department of transportation hazmat ......department of transportation hazmat training course [ 49...

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DEPARTMENT OF TRANSPORTATIONHAZMAT TRAINING COURSE

[ 49 CFR 172.704 ]

ITINERARY

8:00 am - 8:15 am INTRODUCTION

8:15 am - 8:25 am REGULATORY OVERVIEW

8:25 am - 9:00 am HAZARDOUS MATERIAL CLASSES

9:00 am - 9:10 am BREAK

9:10 am - 9:20 am CONTAINER MARKINGS

9:20 am - 9:30 am LOADING AND UNLOADING

9:30 am - 10:00 am HAZARDOUS MATERIALS TABLES

10:00 am - 10:10 am BREAK

10:10 am - 10:45 am HAZARDOUS MATERIALS EXERCISE

10:45 am - 11:40 am UNIFORM HAZARDOUS WASTE MANIFEST

11:40 am - 12:00 pm STRAIGHT BILL OF LADING

12:00 pm - 1:00 pm LUNCH

1:00 pm - 1:20 pm 704 MARKING SYSTEM

1:20 pm - 1:50 pm HAZARD COMMUNICATION

1:50 pm - 2:00 pm BREAK

2:00 pm - 2:30 pm "FIRST ON THE SCENE" VIDEO

2:30 pm - 3:00 pm EMERGENCY RESPONSE GUIDEBOOK

3:00 pm - 3:10 pm BREAK

3:10 pm - 3:40 pm PERSONAL PROTECTIVE EQUIPMENT

3:40 pm - 4:05 pm HAZARDOUS MATERIAL DEFINITIONS

4:05 pm - 4:15 pm BREAK

4:15 pm - 5:00 pm COURSE REVIEW AND FINAL TEST

NOTE:

Times indicate only an approximate guideline.

SUBJECT: INTRODUCTION

Time of Lesson: 15 minutes

Instructor Training Aids: PowerPoint Program

Students Materials: Workbook, Background Survey/Evaluation

Objectives: To explain the training approach to the students and what is tobe accomplished from this course.

LESSON OUTLINE:8:00 am

I. Explain the training approach for the course

A. Student Workbook

B. Hazardous Material Compliance Pocketbook

C. Emergency Response Guidebook

D. Course Test

II. Pass out and have students complete Background forms

III. Review the table of contents with students8:15 AM

IMPORTANT INFORMATION !

Blue text are main headings or other information that needs to bestressed.

Red text is information students need to write in their workbook.

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TABLE OF CONTENTS

REGULATORY OVERVIEW 1

HAZARDOUS MATERIAL CLASSES 2

CONTAINER MARKINGS 5

LOADINGAND UNLOADING 6

HAZARDOUS MATERIALS TABLES 7

HAZARDOUS MATERIAL EXERCISE 10

UNIFORM HAZARDOUS WASTE MANIFEST 11

STRAIGHT BILL OF LADING 22

704 MARKING SYSTEM 23

HAZARD COMMUNICATION 24

EMERGENCY RESPONSE GUIDEBOOK 30

PERSONAL PROTECTIVE EQUIPMENT 32

HAZARDOUS MATERIALS DEFINITIONS 34

ATTACHMENT A: UNIFORM HAZARDOUS WASTE MANIFEST 36

ATTACHMENT B: STRAIGHT BILL OF LADING 38

ATTACHMENT C: FUNCTION SPECIFIC TRAINING VERIFICATION 39

ATTACHMENT D: DRIVER TRAINING VERIFICATION 40

ATTACHMENT E: HAZMAT SECURITY AWARENESS 41

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SUBJECT: REGULATORY OVERVIEW



Students Materials: Workbook Page 1

Objectives: To give the students an understanding of the regulations thatare covered in the course.


Review the following regulations with students:

I. 49 CFR 172.704 (1)

II. 49 CFR 172.704 (2): See Appendix C for a copy of the form.

III. 49 CFR 172.704 (3)

IV. 49 CFR 172.704 (4)

V. 49 CFR 172.704 (5)

VI. 49 CFR 177.816 See Appendix D for a copy of the form.8:25 am


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REGULATORY OVERVIEW

I. 49 CFR 172.704 (1):

Each hazmat employee shall receive general awareness/familiarization training designed toprovide familiarity with the requirements of this subchapter, and to enable the employee torecognize and identify hazardous materials consistent with the hazard communication standardsof this subchapter.

II. 49 CFR 172.704 (2):

Each hazmat employee shall receive function-specific training concerning requirements of thissubchapter, or exemptions issued under subchapter A of this chapter, which are specificallyapplicable to the functions the employee performs.

III. 49 CFR 172.704 (3):

Each hazmat employee shall receive safety training concerning-

( i ) Emergency response information required by subpart G of part 172;

( ii ) Measures to protect the employee from the hazards associated with hazardousmaterials to which they may be exposed in the work place, including specific measuresthe hazmat employer has implemented to protect employees from exposure; and

( iii ) Methods and procedures for avoiding accidents, such as the proper procedures forhandling packages containing hazardous materials.

IV. 49 CFR 172.704 (4):

Security awareness training. Each hazmat employee must receive training that provides anawareness of security risks associated with hazardous materials transportation and methodsdesigned to enhance transportation security. This training must also include a componentcovering how to recognize and respond to possible security threats. New hazmat employeesmust receive the security awareness training required by this paragraph within 90 days afteremployment.

V. 49 CFR 172.704 (5):

In-depth security training. Each hazmat employee of a person required to have a security plan inaccordance with subpart I of this part who handles hazardous materials covered by the plan,performs a regulated function related to the hazardous materials covered by the plan, or isresponsible for implementing the plan must be trained concerning the security plan and itsimplementation Security training must include company security objectives, organizationalsecurity structure, specific security procedures, specific security duties and responsibilities foreach employee, and specific actions to be taken by each employee in the event of a securitybreach.

VI. 49 CFR 177.816:

Drivers must be giving not only general awareness/familiarization, function-specific and safetytraining, but also training on the safe operation of the motor vehicle which they operate or intendto operate and the applicable requirements of the Federal Motor Carrier Safety Regulations. Drivertraining shall include the requirements of Sec. 177.816 (a) (1-6):

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SUBJECT: HAZARDOUS MATERIAL CLASSES



Students Materials: Workbook Page 2, Hazardous Material CompliancePocketbook

Objectives: To give the students an understanding of what hazardoussubstances are and the ability to identify the hazardous materialinvolved in an emergency.


I. Ask student to give their definition of Hazardous Materials:

II. Review the nine different hazard classes of chemicals:

A. Class 1 (Explosives)8:35 am

B. Class 2 (Gases)

C. Class 3 (Flammable & Combustible Liquids)

D. Class 4 (Flammable Solids)

E. Class 5 (Oxidizers & Organic Peroxides)

F. Class 6 (Poisons)

G. Class 7 (Radioactive Materials)

H. Class 8 (Corrosives)

I. Class 9 (Miscellaneous)

III. Discus the D.O.T. General Warning Labeling Guidelines:

BREAK 10 minutes


Have students give examples of different classes of chemicals foundin the workplace.

HAZARDOUS MATERIAL CLASSES

I. DEFINITION §171.8:

Hazardous Materials:A SUBSTANCE OR MATERIAL WHICH HAS BEEN DETERMINED TO BE CAPABLE OF

POSING AN UNREASONABLE RISK TO HEALTH, SAFETY, AND PROPERTY WHEN

TRANSPORTED IN COMMERCE AND WHICH HAS BEEN SO DESIGNATED.

II. HAZARD MATERIAL CLASSES:

Hazardous material shipments are recognizable by entries and theshipper's certification on shipping papers, hazardous material warninglabels and markings on the packages. Hazardous materials are groupedinto nine categories identified by the United Nations Hazard Class NumberSystem, including:

A . C la s s 1 (e x p lo s i v e s ) § 4 9 C F R 1 7 3 .5 0 - D i v i d e d in t o s i x d i v i s i o n s :

1 . D i v i s i o n 1 .1 :

EXPLOSIVES THAT HAVE A MASS EXPLOSION HAZARD.

EX: DYNAMITE, BLACK POWDER.

2. Division 1.2:

EXPLOSIVES THAT HAVE A PROJECTION HAZARD.

EX: AERIAL FLARES, DETONATING CORDS.

3. Division 1.3:

EXPLOSIVES THAT HAVE A FIRE, AND EITHER MINOR BLAST OR

PROJECTION HAZARD OR BOTH.

EX: LIQUID FUELED ROCKET MOTORS.

4. Division 1.4:

EXPLOSIVE DEVICES THAT PRESENT A MINOR BLAST HAZARD

EX: LINE THROWING ROCKETS OR PRACTICE AMMUNITION.

5. Division 1.5:

VERY INSENSITIVE EXPLOSIVES.

EX: AMMONIUM NITRATE-FUEL OIL MIXTURES.

6. Division 1.6:

EXTREMELY INSENSITIVE ARTICLES WHICH DO NOT HAVE A

MASS EXPLOSION HAZARD.

EX: NOT OTHERWISE SPECIFIED( 2 ) © NEI

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SUBJECT: HAZARDOUS MATERIAL CLASSES CONT.

Objectives: To give the students an understanding of what hazardoussubstances are and the ability to identify the hazardousmaterial involved in an emergency.

LESSON OUTLINE:


II. Review the nine different classes of chemicals:

A. Class 1 (Explosives)8:35 am

B. Class 2 (Gases)



E. Class 5 (Oxidizers & Organic Peroxides)8:45 am





III. Discus D.O.T. General Warning Labeling Guidelines:

BREAK 10 minutes


The following is from the new OSHA CFR 29 1910.106(a)(19) and is repeated in 1910.126:

Flammable liquid means any liquid having a flashpoint at or below 199.4°F (93°C). Flammableliquids are divided into four categories as follows: Category 1, Category 2, Category 3 and

Category 4.

B. Class 2 (gases) § 49 CFR 173.115 - Three Divisions:

1. Division 2.1:

GASES THAT ARE FLAMMABLE.

EX: PROPANE OR METHYL CHLORIDE.

2. Division 2.2:

GASES THAT ARE NON-FLAMMABLE AND COMPRESSED.

EX: CARBON DIOXIDE OR COMPRESSED NITROGEN.

3. Division 2.3:

GASES THAT ARE POISONOUS.

EX: PHOSPHINE

C. Class 3 (flammable and combustible liquids) § 49 CFR 173.120:

1. Flammable Liquid:

SUBSTANCE THAT HAS A FLASH POINT OF NOT MORE THAN 1400F.

