428422 73.160796

E 18.427897 73.160583

F 18.427555 73.158853

center 18.428720 73.160039





Figure 2-2 : DNL Plot on Dhatav MIDC plan

Tank Farm for Nitration Plant

Green Belt Area





ETP with Clalifier

DEMAP Plant

Fig.2-3 : Photographs of Site Location





The project site is situated in MIDC Dhatav . It is a notified industrial area where the land

is owned by Maharashtra Industrial Development Corporation (MIDC) and leased to the

Company. The land is meant for industrial activity.The detail plant lay out is attched as

Annexure-I

Land Ownership: Land is owned by Maharashtra Industrial Development Corporation

(MIDC) and leased to the Company for 99 years.

2.3 Details of alternate sites considered and the basis of selecting the

proposed site

The proposal is for modernization/product mix of existing products in the same

manufacturing unit using existing infrastructure only hence consideration of alternate site is not

required

2.4 Size or Magnitude of Operation

The products manufactured and their capacities proposed are shown in below





Table 2.1.

Sr.

NO. Name of Existing Product

Existing

Capacity

Name of Proposed Product

Mix

Proposed

Capacity

1. Para Cumidine(PC) or 2 Ethyl

Hexy Nitrite 200

Para Cumidine(PC) or 3 Amino

Benzotri Flouride (3ABTF) 200

2.

Ortho Anisidine(OA) OR

Tri Methyl Hydro

Quinine(TMHQ)

75 Ortho Anisidine(OA) OR Tri

Methyl Hydro Quinine(TMHQ) 50

3.

2,4 Xylidine and 2,6 Xylidine

or nitrobenzene or


250


or2,3 Xylidine and 3,4 Xylidine

or2,5 Xylidine and 2,3

xylenol2,4 and 2,5 Xylenol

250

4. Meta Cholro Aniline Diphenyl

Amine Derivatives 50 Diphenyl Amine Derivatives 50

5.

Crystal Diethyl Meta Amino

Phenol(Cryst. DEMAP) or

Dibutyl Para Phenylene Di

amine (DBPPDA )

55

50

Crystal Diethyl Meta Amino

Phenol(Cryst. DEMAP) or

Dibutyl Para Phenylene Di

amine (DBPPDA or 3 NAP (3

Nitro Aceto Phenone)/ or

3AAP(3Amino Aceto Phenone)

or 3 HAP (3 Hydroxy Aceto

Phenone)

40

6.

TFMAP(3-

(trifloromethyl)acetophenon

MePPDA Sulphate (2 Methyl

P-phenylene Diamine

Sulphate) or

1,3 CHD(1,3 Cyclohexane

dione) or

4-NAX (Benenamine,N-(1-

ethyloropy)-3-4-dimethyl)

55

50

22

10

TFMAP(3-

(trifloromethyl)acetophenon 80

7.

Pilot Plant Products 1,3

CHD(1,3 Cyclohexane dione)

and

SMIA(syn Methoximino(2

furanyl)acetic acid

5

2 MePPDA Sulphate (2 Methyl

P-phenylene Diamine Sulphate)

or 1,3 CHD(1,3 Cyclohexane

dione)

60

8.

Pilot Plant Products

( synthetic Organic Chemicals) 10

Total 822 740





Size/Magnitude of Proposed By-Production Capacity

Sr.

NO.

Name of Existing by

Product

Existing

Capacity

Name of Proposed by

Product Mix

Proposed

Capacity

1.

Ortho Nitro

Cumene(from p-

cumidiene) 150

Ortho Nitro Cumene(from p-

cumidiene) 150

2.

PPO (Poly phenylene

Oxide) from

product tri methyle

hydro quinine 201

2 NBTF(2 Nitro BTF)/2

ABTF(2 Amino BTF)/

4 ABTF (4 Amino BTF) from

3 Amino BTF

41

3. Ortho Toludine(OT) 20 PPO (Poly phenylene Oxide) 135

4. OHBTF/OA BTF from TFMAP 20

5. Ortho Toludine(OT) 25

Total 371 Total 371





2.5 PROCESS DESCRIPTION

1. 3-Amino acetophenone (3-AAP)

Chemical Reaction:-

Process Description:-

In this step, we simultaneously take the required qty. of water, 10% Sulphuric acid, Iron

powder & Ammonium chloride into the reactor. Then we added the lot wise Iron powder & AAP

slowly into same mass by maintaining the reaction temperature. After completion of reaction, we

filtered out the reaction mass & removed the Iron powder, which recycled to the next batch. Then

we added the sod. Dithionate & chilled the reaction mass, after that we filtered out the AAP by

using Centrifuge. Wet AAP then dried into the dryer & we got finished AAP as a product.

