document release and change form doc no: rev. · modified template is used for purex high level...

DOCUMENT RELEASE AND CHANGE FORM Prepared For the U.S. Department of Energy, Assistant Secretary for Environmental Management By Washington River Protection Solutions, LLC., PO Box 850, Richland, WA 99352 Contractor For U.S. Department of Energy, Office of River Protection, under Contract DE-AC27-08RV14800

1a. Doc No: RPP-RPT-59283 Rev. 00

1b. Project Number: ☒ N/A

1 SPF-001 (Rev.0)

TRADEMARK DISCLAIMER: Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise, does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States government or any agency thereof or its contractors or subcontractors. Printed in the United States of America.

Release Stamp

2. Document Title

Derivation of Best-Basis Inventory for Tank 241-A-106 as of April 1, 2016

3. Design Verification Required

☐ Yes ☒ No

4. USQ Number ☒ N/A 5. PrHA Number ☒ N/A

Rev.

6. USQ Screening:

a. Does the change introduce any new failure modes to the equipment? ☐ Yes ☒ No

Basis is required for Yes:

b. Does the change increase the probability of existing failure modes? ☐ Yes ☒ No


c. For Safety Significant equipment, does the change require a modification to Chapter 4 of the DSA and/or FRED? ☐ Yes ☐ No ☒ N/A


7. Description of Change and Justification (Use Continuation pages as needed)

This document reports the change in the best-basis inventory (BBI) for Tank 241-A-106 for the third quarter of fiscal year 2016. This update incorporates the decay-correction update for radionuclides from January 1, 2008 to July 1, 2015. A re-evaluation of the tank waste phases was also performed.

8. Approvals

Title Name Signature Date

Clearance Review BRATTON, GAYLA E BRATTON, GAYLA E 05/05/2016

Checker FIELD, JIM G FIELD, JIM G 05/02/2016

Document Control Approval MANOR, TAMI MANOR, TAMI 05/05/2016

Originator STURMAN, GRANT A STURMAN, GRANT A 05/02/2016

Other Approver LAURENZ, JULIAN E LAURENZ, JULIAN E 05/02/2016

Responsible Manager BAUNE, HEATHER L BAUNE, HEATHER L 05/05/2016

9. Clearance Review:

Restriction Type:

☒ Public

☐ Undefined

☐ Unclassified Controlled Nuclear Information (UCNI)

☐ Export Control Information (ECI)

☐ Official Use Only Exemption 2-Circumvention of Statute (OUO-2)

☐ Official Use Only Exemption 3-Statutory Exemption (OUO-3)

☐ Official Use Only Exemption 4-Commercial/Proprietary (OUO-4)

☐ Official Use Only Exemption 5-Privileged Information (OUO-5)

☐ Official Use Only Exemption 6-Personal Privacy (OUO-6)

☐ Official Use Only Exemption 7-Law Enforcement (OUO-7)

RPP-RPT-59283 Rev.00 5/5/2016 - 1:53 PM 1 of 34

May 05, 2016DATE:

DOCUMENT RELEASE AND CHANGE FORM Doc No: RPP-RPT-59283 Rev. 00

2 SPF-001 (Rev.0)

10. Distribution:

Name Organization

ANDERSON, MASON A TNK WST INVENTORY & CHARACTZTN

BAUNE, HEATHER L 222S LABORATORY ENGINEERING

CRAWFORD, JORDAN T TNK WST INVENTORY & CHARACTZTN

DETRICH, ELIZABETH J TNK WST INVENTORY & CHARACTZTN

FERRITER, SEAN D TNK WST INVENTORY & CHARACTZTN

FIELD, JIM G BASE OPERATIONS PROCESS ENGRNG

KADINGER, JENNIFER A TNK WST INVENTORY & CHARACTZTN

LUKE, SCOTT N TNK WST INVENTORY & CHARACTZTN

MATTLIN, DEVIN M

NGUYEN, DUC M TNK WST INVENTORY & CHARACTZTN

RASMUSSEN, JUERGEN H TNK WST INVENTORY & CHARACTZTN

RODGERS, MATT J TNK WST INVENTORY & CHARACTZTN

SAMS, TERRY L PROCESS ENGINEERING ANALYSIS

TEMPLETON, ANDREW M TNK WST INVENTORY & CHARACTZTN

11. TBDs or Holds ☒ N/A

12. Impacted Documents – Engineering ☒ N/A

Document Number Rev. Title

13. Other Related Documents ☐ N/A

Document Number Rev. Title

HNF-2978 05 UPDATED PUMPABLE LIQUID VOLUME ESTIMATES AND JET PUMP DURATIONS FOR INTERIM STABILIZATION OF REMAINING SINGLE-SHELL TANKS

HNF-SD-RE-TI-178 09A SINGLE SHELL TANK INTERIM STABILIZATION RECORD

RPP-19822 00A HANFORD DEFINED WASTE MODEL - REVISION 5.0

RPP-7625 12 GUIDELINES FOR UPDATING BEST-BASIS INVENTORY

RPP-8847 01B BEST-BASIS INVENTORY TEMPLATE COMPOSITIONS OF COMMON TANK WASTE LAYERS

RPP-PLAN-60585 00 Software Management Plan for Utility Calculation Software Tank Waste Volume Calculator

RPP-RPT-26878 00 Best-Basis Inventory Templates for Polychlorinated Biphenyls

RPP-RPT-42744 00 2009 AUTO-TCR FOR TANK 241-A-106

RPP-RPT-54981 00 Evaluation of Fourteen Tanks with Decreasing Level Baselines Selected for Review in RPP-PLAN-55113, Revision 1

WHC-SD-RE-TI-200 00A DATA TRANSMITTAL PACKAGE FOR 241-A-106 WASTE TANK CHARACTERIZATION

WHC-SD-WM-TI-302 00 HANFORD WASTE TANK SLUICING HISTORY

14. Related Systems, Structures, and Components:

14a. Related Building/Facilities ☐ N/A

241-A

241-A-106

14b. Related Systems ☐ N/A

241-WST

14c. Related Equipment ID Nos. (EIN) ☒ N/A

RPP-RPT-59283 Rev.00 5/5/2016 - 1:53 PM 2 of 34

3 SPF-001 (Rev.0)

DOCUMENT RELEASE AND CHANGE FORM CONTINUATION SHEET

Document No: RPP-RPT-59283 Rev. 00

N/A

RPP-RPT-59283 Rev.00 5/5/2016 - 1:53 PM 3 of 34

A-6002-767 (REV 3)

RPP-RPT-59283, Rev 0

Derivation of Best-Basis Inventory for

Tank 241-A-106 as of April 1, 2016

G. A. Sturman

Washington River Protection Solutions, LLC

Richland, WA 99352

U.S. Department of Energy Contract DE-AC27-08RV14800

EDT/ECN: DRCF UC: N/A

Cost Center: 2KL00 Charge Code: 202382

B&R Code: N/A Total Pages: 34

Key Words: 241-A-106, Best Basis Inventory, BBI, Fiscal Year 2016

Abstract: This document reports the change in the best-basis inventory (BBI) for Tank 241-A-106 for the third quarter of fiscal year 2016. This update incorporates the decay-correction update for radionuclides from January 1, 2008 to July 1, 2015. A re-evaluation of the tank waste phases was also performed.

TRADEMARK DISCLAIMER. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise, does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof or its contractors or subcontractors.

