Renewable energies | Eco-friendly production | Innovative transport | Eco-efficient processes | Sustainable resources
FBA – IFP Energies nouvelles – CEA-CETAMA – "Nuclear analytical chemistry : New challenges and future trends" – Montpellier 26th may 2011
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ANALYTICAL INNOVATION : SENSORS
TRENDS AND NEEDS FOR ON LINE MICRO ANALYSIS FOR R&D
INNOVAL : INNOVATIVE PROJECT FOR MICRO PROCESS ANALYTICAL TECHNOLOGY
Dr. Franck BACO-ANTONIALIIFP Energies nouvellesBP3, 69360 Solaize, [email protected]
FBA – IFP Energies nouvelles – CEA-CETAMA – "Nuclear analytical chemistry : New challenges and future trends" – Montpellier 26th may 20112
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Agenda
Introduction
Trends and needs for R&D on line micro analysis
INNOVAL Project
Technologic platform INDEED – AXEL'One :An collaborative platform
Conclusions and outlooks
FBA – IFP Energies nouvelles – CEA-CETAMA – "Nuclear analytical chemistry : New challenges and future trends" – Montpellier 26th may 20113
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L’analyse des procédés: un enjeu pour l'industrie chimique
PRODUCTION
Products Quality
Safety of employees
and neighborhood
Environment protection
(pollution)
R&D
Reduction of costs
Process intensification
ANALYSIS = PROCESS CONDITIONS CONTROLS
Objective
FBA – IFP Energies nouvelles – CEA-CETAMA – "Nuclear analytical chemistry : New challenges and future trends" – Montpellier 26th may 20114
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> Quality of the analysis
> Sampling safety
> Wastes management
> Installation cost ($ € )
>Energy consuming systems
Analysis
in the "heart
of
process"
Sampling loop
The future for industrial on line analysis : in situ analysis
FBA – IFP Energies nouvelles – CEA-CETAMA – "Nuclear analytical chemistry : New challenges and future trends" – Montpellier 26th may 20115
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Evolution of needs in term of analyzers in R&D
μ Pilots HTE Pilots Process Intensification
Reducing of sample volume
"Classical" analyzers
μ
Analyzers
μCaptors
FBA – IFP Energies nouvelles – CEA-CETAMA – "Nuclear analytical chemistry : New challenges and future trends" – Montpellier 26th may 20116
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• Employ more compact analyzers to be able to analyze in the heart of process "bring the analyzer to the sample"
• Reduce time of experimentation - Increase the number of tests in the same time
we needSmart analyzers to follow process stabilization, product quality, process control , ...
•Excellent repeatability, accurate systems, good accordance with standard methods, ...
Needs for R&D
and Process Intensification
FBA – IFP Energies nouvelles – CEA-CETAMA – "Nuclear analytical chemistry : New challenges and future trends" – Montpellier 26th may 20117
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Next generation of analyzers:- compacts (micro analyzers, micro captors) - coupling with sampling microsystems- directly integrated in the process
>> Analysis at the closest of the reaction
New Standard (SP76)NeSSI TM
New Sampling and Sensor Initiative from
CPAC
PROBLEMATIC
> Difficulties of direct implementation on industrial sites and R&D laboratories
‐
Unsatisfactory accordance between analyzers and industrials and
R&D needs
‐ Some laboratories techniques are not always available for in situ application
Problematic
FBA – IFP Energies nouvelles – CEA-CETAMA – "Nuclear analytical chemistry : New challenges and future trends" – Montpellier 26th may 20118
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Evolution of NeSSI
Gen III
Miniature/Modular (enabled by Mechanical Standard)
Smart Devices (enabled by Communication Standard)
Micro Analytical(enabled by Technology Advances)
End UserValue
Gen II
Gen I
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Programmable Substrate Heater
NeSSI “Sandwich”
concept
Ethernet LAN
Analyzer
ControllerV
A
P F
SAM
CANbus
PDA
Auxiliary Heating/Cooling
SubstrateT
T
Standard Sampling Interface
dcs o&m user
Standard Connectivity
Interface
Development Focus can be on Sensors !
R. Dubois, Dow
FBA – IFP Energies nouvelles – CEA-CETAMA – "Nuclear analytical chemistry : New challenges and future trends" – Montpellier 26th may 201110
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What is NeSSI?
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The NeSSI Platform Will Also Become the Base for a Micro-Analytical Lab
NMRMSNIRRAMANLCGCSIA Particle SizeViscosityMoistureConductivityMass FlowEtc.