(DOT DEFINITION) EX: GASOLINE

2. Combustible Liquid:

SUBSTANCE THAT HAS A FLASH POINT ABOVE 1400F AND BELOW

2000F. (DOT DEFINITION) EX: FUEL OIL

D. Class 4 (flammable solids) § 49 CFR 173.124 - Three Divisions:

1. Division 4.1:

SOLIDS THAT ARE FLAMMABLE.

EX: SULFUR.

2. Division 4.2:

MATERIALS THAT ARE SPONTANEOUSLY COMBUSTIBLE.

EX: CARBON, ACTIVATED.

3. Division 4.3:

MATERIAL THAT IS DANGEROUS WHEN WET.

EX: LITHIUM.

E. Class 5 (oxidizers and organic peroxides) § 49 CFR 173.127 - Two Divisions:

1. Division 5.1:

MATERIALS THAT ARE OXIDIZERS.

EX: HYDROGEN PEROXIDE.( 3 ) © NEI

SUBJECT: HAZARDOUS MATERIAL CLASSES CONT.

Objectives: To give the students an understanding of what hazardoussubstances are and the ability to identify the hazardousmaterial involved in an emergency.

LESSON OUTLINE:


II. Review the nine different classes of chemicals:

A. Class 1 (Explosives)

B. Class 2 (Gases)



E. Class 5 (Oxidizers & Organic Peroxides)8:45 am





II. Discus D.O.T. General Warning Labeling Guidelines:9:00 am

BREAK 10 minutes

9:10 am


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2. Division 5.2:

MATERIALS THAT ARE ORGANIC PEROXIDE.

EX: BENZOYL PEROXIDE.

F. Class 6 (toxics) § 49 CFR 173.132 - Two Divisions:

1. Division 6.1:

MATERIALS THAT ARE TOXIC.

EX: HYDROGEN CYANIDE, ANHYDROUS.

2. Division 6.2:

MATERIALS THAT ARE AN INFECTIOUS SUBSTANCE.EX: REGULATED MEDICAL WASTE.

G. Class 7 (radioactive material) § Subpart I:

MATERIAL HAVING A SPECIFIC RADIOACTIVE ACTIVITYGREATER THAN 0.002 MICROCURIES.

EX: PLUTONIUM

H. Class 8 (corrosives) § 49 CFR 173.136:

MATERIALS THAT CAUSE VISIBLE DESTRUCTION OR IRREVERSIBLEALTERATION TO HUMAN SKIN OR CORROSION TO STEEL.

EX: HYDROCHLORIC ACID

I. Class 9 (miscellaneous) § 49 CFR 173.140:

MATERIAL WHICH IS A HAZARD, BUT WHICH IS NOT IN ANY OTHERCLASS.EX: FORMALDEHYDE

III. DOT GENERAL GUIDELINES FOR WARNING LABELS:

Labels can help you identify a hazardous materials shipment andthe hazard(s) present. A driver should not accept the shipmentunless the required labels are affixed to the packages.

A. SHIPPER MUST FURNISH AND ATTACH APPROPRIATE LABEL TO EACH

PACKAGE OF HAZARDOUS MATERIAL OFFERED FOR SHIPMENT.

B. IF MATERIAL IN A PACKAGE HAS MORE THAN ONE HAZARD CLASSIFICATION

THE PACKAGE MUST BE LABELED FOR EACH HAZARD.

C. IF MORE THAN ONE LABEL IS INDICATED, THE FIRST ONE LISTED IS THE

PRIMARY LABEL.

D. RADIOACTIVE MATERIAL REQUIRING LABELING, MUST BE LABELED ON TWO

OPPOSITE SIDES OF THE PACKAGE.

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SUBJECT: CONTAINER MARKINGS




Objectives: To provide students with the information on what type ofinformation can be obtained from the markings that are are oncontainers.

LESSON OUTLINE:

9:10 am I. Explain how to use the markings on containers to help in identifying the material

9:20 am


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1A1/Y1.4/150/83USA/VL824/1mmUSA/RB/10-85RL

UN

"1" means a drum"2" means a wooden barrel"3" means a jerrican"4" means a box"5" means a bag"6" means a composite packaging"7" means a pressure receptacles

"A" means steel"B" means aluminum"C" means natural wood"D" means plywood"F" means reconstituted wood"G" means fiberboard"H" means plastic"L" means textile"M" means paper, multi-wall"N" means metal"P" means glass, porcelain or stoneware

"1A1"

"1" indicates a non-removable head drum"2" indicates a removable head drum

"X" packaging meeting Packing Group I, II and III tests."Y" packaging meeting Packing Group II and III tests."Z" packaging meeting Packing Group III tests.

"Y1.4""1.4" is the specific gravity of the

material for which thepackaging was tested.

"150"

"83"

"USA"

"VL824"

"1mm"

"USA"

"RB"

"10-85"

"R"

"L"

the country where reconditioning was performed

the minimum thickness of material for metal or plastic drums or jerricansintended for reuse or reconditioning as single containers

the code of the manufacture

the country of manufacture

the year of manufacture

the symbol of the reconditioner

the package successfully passed the leakproofness test

the drum was reconditioned

the month and year of reconditioning

the test pressure in kPa rounded to the nearest 10

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CONTAINER MARKINGS

I. MARKINGS:

Package markings by manufactures are significantlydifferent. The following is an example of the amountof information that can be obtained from themanufacturer's marking on the package.

SUBJECT: LOADING AND UNLOADING §177.834




Objectives: To give the students an understanding of the rules andrequirements for loading & unloading hazardous substances.


Discuss the loading and unloading rules for all Hazardous Materials Shipments as required under 49 CFR 177.834

9:30 am


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LOADING AND UNLOADING§177.834

There are some regulations for the safe and secure loading and unloadingof hazardous materials shipments which apply to all hazardous

commodities shipments.

A. All classes of hazardous materials must be secured against movement in the vehicle.

Tanks, barrels, drums, cylinders or other packaging not permanently attached.

B. No hazardous materials may be transported in or on any pole trailer.

Pole Trailer: Means any motor vehicle which is designed to be drawnby another motor vehicle and attached to the towing motor vehicle bymeans of a "reach" or "pole" or by being "boomed" or otherwisesecured to the towing motor vehicle, for transporting long or irregularlyshaped loads such as poles, pipes, or structural members, whichgenerally are capable of sustaining themselves as beams between the supporting connections.

C. No smoking while loading or unloading hazardous materials.

No person may smoke or carry any lighted smoking material on or within 25 feet of vehicle.

D. Keep fire away while loading or unloading hazardous materials.

Further, care should be taken to keep all fire sources away from the vehicle.

E. Vehicle handbrake must be set while loading or unloading hazardous materials.

All precautions should be taken to prevent movement of the vehicle.

F. No tools should be used that could damage any package or container.

G. Brace containers to prevent relative motion to the vehicle.

Containers with valves or other similar fittings must be loaded so that there is minimum

likelihood of any damage to them during transportation.

H. Shall be no tampering with container or it's contents between point of origin anddestination.

I. Cargo tank must be attended by a qualified person at all times while being loaded.

The person who is responsible for loading the cargo is also responsible for seeing that the

vehicle is attended.

J. Bonding must first be done to the vehicle to be filled, then to the container fromwhich theflammable liquid will be loaded.

Attachment must be done in this order.

K. No motor carrier may accept for transportation or transport any goods classed as"Forbidden" in the 172.101 Hazardous Materials Table.

Carrier personnel are also responsible for rejecting packagesof hazardous materials which show signs of leakage

or other damage.

SUBJECT: HAZARDOUS MATERIALS TABLES



Students Materials: Workbook Page 7, Hazardous Material CompliancePocketbook

Objectives: To show students how to use the Hazardous Materials Tablesthat are found in 49 CFR.


I. Explain how to use the Segregation Table for hazardous materials to students. §177.848 (d)

II. Explain what each symbol in the Segregation Table means9:40 am

III. Discuss with the student the exception for the CompatibilityTable and how to use it. §177.848 (f)

IV. Give instruction on what each symbol in the table represents

V. Discuss with the students the 172.101 Hazardous MaterialTable and what information can be obtained from it. §172.101

BREAK 10 minutes


Have the student use the hazardous Materials CompliancePocketbook

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HAZARDOUS MATERIALS TABLES

I. SEGREGATION TABLE §177.848 (d):

The Hazardous Materials Regulations contain Segregation requirements which indicate whichhazardous materials may not be loaded, transported or stored together, except as provided inthe following Table:

II. SEGREGATION SYMBOLS §177.848 (e):

A. X = That these materials may not be loaded, transported, or stored together in the same

transport vehicle or storage facility during the course of transportation.

B. O = That these materials may not be loaded, transported, or stored together in the same

transport vehicle or storage facility during the course of transportation unlessseparated in a manner that commingling of hazardous materials would not occur.

C. * = That segregation among different Class 1 (explosive) materials is governed by the

compatibility table.

D. = That no restrictions apply.

F. A = That, notwithstanding the requirements of the letter "X", ammonium nitrate (UN 1942

and Ammonium nitrate fertilizer may be loaded or stored with Division 1.1 (class Aexplosive) or Division 1.5 (blasting agents) materials.

Class or

ExplosivesExplosivesExplosivesVery insensitive

explosivesExtremely insensitive

explosivesFlammable gasesNon-toxic, non-

flammable gasesPoisonous gas Zone APoisonous gas Zone BFlammable liquidsFlammable solidsSpontaneously com-

bustible materialsDangerous when wet

materialsOxidizersOrganic peroxidesPoisonous liquids PG 1

Zone ARadioactive materialsCorrosive liquids

Division

1.1 and 1.21.31.41.5

1.6

2.12.2

2.32.3

34.14.2

4.3

5.15.26.1

7

8

Notes

A

A

A

1.11.2

****

*

XX

XXXXX

X

XXX

XX

1.3

****

*

X

XXX

X

X

XXX

X

1.4

****

*

O

OOO

O

O

O

4.5

****

*

XX

XXXXX

X

XXX

XX

2.1

XXOX

XO

O

O

2.2

X

X

2.3gasZone

A

XXOX

X

XXX

X

XX

X

2.3gasZone

B

XXOX

O

OOO

O

OO

O

3

XXOX

XO

O

X

4.1

X

X

XO

X

X

4.2

XXOX

XO

X

X

4.3

XX

X

XO

X

O

5.1

XX

X

XOO

X

O

5.2

XX

X

XO

X

O

6.1liquidsPGI

ZoneA

XXOX

O

XXX

X

XX

X

7

X

X

O

8liquidsonly

XXOX

XO

OX

O

OOX

4.6

****

*

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SUBJECT: HAZARDOUS MATERIALS TABLES CONT.