Release Approval Date Release Stamp

Approved For Public Release

RPP-RPT-59283 Rev.00 5/5/2016 - 1:53 PM 4 of 34

By G. E. Bratton at 1:56 pm, May 05, 2016

May 05, 2016DATE:

RPP-RPT-59283, REV. 0

2

DERIVATION OF BEST-BASIS INVENTORY FOR TANK

241-A-106 AS OF APRIL 1, 2016

G. A. Sturman

Washington River Protection Solutions, LLC

Richland, WA 99352

U.S. Department of Energy Contract DE-AC27-08RV14800C

Date Published

May 2016

Prepared for the U.S. Department of Energy

Office of River Protection

RPP-RPT-59283 Rev.00 5/5/2016 - 1:53 PM 5 of 34

Approved for Public Release; Further Dissemination Unlimited


iii

TABLE OF CONTENTS

1.0 INTRODUCTION .................................................................................................................... 1

2.0 DERIVATION OF BEST-BASIS INVENTORY .................................................................... 1

2.1 WASTE HISTORY ............................................................................................................... 3

2.2 TANK VOLUME .................................................................................................................. 4

2.3 SAMPLE DATA INFORMATION ....................................................................................... 6

2.4 DENSITY AND WEIGHT PERCENT WATER .................................................................. 7

2.5 TEMPLATE VECTORS ....................................................................................................... 7

2.6 DEVELOPMENT OF THE BBI ............................................................................................ 7

3.0 SUMMARY OF CHANGES ............................................................................................... 8

4.0 REFERENCES .................................................................................................................... 9

LIST OF TABLES

Table 2-1. Tank 241-A-106 Best-Basis Inventory Source Data. ................................................... 2

Table 2-2. Tank 241-A-106 Component Density and Wt% Water ................................................ 7

Table A-1. Condensed Best-Basis Calculation Detail Reports for Tank 241-A-106 Primary and

Supplemental Analytes ............................................................................................................... A-2

LIST OF FIGURES

Figure 2-1. Tank 241-A-106 Surface Level and LOW ................................................................... 5

Figure 2-2. Tank 241-A-106 Waste Surface ................................................................................... 6

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iv

LIST OF TERMS

Abbreviations and Acronyms

A1-SltCk A1-Saltcake

AR Water Washed PUREX Sludge

BBI Best-Basis Inventory

BBIM Best-Basis Inventory Maintenance Application

HDW Hanford Defined Waste

ILL Interstitial Liquid Level

LOW Liquid Observation Well

P1 PUREX high-level waste generated between 1955 and 1962

P2 PUREX high-level waste generated between 1963 and 1967

PCB Polychlorinated biphenyls

PUREX Plutonium Uranium Extraction Plant

SRR High-activity waste from B Plant processing of PUREX acidified sludge, and

Strontium Recovery Waste after solvent extraction (1967-1976).

TWINS Tank Waste Information Network System

Units

g Gram

gal Gallons

in Inch

kgal kilogallons (1,000 gallons)

kL Kiloliters

mL Milliliter

μg Microgram

wt% weight percent

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1

1.0 INTRODUCTION

The Best-Basis Inventory (BBI) effort involves developing and maintaining waste tank

inventories comprising 25 chemical and 46 radionuclide components in the 177 Hanford Site

underground storage tanks. These BBIs provide waste composition data necessary as part of the

River Protection Project process flowsheet modeling work, safety analyses, risk assessments, and

system design for waste retrieval, treatment, and disposal operations.

Development and maintenance of the best-basis inventory is an on-going effort. The previous

BBI effective October 1, 2005 was published in RPP-RPT-42744, 2009 Auto-TCR for Tank

241-A-106. A PUREX high-level waste layer was added to the tank. The decay-correction date

for radionuclides has been updated from January 1, 2008 to July 1, 2015 since the previous BBI.

In addition, sample-based polychlorinated biphenyls (PCB) template estimates have been

established since the previous BBI update, which replace the previous PCB default

concentrations to calculate the PCB inventories of unsampled tank waste layers. An assessment

of the tank waste phases was also performed. As a result, a re-evaluation of the BBI for tank

241-A-106 as of April 1, 2016 was performed and is documented in the following text.

2.0 DERIVATION OF BEST-BASIS INVENTORY

The following information was used as input for the tank 241-A-106 BBI:

Average concentrations from a 1986 push-mode core sampling event (WHC-SD-RE-TI-200,

Data Transmittal Package for 241-A-106 Waste Tank Characterization).

BBI templates for 242-A evaporator saltcake (A1-SltCk), strontium recovery waste (SRR),

and washed Plutonium Uranium Extraction Plant (PUREX) high level waste (AR). A

modified template is used for PUREX high level waste (P2) (RPP-8847, Best-Basis Inventory

Template Compositions of Common Tank Waste Layers).

The templates are based on sample data supplemented with Revision 5 Hanford Defined

Waste (HDW) model data where sample data are not available (RPP-8847 and RPP-19822,

Hanford Defined Waste Model- Revision 5).

Sample-based template estimates for total PCBs in each waste phase (RPP-RPT-26878,

Best-Basis Inventory Templates for Polychlorinated Biphenyls).

Historical Sample data from a 1977 grab sample of the SRR sludge (LET-0-77-115, Analysis

of Tank 106-A Sludge, November 10, 1977).

Three waste phases were identified for the tank: sludge, saltcake solids and drained voids.

Inventories were computed for each phase separately and then summed to obtain the overall tank

inventory.

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2

Table 2-1 represents how the available data were used to derive best-basis inventories for tank

241-A-106:

Table 2-1. Tank 241-A-106 Best-Basis Inventory Source Data

Waste

Phase

Waste

Type

Applicable Concentration

Data1,2

Associated

Density

(g/mL)

Multiplier

Associated

Volume

Saltcake A1-SltCk

(Drained)

Average of the 1986 Cores

1 & 2 Sampling Event

(P/A106/001)

1.55

1.000 84 kL

(22 kgal)

A1-SltCk Solids Template

(TS/U204/025)

1.58 1.000

A-106 Vacuum Evaporator

PCB Template

(TS/A106/001)

1.58 1.000

Drained

Voids

A1-SltCk

(Voids)

Supernatant water

(P/U107/004)

0.00 1.000 27 kL

(7 kgal)

Sludge3 SRR



(P/A106/001)

1.55

1.000 110 kL

(29 kgal)

SRR Sludge Template

(TE/U204/093)

1.51 1.405

1977 Sample

(S/A106/003)

1.51 1.000

A-106 PCB SRR Sludge

Template (TS/A106/002)

1.51 1.000

AR



(P/A106/001)

1.55

1.000 38 kL

(10 kgal)

AR Solids Template

(TE/U204/048)

1.34 1.906

1977 Sample (S/A106/003) 1.51 1.000

A-106 PCB AR Sludge


1.34 1.000

P2 P2 Sludge Template PK

Vector

(TS/A103/005)

1.61 1.000 41 kL

(11 kgal)

A-106 PCB P2 Sludge


1.61 1.000

Total tank

300 kL

(79 kgal)4

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3

Table 2-1. Tank 241-A-106 Best-Basis Inventory Source Data

Waste

Phase

Waste

Type

Applicable Concentration

Data1,2

Associated

Density

(g/mL)

Multiplier

Associated

Volume

Notes: g/mL = grams per milliliter

kgal = kilogallons

kL = kiloliters

1Vector handles, shown in parentheses, are unique serial identifiers for the vectors used in the BBIM database.

2 Note: Concentrations and inventories based on 1986 composite samples for A1-SltCk, AR and SRR are combined

estimates to provide the best total inventory. The same constituent concentrations are used for all 3 waste types

and inventories for each waste type are based on those concentrations. Separate waste type concentrations and

inventories could not be determined based on the 1986 samples. 3 The sludge waste phase includes both solids and interstitial liquid; the interstitial liquid volume was estimated to

be 22 kL (6.0 kgal).

4 The sum of the waste phase volumes in kgal may not exactly match the tank total volume due to rounding.

2.1 WASTE HISTORY

Tank 241-A-106 entered service in 1957. The tank received de-entrained water and PUREX

condensate waste from the boiling waste tanks in the A Tank Farm from the first quarter of 1957

until the fourth quarter of 1961. From the fourth quarter of 1960 until the second quarter of

1968, the tank received PUREX high level waste followed by carbonate waste and organic wash

waste. On May 15, 1963, the in-tank temperature for tank 241-A-106 was 312 oC (594 oF); the

highest temperature recorded for any of the Single-Shell Tanks (RHO-CD-1172, Survey of the

Single-Shell Thermal Histories). The tank received AR sludge waste from tank 241-A-104 and

other A and AX farm tanks in 1969 and SRR waste from the first quarter of 1970 to 1975

(LA-UR-97-311, Waste Status and Transaction Record Summary (WSTRS) Rev. 4 Vol I of II).

From February 17, 1970, until the start of 1971 and again from December 1971 to May 1972, the

tank was sluiced for strontium and cesium recovery. The tank was sluiced again from the end of

1973 until January 1974. From the first quarter of 1974 until the second quarter of 1976, the

tank received predominantly B Plant waste with some AR and SRR waste. The tank contained

evaporator waste between the third quarter of 1976 and the first quarter of 1978. Tank

241-A-106 was sluiced a fourth time in the second and third quarters of 1977. During this time

the tank was part of an in-farm sluicing operation and received sludge waste from tanks

241-A-101, -102 and -103. From the second quarter of 1978 until the third quarter of 1980, the

tank received and sent supernatant to tank 241-A-102 (LA-UR-97-311 and

WHC-SD-WM-TI-302, Hanford Waste Tank Sluicing History).

The tank was administratively interim stabilized in August 1982 and intrusion prevention was

completed in December 1982 (HNF-SD-RE-TI-178, Single-Shell Tank Stabilization Record).