O CH3

NO2

O CH3

NH2

3-NAP 3-AAP

540

+ 3 Fe3O4+ 9 Fe4 + 4 H2O 4

696504 72660





Block Diagram:-





2. 3-Hydroxy Acetophenone (3-HAP)

Chemical Reaction:-


STEP-1 Diazotization & Hydrolysis

In this step, we simultaneously take the required qty. of water, 98% Sulphuric acid, 3-

Aminoacetophenone & toluene into the reactor. Then we added the NaNO2 Solution slowly into

same mass by maintaining the reaction temperature. After completion of reaction, the reaction

mass cooled down up to 5°C & filtered out through Centrifuge. Wet 3-HAP then dried into the

dryer & we got crude 3-HAP. STEP-2 Purification

In this step, we simultaneously take the required qty of water, Methanol, wet cake

(3HAP) & charcoal into the reactor. Then heated the mass up to 60-65°C & maintained it for 1

hrs. Then filtered out the reaction mass through sparkler filter. The clarity of the reaction mass is

checked & the clear solution is taken into another reactor. Then filtered out the slurry mass

through centrifuge. The wet cake (3HAP) is being filled into the bags & Filtered ML transferred to

storage tank for recycling to next batch. Wet 3-HAP then dried into the dryer & we got finished

3-HAP as a product.

O CH3

NH2

O CH3

OH

3-AAP

135.16

+

3-HAP

136.2

++1/2 H2SO4NaNO2

Diazotization

Hydrolysis+ N21/2 Na2SO4 + H2O

49 69 71 28 18





Block Diagram:-





3. 3-Nitro Acetophenone (3-NAP)

Chemical Reaction:-


In this step, we simultaneously take the required qty. of Acetophenone, 98% Sulphuric

acid into the reactor at certain temperature. Then we added the Pre-cooled Mixed Acid (H2SO4 +

HNO3) slowly into same mass by maintaining the reaction temperature. After completion of

reaction, we quenched out the reaction mass by adding crushed ice. Then we filtered out the NAP

by using Centrifuge. Wet NAP then dried into the dryer under certain vacuum & we got finished

NAP as a product.

O CH3

HNO3

H2SO

4

O CH3

NO2

+

Acetophenone

120.15

3-NAP

165.15

+ H2O

Nitric acid

6318





Block Diagram:-





4. 3-Nitrobenzotrifluoride (3-Nitro BTF)

Chemical Reaction:-

Stage: 1 Preparation of 3-Nitrobenzotrifluoride (3-Nitro BTF)

Stage: 2 Preparation of 3-Aminobenzotrifluoride (3-Amino BTF)


1 The 3ABTF manufacturing is a four stage process Nitration, Nitromass Separation,

Hydrogenation & Hydromass Separation.

2 The BTF nitration is done to convert NBTF (Nitromass)

3 The Nitromass separation in to 2NBTF & 3NBTF.

4 The 3NBTF Hydrogenation to form ABTF Hydromass.

5 The 3ABTF Hydromass separation to 3ABTF & 4ABTF.

CF3 CF

3

NO2

BTF 3-NBTF

NitrationHNO3

146.11 191.11

+H2SO4

H2O+

CF3

NO2

CF3

NH2

191.11

5% Pd/C

Methanol

+ 3 H2 + 2 H2O

2.02 18.02

3-NBTF

191.11

3-ABTF

161.13





Block Diagram:-

Stage-I





Stage-II

5. Cyclohexadione (1, 3 CHD)

Chemical Reaction:-

Step-I





Step-II


STEP 1 - Hydrogenation.

In this Step, Hydrogenation is carried out in the presence of caustic lye. The Resorcinol is

charged into hydrogenation reactor. Hydrogenation addition is started at specified Temperature &

pressure. The temperature & pressure are maintained within specified limits during reaction.

After completion of reaction, Sodium salt of 1 3 cyclohexanedione formed & which is used for

further acidification process.

STEP 2 – Acidification

In this step, the required quantity of Sodium salt of 1 3 Cyclohexanedione is taken into

the reactor & then added the required quantity of 30 % HCL into the same. After complete

addition, 1 3 Cyclohexanedione formed which is filtered & dried in the dryer.

Block Diagram:-

Hydrogenation

ISOLATION





1, 3, CHD CRYSTALLISATION





6. 2, 3 Xylenol

Chemical Reaction:-


STEP 1 – Diazotization & Hydrolysis Reaction

In this step, we simultaneously take the required qty. of water, 98% Sulphuric acid, 2,3

Xylidine & MIBK into the reactor. Then we added the NaNO2 Solution slowly into same mass by

maintaining the reaction temperature. After completion of reaction, aqueous layer separated out

& organic mass then washed with 5 % soda soln. Then we transfer organics mass for further

distillation Process.

STEP 2 – Distillation

In this step we recovered MIBK, which is recycled back to Next diazotization Process &

Pure 2,3 Xylenol as a finished product.

NH2 CH3

NaNO

1/2 H2

+ Wate

MIBK





Block Diagram:-





7. 2, 4 Xylidine & 2,6 Xylidine

Chemical Reaction:-

Stage 1: Nitration of Meta-Xylene to 2, 6-Nitro Xylene and 2,4-Nitro Xylene

Stage -2: Separation/Distillation of Nitro-Xylene to 2,6-Nitro Xylene and 2,4-Nitro

Xylene

Stage-3 : Reduction of 2, 6-Nitro Xylene / 2,4-Nitro Xylene to 2,6-Xylidine / 2,4-

Xyledine

Process Description :-

Nitration of Meta-Xylene to 2,6-Nitro Xylene and 2,4-Nitro Xylene

1. Nitration is carried out using spent acid, sulfuric acid & Nitric acid. Along with these

compounds, the compound to be nitrated is continuously charged in to the reactors.