LESSON OUTLINE:

I. Explain how to use the Segregation Table for hazardousmaterials to students. §177.848 (d)

II. Explain what each symbol in the Segregation Table means9:40 am

III. Discuss with the student the exception for the Compatibility Table and how to use it. §177.848 (f)

IV. Give instruction on what each symbol in the table represents9:50 am

V. Discuss with the students the §172.101 Hazardous MaterialTable and what information can be obtained from it. §172.101

BREAK 10 minutes



III. COMPATIBILITY TABLE §177.848 (f):

Class 1 (explosive) materials shall not be be loaded, transported, or stored together, except asprovided in this section and in accordance with the following Table:

Compatibility Group

ABCDEFGHJKLNS

A

XXXXXXXXXXXX

B

X

XX

(4)

XXXXXXXX

4/5

C

XX

22XXXXXXX

4/5

D

XX

(4)

2

2XXXXXXX

4/5

E

XX22

XXXXXXX

4/5

F

XXXXX

XXXXXX

4/5

G

XX666X

XXXXX

4/5

H

XXXXXXX

XXXX

4/5

J

XXXXXXXX

XXX

4/5

K

XXXXXXXXX

XX

4/5

L

XXXXXXXXXX1XX

N

XX333XXXXXX

4/5

S

X4/54/54/54/54/54/54/54/54/5X

4/5

IV. COMPATIBILITY TABLE INSTRUCTIONS §177.848 (g):

A. = That no restrictions apply.

B. X = That explosives of different compatibility groups may not be carried on the same

transport vehicle.

C. The numbers in the table mean the following:

1 = means an explosive from compatibility group L shall only be carried on the same

transport vehicle with an identical explosive.

2 = means any combination of explosives from compatibility groups C, D, or E is

assigned to compatibility group E.

3 = means any combination of explosives from compatibility groups C, D, or E with those

in compatibility group N is assigned to compatibility group D.

4 = means §177.835(g) when transporting detonators.

5 = means Division 1.4S fireworks may not be loaded on the same transport vehicle with

Division 1.1 or 1.2 (Class A explosive) materials.

6 = means explosive articles in compatibility group G, other than fireworks and those

requiring special stowage, may be stowed with articles of compatibility groups C, Dand E, provided no explosive substance are carried in the same vehicle.

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SUBJECT: HAZARDOUS MATERIALS TABLES CONT.


LESSON OUTLINE:

I. Explain how to use the Segregation Table for hazardousmaterials to students. §177.848 (d)

II. Explain what each symbol in the Segregation Table means

III. Discuss with the student the exception for the CompatibilityTable and how to use it. §177.848 (f)

IV. Give instruction on what each symbol in the table represents9:50 am

V. Discuss with the students the §172.101 Hazardous Material Table and what information can be obtained from it. §172.101

10:00 am

BREAK 10 minutes10:10 am



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V. HAZARDOUS MATERIALS TABLE §172.101:

The Hazardous Materials Table identifies the requirements that apply to each shipment of ahazardous material. The table will help you identify:

Column 1 - Symbols:

Five symbols showing special conditions placed on hazardous materials:

"+" = Fixes proper shipping name, hazard class and packing group without regard towhether the material meets the class, packing group or any other hazard class.

"A" = Applies to materials offered or intended for transportation by aircraftunless the material is a hazardous substance or a hazardous waste.

"D" = Identifies proper shipping names for describing materials for domestictransportation may be inappropriate for international transportation.

"I" = Identifies proper shipping names for describing materials in internationaltransportation.

"W" = Applies to materials offered or intended for transportation be vessel unless thematerial is a hazardous substance or a hazardous waste.

Column 2 - Hazardous Material Descriptions:

Proper shipping name

Column 3 - Hazard Class or Division:

In accordance with § 173.50 Definitions

Column 4 - Identification Number:

UN = Can Ship International NA = Only Ship North America

Column 5 - Packing Group:

The degree of danger presented by the material: I = Great, II = Medium, III = Minor

Column 6 - Labels:

Codes for hazard warning labels required for a package

Column 7 - Special Provisions:

See § 172.102 for meaning and requirements

Column 8 - Placard Column: (not part of the 172.101 Table)

Quick indication of the placard required for shipping description

Accumulators, electric, see Batteries, wet etc.

PlacardsConsult regulations(Part 172, Subpart F)*Placard any quantity(7)

Specialprovisions§ 172.102

(6)

Labelcodes

PG

(5)(4)

Identifi-cation

Numbers

Sym-bols

(2)

Hazardous materials descriptions and propershipping names

(3)

Hazardclass orDivision

(1)

Accellerene, See p-Nitrosodimethylaniline

FLAMMABLEUN10883Acetal

FLAMMABLE3UN10893Acetaldehydre

3 IB2, T4, TP1

I

II

CLASS 9IB8, 1P69UN18419Acetaldehydre ammonia IIIA

FLAMMABLEB1, IB3, T4, TP13UN23323Acetaldehydre oxime III

A3, B16, T11TP2, TP7

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SUBJECT: HAZARDOUS MATERIAL EXERCISE

Time of Lesson: 35 minute Exercise


Students Materials: Workbook, Hazardous Material Compliance Pocketbook

Objectives: To show students how to use the Hazardous Material Tables


I. Have students complete the exercise.

II. Review the exercise with students10:45 am


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HazardClass

6.1

6.1

3

3

8

2.3

2.2

9

1.4G

6.1

5.1

8

6.1

3

3

3

2.3

5.1

3

3

HAZARDOUS MATERIAL EXERCISE

Using your Hazard Materials Compliance Pocketbook complete the followingchart.

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Label SubstitutionName(s)

POISON

POISON ( I. H. )

FLAMMABLE LIQUID

FLAMMABLE LIQUID

CORROSIVE

POISON GAS

NON-FLAMMABLE GAS

CLASS 9

EXPLOSIVE 1.4G

POISON

OXIDIZER

CORROSIVE

POISON

NONE

FLAMMABLE LIQUID

FLAMMABLE LIQUID

POISON GAS

OXIDIZER

FLAMMABLE LIQUID

FLAMMABLE LIQUID

Material

Zinc cyanide

Allyl alcohol

Fuel oil, (no 1)

Benzene

Lead azide (dry)

Spent sulfuric acid

Hydrogen iodide

Krypton, compressed

White asbestos

Cord, Igniter

Lead acetate

Lead nitrate

Mercury

Ethyl oxalate

Diesel fuel

Acetone

Amyl Acetate

Phosgene

Silver Nitrate

Xylenes

Gasoline

ID#

UN-1713

UN-1098

NA-1993

UN-1114

UN-1832

UN-2197

UN-1056

UN-2590

UN-0066

UN-1616

UN-1469

UN-2809

UN-2525

NA-1993

UN-1090

UN-1104

UN-1076

UN-1493

UN-1307

UN-1203

RQPounds

10 LBS

100 LBS

NONE

10 LBS

NONE

NONE

NONE

NONE

NONE

10 LBS

10 LBS

1 LBS

NONE

NONE

5000 LBS

5000 LBS

10 LBS

1 LBS

100 LBS

NONE

F O R B I D D E N

SUBJECT: UNIFORM HAZARDOUS WASTE MANIFEST




Objectives: To show students how to fill out and read the Uniform HazardousWaste Manifest required in 49 CFR 172.


I. Explain to the student what type of information can found on the Uniform Hazardous Waste Manifest and how to fill one out.

Attachment A on page 36 & 37 is a sample form10:50 am


It might be a good ideal to have one from your company available.

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UNIFORM HAZARDOUS WASTE MANIFEST

I. INSTRUCTIONS FOR APPENDIX TO PART 172:

UNIFORM HAZARDOUS WASTE MANIFEST AND INSTRUCTIONS (EPAFORM 8700-22):

On September 5, 2006 EPA revised the Uniform Hazardous Waste Manifest used to track hazardouswaste from a generator’s site to the site of its disposition. The new Uniform Hazardous WasteManifest must be used for all hazardous waste shipments.

The Uniform Hazardous Waste Manifest, (form 8700-22 and, if necessary, the continuation sheetform 8700-22A), is a form prepared by all generators who transport, or offer for transport, hazardouswaste for off-site treatment, recycling, storage, or disposal. Currently, the manifest is a paperdocument containing 6 copies of a single form. When completed, it contains information on the typeand quantity of the waste being transported, instructions for handling the waste, and signature linesfor all parties involved in the disposal process. The manifest is required by both Department ofTransportation and EPA. Each party that handles the waste signs the manifest and retains a copy forthemselves. This ensures critical accountability in the transportation and disposal processes. Oncethe waste reaches its destination, the receiving facility returns a signed copy of the manifest to thegenerator, confirming that the waste has been received by the designated facility.

Handlers of waste (generators, or treatment, storage or disposal facilities) must obtain the new formsfrom any source that has been approved by the EPA Manifest Registry to print and distribute theform.

The Uniform Manifest contains 6 copies. ALL COPIES MUST BE LEGIBLE. This form is designed foruse on a 12 pitch (elite) typewriter; a firm ball point pen may also be used only if you press downHARD. The 6 copies must be distributed in the following way:

ORIGINAL: DESTINATION STATE COPY --The TSDF will mail to the destination state where the waste was sent (if required). ADEQ does notrequire the submission of this copy to the state.

COPY 2: GENERATOR STATE COPY--TSDF mails to appropriate state agency (if required). ADEQ does not require the submission ofthis copy to the state.

COPY 3: GENERATOR COPY--TSDF mails back to the generator completed manifest.

COPY 4: TSDF COPY--TSDF keeps this copy for his records.

COPY 5: TRANSPORTER COPY--The transporter keeps for his records.

COPY 6: GENERATOR INITIAL COPY--The generator keeps once transporter signs off and takes waste.

A sample Uniform Hazardous Waste Manifest is located in Appendix A in the back of your studentworkbook.

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SUBJECT: UNIFORM HAZARDOUS WASTE MANIFEST







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GENERATORS SECTION


I. INSTRUCTIONS FOR APPENDIX TO PART 172:

Item 1. Generator’s U.S. EPA Identification Number

Enter the generator’s U.S. EPA twelve digit identification number, or the State generatoridentification number if the generator site does not have an EPA identification number.

Item 2. Page 1 of _____

Enter the total number of pages used to complete this Manifest (i.e., the first page (EPAForm 8700-22) plus the number of Continuation Sheets (EPA Form 8700-22A), if any).