The photographs taken at the time of stabilization showed the waste surface consisted of solids

of irregular configuration, but of relatively low profile. No liquid was visible. The tank was

lanced July 7, 1982, and the results indicated wet and soft solids with no interior liquids zones.

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4

2.2 TANK VOLUME

Tank 241-A-106 auto and manual ENRAF readings on January 1, 2001 were 28.76 inches

[TWINS, queried 4/5/2016 (Level/Temp, Surface Level, Tank Name: A-106, Measurement Date:

1/1/2001 to 4/5/2016, Sensor Type: ENRAF, Date 1/1/2001, 28.76 inches)], (Tank Waste

Information Network System (TWINS)). This corresponds to 299 kL (79 kgal) using conversion

factors of 2.750 kgal/inch and 3.785 kL/kgal. Using the Software Management Plan for Utility

Calculation Software Tank Waste Volume Calculator (RPP-PLAN-60585), which became

available in 2009 and accounts for differences in construction of the various underground tanks,

the measurement of 28.76 inches equals 300 kL (79 kgal).

The most current ENRAF reading, taken June 22, 2007, indicates a tank waste level of

25.28 inches [TWINS, queried 4/4/2016 (Level/Temp, Surface Level, Tank Name: A-106,

Measurement Date: 1/1/2001 to 4/4/2016, Sensor Type: ENRAF, Date 6/22/2007, 25.28 inches)]

for a total waste volume of 264 kL (70 kgal) (RPP-PLAN-60585). Following the 2007 manual

ENRAF reading the ENRAF was found stuck to the waste surface and all subsequent data for the

instrument is considered suspect (no TWINS records exist for surface level after June 2007). On

June 25, 2002, there was a calibration shift as a result of calibrating and flushing of the

measurement weight assembly. This sudden shift accounted for the difference in the

measurements. The shift in level measurements was likely due to a localized surface depression

caused by the water flush. Therefore, the total waste volume was estimated based on the

January 1, 2001, measurement.

The liquid observation well (LOW) measurement as of March 23, 2016, was 12.288 inches

[TWINS, queried 4/4/2016 (Level/Temp, Interstitial Liquid Level, Tank Name: A-106,

Measurement Date: 1/1/2015 to 4/4/2016, Sensor Type: neutron probe, Date: 3/23/2016,

1.024 feet)]. The waste volume based on the LOW measurement is calculated to be 128 kL

(34 kgal) (RPP-PLAN-60585). The LOW measurement is an indication of the minimum

interstitial liquid level (ILL) in the tank, and therefore, only the bottom 128 kL (34 kgal) of

sludge waste contained interstitial liquid.

The LOW measurements have been decreasing since the installation of the LOW in 2002

decreased from a reading of 21.06 inches in September 6, 2002, to 12.288 inches in

March 23, 2016. The decrease in LOW is more than accounted for by the tank heat load and

estimated evaporation rate and there is no basis to suspect a leak from tank 241-A-106

(RPP-RPT-54981, Evaluation of Fourteen Tanks with Decreasing Level Baselines Selected for

Review in RPP-PLAN-55113, Revision 1). The ENRAF and LOW measurements are seen in

Figure 2-1.

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5

Figure 2-1. Tank 241-A-106 Surface Level and LOW

The Hanford Tank Chemical and Radionuclide Inventories: HDW Model Rev. 4

(LA-UR-96-3860) indicates approximately 189 kL (50 kgal) of the waste matrix was sludge

(110 kL (29 kgal) SRR and 79 kL (21 kgal) AR) and the remainder was saltcake. This is

consistent with the 1978 sludge volume estimate of 50 kgal prior to the saltcake addition to tank

241-A-106 (Accession # 1008090496, 1978, Tank 106-A Sludge Inventory). The sludge volumes

listed in Table 2-1 are based on LA-UR-96-3860, and the P2 waste estimate, and the remaining

volume is assumed to be saltcake. The volume of the P2 waste was subtracted from the

estimated AR waste volume, but could also be subtracted from the SRR waste volume. WSTRS

shows both SRR and AR waste were added at different times after 1974.

The estimated drainable porosity of sludge in the tank was 0.17 and the estimated drainable

porosity for saltcake in the tank is 0.24 (HNF-2978, Updated Pumpable Liquid Volume

Estimates and Jet Pump Durations for Interim Stabilization of Remaining Single-Shell Tanks).

The LOW measurement is below the saltcake in the tank indicating the saltcake is drained. The

total saltcake volume is the total tank volume minus the sludge volume 111 kL (29 kgal) (300 kL

– 189 kL = 111 kL). The drained voids volume is 27 kL (7 kgal) (111 kL bulk drained saltcake *

0.24 drainable porosity = 27 kL) and the solids volume in the drained saltcake is 84 kL (22 kgal)

(111 kL bulk drained saltcake – 27 kL drained voids = 84 kL). The volume of drainable

interstitial liquid in the sludge was estimated to be 22 kL (6.0 kgal) (128 kL * 0.17 porosity =

22 kL).

According to photos taken January, 17, 1974, after the third sluicing of tank 241-A-106 the tank

contained 4 inches of waste. This was the lowest waste volume since waste was first introduced

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6

to the tank and indicates a thin layer of P2 waste likely remained in the tank after sluicing. The

4 inches of P2 waste corresponds to 42 kL (11 kgal) (RPP-PLAN-60585).

2.3 SAMPLE DATA INFORMATION

On March 11, 1986, and March 13, 1986, two push-mode core samples were collected from tank

241-A-106, each containing three segments. Recovery from these core samples was recorded in

WHC-SD-RE-TI-200 as 100%, and the sample results are considered representative of the full

vertical profile of the tank waste excluding the P2 sludge layer. Interstitial liquid was decanted

from the solids in each segment sample, and the solids for the three segments were combined in

the hot cell with a masher to create a composite sample of each core. This data set represents the

best available information for the combined inventories for the A1-SltCk, SRR and AR waste

types and is used for all three waste types for available constituents. Separate waste type

concentrations and inventories will vary from the composite estimates, but could not be

determined from the composite samples.

The sludge was sampled in 1977 before the saltcake was added (LET-0-77-115). This sample

represents the top sludge layer and is used for both SRR and AR for constituents for which push

core sample data is not available. The sample includes weight percent water, density and several

constituents. Figure 2-2 shows the waste surface of tank 241-A-106 as of August 12, 2010.

Figure 2-2. Tank 241-A-106 Waste Surface

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7

2.4 DENSITY AND WEIGHT PERCENT WATER

The density and weight percent water for the A1-SltCk and P2 Sludge are based on the

templates. The density and weight percent water for the SRR sludge and AR Sludge is based on

a sample taken in 1977 (LET-0-77-115).

Table 2-2. Tank 241-A-106 Component Density and Wt% Water1

Waste Phase Waste Type

Component

Density (g/mL)

Component

Wt% Water Source

Saltcake

Solids

A1-SltCk

(Drained)

1.58 37.8 A1-SltCk solid template

Sludge SRR 1.51 46.9 1977 Sample

AR 1.51 46.9 1977 Sample

P2 1.61 44.2 P2 Sludge template PK

Vector 1. Note: For 1986 composite sample combined density = 1.55, combined wt% water not determined.

2.5 TEMPLATE VECTORS

Waste type templates are based on sampling data from tanks containing the same waste type as

tank 241-A-106 and supplemented with revision 5 HDW model data where sample data are not

available (RPP-8847 and RPP-19822). The BBI solids templates for AR, SRR, and P2 sludges

and A1-SltCk were used to represent the solids in the sludge and saltcake layers, respectively.

Although the waste designated P2 is mostly P1 waste (waste generated between 1955 and 1962),

the P2 template is used because it is a sample based template and is assumed to better represent

the remaining waste concentrations; the P1 template is entirely model based. A multiplier is

used to scale the AR and SRR waste type template vectors to the sample data using the 1977

sample weight percent water and density. A more detailed description of these multipliers is

found in RPP-8847. Because data representative of only A1-Sltck is not available, a multiplier is

not used for the A1-SltCk template. The multiplier for the template for SRR is 1.405

[1.51 g/mL/1.51 g/mL * (100-46.9%)/(100–62.2%) = 1.405] and the multiplier for the AR

template is 1.906 [1.51 g/mL/1.34 g/mL * (100-46.9%)/(100–68.6%) = 1.906].

