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2019/3/27 RightsLink Printable License https://s100.copyright.com/AppDispatchServlet 1/1 SPRINGER NATURE LICENSE TERMS AND CONDITIONS Ma This Agreement between Virginia Tech -- Shaoyang Lin ("Y and Springer Nature ("Springer Nature") consists of your lic details and the terms and conditions provided by Springer and Copyright Clearance Center. License Number 4557220740046 License date Mar 27, 2019 Licensed Content Publisher Springer Nature Licensed Content Publication Nature Licensed Content Title Crystal structure of oxygen-evolving photosystem II at a of 1.9 Å Licensed Content Author Yasufumi Umena, Keisuke Kawakami, Jian-Ren Shen, Nob Licensed Content Date Apr 17, 2011 Licensed Content Volume 473 Licensed Content Issue 7345 Type of Use Thesis/Dissertation Requestor type academic/university or research institute Format electronic Print This Page

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SPRINGER NATURE LICENSE TERMS AND CONDITIONS

Ma

This Agreement between Virginia Tech -- Shaoyang Lin ("Yand Springer Nature ("Springer Nature") consists of your licdetails and the terms and conditions provided by Springer and Copyright Clearance Center.

License Number 4557220740046

License date Mar 27, 2019

Licensed Content Publisher Springer Nature

Licensed Content Publication Nature

Licensed Content Title Crystal structure of oxygen-evolving photosystem II at a of 1.9 Å

Licensed Content Author Yasufumi Umena, Keisuke Kawakami, Jian-Ren Shen, Nob

Licensed Content Date Apr 17, 2011

Licensed Content Volume 473

Licensed Content Issue 7345

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Title: Mechanism of Water Oxidation

by Single-Site RutheniumComplex Catalysts

Author: Javier J. Concepcion, Ming-KangTsai, James T. Muckerman, et al

Publication: Journal of the AmericanChemical Society

Publisher: American Chemical SocietyDate: Feb 1, 2010Copyright © 2010, American Chemical Society

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Title: Mononuclear Ruthenium(II)

Complexes That Catalyze WaterOxidation

Author: Huan-Wei Tseng, Ruifa Zong,James T. Muckerman, et al

Publication: Inorganic ChemistryPublisher: American Chemical SocietyDate: Dec 1, 2008Copyright © 2008, American Chemical Society

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Title: Mechanisms of Water Oxidation

Catalyzed by the cis,cis-[(bpy)2Ru(OH2)]2O4 Ion

Author: Hiroshi Yamada, William F.Siems, Tohru Koike, et al

Publication: Journal of the AmericanChemical Society

Publisher: American Chemical SocietyDate: Aug 1, 2004Copyright © 2004, American Chemical Society

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Title: Elucidating Molecular Iridium

Water Oxidation Catalysts UsingMetal–Organic Frameworks: AComprehensive Structural,Catalytic, Spectroscopic, andKinetic Study

Author: Cheng Wang, Jin-Liang Wang,Wenbin Lin

Publication: Journal of the AmericanChemical Society

Publisher: American Chemical SocietyDate: Dec 1, 2012Copyright © 2012, American Chemical Society

Logged in as: Shaoyang Lin Virginia Tech Account #: 3001275027

 

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Licensed Content Title Sustained Water Oxidation by a Catalyst Cage-Isolated in a Metal–Organic Framework

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Title: New Powerful and Oxidatively

Rugged Dinuclear Ru WaterOxidation Catalyst: Control ofMechanistic Pathways byTailored Ligand Design

Author: Sven Neudeck, Somnath Maji,Isidoro López, et al

Publication: Journal of the AmericanChemical Society

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JOHN WILEY AND SONS LICENSE TERMS AND CONDITIONS

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This Agreement between Virginia Tech -- Shaoyang Lin ("You")and John Wiley and Sons ("John Wiley and Sons") consists of yourlicense details and the terms and conditions provided by JohnWiley and Sons and Copyright Clearance Center.