Item 3. Emergency Response Phone Number

Enter a phone number for which emergency response information can be obtained in theevent of an incident during transportation. The emergency response phone number must:

1. Be the number of the generator or the number of an agency or organization who iscapable of and accepts responsibility for providing detailed information about theshipment;

2. Reach a phone that is monitored 24 hours a day at all times the waste is intransportation (including transportation related storage); and

3. Reach someone who is either knowledgeable of the hazardous waste being shippedand has comprehensive emergency response and spill § 262 App. I cleanup/incidentmitigation information for the material being shipped or has immediate access to aperson who has that knowledge and information about the shipment.

Note: Emergency Response phone number information should only be entered in Item3 when there is one phone number that applies to all the waste materials described inItem 9b. If a situation (e.g., consolidated shipments) arises where more than oneEmergency Response phone number applies to the various wastes listed on themanifest, the phone numbers associated with each specific material should be enteredafter its description in Item 9b.

Item 4. Manifest Tracking Number

This unique tracking number must be pre-printed on the manifest by the forms printer.

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0 1 2 3 4 5 6 7 8 9 9 8 000000085BRX1 800.123.4567

SUBJECT: UNIFORM HAZARDOUS WASTE MANIFEST CONT.






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GENERATORS SECTION

Item 5. Generator’s Mailing Address, Phone Number and Site Address

Enter the name of the generator, the mailing address to which the completed manifest signedby the designated facility should be mailed, and the generator’s telephone number. Note,the telephone number (including area code) should be the normal business number for thegenerator, or the number where the generator or his authorized agent may be reached toprovide instructions in the event the designated and/or alternate (if any) facility rejects someor all of the shipment. Also enter the physical site address from which the shipmentoriginates only if this address is different than the mailing address.

XYZ COMPANY, INC.1111 MY STREET ANYTOWN, USA 01234


I. INSTRUCTIONS FOR APPENDIX TO PART 172 (CONT.):

Item 6. Transporter 1 Company Name, and U.S. EPA ID Number

Enter the company name and U.S. EPA ID number of the first transporter who will transportthe waste. Vehicle or driver information may not be entered here.

( 123 ) 456-7890

WE CARRY IT CORP. 9 8 7 6 5 4 3 2 1 0 1 2

Item 7. Transporter 2 Company Name and U.S. EPA ID Number

If applicable, enter the company name and U.S. EPA ID number of the second transporterwho will transport the waste. Vehicle or driver information may not be entered here. If morethan two transporters are needed, use a Continuation Sheet(s) (EPA Form 8700-22A).

IF THEY CAN'T WE CAN, INC. 0 0 0 0 0 0 0 0 0 0 0 1

Item 8. Designated Facility Name, Site Address, and U.S. EPA ID Number

Enter the company name and site address of the facility designated to receive the wastelisted on this manifest. Also enter the facility’s phone number and the U.S. EPA twelve digitidentification number of the facility.

WE HAVE IT NOW, LLC.1234 WAY OFF STREET YOUR TOWN, USA 43210

0 1 2 3 4 5 6 7 8 9 9 8(212) 222-0000

GENERATORS SECTION

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BA = Burlap, cloth, paper, or plastic bags DT = Dump truckCF = Fiber or plastic boxes, cartons, cases DW = Wooden drums, barrels, kegsCM = Metal boxes, cartons, cases (including roll-offs) HG = Hopper or gondola carsCW = Wooden boxes, cartons, cases TC = Tank carsCY = Cylinders TP = Portable tanksDF = Fiberboard or plastic drums, barrels, kegs TT = Cargo tanks (tank trucks)DM = Metal drums, barrels, kegs ( 14 ) © NEI



Item 9. U.S. DOT Description (Including Proper Shipping Name, Hazard Class or Division,Identification Number, and Packing Group)

Item 9a. If the wastes identified in Item 9b consist of both hazardous and nonhazardousmaterials, then identify the hazardous materials by entering an “X”in this Itemnext to the corresponding hazardous material identified in Item 9b.

Item 9b. Enter the U.S. DOT Proper Shipping Name, Hazard Class or Division,Identification Number (UN/NA) and Packing Group for each waste as identified in49 CFR 172. Include technical name(s) and reportable quantity references, ifapplicable.

NOTE: If additional space is needed for waste descriptions, enter these additionaldescriptions in Item 27 on the Continuation Sheet (EPA Form 8700-22A). Also, ifmore than one Emergency Response phone number applies to the various wastesdescribed in either Item 9b or Item 27, enter applicable Emergency Responsephone numbers immediately following the shipping descriptions for those Items.

Item 10. Containers (Number and Type)

Enter the number of containers for each waste and the appropriate abbreviation from TableI (below) for the type of container.

TABLE I. TYPES OF CONTAINERS

AMYL ACETATES - 3 - UN 1104 DM002

GENERATORS SECTION

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Item 11. Total Quantity

Enter, in designated boxes, the total quantity of waste. Round partial units to the nearestwhole unit, and do not enter decimals or fractions. To the extent practical, report quantitiesusing appropriate units of measure that will allow you to report quantities with precision.Waste quantities entered should be based on actual measurements or reasonably accurateestimates of actual quantities shipped. Container capacities are generally not acceptable asestimates.

AMYL ACETATES - 3 - UN 1104 DM002 00095 G

Item 12. Units of Measure (Weight/Volume)

Enter, in designated boxes, the appropriate abbreviation from Table II (below) for the unit ofmeasure.

TABLE II. UNITS OF MEASURE

G = Gallons (liquids only) N = Cubic Meters†

K = Kilograms P = PoundsL = Liters (liquids only) T = Tons (2000 pounds)†

M = Metric Tons (1000 kilograms)† Y = Cubic Yards†

†Note: Tons, Metric Tons, Cubic Meters, and Cubic Yards should only be reported inconnection with very large bulk shipments, such as rail cars, tank trucks, or barges.

Item 13. Waste Codes

Enter up to six federal and state waste codes to describe each waste stream identified inItem 9b. State waste codes that are not redundant with federal codes must be entered here,in addition to the federal waste codes which are most representative of the properties of thewaste.

GENERATORS SECTION

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Item 14. Special Handling Instructions and Additional Information

1. Generators may enter any special handling or shipment-specific information necessaryfor the proper management or tracking of the materials under the generator’s or otherhandler’s business processes, such as waste profile numbers, container codes, barcodes, or response guide numbers. Generators also may use this space to enteradditional descriptive information about their shipped materials, such as chemical names,constituent percentages, physical state, or specific gravity of wastes identified withvolume units in Item 12.

2. This space may be used to record limited types of federally required information for whichthere is no specific space provided on the manifest, including any alternate facilitydesignations; the manifest tracking number of the original manifest for rejected wastesand residues that are re-shipped under a second manifest; and the specification of PCBwaste descriptions and PCB out-of-service dates required under 40 CFR 761.207.Generators, however, cannot be required to enter information in this space to meet stateregulatory requirements.

FOR AN EMERGENCY INVOLVING THIS SUBSTANCE, CALL CHEMTREC AT 800-424-9300

GENERATORS SECTION

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Item 15. Generator’s/Offeror’s Certifications

1. The generator must read, sign, and date the waste minimization certification statement.In signing the waste minimization certification statement, those generators who havenot been exempted by statute or regulation from the duty to make a waste minimizationcertification under section 3002(b) of RCRA are also certifying that they have compliedwith the waste minimization requirements. The Generator’s Certification also containsthe required attestation that the shipment has been properly prepared and is in propercondition for transportation (the shipper’s certification). The content of the shipper’scertification statement is as follows: “I hereby declare that the contents of thisconsignment are fully and accurately described above by the proper shipping name, andare classified, packaged, marked, and labeled/placarded, and are in all respects in propercondition for transport by highway according to applicable international and nationalgovernmental regulations. If export shipment and I am the Primary Exporter, I certify thatthe contents of this consignment conform to the terms of the attached EPAAcknowledgment of Consent.” When a party other than the generator prepares theshipment for transportation, this party may also sign the shipper’s certificationstatement as the offeror of the shipment.

2. Generator or Offeror personnel may preprint the words, “On behalf of”in the signatureblock or may hand write this statement in the signature block prior to signing thegenerator/offeror certification, to indicate that the individual signs as the employee oragent of the named principal.

Note: All of the above information except the handwritten signature required in Item 15may be pre-printed.

JOHN J. JOHNSON John J. Johnson 01 01 07

GENERATORS SECTION

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Item 16. International Shipments

INTERNATIONAL SHIPMENT SECTION

For export shipments, the primary exporter must check the export box, and enter the pointof exit (city and state) from the United States. For import shipments, the importer must checkthe import box and enter the point of entry (city and state) into the United States. Forexports, the transporter must sign and date the manifest to indicate the day the shipmentleft the United States. Transporters of hazardous waste shipments must deliver a copy ofthe manifest to the U.S. Customs when importing or exporting the waste across U.S.borders.

Item 17. Transporters’Acknowledgments of Receipt

TRANSPORTERS SECTION

Enter the name of the person accepting the waste on behalf of the first transporter. Thatperson must acknowledge acceptance of the waste described on the manifest by signingand entering the date of receipt. Only one signature per transportation company is required.Signatures are not required to track the movement of wastes in and out of transfer facilities,unless there is a change of custody between transporters. If applicable, enter the name ofthe person accepting the waste on behalf of the second transporter. That person mustacknowledge acceptance of the waste described on the manifest by signing and enteringthe date of receipt.

NOTE: Transporters carrying imports or exports of hazardous waste may also haveresponsibilities to enter information in the International Shipments Block. See aboveinstructions for Item 16.

JIMMY L. LOW 0 1 0 1 0 7Jimmy L. Low

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Item 18. Discrepancy

OWNERS AND OPERATORS OF TREATMENT, STORAGE, AND DISPOSAL FACILITIES

Item 18a. Discrepancy Indication Space

1. The authorized representative of the designated (or alternate) facility’s owner oroperator must note in this space any discrepancies between the waste described on theManifest and the waste actually received at the facility. Manifest discrepancies are: (1)significant differences (as defined by §§ 264.72(b) and 265.72(b)) between the quantityor type of hazardous waste designated on the manifest or shipping paper, and thequantity and type of hazardous waste a facility actually receives, (2) rejected wastes,which may be a full or partial shipment of hazardous waste that the TSDF cannot accept,or (3) container residues, which are residues that exceed the quantity limits for “empty”containers set forth in § 261.7(b).

2. For rejected loads and residues (§ 264.72(d), (e), and (f), or § 265.72(d), (e), or (f)), checkthe appropriate box if the shipment is a rejected load (i.e., rejected by the designated and/or alternate facility and is sent to an alternate facility or returned to the generator) or aregulated residue that cannot be removed from a container. Enter the reason for therejection or the inability to remove the residue and a description of the waste. Also,reference the manifest tracking number for any additional manifests being used to trackthe rejected waste or residue shipment on the original manifest. Indicate the originalmanifest tracking number in Item 14, the Special Handling Block and AdditionalInformation Block of the additional manifests.

