detecting ch4 and other trace species on mars with a soir instrument - f montmessin et al 2007

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European Space Agency European Mars Science and Exploration Conference: Mars Express & ExoMars ESTEC, Noordwijk, The Netherlands, 12 - 16 Novemb er, 2007 DETECTING CH 4 AND OTHER TRACE SPECIES ON MARS WITH A SOIR INSTRUMENT. F. Montmessin 1 , A.C. Vandaele 2 , E. Neefs 2 , J.-L. Bertaux 1 , and F. Daerden 2 , 1 Service d'Aéronomie, réduit de Verrières, 91371 Verrières le Buisson, France, 2 Belgian Institute for Space Aeronomy, 3 av Circulaire, 1180 Brussels, Belgium. [email protected] SOIR (Solar Occultation InfraRed spectrometer) is currently part of the SPICAV/SOIR instrument [1] on board the Venus Express orbiter. SOIR, an Echelle spectrometer using an acousto-optic tunable filter (AOTF) for the order selection, is probing the atmosphere by the technique of solar occultation, operating between 2.2 and 4.3 μm, with a resolution of 0.15 cm -1 . This spectral range is suitable for the detection of several key components of planetary atmospheres, in particular that of CH 4 , using the 3  vibrational band located near 3.3 μm. Detection of CH 4 in the Mars atmosphere has already been reported [2] using the PFS instrument on board Mars Express and from ground-based telescope observations [3]. However, due to the resolution of PFS instrument (1.4 cm -1 ), the P- and R- branches could not be resolved and the detection relied on the observation of a sharp feature attributed to the Q-branch of the band. However, recent measurements [4,5] have revealed the presence of 16 C 12 O 18 C lines in the vicinity of the 3  CH 4 band, around 2982 cm -1 , which might impair the CH 4 detection. With its high resolution capability and its high signal-to-noise ratio (since observing the sun directly), the SOIR instrument could resolve methane individual lines in the 3 vibrational band region and provide a very robust CH 4 detection. In addition, it could detect methane isotopomers (such as 13 CH 4 ) and other methane photochemical by- products (C 2 H 6 , H 2 CO…), thereby providing important clues on the photochemical cycle of hydrocarbons on Mars. We will present simulations of spectra such as would be recorded by a SOIR instrument probing the Mars atmosphere, allowing the determination of lower limits for the detection of trace constituents. A sensitivity study has also been performed regarding some of instrumental characteristics of the SOIR instrument (band pass of the AOT filter, order separation of the Echelle spectrometer). References: [1] Bertaux, J.-L., et al. (2007), PSS (in press). [2] Formisano, V. et al. (2004), Science 306 , 1758- 1761. [3] Krasnopolsky et al. (2004),  Icarus 172, 537-547 [3] Villanueva, G. et al.,  Icarus (submitted). [4] Vandaele, A.C. et al. (2007), 39 th DPS annual Meeting, Abs. #45.03; Bertaux, J.-L. et al.,  Icarus (submitted)

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Page 1: Detecting CH4 and Other Trace Species on Mars With a Soir Instrument - F Montmessin Et Al 2007

8/3/2019 Detecting CH4 and Other Trace Species on Mars With a Soir Instrument - F Montmessin Et Al 2007

http://slidepdf.com/reader/full/detecting-ch4-and-other-trace-species-on-mars-with-a-soir-instrument-f-montmessin 1/1

European Space Agency

European Mars Science and Exploration Conference: Mars Express & ExoMars

ESTEC, Noordwijk, The Netherlands, 12 - 16 November, 2007

DETECTING CH4 AND OTHER TRACE SPECIES ON MARS WITH A SOIR INSTRUMENT. F.

Montmessin1, A.C. Vandaele

2, E. Neefs

2, J.-L. Bertaux

1, and F. Daerden

2,

1Service d'Aéronomie, réduit de

Verrières, 91371 Verrières le Buisson, France,2Belgian Institute for Space Aeronomy, 3 av Circulaire, 1180

Brussels, Belgium. [email protected]

SOIR (Solar Occultation InfraRed spectrometer)is currently part of the SPICAV/SOIR instrument

[1] on board the Venus Express orbiter. SOIR, an

Echelle spectrometer using an acousto-optic tunable

filter (AOTF) for the order selection, is probing the

atmosphere by the technique of solar occultation,

operating between 2.2 and 4.3 μm, with a resolution

of 0.15 cm-1

. This spectral range is suitable for the

detection of several key components of planetary

atmospheres, in particular that of CH4, using the 3 

vibrational band located near 3.3 μm.

Detection of CH4 in the Mars atmosphere has

already been reported [2] using the PFS instrument

on board Mars Express and from ground-based

telescope observations [3]. However, due to the

resolution of PFS instrument (1.4 cm-1

), the P- and

R- branches could not be resolved and the detection

relied on the observation of a sharp feature

attributed to the Q-branch of the band. However,

recent measurements [4,5] have revealed the

presence of 16

C12

O18

C lines in the vicinity of the 3 

CH4 band, around 2982 cm-1

, which might impair

the CH4 detection.

With its high resolution capability and its high

signal-to-noise ratio (since observing the sun

directly), the SOIR instrument could resolve

methane individual lines in the 3 vibrational bandregion and provide a very robust CH4 detection. In

addition, it could detect methane isotopomers (such

as13

CH4) and other methane photochemical by-

products (C2H6, H2CO…), thereby providing

important clues on the photochemical cycle of 

hydrocarbons on Mars.

We will present simulations of spectra such as

would be recorded by a SOIR instrument probing

the Mars atmosphere, allowing the determination of 

lower limits for the detection of trace constituents.

A sensitivity study has also been performed

regarding some of instrumental characteristics of theSOIR instrument (band pass of the AOT filter, order

separation of the Echelle spectrometer).

References: [1] Bertaux, J.-L., et al. (2007), PSS (in

press). [2] Formisano, V. et al. (2004), Science 306 , 1758-

1761. [3] Krasnopolsky et al. (2004), Icarus 172, 537-547

[3] Villanueva, G. et al.,  Icarus (submitted). [4] Vandaele,

A.C. et al. (2007), 39th

DPS annual Meeting, Abs. #45.03;

Bertaux, J.-L. et al., Icarus (submitted)