2. Reaction is conducted under controlled conditions as mentioned.





3. After completion of Nitration, Spent acid is seperated.

4. After Separation Nitro mass is washed in washer to remove acidity.

5. The washed Nitro mass is then send for further Distillation.

Reduction of 2, 6-Nitro Xylene / 2,4-Nitro Xylene to 2,6-Xylidine/2,4-Xyledine

1 Hydrogenation is carried out in presence of a catalyst. The compound to be hydrogenated is

charged into a Hydrogenation reactor.

2. Hydrogen addition is started at specified temperature. The reaction is conducted under

controlled conditions. The temperature and pressure are maintained within specified limits.

3 After complete reaction, catalyst filtered. And transferred it for Distillation.

4 The Process of hydrogenation of p- Nitrosamine, 2, 4 Nitro xylene, 2,6 Nitroxylene and o-Nitro

Anisole are same.





Block Diagram:-

Stage I





Stage II

Product 2,4 Xylidine





Product 2,6 Xylidine

8. 2, 5 Xylenol

Chemical Reaction:-


STEP 1 – Diazotization & Hydrolysis Reaction

In this step, we simultaneously take the required qty. of water, 98% Sulphuric acid, 2,5

Xylidine & MIBK into the reactor. Then we added the NaNO2 Solution slowly into same mass by

maintaining the reaction temperature. After completion of reaction, aqueous layer separated out

then we transfer organics mass for further distillation Process.

STEP 2 – Distillation

NH2

CH3

CH3

OH

CH3

CH3

1) NaNO2 + H2SO4

2 ) MIBK

3) 55- 60 o c





In this step we recovered MIBK, which is recycled back to Next diazotization Process &

Pure 2,5 Xylenol as a finished product.

Block Diagram:-





9. 2, 5 Xylidine

Stage I: Nitration of Para Xylene to Para Nitro Xylene

Stage II: Separation/Distillation of Para Nitro Xylene

Stage III: Reduction of Para Nitro Xylene.


Nitration of P-Xylene to Para Nitro Xylene

1. Nitration is carried out using a mixed acid. This mixed acid, which a mixture of nitric and

Sulphuric acid is to be prepared separately.

2. Add sulfuric Acid in the Reactor. Start addition of nitric acid so that the temperature

remains within specified limits.

3. Charge the compound to be Nitrated in the Reactor. Then add mixed acid gradually under

controlled conditions in the compound to be nitrated. The temperature of the reaction is

maintained within specified limits. A sample is drawn at the end of the addition of a defined

quantity to verify that the reaction is complete.

4. From the nitrated mixture, organic layer is separated and washed with water till free of

acid. The final Nitromass is to be transferred for Distillation.





Distillation

1. In the Distillation 2,5 Nitro Xylene is Separated as pure Product.

Hydrogenation Process:-

1 Hydrogenation is carried out in presence of a catalyst. The compound to be

hydrogenated is charged into a Hydrogenation reactor.

2 Hydrogen addition is started at specified temperature. The reaction is conducted under







Block diagram:-





10. Para Cumidine

Chemical Reaction:-

Stage I: Nitration of Cumene to Para Nitro Cumene and Ortho Nitro Cumene

Stage II: Separation/Distillation of Cumene to Para Nitro Cumene and Ortho Nitro

Cumene

Stage III: Reduction of Para Nitro Cumene.


Nitration of Cumene to Para Nitro Cumene and Ortho Nitro Cumene

1. Nitration is carried out using a mixed acid. This mixed acid, which a mixture of nitric and

Sulphuric acid is to be prepared separately.

2. Add sulfuric Acid in the Reactor. Start addition of nitric acid so that the temperature

remains within specified limits.

3. Charge the compound to be nitrated in the Reactor. Then add mixed acid gradually under

controlled conditions in the compound to be nitrated. The temperature of the reaction is

maintained within specified limits. A sample is drawn at the end of the addition of a defined

quantity to verify that the reaction is complete.

4. From the nitrated mixture, organic layer is separated and washed with water till free of acid.

The final Nitromass is to be transferred for Distillation.





Hydrogenation Process:-

1 Hydrogenation is carried out in presence of a catalyst. The compound to be hydrogenated is

charged into a Hydrogenation reactor.

2 Hydrogen addition is started at specified temperature. The reaction is conducted under



Block Diagram:-

Nitration





Distillation

Reduction





11. Meta Chloro Aniline (MCA)

Stage I: Chlorination of Nitro-Benzene to Nitro- ChloroBenzene

Stage II: Distillation of Nitro Chloro Benzene to Meta Nitro Chloro Benzene

Stage III: Reduction of Meta Nitro Chloro Benzene to Meta Chloro Aniline


1. Nitro Benzene Reacted with Chlorine in presence of Ferrous Chloride to Form Crude

Chloro Nitro Benzene

2. Meta Nitro Chloro Benzene is Separated from Crude Chloro Nitro Benzene in Distillation.

3. Meta Nitro Chloro Benzene is then reacted with Caustic Lye and Sulfur to form Meta

Chloro Aniline.





Block Diagram:-





12. 2 Methyl P- Phenylene Diamine Sulphate ( 2 MePPDA Sulfate )

Chemical Reaction:-

Step I - 2-Methyl-p-Phenelene diamine

Step II - 2-Methyl-p-Phenelene diamine sulfate


Step-I

1. 2-Methyl-p-Phenelene diamine is prepared by Hydrogenation in the presence of methanol

+ Rec. OT as a solvent.