3. Owners or operators of facilities located in unauthorized States (i.e., states in which theU.S. EPA administers the hazardous waste management program) who cannot resolvesignificant differences in quantity or type within 15 days of receiving the waste mustsubmit to their EPA Regional Administrator a letter with a copy of the Manifest at issuedescribing the discrepancy and attempts to reconcile it (§§ 264.72(c) and 265.72(c)).

4. Owners or operators of facilities located in authorized States (i.e., those States that havereceived authorization from the U.S. EPA to administer the hazardous wastemanagement program) should contact their State agency for information on where toreport discrepancies involving “significant differences”to state officials.

N/A

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Item 18. Discrepancy


Item 18b. Alternate Facility (or Generator) for Receipt of Full Load Rejections:

Enter the name, address, phone number, and EPA Identification Number of the AlternateFacility which the rejecting TSDF has designated, after consulting with the generator, toreceive a fully rejected waste shipment. In the event that a fully rejected shipment is beingreturned to the generator, the rejecting TSDF may enter the generator’s site information inthis space. This field is not to be used to forward partially rejected loads or residue wasteshipments.

Item 18c. Alternate Facility (or Generator)Signature.:

The authorized representative of the alternate facility (or the generator in the event of areturned shipment) must sign and date this field of the form to acknowledge receipt of thefully rejected wastes or residues identified by the initial TSDF.

Item 19. Hazardous Waste Report Management Method Codes:

Enter the most appropriate Hazardous Waste Report Management Method code for eachwaste listed in Item 9. The Hazardous Waste Report Management Method code is to beentered by the first treatment, storage, or disposal facility (TSDF) that receives the wasteand is the code that best describes the way in which the waste is to be managed whenreceived by the TSDF.

Note: See the following website for more information on the codes used:http://www.epa.gov/epaoswer/hazwaste/gener/manifest/registry/codes.pdf

N/A

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Item 20. Designated Facility Owner or Operator Certification of Receipt (Except As Noted in Item 18a):


Enter the name of the person receiving the waste on behalf of the owner or operator of thefacility. That person must acknowledge receipt or rejection of the waste described on theManifest by signing and entering the date of receipt or rejection where indicated. Since theFacility Certification acknowledges receipt of the waste except as noted in the DiscrepancySpace in Item 18a, the certification should be signed for both waste receipt and wasterejection, with the rejection being noted and described in the space provided in Item 18a.Fully rejected wastes may be forwarded or returned using Item 18b after consultation withthe generator. Enter the name of the person accepting the waste on behalf of the owner oroperator of the alternate facility or the original generator. That person must acknowledgereceipt or rejection of the waste described on the Manifest by signing and entering the datethey received or rejected the waste in Item 18c. Partially rejected wastes and residues mustbe re-shipped under a new manifest, to be initiated and signed by the rejecting TSDF asofferor of the shipment.

JANE S. DOE 01 01 07Jane S. Doe

SUBJECT: STRAIGHT BILL OF LADING




Objectives: To show students how to find hazardous material informationform the shipping papers that are carried on the transportvehicle


I. Explain to the student what type of information can found on the Straight Bill Of Lading and how to read and understand one.

Attachment B on page 35 is a complete form12:00 pm

LUNCH 60 minutes

1:00 pm



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STRAIGHT BILL OF LADING

Whenever a hazardous material is transported, its description must appear on the shipping paper. Thedescription must adhere to these requirements. (See Appendix B for a Full Sample Form)

1. If a hazardous material and a non-hazardous material are described on the same shipping paper, thehazardous material must be:

A. Listed First

B. Shown In A Contrasting Color ( Highlighted On Multi-Page Or A Reproduced Form )

C. Identified With An "X" Or "RQ" Before The Proper Shipping Name In The Column Marked "HM".

2. The required shipping description on a shipping paper must be legible and printed in English.

3. Unless otherwise permitted, the required shipping description may not contain any code or abbreviation.

4. Unless otherwise permitted, additional information must be placed after the basic description required.

5. If more than one page is required, the first page must indicate such, (for example, Page 1 of 4).

6. Shipping paper must contain an emergency response telephone number.

7. Shipping paper must contain shipper's certification.

2 AMYL ACETATES - DM 3 UN1104 III 95 gal 2

The shipping description of a hazardous material on the shipping paper must include:

1. The proper shipping name prescribed for the material in column 2 of the § 172.101 table;

2. The hazard class or division prescribed for the material as shown in column 3 of the § 172.101 table;

3. The identification number prescribed for the material as shown in column 4 of the § 172.101 table;

4. The packing group in Roman numerals, as designated for the hazardous material in Column 5 of the§ 172.101 Table.

5. Except for empty packaging, the total quantity, including the unit of measurement, of the hazardousmaterial covered by the description (e.g., "800 lbs", "55 gal.", "3629 kg", or "208 L").

WE CARRY IT CORP. PH: ( 111 ) 555-55554321 DUMPIT ROADWASTETOWN, USA 01234

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SUBJECT: 704 MARKING SYSTEM



Students Materials: Workbook Page 23, 704 Marking System Wallet Card

Objectives: To give the students an understanding of how to recognize thepresence of hazardous substances in an emergency situation.

LESSON OUTLINE:1:00 pm

I. Discuss how the 704 Marking System works

II. Have the students give the answers for the exercise1:20 pm


Give the 704 marking system wallet cards to the students.

704 MARKING SYSTEM

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NFPA 704, Standard System for the Identification of the Hazards of Materials for EmergencyResponse, was developed as a manual by the Sectional Committee on Classification, Labeling andProperties of Flammable Liquids of the NFPA Committee on Flammable Liquids starting in 1952. Itsfirst adoption as a guide occurred in 1961, with regular revisions being adopted through 1987. In 1990it became an NFPA standard, and extensive quantitative health hazard rating criteria were introduced.

The purpose of the standard, as originally conceived, is to safeguard the lives of those individualswho respond to emergencies occurring in an industrial plant or storage location, or other locationwhere relatively large quantities of chemicals are used, and where the hazards of materials are notreadily apparent.

A. FLAMMABILITY B. WATER REACTIVE

V. EXERCISE:

List the most serious hazard for each substance shown.

I. HAZARDS:

A. HEALTH

B. FLAMMABILITY

C. REACTIVITY

D. SPECIAL NOTES

III. NUMBERS:

A. 4 = EXTREME

B. 3 = HIGH

C. 2 = MODERATE

D. 1 = SLIGHT

E. 0 = LEAST

IV. SPECIAL NOTES:

A. W = REACTIVE WITH WATER

B. OXY = OXIDIZING AGENT

C. COR = CORROSIVE MATERIAL

D. ALK = ALKALI

E. ACID= ACIDIC MATERIAL

II. COLORS:

A. BLUE

B. RED

C. YELLOW

D. WHITE

1

4

0 1

0

1

W

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SUBJECT: HAZARD COMMUNICATION



Student Materials: Workbook Page 24, Company Safety Data Sheet's

Objectives: To explain the importance of the Hazard Communicationstandard and the requirements that are stated in it. To give thestudents an understanding of how to use SDS's to aid inidentifying and realizing the need for additional support when incontact with Hazardous Materials.


I. Explain to students the purpose of the standard1:30 pm

II. Explain the two types of hazards presented by a chemical

III. Explain to students the items excluded from the standard

IV. Discuss the Safety Data Sheets requirements & elements

V. Explain the requirements for Container Labels

BREAK 10 minutes

Show "First On The Scene" Video 30 Minutes


HAZARD COMMUNICATION

I. PURPOSE OF § 29 CFR 1910.1200 IS TO:

A. ENSURE THAT THE HAZARDS OF ALL CHEMICALS PRODUCED OR

IMPORTED HAVE BEEN CLASSIFIED;

B. ENSURE THAT THE INFORMATION CONCERNING THEIR HAZARDS

ARE TRANSMITTED TO BOTH EMPLOYEE'S AND EMPLOYER'S;

C. ENSURE EMPLOYERS ADDRESS FIVE MAJOR AREAS:

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The employer should evaluate all chemical products that areused by employees in carrying out their responsibilities to

determine if those products are hazardous.

This requirement of the standard is for the company to provide informationconcerning the location and availability of the company's written hazard

communication program. The hazard communication program shouldinclude a list of all hazardous chemicals present in the workplace.

2. WRITTEN HAZARD COMMUNICATION PROGRAM - 1910.1200 (e)

1. HAZARD CLASSIFICATION - 1910.1200 (d)

If a hazard evaluation reveals a potential for a health orphysical hazard, an appropriate warning label must

appear on or be attached to the container.

3. CONTAINER LABELING - 1910.1200 (f)

4. SAFETY DATA SHEET USE - 1910.1200 (g)

This is a document describing the results of the health andphysical hazard evaluation the manufacturer of the producthas performed. A company must have an SDS for each

chemical in the workplace.

This requirement of the standard helps to ensure yourhealth and safety while working with hazardous materials.

(f) "Labels and other forms ofwarning.“

(g) "Material safety datasheets.“

(h) "Employee informationand training."

HazCom Training Program

(f) "Labels and other forms ofwarning.“

(g) "Material safety datasheets.“

(h) "Employee informationand training."

HazCom Training Program

5. EMPLOYEE TRAINING AND INFORMATION - 1910.1200 (h)

SUBJECT: HAZARD COMMUNICATION CONT.


LESSON OUTLINE:

I. Explain to students the purpose of the standard1:30 pm


III. Explain to students the items excluded from the standard1:40 pm


V. Explain the requirements for Container Labels

BREAK 10 minutes



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II. PRIMARY CHEMICAL HAZARDS:

The current HCS has specific criteria for each health and physical hazard,along with detailed instructions for hazard evaluation and determinations asto whether mixtures or substances are covered.

A. "Health hazard" means a chemical which is classified as posing one ofthe following hazardous effects: acute toxicity (any route of exposure); skincorrosion or irritation; serious eye damage or eye irritation; respiratory orskin sensitization; germ cell mutagenicity; carcinogenicity; reproductivetoxicity; specific target organ toxicity (single or repeated exposure); oraspiration hazard. The criteria for determining whether a chemical isclassified as a health hazard are detailed in Appendix A to §1910.1200 -- HealthHazard Criteria.

B. "Physical hazard" means a chemical that is classified as posing one of thefollowing hazardous effects: explosive; flammable (gases, aerosols, liquids,or solids); oxidizer (liquid, solid or gas); self-reactive; pyrophoric (liquid orsolid); self-heating; organic peroxide; corrosive to metal; gas underpressure; or in contact with water emits flammable gas. See Appendix B to§1910.1200 -- Physical Hazard Criteria.