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Licensed Content Publisher John Wiley and Sons

Licensed Content Publication ChemSusChem

Licensed Content Title Insight into Metal–Organic Framework Reactivity: Chemical WaterOxidation Catalyzed by a [Ru(tpy)(dcbpy)(OH2)]2 -Modified UiO-67

Licensed Content Author Shaoyang Lin, Alireza K. Ravari, Jie Zhu, et al

Licensed Content Date Jan 5, 2018

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Licensed Content Pages 8

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Functionalized Metal-Organic Frameworks for Water OxidationCatalysis

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Publication), translated, reproduced, transferred ordistributed, in any form or by any means, and no derivativeworks may be made based on the Wiley Materials withoutthe prior permission of the respective copyright owner.ForForSTM Signatory Publishers clearing permission under theSTM Signatory Publishers clearing permission under theterms of the terms of the STM Permissions GuidelinesSTM Permissions Guidelines only, the terms of only, the terms ofthe license are extended to include subsequent editions andthe license are extended to include subsequent editions andfor editions in other languages, provided such editions arefor editions in other languages, provided such editions arefor the work as a whole in situ and does not involve thefor the work as a whole in situ and does not involve theseparate exploitation of the permitted figures or extracts,separate exploitation of the permitted figures or extracts, Youmay not alter, remove or suppress in any manner anycopyright, trademark or other notices displayed by the WileyMaterials. You may not license, rent, sell, loan, lease, pledge,offer as security, transfer or assign the Wiley Materials on astand-alone basis, or any of the rights granted to youhereunder to any other person.

The Wiley Materials and all of the intellectual property rightstherein shall at all times remain the exclusive property of JohnWiley & Sons Inc, the Wiley Companies, or their respectivelicensors, and your interest therein is only that of havingpossession of and the right to reproduce the Wiley Materialspursuant to Section 2 herein during the continuance of thisAgreement. You agree that you own no right, title or interestin or to the Wiley Materials or any of the intellectual propertyrights therein. You shall have no rights hereunder other thanthe license as provided for above in Section 2. No right,license or interest to any trademark, trade name, service markor other branding ("Marks") of WILEY or its licensors isgranted hereunder, and you agree that you shall not assertany such right, license or interest with respect thereto

NEITHER WILEY NOR ITS LICENSORS MAKES ANYWARRANTY OR REPRESENTATION OF ANY KIND TO YOUOR ANY THIRD PARTY, EXPRESS, IMPLIED OR STATUTORY,WITH RESPECT TO THE MATERIALS OR THE ACCURACY OFANY INFORMATION CONTAINED IN THE MATERIALS,INCLUDING, WITHOUT LIMITATION, ANY IMPLIEDWARRANTY OF MERCHANTABILITY, ACCURACY,SATISFACTORY QUALITY, FITNESS FOR A PARTICULAR

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WILEY OPEN ACCESS TERMS AND CONDITIONSWILEY OPEN ACCESS TERMS AND CONDITIONSWiley Publishes Open Access Articles in fully Open AccessJournals and in Subscription journals offering Online Open.Although most of the fully Open Access journals publish openaccess articles under the terms of the Creative CommonsAttribution (CC BY) License only, the subscription journals and afew of the Open Access Journals offer a choice of CreativeCommons Licenses. The license type is clearly identified on thearticle.The Creative Commons Attribution LicenseThe Creative Commons Attribution LicenseThe Creative Commons Attribution License (CC-BY) allows usersto copy, distribute and transmit an article, adapt the article andmake commercial use of the article. The CC-BY license permitscommercial and non-Creative Commons Attribution Non-Commercial LicenseCreative Commons Attribution Non-Commercial LicenseThe Creative Commons Attribution Non-Commercial (CC-BY-NC)License permits use, distribution and reproduction in anymedium, provided the original work is properly cited and is notused for commercial purposes.(see below)

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The Creative Commons Attribution Non-Commercial-NoDerivsLicense (CC-BY-NC-ND) permits use, distribution andreproduction in any medium, provided the original work isproperly cited, is not used for commercial purposes and nomodifications or adaptations are made. (see below)Use by commercial "for-profit" organizationsUse by commercial "for-profit" organizationsUse of Wiley Open Access articles for commercial, promotional,or marketing purposes requires further explicit permission fromWiley and will be subject to a fee.Further details can be found on Wiley Online Libraryhttp://olabout.wiley.com/WileyCDA/Section/id-410895.html Other Terms and Conditions:Other Terms and Conditions:

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JOHN WILEY AND SONS LICENSE TERMS AND CONDITIONS

Mar 29, 2019

This Agreement between Virginia Tech -- Shaoyang Lin ("You")and John Wiley and Sons ("John Wiley and Sons") consists of yourlicense details and the terms and conditions provided by JohnWiley and Sons and Copyright Clearance Center.