2.6 DEVELOPMENT OF THE BBI

The inventories in this BBI were developed in accordance with the BBI rules in Guidelines for

Updating Best-Basis Inventory (RPP-7625). All inventory calculations were performed using the

Best-Basis Inventory Maintenance (BBIM) tool. The updated BBI values for tank 241-A-106 can

be found in the Best-Basis Calculation Detail Report and the Best-Basis Calculation Detail-

Supplemental Analytes report in TWINS. A condensed version of these reports is included in

Appendix A. Radionuclides in these reports are decay-corrected to July 1, 2015. Discussions of

unique data treatments and/or exceptions to the rules in RPP-7625 are provided below by

analyte.

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8

155Eu: The ratio between 154Eu template concentration and 155Eu sample concentration was

significantly larger than expected. The template value for 155Eu is used in lieu of the sample

value.

Alpha-Emitting Isotopes: Data from analysis of 239/240Pu, 241Am, and total uranium and the

template isotopic distribution ratios were used to generate inventories for the various

alpha-emitting isotopes.

Hg: The concentration of Mercury in the 1977 sample was unreasonably high. The template

values is used.

PCBs: The PCB inventory is estimated per guidelines established in RPP-7625 PCB inventories

for each waste phase were developed using the sample-based PCB template values reported in

RPP-RPT-26878, since current sample data were not available.

The sample-based PCB concentrations for the PCB solids templates are reported on a dry

weight basis. The reported concentrations are converted to wet weight using the associated

waste weight percent water result. The Vacuum Evaporator Saltcake PCB concentration of

< 0.256 µg/g was used for the saltcake solids waste phase. When this concentration is converted

to wet weight using the template weight percent water of 37.8% it equals < 0.159 μg/g

[< 0.256μg/g * (100% - 37.8 %)/100]. The Sludge PCB concentration of <3.263 µg/g was used

for the sludge waste phase. When this concentration is converted to wet weight using the 1977

sample weight percent water of 46.9 for SRR and AR sludge, it equals <1.733 μg/g [<3.263 μg/g

* (100% - 46.9%) /100]. When this concentration is converted to wet weight using the mean

sludge (P2) template weight percent water of 44.2, it equals <1.821 μg/g

[<3.263 μg/g * (100% - 44.2%) /100].

3.0 SUMMARY OF CHANGES

In this update the volume of A1-SltCk solids was reduced to account for drained liquids, 1977

sample data was added, clarifications were added for the 1986 core composite sample data and

associated inventories, radionuclides were decayed to July 1, 2015, the total PCB concentration

for the waste phase was updated to use sample based rather than default process knowledge

values and a P2 sludge layer was added. The total volume of the waste in the tank increased

from 299 kL (79 kgal) to 300 kL (79 kgal), from a volume increase in the saltcake layer. The

concentrations of constituents in tank 241-A-106 changed due to the change in waste phases and

the decay date update.

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9

4.0 REFERENCES

Accession # 1008090496, 1978, Tank 106-A Sludge Inventory.

HNF-2978, 2003, Updated Pumpable Liquid Volume Estimates and Jet Pump Durations for

Interim Stabilization of Remaining Single-Shell Tanks, Rev. 5, CH2M HILL Hanford

Group, Inc., Richland, Washington.

HNF-SD-RE-TI-178, 2007 Single-Shell Tank Stabilization Record, Rev. 9A, Babcock Services,

Inc. Richland, Washington.

LA-UR-96-3860, 1997, Hanford Tank Chemical and Radionuclide Inventories: HDW Model

Rev. 4, Los Alamos National Laboratory, Los Alamos, New Mexico.

LA-UR-97-311, 1997, Waste Status and Transaction Record Summary (WSTRS) Rev. 4 Vol I of

II, Los Alamos National Laboratory, Los Alamos, New Mexico.

LET-0-77-115, 1977, Analysis of Tank 106-A Sludge, November 10, 1977, Rockwell

International, Richland, Washington.

RPP-7625, 2015, Guidelines for Updating Best-Basis Inventory, Rev. 12, Washington River

Protection Solutions, LLC, Richland, Washington.

RPP-8847, 2007, Best-Basis Inventory Template Compositions of Common Tank Waste Layers,

Rev. 1B, CH2M HILL Hanford Group, Inc., Richland, Washington.

RPP-19822, 2005, Hanford Defined Waste Model – Revision 5, Rev. 0A, CH2M HILL Hanford

Group, Inc., Richland, Washington.

RHO-CD-1172, 1981, Survey of the Single-Shell Tank Thermal Histories, Rockwell Hanford

Operations, Richland, Washington.

RPP-PLAN-60585, 2015, Software Management Plan for Utility Calculation Software Tank

Waste Volume Calculator, Rev. 0, Washington River Protection Solutions LLC,

Richland, Washington.

RPP-RPT-26878, 2014, Best-Basis Inventory Templates for Polychlorinated Biphenyls, Rev. 0,

Washington River Protection Solutions, LLC, Richland, Washington.

RPP-RPT-42744, 2009, 2009 Auto-TCR for Tank 241-A106, Rev. 0, Washington River

Protection Solutions, LLC, Richland, Washington

RPP-RPT-54981, 2013, Evaluation of Fourteen Tanks with Decreasing Level Baselines Selected

for Review in RPP-PLAN-55113, Revision 1, Rev. 0, Washington River Protection

Solutions, LLC, Richland, Washington

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10

TWINS, 2016, Queried April 5, 2016 [Level/Temp, Surface Level, Tank Name: A-106,

Measurement Date: 1/1/2001 to 4/5/2016, Sensor Type: ENRAF, Date 1/1/2001,

28.76 inches].

TWINS, 2016, Queried April 4, 2016 [Level/Temp, Surface Level, Tank Name: A-106,

Measurement Date: 1/1/2001 to 4/4/2016, Sensor Type: ENRAF, Date 6/22/2007,

25.28 inches].

TWINS, 2016, Queried April 4, 2016 [Level/Temp, Interstitial Liquid Level, Tank Name: A-106,

Measurement Date: 1/1/2001 to 4/4/2016, Sensor Type: neutron probe, Date: 3/23/2016,

1.024 feet].

WHC-SD-RE-TI-200, 2004, Data Transmittal Package for 241-A-106 Waste Tank

Characterization, Rev. 0A, CH2M HILL Hanford Group, Inc., Richland, Washington.

WHC-SD-WM-TI-302, 1987, Hanford Waste Tank Sluicing History, Rev. 0, Westinghouse

Hanford Company, Richland, Washington.

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A- 1

APPENDIX A

CONDENSED BEST-BASIS CALCULATION DETAIL REPORTS FOR

TANK 241-A-106 PRIMARY AND SUPPLEMENTAL ANALYTES

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A- 2

Table A-1. Condensed Best-Basis Calculation Detail Reports for Tank 241-A-106 Primary and Supplemental Analytes

Radionuclide Decay Date 7/1/2015

Analyte Phase Waste

Type Qualifier Inventory Units RSD (%) Basis

Calculation (density*volume*

concentration*conversion*multiplier)a

Al Saltcake Solid

A1-SltCk

(Drained) 2.96E+03 kg

Process

Knowledge 1.55 g/ml * 84 kL * 22750 ug/g * 0.001 * 1

Al Sludge (Liquid & Solid) AR (Solid) 1.34E+03 kg

Process


Al Sludge (Liquid & Solid) SRR (Solid) 3.88E+03 kg

Process


Al Sludge Solid P2 (Solid) 2.01E+03 kg 6.32E+01 Template Sample 1.61 g/ml * 41 kL * 30500 ug/g * 0.001 * 1

Bi Saltcake Solid

A1-SltCk


Process


Bi Sludge (Liquid & Solid) AR (Solid) 1.08E+01 kg

Process


Bi Sludge (Liquid & Solid) SRR (Solid) 3.12E+01 kg

Process


Bi Sludge Solid P2 (Solid) 0.00E+00 kg

Template

Engineering 1.61 g/ml * 41 kL * 0 ug/g * 0.001 * 1

Ca Saltcake Solid

A1-SltCk


Process


Ca Sludge (Liquid & Solid) AR (Solid) 3.10E+02 kg

Process


Ca Sludge (Liquid & Solid) SRR (Solid) 8.99E+02 kg

Process


Ca Sludge Solid P2 (Solid) 4.01E+02 kg 7.60E+01 Template Sample 1.61 g/ml * 41 kL * 6080 ug/g * 0.001 * 1

Cl Saltcake Solid

A1-SltCk

(Drained) 5.96E+02 kg 1.15E+02 Template Sample 1.58 g/ml * 84 kL * 4490 ug/g * 0.001 * 1