III. EXCLUDED FROM THE STANDARD § 29 CFR 1910.1200(b)(6):

The following items are excluded from this standard; however, they may beregulated under a different regulation:

A. HAZARDOUS WASTE REGULATED BY THE EPA ( 1910.1200 (b)(6)(i)-(ii) )

B. TOBACCO OR TOBACCO PRODUCTS ( 1910.1200 (b)(6)(iii) )

C. UNTREATED WOOD OR WOOD PRODUCTS ( 1910.1200 (b)(6)(iv) )

D. FOOD OR ALCOHOLIC BEVERAGES ( 1910.1200 (b)(6)(vi) )

E. DRUGS FOR PERSONAL CONSUMPTION ( 1910.1200 (b)(6)(vii) )

F. COSMETICS FOR PERSONAL CONSUMPTION ( 1910.1200 (b)(6)(viii) )



LESSON OUTLINE:

I. Explain to students the purpose of the standard




V. Explain the requirements for Container Labels1:50 pm

BREAK 10 minutes



Stress the need for the students to find out where the SDS's are fortheir work location.

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IV. SAFETY DATA SHEETS (SDS):

The Hazard Communication Standard (HCS) (29 CFR 1910.1200(g)), requires thatthe chemical manufacturer, distributor, or importer provide Safety Data Sheets(SDSs) (formerly MSDSs or Material Safety Data Sheets) for each hazardouschemical to downstream users to communicate information on these hazards.The information contained in the SDS is largely the same as the MSDS, exceptnow the SDSs are required to be presented in a consistent user-friendly, 16-section format.

Sections 1 through 8 contain general information about the chemical. Sections 9through 11 and 16 contain other technical and scientific information. The SDSmust also state that no applicable information was found when the preparer doesnot find relevant information for any required element.

The SDS must also contain Sections 12 through 15, to be consistent with the UNGlobally Harmonized System of Classification and Labeling of Chemicals (GHS),but OSHA will not enforce the content of these sections because they concernmatters handled by other agencies.

A brief description of all 16 sections of the SDS is presented here:

Section 1: IDENTIFICATION

This section identifies the chemical on the SDS as well as the recommendeduses. It also provides the essential contact information of the supplier.

This section identifies the hazards of the chemical presented on the SDS andthe appropriate warning information associated with those hazards.

Section 2: HAZARD(S) IDENTIFICATION

This section identifies the ingredient(s) contained in the product indicated onthe SDS, including impurities and stabilizing additives. This section includesinformation on substances, mixtures, and all chemicals where a trade secretis claimed.

Section 3: COMPOSITION/INFORMATION ON INGREDIENTS



LESSON OUTLINE:






BREAK 10 minutes




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III. SAFETY DATA SHEETS (SDS) CONT.:

This section describes the initial care that should be given by untrainedresponders to an individual who has been exposed to the chemical.

Section 4: FIRST-AID MEASURES

This section provides recommendations for fighting a fire caused by thechemical.

Section 5: FIRE-FIGHTING MEASURES

This section provides recommendations on the appropriate response to spills,leaks, or releases, including containment and cleanup practices to prevent orminimize exposure to people, properties, or the environment. It may alsoinclude recommendations distinguishing between responses for large andsmall spills where the spill volume has a significant impact on the hazard.

Section 6: ACCIDENTAL RELEASE MEASURES

This section provides guidance on the safe handling practices and conditionsfor safe storage of chemicals.

Section 7: HANDLING AND STORAGE

This section indicates the exposure limits, engineering controls, and personalprotective measures that can be used to minimize worker exposure.

Section 8: EXPOSURE CONTROL/PERSONAL PROTECTION

This section identifies physical and chemical properties associated with thesubstance or mixture.

Section 9: PHYSICAL AND CHEMICAL PROPERTIES

This section describes the reactivity hazards of the chemical and thechemical stability information. This section is broken into three parts:reactivity, chemical stability, and other.

Section 10: STABILITY AND REACTIVITY

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LESSON OUTLINE:






BREAK 10 minutes




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III. SAFETY DATA SHEETS (SDS) CONT.:

This section identifies toxicological and health effects information or indicatesthat such data are not available.

Section 11: TOXICOLOGICAL INFORMATION

This section provides information to evaluate the environmental impact of thechemical(s) if it were released to the environment.

Section 12: ECOLOGICAL INFORMATION (non-mandatory)

This section provides guidance on proper disposal practices, recycling orreclamation of the chemical(s) or its container, and safe handling practices.To minimize exposure, this section should also refer the reader to Section 8(Exposure Controls/Personal Protection) of the SDS.

Section 13: DISPOSAL CONSIDERATIONS (non-mandatory)

This section provides guidance on classification information for shipping andtransporting of hazardous chemical(s) by road, air, rail, or sea.

Section 14: TRANSPORT INFORMATION (non-mandatory)

This section identifies the safety, health, and environmental regulationsspecific for the product that is not indicated anywhere else on the SDS.

Section 15: REGULATORY INFORMATION (non-mandatory)

This section indicates when the SDS was prepared or when the last knownrevision was made. The SDS may also state where the changes have beenmade to the previous version. You may wish to contact the supplier for anexplanation of the changes. Other useful information also may be includedhere.

Section 16: OTHER INFORMATION

Employers must ensure that the SDSs are readily accessible to employees for allhazardous chemicals in their workplace. For example, employers may keep theSDSs in a binder or on computers as long as the employees have immediateaccess to the information without leaving their work area when needed and aback-up is available for rapid access to the SDS in the case of a power outage orother emergency. ( 28 ) © NEI



LESSON OUTLINE:






BREAK 10 minutes2:00 pm

Show "First On The Scene" Video 30 Minutes2:30 pm



© NEI ( LP 29 )

V. CONTAINER LABELS:

Product Identifier Supplier Identifier Chemical IdentityHazard Pictograms Signal Words Hazard StatementsPrecautionary Information

OSHA has updated the requirements for labeling of hazardous chemicals underits Hazard Communication Standard (HCS). As of June 1, 2015, all labels will berequired to have the following:

A sample revised HCS label, identifying the required label elements, is shownbelow. Supplemental information can also be provided on the label as needed.

( 29 ) © NEI

SUBJECT: EMERGENCY RESPONSE GUIDEBOOK

Time of Lesson: 30 minute Lecture & Exercise


Students Materials: Workbook Page 30, Emergency Response Guidebook

Objectives: To give the students an understanding of how to use theEmergency Response Guidebook as a guide to protectingthemselves and the public.


I. Review the 5 sections of the Emergency Response Guidebook

II. Explain the three steps on how to use the book2:45 pm

III. Have the students complete the exercise then review it


Have the students use their book.

© NEI ( LP 30 )

EMERGENCY RESPONSE GUIDEBOOK

The Emergency Response Guidebook is primarily a guide to aid firstresponders in quickly identifying the specific or generic hazards of thematerial(s) involved in an incident, and protect themselves and thegeneral public during the initial response phase of the incident.

I. SECTIONS:

COLOR DESCRIPTION

A. WHITE TABLE OF PLACARDS

Guide numbers are circled at the top of the placards class.

B. YELLOW CHEMICALS BY ID # (NUMERICAL ORDER)

Use this section if only the chemicals ID number is known.

C. BLUE CHEMICALS BY NAME (ALPHABETICAL)

Use this section if the chemicals name is known.

D. ORANGE GUIDE SECTIONS

Use this section to find out initial information in an emergency.

E. GREEN ISOLATION DISTANCE / WATER REACTIVE

Use this section if the chemicals are highlighted in yellow or blue.

II. HOW TO USE THE GUIDEBOOK:

The following steps are used in the guidebook during an incident:

STEP 1 = IDENTIFY THE MATERIAL (BY THE NAME, ID#, OR PLACARD).

STEP 2 = LOOK UP THE MATERIAL'S 3-DIGIT GUIDE NUMBER.

STEP 3 = TURN TO THE NUMBERED GUIDE AND READ CAREFULLY.

( 30 ) © NEI

UN 1203GASOLINE

© NEI ( LP 31 )

SUBJECT: EMERGENCY RESPONSE GUIDEBOOK CONT.

Objectives: To give the students an understanding of how to use theEmergency Response Guidebook as a guide to protectingthemselves and the public.

LESSON OUTLINE:

I. Review the 5 sections of the Emergency Response Guidebook

II. Explain the three steps on how to use the book2:45 pm

III. Have the students complete the exercise then review it3:00 pm



Have the students use their book.

HEXANES

AMYL ACETATE ID 1208

USE GUIDE 129

150 FEET

GUIDE 143

150 FT. LIQUIDS

75 FT. SOLIDS

GUIDE 128

150 FEET

ID 2188---GUIDE 119

150 METERS 500 FEET

NOT LISTED

USE GUIDE 111

330 FEET

DIMETHYL ETHER

GUIDE 115 - 300 FT.

ID 2705-GUIDE 153P

150 FT. LIQUIDS

75 FT. SOLIDS

UN 1104

ARSINE UN 2553

UN 1033 1-PENTOL

III. EXERCISE:

Fill in the blanks using the Emergency Response Guidebook. Provide eitherthe product name or ID number, the guide number, and the inital isolationdistance for a small spill (when highlighted), if available.

( 31 ) © NEI

GUIDE 139

150 FT. LIQUIDS

75 FT. SOLIDS

GUIDE 171

150 FT. LIQUIDS

75 FT. SOLIDS

SUBJECT: PERSONAL PROTECTIVE EQUIPMENT




Objectives: To explain to students how to select and use proper personalprotective equipment provided to them.


I. Discuss with students the protection that PPE affords

II. Discuss the three types of protective clothing3:25 pm

III. Discuss the three types of respiratory protection

IV. Review with students the levels of protection


© NEI ( LP 32 )

( 32 ) © NEI

C. HIGH TEMPERATURE PROTECTIVE CLOTHING

There is no NFPA standard on high temperature protective clothing.

B. CHEMICAL PROTECTIVE CLOTHING

Designed and intended to provide protection, generally, againstchemical exposure. Clothing appropriate for an incident isgreatly dependent on the types of hazards that are present.

A. STRUCTURAL FIRE FIGHTING PROTECTIVE

CLOTHING

Configured as a coat and trousers, or as a coverall, anddesigned to provide protection to the fire fighter's body.

PERSONAL PROTECTIVE EQUIPMENT

The purpose of personal protective equipment is to shield orisolate individuals from the chemical, physical, and biologichazards that they may encounter.