Stage-II

2. 2-Methyl-p-Phenelene diamine Sulphate is prepared by reacting with sulfuric acid.

3. In filtration the solid 2-Methyl-p-Phenelene diamine sulphate is separated from mother

liquor.

Block Diagram:-

CH3

NH2

NH2

NH2

NH2

CH3

H2SO

4

H2SO

4





13. 4-Methoxy 2-Methyl Diphenyl Amine (MMDPA)

Chemical Reaction:-

Methylation





Bromination





Condensation

Hydrolysis






1. MMDPA is produced by carrying out reaction stages called Methylation, Bromination,

Condensation & Hydrolysis followed by purification stages.

2. Charge a measured quantity of water in to the methylation reactor. Then charge caustic lye

with specified strength from metering tank. Charge M-Cresol into the reactor.

3. Add DMS gradually.

4. Charge water in to reaction mass and then charge Sulphuric acid Separate aq. and organic

Layer.

5. Separate organic from the previous aq. layer, Collect the both organic layer.

6. Charge HBr of specified strength then charge measured quantity of 3-Me-Anisole in to the

reactor gradually. Start addition of Nitric Acid. Neutralize the mass and then allow the mass to

settle. Drain out the aqueous layer and collect the organic layer.

7. Charge measured quantity of 4-Br-3-Me Anisole into the reactor. Subsequently charge

measured quantity of Soda Ash, acetanilide, cuprous chloride & iodine. Heat gradually to the

temperatures and maintain subsequently.

8. Charge measured quantity of potassium hydroxide, Caustic & water into condensation mass.

Hydrolyzed the mass till specified temperature approaches.

9. Filter the mass & Separate the aqueous and organic layer.

10. Charge Crude MMDPA and Distill out.

11. Charge methanol followed by a measured quantity of semi pure MMDPA into the crystallizer.

12. Separated out the Solid MMDPA & Mother liquor from centrifuge.

13. Wet MMDPA dried out in RCVD.





Block Diagram:-

Methylation

Bromination

Condensation

Distillation





Crystallization

Drying

MeOH Distillation





14. Ortho Anicidine (OA)

Chemical Reaction:-

Stage I: Nitration of Anisole to Ortho Nitro Aniline

Stage II: Reduction of Ortho Nitro Anisole to Orhto Anicidine


Nitration of Anisole to Ortho Nitro Aniline

1. Mix Acid is prepared by Nitric and Sulfuric Acid.

2. Mix Acid is added to Anisole gradually.

3. Then Spent Acid is separated from ONA.

4. After washing ONA is send for reduction.

Reduction of Ortho Nitro Anisole to Orhto Anicidine





1. Ortho Nitro Anisole is reduced to Ortho Anicidine by hydrogen.

2. Then the crude OA is Distilled to have pure Ortho Anicidine

Block Diagram:-

Nitration





Reduction of ONA

15. 2,3-Xylidene and 3,4-Xylidene

Chemical Reaction:-

Stage I: Nitration of Ortho-Xylene to 2,3-Nitro Xylene and 3,4-Nitro Xylene

Stage II: Separation/Distillation of Nitro-Xylene to 2,3-Nitro Xylene and 3,4-Nitro

Xylene





Stage III: Reduction of 2, 3-Nitro Xylene and 3,4-Nitro Xylene to 2,3-Xyledine and 3,4-

Xyledine


Nitration of Ortho-Xylene to 2, 3-Nitro Xylene and 3,4-Nitro Xylene

1. Nitration is carried out using spent acid, sulfuric acid & Nitric acid. Along with these

compounds, the compound to be nitrated is continuously charged in to the reactors.

2. Reaction is conducted under controlled conditions as mentioned.

3. After completion of Nitration, Spent acid is separated.

4. After Separation Nitro mass is washed in washer to remove acidity.

5. The washed Nitro mass is then sending for further Distillation.

6. In the Distillation 2,3-Nitro Xylene and 3,4-Nitro Xylene is Separated as pure Product.

Reduction of 2,3-Nitro Xylene and 3,4-Nitro Xylene to 2,3-Xyledine and 3,4-Xyledine

1. 2, 3-Nitro Xylene is then reduced by Hydrogene to Produce 2,3-Xylidene.

2. 3, 4-Nitro Xylene is then reduced by Hydrogene and Catalyst to Produce 3,4-Xylidene.





Block Diagram:-

Nitration





Distillation





Reduction 2, 3-Xylidene

Reduction 3,4-Xylidene





16. 3'-(Trifluoromethyl) – acetophenone (TFMAP)

Chemical Reaction:-

Stage :- I Diazotization

Stage: - II Hydrolysis


Stage-I

1. 3'-(Trifluoromethyl)- acetophenone oxime is prepared by 3-amino-benzotrifluoride

diazotization and with acetaldoxime.

Stage-II

2. 3'-(Trifluoromethyl) - acetophenone is prepared by hydrolysis of 3- (Trifluoromethyl) -

acetophenone-oxime.