Cl Sludge (Liquid & Solid) AR (Solid) 4.03E+01 kg

Template

Engineering 1.34 g/ml * 38 kL * 415 ug/g * 0.001 * 1.906

Cl Sludge (Liquid & Solid) SRR (Solid) 2.68E+02 kg

Template

Engineering

1.51 g/ml * 110 kL * 1150 ug/g * 0.001 *

1.405

Cl Sludge Solid P2 (Solid) 1.60E+01 kg 1.13E+02 Template Sample 1.61 g/ml * 41 kL * 243 ug/g * 0.001 * 1

TIC as

CO3 Saltcake Solid

A1-SltCk


TIC as

CO3 Sludge (Liquid & Solid) AR (Solid) 8.37E+02 kg

Template


TIC as

CO3 Sludge (Liquid & Solid) SRR (Solid) 4.83E+03 kg

Template

Engineering

1.51 g/ml * 110 kL * 20700 ug/g * 0.001 *

1.405

TIC as

CO3 Sludge Solid P2 (Solid) 3.59E+03 kg

Template


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A- 3



Analyte Phase Waste




Cr Saltcake Solid

A1-SltCk


Process


Cr Sludge (Liquid & Solid) AR (Solid) 2.98E+02 kg

Process


Cr Sludge (Liquid & Solid) SRR (Solid) 8.64E+02 kg

Process


Cr Sludge Solid P2 (Solid) 1.10E+02 kg 9.00E+01 Template Sample 1.61 g/ml * 41 kL * 1660 ug/g * 0.001 * 1

F Saltcake Solid

A1-SltCk


F Sludge (Liquid & Solid) AR (Solid) 5.01E-01 kg

Template

Engineering 1.34 g/ml * 38 kL * 5.16 ug/g * 0.001 * 1.906

F Sludge (Liquid & Solid) SRR (Solid) 0.00E+00 kg

Template


F Sludge Solid P2 (Solid) 5.18E+00 kg 1.13E+02 Template Sample 1.61 g/ml * 41 kL * 78.5 ug/g * 0.001 * 1

Fe Saltcake Solid

A1-SltCk


Process


Fe Sludge (Liquid & Solid) AR (Solid) 1.55E+03 kg

Process


Fe Sludge (Liquid & Solid) SRR (Solid) 4.49E+03 kg

Process


Fe Sludge Solid P2 (Solid) 8.85E+03 kg 7.80E+01 Template Sample 1.61 g/ml * 41 kL * 134000 ug/g * 0.001 * 1

Hg Saltcake Solid

A1-SltCk

(Drained) 1.21E-01 kg

Template

Engineering 1.58 g/ml * 84 kL * 0.915 ug/g * 0.001 * 1

Hg Sludge (Liquid & Solid) AR (Solid) 1.14E+01 kg

Template


Hg Sludge (Liquid & Solid) SRR (Solid) 1.62E+02 kg

Template


Hg Sludge Solid P2 (Solid) 6.59E+00 kg

Template


K Saltcake Solid

A1-SltCk


Process

Knowledge 1.55 g/ml * 84 kL * 2251.5 ug/g * 0.001 * 1

K Sludge (Liquid & Solid) AR (Solid) 1.33E+02 kg

Process


K Sludge (Liquid & Solid) SRR (Solid) 3.84E+02 kg

Process


K Sludge Solid P2 (Solid) 6.43E+00 kg

Template


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A- 4



Analyte Phase Waste




La Saltcake Solid

A1-SltCk


Template


La Sludge (Liquid & Solid) AR (Solid) 0.00E+00 kg

Template


La Sludge (Liquid & Solid) SRR (Solid) 0.00E+00 kg

Template


La Sludge Solid P2 (Solid) 7.53E+01 kg 1.13E+02 Template Sample 1.61 g/ml * 41 kL * 1140 ug/g * 0.001 * 1

Mn Saltcake Solid

A1-SltCk


Process


Mn Sludge (Liquid & Solid) AR (Solid) 8.33E+01 kg

Process


Mn Sludge (Liquid & Solid) SRR (Solid) 2.41E+02 kg

Process


Mn Sludge Solid P2 (Solid) 3.77E+02 kg 6.41E+01 Template Sample 1.61 g/ml * 41 kL * 5710 ug/g * 0.001 * 1

Na Saltcake Solid

A1-SltCk


Process


Na Sludge (Liquid & Solid) AR (Solid) 7.18E+03 kg

Process


Na Sludge (Liquid & Solid) SRR (Solid) 2.08E+04 kg

Process


Na Sludge Solid P2 (Solid) 3.41E+03 kg 6.35E+01 Template Sample 1.61 g/ml * 41 kL * 51600 ug/g * 0.001 * 1

Ni Saltcake Solid

A1-SltCk


Process


Ni Sludge (Liquid & Solid) AR (Solid) 3.68E+01 kg

Process


Ni Sludge (Liquid & Solid) SRR (Solid) 1.06E+02 kg

Process


Ni Sludge Solid P2 (Solid) 4.79E+02 kg 7.74E+01 Template Sample 1.61 g/ml * 41 kL * 7250 ug/g * 0.001 * 1

NO2 Saltcake Solid

A1-SltCk


NO2 Sludge (Liquid & Solid) AR (Solid) < 8.74E+01 kg

Process


NO2 Sludge (Liquid & Solid) SRR (Solid) < 2.53E+02 kg

Process


NO2 Sludge Solid P2 (Solid) 1.15E+02 kg 1.13E+02 Template Sample 1.61 g/ml * 41 kL * 1740 ug/g * 0.001 * 1

NO3 Saltcake Solid

A1-SltCk


Process


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A- 5



Analyte Phase Waste




NO3 Sludge (Liquid & Solid) AR (Solid) 4.60E+03 kg

Process


NO3 Sludge (Liquid & Solid) SRR (Solid) 1.33E+04 kg

Process


NO3 Sludge Solid P2 (Solid) 2.94E+03 kg 5.66E+01 Template Sample 1.61 g/ml * 41 kL * 44500 ug/g * 0.001 * 1

Free OH Saltcake Solid

A1-SltCk

(Drained) 3.69E+00 kg Calculated 11029 * 95.0613 / 283966

Free OH Sludge (Liquid & Solid) AR (Solid) 2.93E-02 kg Calculated 87.4471 * 95.0613 / 283966

Free OH Sludge (Liquid & Solid) SRR (Solid) 8.47E-02 kg Calculated 253.136 * 95.0613 / 283966

Free OH Sludge Solid P2 (Solid) 3.85E-02 kg Calculated 114.857 * 95.0613 / 283966

Oxalate Saltcake Solid

A1-SltCk

(Drained) 1.58E+03 kg Calculated (871.038 kg * 0.496 )/ 0.273

Oxalate Sludge (Liquid & Solid) AR (Solid) 2.37E+02 kg Calculated (394.041 kg * 0.164 )/ 0.273

Oxalate Sludge (Liquid & Solid) SRR (Solid) 1.56E+03 kg Calculated (1140.65 kg * 0.374 )/ 0.273

Oxalate Sludge Solid P2 (Solid) 0.00E+00 kg Calculated (0 kg * 0.164 )/ 0.273

Pb Saltcake Solid

A1-SltCk


Process


Pb Sludge (Liquid & Solid) AR (Solid) 6.14E+01 kg

Process


Pb Sludge (Liquid & Solid) SRR (Solid) 1.78E+02 kg

Process


Pb Sludge Solid P2 (Solid) 4.75E+02 kg 1.13E+02 Template Sample 1.61 g/ml * 41 kL * 7200 ug/g * 0.001 * 1

PO4 Saltcake Solid

A1-SltCk


Process


PO4 Sludge (Liquid & Solid) AR (Solid) 3.17E+03 kg

Process


PO4 Sludge (Liquid & Solid) SRR (Solid) 9.17E+03 kg

Process


PO4 Sludge Solid P2 (Solid) 1.64E+03 kg 1.06E+02 Template Sample 1.61 g/ml * 41 kL * 24800 ug/g * 0.001 * 1

Aroclors

(Total

PCB) Saltcake Solid

A1-SltCk

(Drained) < 2.11E-02 kg 1.39E+02 Template Sample 1.58 g/ml * 84 kL * 0.159 ug/g * 0.001 * 1

Aroclors

(Total

PCB) Sludge (Liquid & Solid) AR (Solid) < 8.82E-02 kg 2.77E+02 Template Sample 1.34 g/ml * 38 kL * 1.733 ug/g * 0.001 * 1

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A- 6



Analyte Phase Waste




Aroclors

(Total

PCB) Sludge (Liquid & Solid) SRR (Solid) < 2.88E-01 kg 2.77E+02 Template Sample 1.51 g/ml * 110 kL * 1.733 ug/g * 0.001 * 1