I. SELECTION OF PROTECTION:

Careful selection and use of adequate PPE should protect the following:

A. RESPIRATORY SYSTEM E. HANDS

B. SKIN F. FEET

C. EYES G. BODY/HEAD

D. FACE H. HEARING

Personal Protective Equipment (PPE) includes both ChemicalProtective Clothing (CPC) and Respiratory Protection.

II. PROTECTIVE CLOTHING:

Protective clothing is designed to protect the wearer from heat and/orhazardous materials contacting the skin or eyes. Protective clothingis divided into three types:

SUBJECT: PERSONAL PROTECTIVE EQUIPMENT CONT.

Objectives: To explain to students how to select and use proper personalprotective equipment provided to them.

LESSON OUTLINE:

I. Discuss with students the protection that PPE should afford

II. Discuss the three types of protective clothing3:25 pm

III. Discuss the three types of respiratory protection

IV. Review with students the levels of protection3:40 pm


© NEI ( LP 33 )

III. RESPIRATORY PROTECTION:

Equipment designed to protect the wearer from the inhalation of contaminants.Respiratory protection is divided into three types:

C. AIR PURIFYING RESPIRATORS ( APR )Passes ambient air through a filtering or absorbing deviceprior to inhalation by the user. They do not have a separateair supply.

A. SELF-CONTAINED BREATHING APPARATUS ( SCBA )A respirator worn by the user that supplies a respirableatmosphere that is either carried in or generated by theapparatus.

IV. LEVELS OF PROTECTION:

Personal protective equipment is divided into four categories based on thedegree of protection afforded.

A. LEVEL A Selected when the greatest level of skin, respiratory, and eyeprotection is required.

B. LEVEL B Selected when the highest level of respiratory protection isnecessary but a lesser level of skin protection is needed.

C. LEVEL C Concentration(s) and type(s) of airborne substance is knownand the criteria for using air purifying respirators are met.

D. LEVEL D A work uniform affording minimal protection, used fornuisance contamination only.

The selection of Personal Protective Equipment should be based onthe hazardous materials and/or conditions present and

be appropriate for the hazards encountered.

Inhalation of toxics is one of the principal causes of serious injury toresponders, so respiratory protection is of the utmost importance.

B. SUPPLIED AIR RESPIRATORS ( SAR )Supplies breathing air from a source located at somedistance from the user and connected to the user byan air-line hose.

( 33 ) © NEI

SUBJECT: HAZARDOUS MATERIALS DEFINITIONS




Objectives: To give students an understanding of basic hazardous materialterms they may encounter while review different types ofreference sources.


Review hazardous materials terms with students4:05 pm

BREAK 10 minutes


TAKE A LOOK AT YOUR TIME:

If you are running out of time, take less time going over thisinformation. If you need to add more time, go over this informationin detail.

© NEI ( LP 34 )

HAZARDCOMMUNICATION

GLOSSARY

ACUTE EFFECT - An adverse effect on a human or animal, withsymptoms developing rapidly and quickly becoming a crisis.See "Chronic Effect".

ANTIDOTE - An agent that neutralizes or counteracts the effectsof a poison.

ASPHYXIANTS - A chemical gas or vapor that can cause uncon-sciousness or death by suffocation. Simple asphyxiates,such as nitrogen, either use up or displace oxygen in the air.Chemical asphyxiates, such as carbon monoxide, interferewith the body's ability to receive or use an adequate supplyof oxygen.

BOILING POINT - The temperature at which liquid changes to avapor. Expressed in degrees Fahrenheit at sea levelpressure. Flammable materials with low boiling pointsgenerally present special fire hazards.

BURNBACK - The distance a flame will travel from the ignitionsource back to the aerosol container.

C.A.S. NUMBER - Chemical Abstracts Service, a service of theAmerican Chemical Society, identifies particular chemicalswith a number.

CARCINOGEN - A chemical is considered to be a carcino-gen if it is a substance or agent that may causecancer in humans or animals.

CHEMICAL - An element, chemical compound or mixture ofelements and/or compounds.

CHEMICAL FAMILY - Agroup of compounds with related chemicaland physical properties, such as ketone or aldehyde family.

CHEMICAL NAME - The scientific designation of a chemical inaccordance with the naming system developed by theInternational Union of Pure and Applied Chemistry.

CHRONIC EFFECT - An adverse effect on an animal or human.Symptoms develop slowly over a long period of time or recurfrequently.

CARBON DIOXIDE - (CO2) Aheavy, colorless, nonflammable and

relatively nontoxic gas. Produced by the combustion anddecomposition of organic substances and as a by-product ofmany chemical processes. Also used as a fire fighting agent.

COMBUSTIBLE - A substance capable of fueling a fire. Accordingto DOT, any liquid having a flash point at or above 140oF andless than 200oF is a combustible liquid.

CONCENTRATION - The amount of a substance in a stated unit ofmixture or solution. For example, 5 parts (of acetone) permillion (parts air). See PPM

CORROSIVE - Asubstance that, according to the DOT, causesvisible destruction or permanent changes in human skintissue at the site of contact. Or, a liquid that has a severecorrosive rate on steel.

DECOMPOSITION - The breakdown of a chemical or substanceinto different parts or simpler compounds. Decompositioncan occur due to heat, chemical reaction, decay, etc.

DEFATTING - The removal of natural oils from the skin by fatdissolving solvent.

DERMATITIS - An inflammation of the skin.

D.O.T. - The U.S. Department of Transportation regulates thetransportation of materials.

EMULSION - A stable mixture of two or more immiscible liquidsheld in suspension by small percentages of substancescalled emulsifiers.

EVAPORATION RATE - The rate at which a material is convertedto vapor (evaporates) at a given temperature and pressurewhen compared to the evaporation rate of a givensubstance. For example, this MSDS shows n-BuAc(normal butyl acetate) as a given substance.

EXPOSURE - Subjection to a hazardous chemical through anyroute of entry (inhalation, ingestion, injection, andabsorption).

FLAME EXTENSION - The distance a flame will travel from theaerosol container when exposed to an ignition source.

FLAMMABLE - A material that is easily ignited and burns veryrapidly.

FLAMMABLE LIQUID - As defined by DOT, any liquid with aflash point below 140oF.

FLASH POINT - The minimum temperature at which a liquid willgive off enough flammable vapor just above the surface toignite in the presence of an ignition source.

HAZARDOUS CHEMICAL - Any chemical that is a physical orhealth hazard.

HEALTH HAZARD - Means a chemical which is classified asposing one of the following hazardous effects: acutetoxicity (any route of exposure); skin corrosion or irritation;serious eye damage or eye irritation; respiratory or skinsensitization; germ cell mutagenicity; carcinogenicity;reproductive toxicity; specific target organ toxicity (singleor repeated exposure); or aspiration hazard.

IGNITABLE - Asolid, liquid, or compressed gas that has a flashpoint of less than 140oF. Capable of being set on fire.

INCOMPATIBLE - The term used for two substances to indicatethat one material cannot be mixed with the other withoutthe possibility of a dangerous reaction.

INGESTION - Taking a substance into the body through themouth.

INHALATION - The breathing of an airborne substance into thebody (lungs), through the nose, mouth and breathingpassages. May be in the form of a gas, vapor, fume, mist ordust.

IRRITANT - A substance that produces an irritating effect whenit contacts the skin, eyes, nose or respiratory system.

( 34 ) © NEI

© NEI ( LP 35 )

SUBJECT: HAZARDOUS MATERIALS DEFINITIONS CONT.

Objectives: To give students an understanding of basic hazardous materialterms they may encounter while review different types ofreference sources.


Review hazardous materials terms with students4:05 pm



TAKE A LOOK AT YOUR TIME:

If you are running out of time, take less time going over thisinformation. If you need to add more time, go over this informationin detail.

LOWER EXPLOSIVE LIMIT - (LEL) The lowest concentration of asubstance that will produce a fire or flash when an ignitionsource is present. It is expressed as a percent of vapor orgas in the air by volume. At concentrations below the LEL,the mixture is too "lean" to burn.

MELTING POINT - The temperature at which a solid substancechanges to a liquid.

MIXTURE - Any combination of two or more chemicals if thecombination is not, in whole or in part, the result of achemical reaction.

MUTAGEN - Asubstance or agent capable of changing the geneticmaterial of a living cell.

N/A - An abbreviation for Not Applicable.

NARCOSIS - Stupor or unconsciousness caused by exposure to achemical.

NIOSH - The National Institute for Occupational Safety and Healthis a federal agency that trains occupational health and safetyprofessionals, conducts research and tests and certifiesrespirators, etc.

OSHA - The Occupational Safety and Health Administration is afederal agency that publishes and enforces health and safetyregulations for most businesses and industries.

OXIDIZER - A chemical that initiates or promotes combustion inother materials, thereby causing fire either of itself orthrough the release of oxygen or other gases.

PERMISSIBLE EXPOSURE LIMIT - (PEL) An exposure limitestablished by OSHA as a legal standard. May be a time-weighted average (TWA) limit or a minimum concentrationexposure limit.

pH - Value that represents the acidity or alkalinity of an aqueous(water-based) solution.

PHYSICAL HAZARD - Means a chemical that is classified asposing one of the following hazardous effects: explosive;flammable (gases, aerosols, liquids, or solids); oxidizer(liquid, solid or gas); self-reactive; pyrophoric (liquid or solid);self-heating; organic peroxide; corrosive to metal; gas underpressure; or in contact with water emits flammable gas.

PARTS PER MILLION (PPM) - Aunit for measuring theconcentration of a gas or vapor in contaminated air. Alsoused to indicate the concentration of a particular substancein a liquid or solid.

POLYMERIZATION - Achemical reaction in which one or moresmall molecules combine to form larger molecules. Ahazardous polymerization is a reaction that takes place at arate that releases large amounts of energy.

REACTIVITY - A substance's tendency to undergo a chemicalreaction or change that may result in dangerous side effects,such as explosion, burning and corrosive or toxic emissions.

RESPIRATOR - A device that is designed to protect the wearerfrom inhaling harmful contaminants.

SENSITIZER - A substance that may cause no reaction in a personduring initial exposure, but to which further exposure willcause an allergic response.

SOLUBILITY - The percentage of a material (by weight) that willdissolve in water at a specified temperature.

SPECIFIC GRAVITY - The weight of a material compared to theweight of an equal volume of water; an expression of thedensity (or heaviness) of the material. Insoluble materialswith specific gravity less than 1 will float, an importantconsideration for fire suppression and spill clean up.

TERATOGEN - Asubstance or agent to which exposure of apregnant female can cause malformations in the fetus.

THRESHOLD LIMIT VALUE (TLV) - Aterm used to express theairborne concentration of a material to which nearly allpersons can be exposed day after day without adverseeffects.