License Number 4558290056366

License date Mar 29, 2019

Licensed Content Publisher John Wiley and Sons

Licensed Content Publication ChemSusChem

Licensed Content Title Electrochemical Water Oxidation by a Catalyst-Modified Metal–Organic Framework Thin Film

Licensed Content Author Shaoyang Lin, Yuliana Pineda-Galvan, William A. Maza, et al

Licensed Content Date Dec 15, 2016

Licensed Content Volume 10

Licensed Content Issue 3

Licensed Content Pages 9

Type of use Dissertation/Thesis

Requestor type Author of this Wiley article

Format Electronic

Portion Full article

Will you be translating? No

Title of your thesis /dissertation

Functionalized Metal-Organic Frameworks for Water OxidationCatalysis

Expected completion date Apr 2019

Expected size (number ofpages)

190

Requestor Location Virginia Tech 460 Davison Hall

BLACKSBURG, VA 24060

United States Attn: Shaoyang Lin

Publisher Tax ID EU826007151

Total 0.00 USD

Terms and Conditions

TERMS AND CONDITIONSTERMS AND CONDITIONSThis copyrighted material is owned by or exclusively licensed toJohn Wiley & Sons, Inc. or one of its group companies (eacha"Wiley Company") or handled on behalf of a society with which aWiley Company has exclusive publishing rights in relation to a

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particular work (collectively "WILEY"). By clicking "accept" inconnection with completing this licensing transaction, you agreethat the following terms and conditions apply to this transaction(along with the billing and payment terms and conditionsestablished by the Copyright Clearance Center Inc., ("CCC's Billingand Payment terms and conditions"), at the time that you openedyour RightsLink account (these are available at any time athttp://myaccount.copyright.com). Terms and ConditionsTerms and Conditions

The materials you have requested permission to reproduceor reuse (the "Wiley Materials") are protected by copyright. You are hereby granted a personal, non-exclusive, non-sublicensable (on a stand-alone basis), non-transferable,worldwide, limited license to reproduce the Wiley Materialsfor the purpose specified in the licensing process. Thislicense, and any CONTENT (PDF or image file) purchased asand any CONTENT (PDF or image file) purchased aspart of your order,part of your order, is for a one-time use only and limited toany maximum distribution number specified in the license.The first instance of republication or reuse granted by thislicense must be completed within two years of the date of thegrant of this license (although copies prepared before theend date may be distributed thereafter). The Wiley Materialsshall not be used in any other manner or for any otherpurpose, beyond what is granted in the license. Permission isgranted subject to an appropriate acknowledgement given tothe author, title of the material/book/journal and thepublisher. You shall also duplicate the copyright notice thatappears in the Wiley publication in your use of the WileyMaterial. Permission is also granted on the understandingthat nowhere in the text is a previously published sourceacknowledged for all or part of this Wiley Material. Any thirdparty content is expressly excluded from this permission.

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Publication), translated, reproduced, transferred ordistributed, in any form or by any means, and no derivativeworks may be made based on the Wiley Materials withoutthe prior permission of the respective copyright owner.ForForSTM Signatory Publishers clearing permission under theSTM Signatory Publishers clearing permission under theterms of the terms of the STM Permissions GuidelinesSTM Permissions Guidelines only, the terms of only, the terms ofthe license are extended to include subsequent editions andthe license are extended to include subsequent editions andfor editions in other languages, provided such editions arefor editions in other languages, provided such editions arefor the work as a whole in situ and does not involve thefor the work as a whole in situ and does not involve theseparate exploitation of the permitted figures or extracts,separate exploitation of the permitted figures or extracts, Youmay not alter, remove or suppress in any manner anycopyright, trademark or other notices displayed by the WileyMaterials. You may not license, rent, sell, loan, lease, pledge,offer as security, transfer or assign the Wiley Materials on astand-alone basis, or any of the rights granted to youhereunder to any other person.

The Wiley Materials and all of the intellectual property rightstherein shall at all times remain the exclusive property of JohnWiley & Sons Inc, the Wiley Companies, or their respectivelicensors, and your interest therein is only that of havingpossession of and the right to reproduce the Wiley Materialspursuant to Section 2 herein during the continuance of thisAgreement. You agree that you own no right, title or interestin or to the Wiley Materials or any of the intellectual propertyrights therein. You shall have no rights hereunder other thanthe license as provided for above in Section 2. No right,license or interest to any trademark, trade name, service markor other branding ("Marks") of WILEY or its licensors isgranted hereunder, and you agree that you shall not assertany such right, license or interest with respect thereto