3. In Distillation 3'-(Trifluoromethyle)-Acetophenone is separated as finished product.

Block Diagram:-





17. TMHQ

Chemical Reaction:-


STEP 1 – Oxidation of TMP to TMBQ

In this step, TMBQ is prepared by oxidation of TMP with Hydrogen peroxide with

catalyst in presence of Methanol. The resultant reaction mass is filtered for recovery of

catalyst which is recycle back.

STEP 2 – Hydrogenation of TMBQ to TMHQ

In this step TMBQ prepared in the earlier step is hydrogenated using catalyst . The

hydromass is then separated from catalyst which is recycled back into system .The

filtered mass is then sent for solvent recovery

STEP 3 – Solvent recovery

Methanol is recovered in this step & methanol free reaction mass is sent for purification.

STEP 4 – Purification

The reaction mass free from methanol is purified, using Toluene, precipitated,

filtered t get crude TMHQ. The crude is treated with charcoal & then again purified with

solvent & reprecipitated. The final mass is again filtered through centrifuge to get wet

cake & the solvent is recovered & recycled back

STEP 5– Drying

The wet cake obtained from previous step is then dried in suitable dryer to get

finished product.

OH

CH3

+

N2 + 1/2 Na2S

+

2-

Me

2-Me

NH2





Block Diagram;-





2.6 Raw material required along with estimated quantity, likely source,

marketing area of final Product/s, mode of transport of raw material and

finished product.

Raw Materials:

The detailed raw material list for product mixed products as per selected capacity is

detailed below for all reactants, solvents and support chemicals.

Source for Raw Material Procurement:

Raw Materials are easily available in the local market, from Mumbai and Gujarat.

Part of the raw materials are generated In-house and used internally and some raw

material will be imported Viz.

Mode of Transport of Raw Materials:

Raw Materials will be transported through Trucks/ Tankers from suppliers factories

or traders go-downs. Those which are in house will be transported through internal

pipelines as per the requirements.

Storage at the site:

Raw Materials are stored in storage yard at the project site. Location of storage

yard is demarcated in Layout Plan.

Table 2-2: Details of Raw material Quantity





2.7 Resource optimization/recycling and reuse envisaged in the project

To conserve the water, various recycle/ reuse schemes will be implemented. Most

energy efficient technology is selected.

2.8 Availability of water its source, energy/power requirement and

source

2.8.1 Water Requirement and Source

Fresh water requirement of the project for domestic and industrial activity during

operation phase will be same as existing, which is 524 CMD. The existing source of water

supply is from MIDC. The details of water requirement are given below

Table 2-3: Details of Raw water consumption

S.

No.

Units Raw Water

Qty.(KLD)

A Process 328

B Utilities 156

1 Cooling water make up

2 Boiler make up

C Domestic 35

Total 519

D Gardening 15 ( Recycled from STP)

Recycled water from STP will be near about 30 CMD which will be used for

gardening, floor washing flushing, spraying on coal etc.

2.8.2 Power Requirement

Existing power requirement is 2100 KW and is sufficient for product mix. No extra

power is required. Source is State Electricity Board.





2.8.2.1 Emergency power

Existing 3 no of D. G. set having capacities 750 KVA (2 no) and 500 KVA (1 no.) are

sufficient to meet emergency power requirement

1.8.3.1 Utility Existing

Sr No Item Quantity Capacity Type Rating

1 Boiler -1 1 8 TPH

Imported

/Indian Coal

fired

Kg/cm2

Boiler -2 1 6 TPH FO based Kg/cm2

2 Thermopack 2 6 Lac Kcal

4 Lacs Kcal

Coal/

FO

0 C

3 D G Set 3 750(2 nos.)

500 (1 no.)

HSD --

Fuel Requirement

Sr

No Item Fuel

Quantity

required at

full load

1 Boiler Imported

Coal/FO

- 32.83 TPD

(Indian Coal)

- 20.53 TPD

(Imported

Coal)

- 9 TPD FO

2 Thermopack FO 1 TPD/

0.5 TPD

3 D G set HSD 6MTD





2.9 Quantity of wastes to be generated (liquid and solid) and scheme

for their management/disposal

2.9.1 Gaseous Emissions

Details of gaseous emissions from Process and Flue gas are given in Table 2-4

Table 2-4: Details of emissions from process and flue gas

Sr. No. Pollutant Source of Emission Concentration in

flue gas

1. SO2 Boiler (Coal)

Boiler(FO)

Thermopack (FO)

< 164.2 Kg/D

< 810 Kg/D

< 45 Kg/D

2. NOX -- --

3. CO -- --

4. Others -- --

5. PM10 Boiler <1 18 mg/Nm3





Details of stack are given in Table 2-5.

Table 2-5: Details stacks along with their mitigation methods

Attached to Boiler TPH Thermopack DG KVA

Existing Proposed Existing Proposed Existing Proposed

Capacity 08 (1 nos.)

06 (1 nos.) --

6 Lac Kcal

4 Lacs Kcal --

750(2 nos.)

500 (1 no.) --

Fuel type

Coal

FO

-- Coal/

FO -- HSD --

Fuel

quantity.