FBA – IFP Energies nouvelles – CEA-CETAMA – "Nuclear analytical chemistry : New challenges and future trends" – Montpellier 26th may 201112
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Needs
Need to employ more compact analyzers to be able to analyze "in the heart of process"
Properties Molecular Properties Molecular
Analysis in liquids Analysis in gasesElementary analysis
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Elementary AnalysisIn situ analysis of elements in industrial liquids
traces of S, Ni & V in petroleum productstraces analysis of contaminants in ex biomass and chemical products, ...traces analysis of contaminants in waterfollowing of corrosion (traces of metals)...
Laser Induced Breakdown Spectroscopy
FBA – IFP Energies nouvelles – CEA-CETAMA – "Nuclear analytical chemistry : New challenges and future trends" – Montpellier 26th may 201114
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IVEA –
SOLUTION
Development of LIBS on NeSSI platform
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Analysis in liquids -
Properties
In situ analysis of elements in industrial liquids
in situ density, viscosity analysis of liquids with μsystemsin situ refractive index analysis with μsystemsparticles analysis in liquid (solid, catalyst, macromolecules, ...)calculation of other properties using μspectrometers
Adaptation in function of specific needsSpecific developments
FBA – IFP Energies nouvelles – CEA-CETAMA – "Nuclear analytical chemistry : New challenges and future trends" – Montpellier 26th may 201116
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Analysis in liquids -
Properties Example of In situ density with
AVENISENSE µdensimeter Response
to a periodic
feed
change
23
23.5
24
24.5
25
25.5
26
26.5
27
31/1/08 11:15 31/1/08 11:18 31/1/08 11:21 31/1/08 11:24 31/1/08 11:26 31/1/08 11:29 31/1/08 11:32 31/1/08 11:35 31/1/08 11:38 31/1/08 11:41
Time
Tem
pera
ture
(°C)
0.8405
0.8415
0.8425
0.8435
0.8445
0.8455
0.8465
0.8475
0.8485
0.8495
0.8505
dens
ity
(g/c
m3 )
T captor (°C)
Raw density
Corrected density
Gasoil A Gasoil A Gasoil A
Gasoil B Gasoil B
less than 30s – Flow 2ml/min
difference (A-B) 0.0006 g/cm3
FBA – IFP Energies nouvelles – CEA-CETAMA – "Nuclear analytical chemistry : New challenges and future trends" – Montpellier 26th may 201117
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In situ analysis in different industrial liquids
in situ analysis with μspectrometric methods (miniaturized systems), using in situ probes
Development and performance optimization
in situ analysis of dissolved gases (traces) in hydrocarbons (H2, O2, ...)
optimization of liquid injection systems for on line GC analysis
in situ analysis of liquid by μGC (at the moment only used for gas analysis)...
Analysis in liquids-
Molecular Analysis
min0 20 40 60 80 100
pA
10
15
20
25
30
35
40
45
FID1 A, (D:\DOCUMENTS AND SETTINGS\JACQUINE\BUREAU\ETUDE HPLIS\DATA\P20BARS\001F0101.D)
PIC
1
PIC
2
PIC
3
PIC
4
FBA – IFP Energies nouvelles – CEA-CETAMA – "Nuclear analytical chemistry : New challenges and future trends" – Montpellier 26th may 201118
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NIR mini spectrometer
FBA – IFP Energies nouvelles – CEA-CETAMA – "Nuclear analytical chemistry : New challenges and future trends" – Montpellier 26th may 201119
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On line dissolved
O2
in Liquid
FBA – IFP Energies nouvelles – CEA-CETAMA – "Nuclear analytical chemistry : New challenges and future trends" – Montpellier 26th may 201120
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In situ analysis in different industrial gases
in situ analysis with μspectrometric methods using in situ probes
Development en optimization of performances
Optimization of Tunable Diode Laser for specific applications
Optimization of sensors Density, moisture, H2, ...
Analysis in corrosive environments (HF, HCl, ...)