NEITHER WILEY NOR ITS LICENSORS MAKES ANYWARRANTY OR REPRESENTATION OF ANY KIND TO YOUOR ANY THIRD PARTY, EXPRESS, IMPLIED OR STATUTORY,WITH RESPECT TO THE MATERIALS OR THE ACCURACY OFANY INFORMATION CONTAINED IN THE MATERIALS,INCLUDING, WITHOUT LIMITATION, ANY IMPLIEDWARRANTY OF MERCHANTABILITY, ACCURACY,SATISFACTORY QUALITY, FITNESS FOR A PARTICULAR

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PURPOSE, USABILITY, INTEGRATION OR NON-INFRINGEMENT AND ALL SUCH WARRANTIES ARE HEREBYEXCLUDED BY WILEY AND ITS LICENSORS AND WAIVED BYYOU.

WILEY shall have the right to terminate this Agreementimmediately upon breach of this Agreement by you.

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IN NO EVENT SHALL WILEY OR ITS LICENSORS BE LIABLETO YOU OR ANY OTHER PARTY OR ANY OTHER PERSONOR ENTITY FOR ANY SPECIAL, CONSEQUENTIAL,INCIDENTAL, INDIRECT, EXEMPLARY OR PUNITIVEDAMAGES, HOWEVER CAUSED, ARISING OUT OF OR INCONNECTION WITH THE DOWNLOADING, PROVISIONING,VIEWING OR USE OF THE MATERIALS REGARDLESS OF THEFORM OF ACTION, WHETHER FOR BREACH OF CONTRACT,BREACH OF WARRANTY, TORT, NEGLIGENCE,INFRINGEMENT OR OTHERWISE (INCLUDING, WITHOUTLIMITATION, DAMAGES BASED ON LOSS OF PROFITS,DATA, FILES, USE, BUSINESS OPPORTUNITY OR CLAIMS OFTHIRD PARTIES), AND WHETHER OR NOT THE PARTY HASBEEN ADVISED OF THE POSSIBILITY OF SUCH DAMAGES.THIS LIMITATION SHALL APPLY NOTWITHSTANDING ANYFAILURE OF ESSENTIAL PURPOSE OF ANY LIMITED REMEDYPROVIDED HEREIN.

Should any provision of this Agreement be held by a court ofcompetent jurisdiction to be illegal, invalid, or unenforceable,that provision shall be deemed amended to achieve as nearlyas possible the same economic effect as the originalprovision, and the legality, validity and enforceability of theremaining provisions of this Agreement shall not be affectedor impaired thereby.

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These terms and conditions together with CCC's Billing andPayment terms and conditions (which are incorporatedherein) form the entire agreement between you and WILEYconcerning this licensing transaction and (in the absence offraud) supersedes all prior agreements and representationsof the parties, oral or written. This Agreement may not beamended except in writing signed by both parties. ThisAgreement shall be binding upon and inure to the benefit ofthe parties' successors, legal representatives, and authorizedassigns.

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Chemical Science

Is iron unique in promoting electrical conductivity in MOFs?

Lei Sun,   Christopher H. Hendon,   Sarah S. Park,   Yuri Tulchinsky,   Ruomeng Wan,   Fang Wang,   Aron Walsh   and  Mircea Dincă*  

Abstract

Identifying the metal ions that optimize charge transport and charge density in metal–organic frameworks is critical for systematic

improvements in the electrical conductivity in these materials. In this work, we measure the electrical conductivity and activation

energy for twenty different MOFs pertaining to four distinct structural families: M (DOBDC)(DMF) (M = Mg , Mn , Fe , Co , Ni ,

Cu , Zn ); H DOBDC = 2,5-dihydroxybenzene-1,4-dicarboxylic acid; DMF = N,N-dimethylformamide), M (DSBDC)(DMF) (M =

Mn , Fe ; H DSBDC = 2,5-disulfhydrylbenzene-1,4-dicarboxylic acid), M Cl (BTDD)(DMF) (M = Mn , Fe , Co , Ni ; H BTDD =

bis(1H-1,2,3-triazolo[4,5-b],[4′,5′-i]dibenzo[1,4]dioxin), and M(1,2,3-triazolate) (M = Mg , Mn , Fe , Co , Cu , Zn , Cd ). This

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a a a a a a bc a

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2 22+ 2+ 2+ 2+ 2+

2+ 2+4 2 2

2+ 2+4 2 2 2

2+ 2+ 2+ 2+2

22+ 2+ 2+ 2+ 2+ 2+ 2+

nced

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comprehensive study allows us to single-out iron as the metal ion that leads to the best electrical properties. The iron-based MOFs

exhibit at least five orders of magnitude higher electrical conductivity and significantly smaller charge activation energies across all

different MOF families studied here and stand out materials made from all other metal ions considered here. We attribute the unique

electrical properties of iron-based MOFs to the high-energy valence electrons of Fe and the Fe mixed valency. These results

reveal that incorporating Fe in the charge transport pathways of MOFs and introducing mixed valency are valuable strategies for

improving electrical conductivity in this important class of porous materials.