Aroclors

(Total

PCB) Sludge Solid P2 (Solid) < 1.20E-01 kg 2.77E+02 Template Sample 1.61 g/ml * 41 kL * 1.821 ug/g * 0.001 * 1

Si Saltcake Solid

A1-SltCk


Process


Si Sludge (Liquid & Solid) AR (Solid) 2.26E+03 kg

Process


Si Sludge (Liquid & Solid) SRR (Solid) 6.55E+03 kg

Process


Si Sludge Solid P2 (Solid) 4.13E+02 kg 1.04E+02 Template Sample 1.61 g/ml * 41 kL * 6250 ug/g * 0.001 * 1

SO4 Saltcake Solid

A1-SltCk


SO4 Sludge (Liquid & Solid) AR (Solid) 5.11E+03 kg

Process


SO4 Sludge (Liquid & Solid) SRR (Solid) 1.48E+04 kg

Process


SO4 Sludge Solid P2 (Solid) 1.52E+03 kg 9.92E+01 Template Sample 1.61 g/ml * 41 kL * 23000 ug/g * 0.001 * 1

Sr Saltcake Solid

A1-SltCk


Process


Sr Sludge (Liquid & Solid) AR (Solid) 3.06E+00 kg

Process


Sr Sludge (Liquid & Solid) SRR (Solid) 8.87E+00 kg

Process


Sr Sludge Solid P2 (Solid) 6.20E+01 kg 5.70E+01 Template Sample 1.61 g/ml * 41 kL * 940 ug/g * 0.001 * 1

Th Saltcake Solid

A1-SltCk


Template


Th Sludge (Liquid & Solid) AR (Solid) 5.37E-03 kg

Template

Engineering

1.34 g/ml * 38 kL * 0.0553 ug/g * 0.001 *

1.906

Th Sludge (Liquid & Solid) SRR (Solid) 1.05E-07 kg

Template

Engineering

1.51 g/ml * 110 kL * 4.5e-007 ug/g * 0.001 *

1.405

Th Sludge Solid P2 (Solid) 5.30E-08 kg

Template

Engineering

1.61 g/ml * 41 kL * 8.03e-007 ug/g * 0.001 *

1

TOC Saltcake Solid

A1-SltCk


Process


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A- 7



Analyte Phase Waste




TOC Sludge (Liquid & Solid) AR (Solid) 3.94E+02 kg

Process


TOC Sludge (Liquid & Solid) SRR (Solid) 1.14E+03 kg

Process


TOC Sludge Solid P2 (Solid) 0.00E+00 kg

Template


UTOTAL Saltcake Solid

A1-SltCk


Process


UTOTAL Sludge (Liquid & Solid) AR (Solid) 4.73E+01 kg

Process


UTOTAL Sludge (Liquid & Solid) SRR (Solid) 1.37E+02 kg

Process


UTOTAL Sludge Solid P2 (Solid) 1.68E+02 kg 1.13E+02 Template Sample 1.61 g/ml * 41 kL * 2550 ug/g * 0.001 * 1

Zr Saltcake Solid

A1-SltCk


Process


Zr Sludge (Liquid & Solid) AR (Solid) 7.09E+01 kg

Process


Zr Sludge (Liquid & Solid) SRR (Solid) 2.05E+02 kg

Process


Zr Sludge Solid P2 (Solid) 2.03E+02 kg 1.13E+02 Template Sample 1.61 g/ml * 41 kL * 3070 ug/g * 0.001 * 1

3H Saltcake Solid

A1-SltCk

(Drained) 7.75E-01 Ci

Template

Engineering 1.58 g/ml * 84 kL * 0.00584009 uCi/g * 1 * 1

3H Sludge (Liquid & Solid) AR (Solid) 2.79E-01 Ci

Template

Engineering

1.34 g/ml * 38 kL * 0.0028758 uCi/g * 1 *

1.906

3H Sludge (Liquid & Solid) SRR (Solid) 4.09E-01 Ci

Template

Engineering

1.51 g/ml * 110 kL * 0.00175203 uCi/g * 1 *

1.405

3H Sludge Solid P2 (Solid) 1.50E-01 Ci

Template


14C Saltcake Solid

A1-SltCk


Process

Knowledge

1.55 g/ml * 84 kL * 0.000803235 uCi/g * 1 *

1

14C Sludge (Liquid & Solid) AR (Solid) 4.73E-02 Ci

Process

Knowledge

1.55 g/ml * 38 kL * 0.000803235 uCi/g * 1 *

1

14C Sludge (Liquid & Solid) SRR (Solid) 1.37E-01 Ci

Process

Knowledge

1.55 g/ml * 110 kL * 0.000803235 uCi/g * 1 *

1

14C Sludge Solid P2 (Solid) 8.50E-02 Ci

Template


59Ni Saltcake Solid

A1-SltCk

(Drained) 1.01E+00 Ci

Template


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A- 8



Analyte Phase Waste




59Ni Sludge (Liquid & Solid) AR (Solid) 3.04E+00 Ci

Template

Engineering

1.34 g/ml * 38 kL * 0.0312959 uCi/g * 1 *

1.906

59Ni Sludge (Liquid & Solid) SRR (Solid) 6.91E-01 Ci

Template

Engineering

1.51 g/ml * 110 kL * 0.00295961 uCi/g * 1 *

1.405

59Ni Sludge Solid P2 (Solid) 2.22E+00 Ci

Template


60Co Saltcake Solid

A1-SltCk


Process

Knowledge 1.55 g/ml * 84 kL * 0.0168626 uCi/g * 1 * 1

60Co Sludge (Liquid & Solid) AR (Solid) 9.93E-01 Ci

Process


60Co Sludge (Liquid & Solid) SRR (Solid) 2.88E+00 Ci

Process


60Co Sludge Solid P2 (Solid) 1.16E+01 Ci 1.13E+02 Template Sample 1.61 g/ml * 41 kL * 0.175433 uCi/g * 1 * 1

63Ni Saltcake Solid

A1-SltCk


Template


63Ni Sludge (Liquid & Solid) AR (Solid) 2.61E+02 Ci

Template

Engineering 1.34 g/ml * 38 kL * 2.68612 uCi/g * 1 * 1.906

63Ni Sludge (Liquid & Solid) SRR (Solid) 5.89E+01 Ci

Template

Engineering

1.51 g/ml * 110 kL * 0.252332 uCi/g * 1 *

1.405

63Ni Sludge Solid P2 (Solid) 1.93E+02 Ci

Template


79Se Saltcake Solid

A1-SltCk


Template

Engineering

1.58 g/ml * 84 kL * 0.000744119 uCi/g * 1 *

1

79Se Sludge (Liquid & Solid) AR (Solid) 3.09E-02 Ci

Template

Engineering

1.34 g/ml * 38 kL * 0.000318268 uCi/g * 1 *

1.906

79Se Sludge (Liquid & Solid) SRR (Solid) 3.63E-02 Ci

Template

Engineering

1.51 g/ml * 110 kL * 0.000155548 uCi/g * 1 *

1.405

79Se Sludge Solid P2 (Solid) 1.56E-02 Ci

Template

Engineering

1.61 g/ml * 41 kL * 0.000235992 uCi/g * 1 *

1

90Sr Saltcake Solid

A1-SltCk


Process


90Sr Sludge (Liquid & Solid) AR (Solid) 3.39E+04 Ci

Process


90Sr Sludge (Liquid & Solid) SRR (Solid) 9.82E+04 Ci

Process


90Sr Sludge Solid P2 (Solid) 1.59E+06 Ci 1.13E+02 Template Sample 1.61 g/ml * 41 kL * 24051.9 uCi/g * 1 * 1