- 32.83 TPD

(Indian Coal)

- 20.53 TPD

(Imported

Coal)

- 9 TPD FO

--

1 TPD/

0.5 TPD

-- 6 TPD --

MOC MS --- MS -- MS --

Shape Round -- Round Round --

Height m

(above

ground

level)

- 34 M

- 24.5 M

Common for

Thermopack &

Boiler

--

24.5 M

Common for

Thermopack

& Boiler

4.5 each --

Mitigation

Measures

-cyclone with

Dust Collector

-Chimney &

Membrane

dust collector

--

Chimney &

Membrane

dust collector

Stack,

Acoustic

enclosure

Stack,

Acoustic

enclosure





2.9.2 Effluent

The quantity of effluent generated proposed project is given in Table 2.6

Table 2-6: Details of Effluent Generation

S.

No. Units

Effluent generation

(KLD)

A Process 234

B Utilities 9

1 Cooling water make up

2 Boiler water make up

Trade effluent Total 243

Domestic 31

Maximum effluent generation from the proposed product mix will be 247 LKD and

will be treated in existing ETP of capacity 400 KLD. Domestic effluent will be treated

separately in proposed STP. Treated domestic waste water will be reused for gardening,

floor washing flushing, spraying on coal etc.

Existing treatment Scheme for Trade Effluent

Primary Treatment

The system is designed to treat 400 KLD of waste water. Wastewaters from different

streams of process along with wastewater from cooling tower, boiler blow down etc. will be

collected in the Equalization Tank and air stripped. This effluent will be then be pumped to the

Flash Mixer where it is dosed with alum for coagulation. Flash Mixer is followed by a flocculator

where poly will be dosed for bigger flock formation. This effluent is overflowed into the settling

tank where the solids will be settled down and removed.

Secondary (Aerobic) Treatment:

The system will be designed to treat 400 KLD waste water. The neutralized effluent will

enter the bioreactor @ 16.5 m3 / hr. In the bio reactor, dissolved organic material is degraded

by the micro–organisms present in the bio reactor. Oxygen required for the oxidation of organic

matter will be provided by means of proposed diffuser aeration system which will mix the

contents of the bioreactor also. The mixed liquor will overflow into Secondary Settling Tank

(SST).

In the secondary settling tank, solid-liquid separation takes place and solids i.e. biomass will

settle at the bottom of the tank. Settled biomass will be recycled to the bio reactor for

maintaining the MLVSS concentration by using proposed sludge recycle pumps and excess

biomass will be wasted periodically to the sludge sump. Two stage treatments are proposed





where the overflow from the 1st stage clarifier will enter the 2nd stage bioreactor where the

non-degraded organics from the 1st stage bioreactor will be treated. The clear overflow from the

2nd stage Secondary Settling Tank will be Collection in the intermediate sump.

Tertiary Treatment:

The system will be designed to treat 400 KLD of waste water. The clear effluent from the

intermediate sump will be pumped by tertiary Feed pumps through the pressure sand filter

(PSF) & activated carbon filters. The final treated effluent will be Collection in the final

Collection tank from where it will be discharge to proposed upgraded CETP.

Sludge Handling:

Primary sludge, excess biomass from the secondary treatment and backwash water from PSF

will be collected in the sludge sump. From the sludge sump the sludge will be pumped to the

decanter for dewatering. The solid cake from the decanter will be sent for disposal to Hazardous

waste disposal site. The filtrate from the Filter press will be drained to the collection tank. Table

2-6: Design details and Performance Projection of ETP.





Table 2-6 Design Parameters for ETP

S.

No. Parameters Unit

Inlet Effluent

Characteristics

Outlet Effluent

Characteristics

Effluent

discharge

standards

(MPCB)

1 Design Quantity M3/day 247 247 --

2 pH ---- 4-9 6.9-7.3 6.5 -9.0

3 BOD3 270C mg/L 400-650 50-95 <100

4 COD mg/L 1500-2000 175-215 <250

5 TSS mg/L 350-450 35-75 <100

6 TDS mg/L 3000 1800 <2100

7 Oil & Grease mg/L 10 – 20 5-6 <10

Treatment Scheme for Domestic Wastewater

The sewage generated due to domestic activities will be treated separately in

proposed sewage treatment plant.

2.9.3 Details of Hazardous wastes

The types of Hazardous wastes generated from the project, method of disposal is

shown in below table below

Table 2-7: Details of Proposed Hazardous Solid waste along with the Category and

disposal method

S.

No. Waste Name

Categor

y

Quantity MTPA Form

(Sludge

/dry/

slurry)

Disposal Method Existin

g

Propos

ed

Tota

l

Hazardous Waste

1 Used Spent oil

(Kg) 5.1 91 -- 91 Liq.

Sale to Authorized

re processor

2

Spent Chemical

/ Acid

( T/M)

32.1 836 -- 836 solid Sale to Authorized

re processor

3 Spent

Chemicals 32.1 91 -- 91 solid

Sale to Authorized

re processor

4

Discarded

containers/barr

els/liner

33.3 25 -- 25 Liq/solid

To CHWTSDF

,Taloja/ Sale to

Authorized party

5

Chemical

sludge from

waste water

treatment

34.3 50 -- 50 Solid To CHWTSDF

,Taloja





S.

No. Waste Name

Categor

y

Quantity MTPA Form

(Sludge

/dry/

slurry)

Disposal Method Existin

g

Propos

ed

Tota

l

6 Spent catalyst 35.2 0.07 -- 0.07 Solid Send back to

Authorized party

7

Distillation

residue from

contaminated

organic

solvents

36.4 28 -- 28 Solid/Liq To CHWTSDF

,Taloja

Non- Hazardous Waste

1 Ash from boiler 2.50 T/day -- 2.50 T/day Sale to brick

manufacturer.