2+ 3+/2+

2+

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Is iron unique in promoting electrical conductivity in MOFs?

L. Sun, C. H. Hendon, S. S. Park, Y. Tulchinsky, R. Wan, F. Wang, A. Walsh and M. Dincă, Chem. Sci., 2017, 8, 4450

DOI: 10.1039/C7SC00647K

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Title: Polymer films on electrodes. 9.Electron and mass transfer inNafion films containing tris(2,2'-bipyridine)ruthenium(2+)

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2018/4/17 Bias-Switchable Permselectivity and Redox Catalytic Activity of a Ferrocene-Functionalized, Thin-Film Metal–Organic Framework Compound - The Journal of Physical Chemistry Letters (ACS Publications)

https://pubs.acs.org/doi/abs/10.1021/acs.jpclett.5b00019 1/4

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J. Phys. Chem. Lett., 2015, 6 (4), pp 586–591DOI: 10.1021/acs.jpclett.5b00019Publication Date (Web): January 26, 2015Copyright © 2015 American Chemical Society

Cite this: J. Phys. Chem. Lett. 6, 4, 586-591

Bias-Switchable Permselectivity and Redox Catalytic Activity of aFerrocene-Functionalized, Thin-Film Metal–Organic FrameworkCompoundIdan Hod†, Wojciech Bury†‡, Daniel M. Gardner†, Pravas Deria†, Vladimir Roznyatovskiy†, Michael R.Wasielewski†, Omar K. Farha*†§, and Joseph T. Hupp*†† Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States‡ Department of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland§ Department of Chemistry, Faculty of Science, King Abdulaziz University, Jeddah, Saudi Arabia

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2018/4/17 Bias-Switchable Permselectivity and Redox Catalytic Activity of a Ferrocene-Functionalized, Thin-Film Metal–Organic Framework Compound - The Journal of Physical Chemistry Letters (ACS Publications)

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*E-mail: [email protected] (J.T.H.)., *E-mail: [email protected] (O.K.F.).

Abstract

The installation of ferrocene molecules within the wide-channel metal–organic framework (MOF)compound, NU-1000, and subsequent configuration of the modified MOF as thin-film coatings onelectrodes renders the MOF electroactive in the vicinity of the ferrocenium/ferrocene (Fc+/Fc)redox potential due to redox hopping between anchored Fc+/0 species. The observation ofeffective site-to-site redox hopping points to the potential usefulness of the installed species as aredox shuttle in photoelectrochemical or electrocatalytic systems. At low supporting electrolyteconcentration, we observe bias-tunable ionic permselectivity; films are blocking toward solution

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2018/4/17 Bias-Switchable Permselectivity and Redox Catalytic Activity of a Ferrocene-Functionalized, Thin-Film Metal–Organic Framework Compound - The Journal of Physical Chemistry Letters (ACS Publications)

https://pubs.acs.org/doi/abs/10.1021/acs.jpclett.5b00019 3/4

cations when the MOF is in the ferrocenium form but permeable when in the ferrocene form.Additionally, with ferrocene-functionalized films, we observe that the MOF’s pyrene-based linkers,which are otherwise reversibly electroactive, are now redox-silent. Linker electroactivity is fullyrecovered, however, when the electrolyte concentration is increased 10-fold, that is, to aconcentration similar to or exceeding that of an anchored shuttle molecule. The findings haveclear implications for the design and use of MOF-based sensors, electrocatalysts, andphotoelectrochemical devices.

Keywords: charge hopping; electrocatalysis; metal−organic framework; permselectivity; redoxshuttle

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Received 5 January 2015Date accepted 26 January 2015Published online 26 January 2015Published in print 19 February 2015

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Electroactive Ferrocene at or near the Surface of Metal–OrganicFramework UiO-66Rebecca H. PalmerJian LiuChung-Wei KungIdan HodOmar K. FarhaJoseph T. HuppLangmuir 2018 Article ASAPAbstract | Full Text HTML | PDF | PDF w/ Links

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