90Y Saltcake Solid

A1-SltCk

(Drained) 7.50E+04 Ci Calculated 90Sr * 1

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A- 9



Analyte Phase Waste




90Y Sludge (Liquid & Solid) AR (Solid) 3.39E+04 Ci Calculated 90Sr * 1

90Y Sludge (Liquid & Solid) SRR (Solid) 9.82E+04 Ci Calculated 90Sr * 1

90Y Sludge Solid P2 (Solid) 1.59E+06 Ci Calculated 90Sr * 1

93mNb Saltcake Solid

A1-SltCk


Template

Engineering 1.58 g/mL * 84 kL * 0.0177104 uCi/g

93mNb Sludge (Liquid & Solid) AR (Solid) 7.35E-01 Ci

Template


93mNb Sludge (Liquid & Solid) SRR (Solid) 8.41E-01 Ci

Template


93mNb Sludge Solid P2 (Solid) 8.22E-01 Ci

Template


93Zr Saltcake Solid

A1-SltCk


Template


93Zr Sludge (Liquid & Solid) AR (Solid) 8.18E-01 Ci

Template

Engineering

1.34 g/ml * 38 kL * 0.00842994 uCi/g * 1 *

1.906

93Zr Sludge (Liquid & Solid) SRR (Solid) 9.64E-01 Ci

Template

Engineering

1.51 g/ml * 110 kL * 0.00412997 uCi/g * 1 *

1.405

93Zr Sludge Solid P2 (Solid) 9.24E-01 Ci

Template


99Tc Saltcake Solid

A1-SltCk


Process


99Tc Sludge (Liquid & Solid) AR (Solid) 1.35E+01 Ci

Process


99Tc Sludge (Liquid & Solid) SRR (Solid) 3.92E+01 Ci

Process


99Tc Sludge Solid P2 (Solid) 4.86E+00 Ci

Template


106Ru Saltcake Solid

A1-SltCk


Template

Engineering

1.58 g/ml * 84 kL * 3.36659e-012 uCi/g * 1 *

1

106Ru Sludge (Liquid & Solid) AR (Solid) 9.68E-10 Ci

Template

Engineering

1.34 g/ml * 38 kL * 9.97312e-012 uCi/g * 1 *

1.906

106Ru Sludge (Liquid & Solid) SRR (Solid) 2.70E-07 Ci

Template

Engineering

1.51 g/ml * 110 kL * 1.15561e-009 uCi/g * 1

* 1.405

106Ru Sludge Solid P2 (Solid) 1.38E-08 Ci

Template

Engineering

1.61 g/ml * 41 kL * 2.09488e-010 uCi/g * 1 *

1

113mCd Saltcake Solid

A1-SltCk


Template


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A- 10



Analyte Phase Waste




113mCd Sludge (Liquid & Solid) AR (Solid) 4.10E-01 Ci

Template

Engineering

1.34 g/ml * 38 kL * 0.00422238 uCi/g * 1 *

1.906

113mCd Sludge (Liquid & Solid) SRR (Solid) 6.48E-01 Ci

Template

Engineering

1.51 g/ml * 110 kL * 0.00277569 uCi/g * 1 *

1.405

113mCd Sludge Solid P2 (Solid) 5.24E-01 Ci

Template


125Sb Saltcake Solid

A1-SltCk


Template

Engineering

1.58 g/ml * 84 kL * 7.98527e-005 uCi/g * 1 *

1

125Sb Sludge (Liquid & Solid) AR (Solid) 7.23E-01 Ci

Process


125Sb Sludge (Liquid & Solid) SRR (Solid) 2.09E+00 Ci

Process


125Sb Sludge Solid P2 (Solid) 2.33E-01 Ci

Template


126Sn Saltcake Solid

A1-SltCk


Template


126Sn Sludge (Liquid & Solid) AR (Solid) 6.20E-02 Ci

Template

Engineering

1.34 g/ml * 38 kL * 0.000639128 uCi/g * 1 *

1.906

126Sn Sludge (Liquid & Solid) SRR (Solid) 7.51E-02 Ci

Template

Engineering

1.51 g/ml * 110 kL * 0.000321738 uCi/g * 1 *

1.405

126Sn Sludge Solid P2 (Solid) 6.48E-02 Ci

Template

Engineering

1.61 g/ml * 41 kL * 0.000981957 uCi/g * 1 *

1

129I Saltcake Solid

A1-SltCk


Process

Knowledge

1.55 g/ml * 84 kL * 9.79999e-005 uCi/g * 1 *

1

129I Sludge (Liquid & Solid) AR (Solid) 5.77E-03 Ci

Process

Knowledge

1.55 g/ml * 38 kL * 9.79999e-005 uCi/g * 1 *

1

129I Sludge (Liquid & Solid) SRR (Solid) 1.67E-02 Ci

Process

Knowledge

1.55 g/ml * 110 kL * 9.79999e-005 uCi/g * 1

* 1

129I Sludge Solid P2 (Solid) 2.92E-04 Ci

Template

Engineering 1.61 g/ml * 41 kL * 4.42e-006 uCi/g * 1 * 1

134Cs Saltcake Solid

A1-SltCk


Template

Engineering

1.58 g/ml * 84 kL * 1.68087e-006 uCi/g * 1 *

1

134Cs Sludge (Liquid & Solid) AR (Solid) 1.12E-04 Ci

Template

Engineering

1.34 g/ml * 38 kL * 1.14885e-006 uCi/g * 1 *

1.906

134Cs Sludge (Liquid & Solid) SRR (Solid) 1.09E-03 Ci

Template

Engineering

1.51 g/ml * 110 kL * 4.68023e-006 uCi/g * 1

* 1.405

134Cs Sludge Solid P2 (Solid) 1.02E-03 Ci 1.13E+02 Template Sample

1.61 g/ml * 41 kL * 1.54208e-005 uCi/g * 1 *

1

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A- 11



Analyte Phase Waste




137Cs Saltcake Solid

A1-SltCk


Process


137Cs Sludge (Liquid & Solid) AR (Solid) 4.51E+03 Ci

Process


137Cs Sludge (Liquid & Solid) SRR (Solid) 1.30E+04 Ci

Process


137Cs Sludge Solid P2 (Solid) 3.50E+04 Ci 5.41E+01 Template Sample 1.61 g/ml * 41 kL * 529.823 uCi/g * 1 * 1

137mBa Saltcake Solid

A1-SltCk

(Drained) 9.40E+03 Ci Calculated 137Cs * 0.944

137mBa Sludge (Liquid & Solid) AR (Solid) 4.25E+03 Ci Calculated 137Cs * 0.944

137mBa Sludge (Liquid & Solid) SRR (Solid) 1.23E+04 Ci Calculated 137Cs * 0.944

137mBa Sludge Solid P2 (Solid) 3.30E+04 Ci Calculated 137Cs * 0.944

151Sm Saltcake Solid

A1-SltCk


Template


151Sm Sludge (Liquid & Solid) AR (Solid) 1.19E+04 Ci

Template

Engineering 1.34 g/ml * 38 kL * 122.53 uCi/g * 1 * 1.906

151Sm Sludge (Liquid & Solid) SRR (Solid) 1.84E+05 Ci

Template

Engineering

1.51 g/ml * 110 kL * 789.734 uCi/g * 1 *

1.405

151Sm Sludge Solid P2 (Solid) 2.25E+04 Ci

Template


152Eu Saltcake Solid

A1-SltCk


Template


152Eu Sludge (Liquid & Solid) AR (Solid) 1.19E+00 Ci

Template


152Eu Sludge (Liquid & Solid) SRR (Solid) 2.42E+01 Ci

Template


152Eu Sludge Solid P2 (Solid) 1.19E+01 Ci

Template



A1-SltCk


Template



Template

Engineering

1.34 g/ml * 38 kL * 0.621255 uCi/g * 1 *

1.906


Template

Engineering

1.51 g/ml * 110 kL * 5.18748 uCi/g * 1 *

1.405

154Eu Sludge Solid P2 (Solid) 6.23E+02 Ci 1.13E+02 Template Sample 1.61 g/ml * 41 kL * 9.44307 uCi/g * 1 * 1