Analysis in gases -
Properties and Molecular
Analysis
TDL
FBA – IFP Energies nouvelles – CEA-CETAMA – "Nuclear analytical chemistry : New challenges and future trends" – Montpellier 26th may 201121
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Analysis in gases -
Properties Example of in situ density in gas phase in µPilot: total gas
flow 1l/h
density 1200
0
200
400
600
800
1000
1200
1400
23/0413:12
23/0418:00
23/0422:48
24/0403:36
24/0408:24
24/0413:12
24/0418:00
24/0422:48
25/0403:36
25/0408:24
25/0413:12
25/0418:00
25/0422:48
26/0403:36
26/0408:24
26/0413:12
26/0418:00
26/0422:48
27/0403:36
27/0408:24
27/0413:12
27/0418:00
27/0422:48
28/0403:36
28/0408:24
28/0413:12
28/0418:00
28/0422:48
29/0403:36
29/0408:24
29/0413:12
29/0418:00
29/0422:48
30/0403:36
30/0408:24
30/0413:12
30/0418:00
Date & Hour
Den
sity
(g/m
3)
GC analysisDensity (g/m3) at 15°C
CPG analysis for calculate gas density
Put to atmospheric presure of gas/liquid pot duringliquid sampling
No flow - Pilot's problem
Start Pilot
We are able to follow the "real life" of processBetter knowledge for R&D development
FBA – IFP Energies nouvelles – CEA-CETAMA – "Nuclear analytical chemistry : New challenges and future trends" – Montpellier 26th may 201122
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At
line GC's
with
NeSSI
compatability
FBA – IFP Energies nouvelles – CEA-CETAMA – "Nuclear analytical chemistry : New challenges and future trends" – Montpellier 26th may 201123
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At
line GC's
with
NeSSI
compatability
C2V SLS
FBA – IFP Energies nouvelles – CEA-CETAMA – "Nuclear analytical chemistry : New challenges and future trends" – Montpellier 26th may 201124
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Kaiser Airhead
Raman Gas
Probe
FBA – IFP Energies nouvelles – CEA-CETAMA – "Nuclear analytical chemistry : New challenges and future trends" – Montpellier 26th may 201125
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How to answer
to the needs
for Micro Analysis?
Micro Analysis Needs Collaborative project
USERSRequest ‐
Validation
LABORATORIESResearch
INSTRUMENTALISTSDevelopment & Industrialization
INNovAL Project
FBA – IFP Energies nouvelles – CEA-CETAMA – "Nuclear analytical chemistry : New challenges and future trends" – Montpellier 26th may 201126
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Targets:
-Development of new in situ on line analyzers in accordance with industrial and R&D needs
> On the cutting
edge
of technology
-Optimization
available technologies presents on the market
-Development of new and innovating
solutions
INNovAL Project (AXELERA)"L'Analyse en Ligne au cœur du procédé"
FBA – IFP Energies nouvelles – CEA-CETAMA – "Nuclear analytical chemistry : New challenges and future trends" – Montpellier 26th may 201127
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Skids
for development
of on line applications –
Evaluation in real conditions
FBA – IFP Energies nouvelles – CEA-CETAMA – "Nuclear analytical chemistry : New challenges and future trends" – Montpellier 26th may 201128
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INNOVAL – Main Actors
USERSRequest ‐
Validation
LABORATORIESResearch
INSTRUMENTALISTSDevelopment & Industrialization
FBA – IFP Energies nouvelles – CEA-CETAMA – "Nuclear analytical chemistry : New challenges and future trends" – Montpellier 26th may 201129
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First innovative collaborative technological platform in Lyon
INDEED (2013)National Institute for the Development of Ecotechnology and Decarbonized Energy
INNovAL – A structuring project
USERSRequest ‐
Validation
LABORATORIESResearch
INSTRUMENTALISTS
Development & Industrialization
INNovALINDEED
FBA – IFP Energies nouvelles – CEA-CETAMA – "Nuclear analytical chemistry : New challenges and future trends" – Montpellier 26th may 201130
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INDEED An innovative collaborative platform
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Conclusion & outlooksIn R&D we need μanalyzers to intensify and optimize research productivity and results quality
Increase the links between industrials, academic laboratories and instrumentalists to develop new analytical solutions in accordance with real industrial needs
INNOVAL project
Need to employ an innovative collaborative platform in order to develop & evaluate analytical instruments : pre industrialization before implementation on site
Platform INDEED
FBA – IFP Energies nouvelles – CEA-CETAMA – "Nuclear analytical chemistry : New challenges and future trends" – Montpellier 26th may 201132
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Lyon : Center of Excellence for "Industrial Analysis" in AXELERA
Academics laboratories in UCBLLaboratories in CNRS/SCAEcole des Mines de St. Etienne
in all laboratories : teams, evaluation benchesanalyzers, ....
In INDEED platformlaboratories for industrial experimentations,
Industrial users (Industrial partners : INnovAL, others)
Project of training in UCBL (Master II) specialized in "IndustrialAnalysis"
FBA – IFP Energies nouvelles – CEA-CETAMA – "Nuclear analytical chemistry : New challenges and future trends" – Montpellier 26th may 201133
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Lyon : Center of Excellence for "Industrial
Analysis" in AXELERA
Reseach
laboratories
–
Industrial
laboratories
-
Training
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Thank you
Dr. Franck BACO-ANTONIALIIFP Energies nouvellesBP3, 69360 Solaize, [email protected]
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Renewable energies | Eco-friendly production | Innovative transport | Eco-efficient processes | Sustainable resources
www.ifpenergiesnouvelles.com