2 Insulating Material 2 T/A -- 2 T/A To CHWTSDF

,Taloja / Sale

3 Glass ware / Broken

Discarded Glass 1 T/A -- 1 T/A

To CHWTSDF

,Taloja / Sale

4 Non- hazardous

industrial waste 2 T/A -- 2 T/A

To CHWTSDF

,Taloja / Sale





2.10 Schematic representations of the feasibility drawing which give

information of EIA purpose.

Project Identification

What environmental impacts are normally associated with such type of projects being

proposed?

Pre-feasibility Analysis

Is the Project feasible from an environment point of view?

Project Design

(a) What negative environmental impacts could arise if the proposed project is implemented

with proposed design? (b) Is there alternative design with less environmental impacts?

Project Appraisal

Have all the environmental concerns associated with the project been eliminated?

Project Implementation

What environmental concerns might arise at the implementation phase of the project?

Preparation of an Environment Monitoring and Evaluation Plan

(a) What environment monitoring indicators are required to ensure that the

implementation of components of the project will be executed within

environmentally sound limits?

(b) What is required to ensure that the recommended environmental control

measures will be implemented and enforced?

(c)

(Prepare a comprehensive environment monitoring and management plan)

Post EIA Monitoring and Environment Audit

(a) Is the implementation of components of the project being executed in an

environmentally sound manner?

(b) Are all the recommended environmental control measures being implemented and

enforced?

(d) Are there any environmental impacts that were earlier not anticipated when EIA was

done?

( Identify gaps and corrective action )





3.0 SITE ANALYSIS

3.1 Connectivity

Proposed unit is planned at Plot No. 105, Dhatav MIDC, Roha, Raigad.-402116, Maharashtra.

The nearest city from the site is Roha at a distance of 5.0 Km

The nearest railway station is Roha at a distance of 7 Km from the site on Mumbai Goa

Manglore Kokan railway.

The nearest airport is at Mumbai 117 km and Pune at 125 km.

National Highway NH 66 (previously known as NH 17) passes through Kolad (9 km) It

connects Panvel (south of Mumbai city) to Kanyakumari, passing through the states of

Maharashtra, Goa, Karnataka, Kerala and Tamil Nadu. Maharashtra State Road Transport

Corporation has a Bus Depot at Roha for public transport.\

3.2 Land Form, Land use and Land ownership

The proposed land is situated in approved chemical zone of MIDC where land use

is industrial. Land is owned by MIDC and is leased for 99 years.

3.3 Topography

The proposed industry is located at Latitude - 18.4287200N and Longitude-

73.1600390. Elevation above mean sea level is: 12 m. Toposheet of the site is shown

below. The study area (10 km radius) around the project site exhibits flat terrain in the

east and relatively elevated terrain in the west side.

Figure 3.1: Toposheet Showing Project site and 10Km of area





3.4 Existing land use pattern (agriculture, non-agriculture, forest,

water bodies (including area under CRZ)), shortest distances from

the periphery of the project to periphery of the forests, national

park, wild life sanctuary, eco sensitive areas, water bodies

(distance from HFL of the river), CRZ.

Proposed site falls under the Industrial MIDC. The land is reserved for Industrial

use. River Kundalika is sufficiently away from project site.

3.5 Soil classification

There is sandy loam to clay in texture, yellowish in colour and under laid with murum

derived from the basic rock basalt.

3.6 Climatic data from secondary sources

The climate, if proposed area is characterized by hot summer and general

dryness throughout the year except the south west monsoon season. The year may be

divided into three seasons. The winter or cold season is from December to February,

summer or hot season from March to May. The south west monsoon season is from

June to September, while October and November constitute the post monsoon season.

The annual average rainfall of the area is 3038.2 mm, month of May is the generally

the hottest month of the year with average temperature in between 32 to 370 C. In

cold season the area is sometimes affected by the cold waves over north India and the

minimum temperature may drop to 14 to 170 C. The air is generally dry except during

the south west monsoon season, when the relative humidity is high.

3.7 Social Infrastructure Availability

Key infrastructure such as hospitals, schools, bank, places of worship and social/

community facilities such as park, market, playground etc. education, health care,

community development, income distribution, employment and social welfare are available

in nearby area of Maharashtra Industrial Estate.





4.0 Planning In Brief

4.1 Planning Concept

MIDC Industrial area, Dhatav provides many basic facilities like uninterrupted

water supply, power and road network & solids disposal facility if feasible. When

various sites were seen, this site appeared to be environmentally best as also from the

business angle and therefore this option was finally adopted. This site is inside the

campus of the MIDC and means safe transportation, less need of Utilities, less

constructing buildings and roads, less fuel, less water with optimization of

infrastructure.

4.2 Land Use Planning

Existing land is converted for industrial purpose. The land is located in a

designated industrial area. No change in land use

Table 4-1: Land Use Break Up

Sr.no Particular Area in

Sq.m

1 Plant Area 8501

2 Raw material storage area+

Finished goods 3279 +1459

3 ETP 1509

4 Parking 288

5 Internal road 4007

6 Open Space 5000

7 Green Belt 2581

Total 26624

4.3 Assessment of Infrastructure Demand (Physical & Social)

Key infrastructure such as hospitals, schools, bank, places of worship and social/

community facilities such as park, market, playground etc. education, health care,

community development, income distribution, employment and social welfare are

available in nearby area of Maharashtra Industrial Estate.