TOXIN - A substance that is poisonous to varying degrees.

UPPER EXPLOSIVE LIMIT (UEL) - The highest concentration of asubstance that will burn or explode when an ignitionsource is present. Expressed in percent of vapor or gas inthe air by volume.

UNSTABLE - Achemical that in the pure state, will vigorouslypolymerize, decompose, condense, or become self-reactive under conditions of shock, pressure ortemperature.

VAPOR - The gaseous form of substances that are usuallyliquid or solid.

VAPOR DENSITY - The weight of a vapor or gas compared to theweight of an equal volume of air. An expression of densityof the vapor or gas. Materials lighter than air have vapordensities less than 1. Lighter materials tend to rise anddissipate. Heavier vapors are likely to concentrate in lowplaces where they may create fire or health hazards.

VAPOR PRESSURE - The pressure exerted by a saturated vaporabove its own liquid in a closed container. Vapor pressureis usually expressed as pounds per square inch, but onMSDS's is in millimeters of mercury (mmHG) at 68oF. Thelower the boiling point of a substance, the higher its vaporpressure.

VISCOSITY - A fluid's internal resistance to flow.

VOLATILE - The tendency or ability of a liquid to vaporize.Liquids such as alcohol or gasoline are volatile becausethey have a tendency to evaporate quickly.

WATER-REACTIVE - Achemical that reacts with water torelease a gas that is either flammable or presents a healthhazard.

( 35 ) © NEI

© NEI ( LP 36 )

Supplemental information to be used at the Instructor's discretion.



NOTE TO INSTRUCTOR:

Have a copy of your company's form available

( 39 ) © NEI

Attachment " C "

EMPLOYEE: DATE:

DOT HAZMAT training consists of four modules. One of these modules is Drivers training, it isintended to ensure that all over-the-road drivers receive training regarding the safe

operation of the motor vehicle they operate or intend to operate.

DOT HAZMAT allows companies and trainers/instructors the freedom to provide the amountand level of training and testing they deem adequate and necessary.

Please initial below to signify that the employee has adequate training in the following areas,as are necessary for his or her specific job function. (Mark blank with an "X" if it does notapply to a specific job function.)

Supervisor Employee

____ ____ 1. Hazardous Materials Table (How to locate table and information found in the table

____ ____ 2. Shipping Papers (Entrees legible/in English and the contents of the documents.)

____ ____ 3. Packaging and Package Marking (Performance Packing and Packing Groups)

____ ____ 4. Labeling (Hazard classes, divisions, and label visibility.)

____ ____ 5. Placarding (Location on vehicle and visibility.)

____ ____ 6. Loading & Securement (Separation distances, segregation, and compatibility.)

____ ____ 7. Emergency Rsponse (Basic emergency training, basic first aid, and risksassociated with specific chemicals handled.)

8. Please list any other topics of training received that are important to theemployee's specific job function.

a.

b.

c.

d.

Please certify by signing below that the employee named herein has received the traininginitialed above.

SUPERVISOR _______________________________

EMPLOYEE _______________________________

FUNCTION SPECIFIC TRAINING VERIFICATION49 CFR 172.704 (a)(2)

Attachment " D "

EMPLOYEE: DATE:

DOT HAZMAT training consists of four modules. One of these modules is Drivers training, it isintended to ensure that all over-the-road drivers receive training regarding the safeoperation of the motor vehicle they operate or intend to operate.

DOT HAZMAT allows companies and trainers/instructors the freedom to provide the amountand level of training and testing they deem adequate and necessary.

Please initial below to signify the employee has adequate training in the following areas, as arenecessary for his or her specific job function. (Mark blank with an "X" if it does notapply to a specific job function.)

Supervisor Employee

____ ____ 1. CDL with hazardous materials endorsement.

____ ____ 2. Cargo Tank Operations (Inspection requirements & operation of emergencycontrol features.)

____ ____ 3. Portable Tank Operations (Vehicle handling with regard to sloshing, surging &stability.)

____ ____ 4. Pre-tip Inspection (Operators manual, including inspection information.)

____ ____ 5. Vehicle Controls, Equipment, and Emergency Equipment (Function &procedure of all controls and equipment.)

____ ____ 6. Vehicle Operation (Driving basics, turning, backing up etc.)

____ ____ 7. Navigating Tunnels, Bridges, and Railroad Crossings (Discuss hazmatregulations that apply as well as company policy.)

____ ____ 8. Company Guidelines (Smoking, routing, & incident report.)

____ ____ 9. Loading and Unloading (Compatibility, segregation, & package handling.)

Please certify by signing below that the employee named herein has received the traininginitialed above.

SUPERVISOR _______________________________

EMPLOYEE _______________________________

DRIVERS TRAINING VERIFICATION49 CFR 177.816

( 40 ) © NEI

SUBJECT: HAZMAT TRANSPORTATION SECURITY AWARENESS


Instructor Training Aids: Security Awareness CD-ROM

Students Materials: None

LESSON OUTLINE:

Before students take the test have them watch the Security Awareness CD.


You may use the Test that is provided on the next page. That test will testthe student on the contents of the security awareness cd.

© NEI ( LP 41 )

HAZMAT TRANSPORTAION SECURITY AWARENESS

Changes effective March 25, 2003, impose new security requirements for hazardous materialshippers and carriers that include mandatory security awareness training and written security plans.These new security requirements are designed to increase awareness of terrorist threats to thecarriers of any hazardous material.

DOT has released a training module CD that meets this security training requirement. Themodule reviews vulnerabilities and preventive safety measures to help ensure a safe shipment. Thetraining focuses on helping employees recognize possible threats involving hazmats that could beused as weapons: Flammable fuels, chlorine gas, and ammonium nitrate are used as examples.

While this module has been approved by DOT to satisfy the training requirements for hazmatsecurity, all hazmat employers are still required to ensure hazmat security risks not covered in themodule have been addressed in their employee training.

( 41 ) © NEI

SUBJECT: HAZMAT TRANSPORTATION SECURITY AWARENESS


Instructor Training Aids: Security Awareness CD-ROM

Students Materials: None

LESSON OUTLINE:

Before students take the test have them watch the Security Awareness CD.


You may use this Test in addition the the course test. This test will test thestudent on the contents of the security awareness cd.

© NEI ( LP iii )

HAZMAT SECURITY MODULE FINAL TEST

NAME: _______________________________ DATE: _________________

SCORE: _____________________________

1. Many materials that are classified as hazardous materials are T Fessential products to industry, but potential deadly weaponsin the hands of a terrorist.

2. Hazardous materials are least vulnerable when in transit. T F

3. Casual discussions with strangers along transportation routes T Fabout loads and destinationsare encouraged by general securitystandards.

4. Some mixtures containing hazardous materials can cause a T Fpowerful explosion if detonated or ignited.

5. One easy way to increase security of hazardous materials in T Ftransportation is to lock alldoors of transport vehicles.

6. The most likely terrorist threats are internal. T F

7. With the use of commonplace equipment like scanners and T Fcolor printers, a driver’s license, certifications, passports, andother types of personal identification can be forged.

8. All terrorists fit a preconceived picture of a criminal. T F

9. A careful employee background check and verification of T Finformation provided on an employment application can bean effective deterrent to the insider threat.

10. When you are questioned about hazardous materials transportation T Fit is important that you know the person asking and that he or shehas a need to know.

© NEI

INSTRUCTOR'S KEY

© NEI ( LP iv )

SUBJECT: COURSE REVIEW AND FINAL TEST



Students Materials: Workbook, Course Test

Objectives: To measure and improve student comprehension of materialspresented in this course.


I. Course Review

A. Review each area discussed

B. Answer questions as applicable

II. Administer Test

A. Rules

1. Do your own work

2. 20 minute time limit

3. Leave area after completion

B. Review test, cover any incorrect answers, and answer any questions

III. Have students complete course critique5:00 pm


DEPARTMENT OF TRANSPORTATIONHAZMAT TRAINING COURSE

[ 49 CFR 172.704 ]

COURSE TEST© 2012 New Environment, Inc.

All rights reserved.

© NEI

INSTRUCTOR'S KEYSTUDENT NAME:

DATE ADMINISTERED:

INSTRUCTOR'S NAME:

STUDENT SCORE:

GENERAL INSTRUCTIONS:

You have twenty minutes to complete twenty questions.

Carefully read the instructions given at thebeginning of each section, if any.

Read each question twice.

Do your own work.

WAIT TO BEGIN, UNTIL INSTRUCTED.

Define the following term.

1. Hazardous materials -A SUBSTANCE OR MATERIAL WHICH HAS BEEN DETERMINED TO BECAPABLE OF POSING AN UNREASONABLE RISK TO HEALTH, SAFETY, ANDPROPERTY WHEN TRANSPORTED IN COMMERCE AND WHICH HAS BEEN SODESIGNATED.

Circle the letter preceding the Most Correct response.

2. A Safety Data Sheet (SDS) would most likely be supplied by:

a) The secretaryb) Roger Clemensc) The manufacturerd) The EPA

3. The 704 Marking System provides hazard information in reference to:

a) Health Hazardb) Fire Hazardc) Reactivity Hazardd) All of the above

4. Which of the following is most likely to provide information on proper storageprocedures?

a) D.O.T. Emergency Response Guidebookb) Safety Data Sheetsc) Labels and Placardsd) None of the above

5. Which of the following is listed as a class two hazardous material?

a) Poisonous Gasesb) Flammable Solidsc) Oxidizersd) Poisonous Materials

6. The Emergency Response Guidebook provides:

a) Initial actions for emergency situationsb) Help in Identifying chemicalsc) Isolation distancesd) All of the above

7. Which of the following would use an air-purifying respirator.

a) Level Ab) Level Bc) Level Cd) All of the above

( 1 ) © NEI

8. Clothing appropriate for an incident is greatly dependant upon what?

a) Type of material availableb) Cost of materialc) Types of hazard presentd) Site location

Fill in the blank with the correct color for the Emergency Response Guidebook

9. Table of Placards WHITE

10. Chemicals listed by ID # YELLOW

11. Chemicals listed by name BLUE

12. Guide section ORANGE

13. Isolation Distance GREEN

Indicate if the following statements are True (T) or False (F).

14. Dynamite falls into the radioactive hazard class. T F

15. An employee should know where the SDS is for each hazardous T Fchemical in the work area.

16. An employer must have a SDS for only hazard class 9 chemicals. T F

Fill in the blank with the correct color for the NFPA704 Marking System.

17. Reactivity YELLOW

18. Special Notes WHITE

19. Flammability RED

20. Health BLUE

( 2 ) © NEI

department of transportation hazmat ......department of transportation hazmat training course [ 49...

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