A1-SltCk


Template


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A- 12



Analyte Phase Waste





Process



Template


155Eu Sludge Solid P2 (Solid) 1.34E+02 Ci

Template


226Ra Saltcake Solid

A1-SltCk


Template

Engineering

1.58 g/ml * 84 kL * 3.71658e-008 uCi/g * 1 *

1

226Ra Sludge (Liquid & Solid) AR (Solid) 5.89E-07 Ci

Template

Engineering

1.34 g/ml * 38 kL * 6.07173e-009 uCi/g * 1 *

1.906

226Ra Sludge (Liquid & Solid) SRR (Solid) 8.70E-07 Ci

Template

Engineering

1.51 g/ml * 110 kL * 3.72651e-009 uCi/g * 1

* 1.405

226Ra Sludge Solid P2 (Solid) 6.82E-07 Ci

Template

Engineering

1.61 g/ml * 41 kL * 1.03349e-008 uCi/g * 1 *

1

227Ac Saltcake Solid

A1-SltCk


Template

Engineering 1.58 g/mL * 84 kL * 1.52345e-005 uCi/g

227Ac Sludge (Liquid & Solid) AR (Solid) 5.50E-06 Ci

Template


227Ac Sludge (Liquid & Solid) SRR (Solid) 5.12E-06 Ci

Template


227Ac Sludge Solid P2 (Solid) 3.79E-06 Ci

Template


228Ra Saltcake Solid

A1-SltCk

(Drained) 7.17E-06 Ci Calculated 232Th * 1

228Ra Sludge (Liquid & Solid) AR (Solid) 5.90E-07 Ci Calculated 232Th * 1

228Ra Sludge (Liquid & Solid) SRR (Solid) 1.16E-11 Ci Calculated 232Th * 1

228Ra Sludge Solid P2 (Solid) 5.84E-12 Ci Calculated 232Th * 1

229Th Saltcake Solid

A1-SltCk


Template

Engineering

1.58 g/ml * 84 kL * 1.48795e-008 uCi/g * 1 *

1

229Th Sludge (Liquid & Solid) AR (Solid) 2.32E-07 Ci

Template

Engineering

1.34 g/ml * 38 kL * 2.38671e-009 uCi/g * 1 *

1.906

229Th Sludge (Liquid & Solid) SRR (Solid) 5.20E-09 Ci

Template

Engineering

1.51 g/ml * 110 kL * 2.22693e-011 uCi/g * 1

* 1.405

229Th Sludge Solid P2 (Solid) 4.15E-09 Ci

Template

Engineering

1.61 g/ml * 41 kL * 6.29134e-011 uCi/g * 1 *

1

231Pa Saltcake Solid

A1-SltCk


Template

Engineering

1.58 g/ml * 84 kL * 4.06875e-005 uCi/g * 1 *

1

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A- 13



Analyte Phase Waste




231Pa Sludge (Liquid & Solid) AR (Solid) 8.22E-06 Ci

Template

Engineering

1.34 g/ml * 38 kL * 8.46741e-008 uCi/g * 1 *

1.906

231Pa Sludge (Liquid & Solid) SRR (Solid) 6.72E-06 Ci

Template

Engineering

1.51 g/ml * 110 kL * 2.87912e-008 uCi/g * 1

* 1.405

231Pa Sludge Solid P2 (Solid) 4.85E-06 Ci

Template

Engineering

1.61 g/ml * 41 kL * 7.34775e-008 uCi/g * 1 *

1

232Th Saltcake Solid

A1-SltCk


Template


232Th Sludge (Liquid & Solid) AR (Solid) 5.90E-07 Ci

Template

Engineering

1.34 g/ml * 38 kL * 6.08e-009 uCi/g * 1 *

1.906

232Th Sludge (Liquid & Solid) SRR (Solid) 1.16E-11 Ci

Template

Engineering

1.51 g/ml * 110 kL * 4.96e-014 uCi/g * 1 *

1.405

232Th Sludge Solid P2 (Solid) 5.84E-12 Ci

Template


232U Saltcake Solid

A1-SltCk

(Drained) 3.20E-03 Ci Calculated 1.55 g/mL * 84 kL * 2.45629e-005 uCi/g

232U Sludge (Liquid & Solid) AR (Solid) 8.64E-05 Ci Calculated 1.55 g/mL * 38 kL * 1.46612e-006 uCi/g

232U Sludge (Liquid & Solid) SRR (Solid) 3.84E-06 Ci Calculated 1.55 g/mL * 110 kL * 2.25365e-008 uCi/g

232U Sludge Solid P2 (Solid) 3.89E-06 Ci

Template


233U Saltcake Solid

A1-SltCk

(Drained) 2.22E-01 Ci Calculated 1.55 g/mL * 84 kL * 0.00170634 uCi/g

233U Sludge (Liquid & Solid) AR (Solid) 6.10E-03 Ci Calculated 1.55 g/mL * 38 kL * 0.000103588 uCi/g



Template


234U Saltcake Solid

A1-SltCk



234U Sludge (Liquid & Solid) SRR (Solid) 4.70E-02 Ci Calculated 1.55 g/mL * 110 kL * 0.000275402 uCi/g


Template


235U Saltcake Solid

A1-SltCk




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A- 14



Analyte Phase Waste





Template


236U Saltcake Solid

A1-SltCk





Template


237Np Saltcake Solid

A1-SltCk


Template

Engineering

1.58 g/ml * 84 kL * 0.000767996 uCi/g * 1 *

1

237Np Sludge (Liquid & Solid) AR (Solid) 1.78E-02 Ci

Template

Engineering

1.34 g/ml * 38 kL * 0.000182999 uCi/g * 1 *

1.906

237Np Sludge (Liquid & Solid) SRR (Solid) 1.62E-02 Ci

Template

Engineering

1.51 g/ml * 110 kL * 6.93997e-005 uCi/g * 1

* 1.405

237Np Sludge Solid P2 (Solid) 1.31E-02 Ci

Template

Engineering

1.61 g/ml * 41 kL * 0.000197999 uCi/g * 1 *

1

238Pu Saltcake Solid

A1-SltCk


238Pu Sludge (Liquid & Solid) AR (Solid) 2.43E+00 Ci Calculated 1.34 g/mL * 38 kL * 0.0477615 uCi/g

238Pu Sludge (Liquid & Solid) SRR (Solid) 4.41E+01 Ci Calculated 1.51 g/mL * 110 kL * 0.26562 uCi/g

238Pu Sludge Solid P2 (Solid) 7.48E+00 Ci

Template


238U Saltcake Solid

A1-SltCk



238U Sludge (Liquid & Solid) SRR (Solid) 4.57E-02 Ci Calculated 1.55 g/mL * 110 kL * 0.000267833 uCi/g


Template



A1-SltCk


Template


239Pu Sludge (Liquid & Solid) AR (Solid) 8.16E+01 Ci

Template


239Pu Sludge (Liquid & Solid) SRR (Solid) 1.17E+03 Ci

Template



Template


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A- 15



Analyte Phase Waste





A1-SltCk


Template



Template



Template



Template


241Am Saltcake Solid

A1-SltCk


Process

Knowledge 1.55 g/mL * 84 kL * 0.781999 uCi/g

241Am Sludge (Liquid & Solid) AR (Solid) 5.21E+01 Ci

Process


241Am Sludge (Liquid & Solid) SRR (Solid) 2.43E+02 Ci

Process


241Am Sludge Solid P2 (Solid) 9.54E+02 Ci 1.13E+02 Template Sample 1.61 g/mL * 41 kL * 14.4578 uCi/g


A1-SltCk

(Drained) 1.76E+00 Ci Calculated 1.58 g/mL * 84 kL * 0.0132896 uCi/g


Template



Template



Template


242Cm Saltcake Solid

A1-SltCk


242Cm Sludge (Liquid & Solid) AR (Solid) 1.30E-01 Ci

Template


242Cm Sludge (Liquid & Solid) SRR (Solid) 3.00E+00 Ci

Template


242Cm Sludge Solid P2 (Solid) 8.11E-01 Ci

Template



A1-SltCk


242Pu Sludge (Liquid & Solid) AR (Solid) 8.70E-04 Ci

Template


242Pu Sludge (Liquid & Solid) SRR (Solid) 1.88E-02 Ci

Template


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A- 16



Analyte Phase Waste




242Pu Sludge Solid P2 (Solid) 3.10E-03 Ci

Template


243Am Saltcake Solid

A1-SltCk


243Am Sludge (Liquid & Solid) AR (Solid) 1.10E-01 Ci

Template


243Am Sludge (Liquid & Solid) SRR (Solid) 2.40E+00 Ci

Template


243Am Sludge Solid P2 (Solid) 5.16E-01 Ci

Template



A1-SltCk



Template


243Cm Sludge (Liquid & Solid) SRR (Solid) 1.80E-01 Ci

Template



Template



A1-SltCk



Template


244Cm Sludge (Liquid & Solid) SRR (Solid) 3.55E+00 Ci

Template



Template


Component

wt% water Saltcake Solids

A1-SltCk

(Solid) 37.8 wt%

Component

wt% water Sludge (Liquid & Solid) P2 (Solid) 44.2 wt%

Component

wt% water Sludge (Liquid & Solid) AR (Solid) 46.9 wt%

Component

wt% water Sludge (Liquid & Solid) SRR (Solid) 46.9 wt%

Component

density Saltcake Solids

A1-SltCk

(Solid) 1.58 g/mL

Component

density Sludge (Liquid & Solid) P2 (Solid) 1.61 g/mL

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A- 17



Analyte Phase Waste




Component

density Sludge (Liquid & Solid) AR (Solid) 1.51 g/mL

Component

density Sludge (Liquid & Solid) SRR (Solid) 1.51 g/ml

Notes:

Ci = Curies

g/mL = grams per milliliter

kL = kiloliters

PCB = polychlorinated biphenyls

RSD = relative standard deviation

uCi/g = microcuries per gram

Wt% = weight percent

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