4.4 Amenities/Facilities

In proposed site many basic facilities like uninterrupted water supply, Power and

Road Network & solids disposal facility if feasible are available. This site is inside the

campus of the MIDC and means safe transportation, less need of utilities, less

constructing buildings and roads, less fuel, less water with optimization of infrastructure

and networking with CHWSTDF (Common Hazardous Waste Storage Treatment and

Disposal facility), MWML, Taloja in vicinity established with support of MIDC and MPCB.

All nearby villages are provided with drinking water from wells or Government

Water Supply Schemes RWS. Hence we do not encroach upon their supply..

4.5 Population Projection

Roha city has a population of 34,345 as per census 2011. It has more than 7,563

households of Maratha, Muslim, Buddhist, and also includes SC, ST, OBC and open

categories community. The village has basically an agrarian economy and industrial

workers and farming is the main occupation of the villagers. The local self-Government

vests with a Grampanchayat having an elected body of headed by a Sarpanch.

Population growth is being increased at alarming rate with their basic

requirements. Amongst, Medicine is one of the basic need, which is very essential for

everyone to live happy life. So to fulfil their future basic need of Medicine for social

community there is a necessity to promote R & D Centre in each industrial sector. There

will be in ratio of population increase in similar way their need also increases so to fulfil

their needs we are going to set up a proposed unit which again generates employment.





5.0 Existing infrastructure

5.1 Industrial area

Industrial Area (Processing area)

Utilities

Cooling towers

HSD unloading/storage area

Boilers

DM water plant

Cooling towers

Hydrogen trolley area

Non- Processing Area

Weighbridge

Administrative Buildings

Security cabins

Workers restroom

Vehicle Shed

Water reservoirs

Temporary storage sites

Works block etc.

For proposed product mix existing infrastructure will be utilized and is sufficient for the

proposed activity

5.2 Residential Area

There is no any residential area has been proposed.

5.3 Green Belt

The project is built on an MIDC plot with plot area of 26624 sq. m. and green belt

area -2581 sq. m. Green belt will be developed at proposed project site and details will be

provided in EIA report.

5.4 Social Infrastructure

The basic amenities within the study area include primary schools, dispensaries,

water supply, electric supply, public telephones, hotels, banks, post offices, petrol pumps,

bus services, technical training institute and entertainment etc.

5.5 Connectivity

Connectivity

Proposed unit is planned at Plot No. 105, Dhatav MIDC, Roha, Raigad.-402116, Maharashtra.

The nearest city from the site is Roha at a distance of 5.0 Km





The nearest railway station is Roha at a distance of 7 Km from the site on Mumbai Goa

Manglore Kokan railway.

The nearest airport is at Mumbai 117 km and Pune at 125 km.

National Highway NH 66 (previously known as NH 17) passes through Kolad (9 km) It

connects Panvel (south of Mumbai city) to Kanyakumari, passing through the states of

Maharashtra, Goa, Karnataka, Kerala and Tamil Nadu. Maharashtra State Road Transport

Corporation has a Bus Depot at Roha for public transport

5.6 Drinking Water Management

The source of water supply is from MIDC Dhatav.

5.7 Sewage System

The domestic effluent will be treated in proposed sewage treatment plant.

5.8 Industrial Water Management

Trade effluent will be treat in existing ETP and treated effluent after meeting the

MPCB norms for discharge will be sent to CETP for final disposal.

5.9 Solid Waste Management

Hazardous solid waste generated from the process will be collected, stored,

transported Transboundry Movement) Rules 2008.

5.10 Power Requirement & Supply / source

The Total Power required for the proposed project is 2100 KW.





6.0 Rehabilitation and Resettlement (R & R) Plan

6.1 Policy to be adopted (Central/State) in respect of the project

affected persons including home oustees, land oustees and

landless.

Proposed activity will be at existing manufacturing unit located at MIDC area.

Hence, there is no any kind of activity of Rehabilitation and resettlement carried out over

it.





7.0 PROJECT SCHEDULE & COST ESTIMATES

7.1 Likely date of start of construction and likely date of completion

The modernization/product mix activity is likely to start after getting Environmental

Clearance and NOC/CTE from the authorized committee.

7.2 Estimated project cost along with analysis in terms of economic

viability of the project

The total investment envisaged is Rs. 38.68 Crore .

Economic Viability

The project has been conceived assuming that there will be a growth in demand for the

proposed products, leading to a reasonable rate of return in the medium term. The project is

considered ‘bankable’.





8.0 ANALYSIS OF PROPOSAL (FINAL RECOMMENDATIONS)

Proposed product mix activity will provide benefits to the local people in terms of

financial and social welfare.

Company will contribute in improving education and health facilities in nearby area.


for the country since they are import substitutes and besides which some of them will

generate $10 million of exchange for our country through their export. Needless to say that

these initiatives shall be our contribution to make in India movement and shall generate

additional profits for the company and revenue for the states

Annexure –I

Plant Lay out

deepak nitrite ltd. -...

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