Download - Biomass2010 Track3 s2 Hansen
-
8/20/2019 Biomass2010 Track3 s2 Hansen
1/20
TopsoeTopsoeTopsoeTopsoeTopsoeTopsoeTopsoeTopsoe IntegratedIntegratedIntegratedIntegratedIntegratedIntegratedIntegratedIntegrated gasolinegasolinegasolinegasolinegasolinegasolinegasolinegasoline SynthesisSynthesisSynthesisSynthesisSynthesisSynthesisSynthesisSynthesis -------- TIGASTIGASTIGASTIGASTIGASTIGASTIGASTIGAS
JJoohhnn BBøøggiilldd HHaannsseenn
HHAALLDDOORR TTOOPPSSOOEE AA//SS
-
8/20/2019 Biomass2010 Track3 s2 Hansen
2/20
Topsøe Group
– Key figures 2008
� Turnover: DKK 5.0 bn(USD 920 MM)
� Result: DKK 533 MM(USD 97 MM)
� 2100 employees
Headquarters, Lyngby, DK
Catalyst plant, Houston, TexasCatalyst plant, Frederikssund, DK
-
8/20/2019 Biomass2010 Track3 s2 Hansen
3/20
TTooppssooee SSyynnGGaass TTeecchhnnoollooggiieess Oryx GTL, Qatar – 34,000 bbl/d
2100 TPD Ammonia Plant
� Synthesis Gas
� Ammonia
� Hydrogen
�
Carbon Monoxide � Methanol
� Formaldehyde
� DME
� Gasoline - TIGAS
�SNG
-
8/20/2019 Biomass2010 Track3 s2 Hansen
4/20
Topsoe Methanol Plnats� 10 Plants commisioned since
2010
� Combined capacity:
13350 MTPD
� Feedstocks ranging from Coalto Natural Gas and NaturalGas plus CO2
-
8/20/2019 Biomass2010 Track3 s2 Hansen
5/20
55 TT//dd DDMMEE ffrroomm BBllaacckk LLiiqquuoorr PPiilloott PPllaanntt,,PPiitteeåå,, SSwweeddeenn
VOLVO CHEMREC TOPSØE
-
8/20/2019 Biomass2010 Track3 s2 Hansen
6/20
SSyynntthheessiiss GGaass ttoo GGaassoolliinnee
Classic (MTG)
SynGas ���� MeOH ; MeOH ���� DME ���� Gasoline
Integrated (TIGAS)
SynGas ���� MeOH/DME ���� Gasoline
(Topsoe Integrated Gasoline Synthesis)
-
8/20/2019 Biomass2010 Track3 s2 Hansen
7/20
MMeeOOHH//DDMMEE SSyynntthheessiiss
– Low H2/CO
– ∆H (kJ/mol)
2H2 + CO
=
CH3OH
90.7
2CH3OH
= CH3OCH3 + H2O 23.6
CO + H2O = CO2 + H2 41.1
3333HHHH2222 ++++ 3333CCCCOOOO ==== CCCCHHHH3333OOOOCCCCHHHH3333 ++++ CCCCOOOO2222
-
8/20/2019 Biomass2010 Track3 s2 Hansen
8/20
C o n v e r s i o n
( H 2 + C O )
Pressure (bar g)
� T = 250°C
� Feed Gas (mol%):
H2= 51
CO = 48
CO2
= 1
0
20
40
60
80
100
0 20 40 60 80 100
MeOH
MeOH / DME
SyngasSyngas Eq.Eq. ConversionConversion vs.vs. PressurePressure(H
2/CO = 1)
-
8/20/2019 Biomass2010 Track3 s2 Hansen
9/20
Methanol
Synthesis
Gasoline
C3-C4
Water
MTGMethanol To Gasoline
MeOH↔DMEGasoline
Synthesis Separation
Day Tank(Raw Methanol)
Off-gas to Power IslandSynthesis Gas
MeOH/DMESynthesis
-
8/20/2019 Biomass2010 Track3 s2 Hansen
10/20
Gasoline
C3-C4
Water
MeOH↔DMEGasoline
SynthesisSeparation
Off-gas to Power Island
Synthesis Gas
TIGASTopsøe Integrated Gasoline Synthesis
70-90% single-pass syngas conversion
Recycle to Gasifier
Flexibility - Versatility
-
8/20/2019 Biomass2010 Track3 s2 Hansen
11/20
Gasoline
C3-C4
Water
Gasoline
SynthesisSeparation
Off-gas
Oxygenate
Synthesis
Synthesis Gas
BioethanolBioethanol CoCo--conversionconversion
AqueousBio-EtOH
Multiple catalytic functions in loop enable co-processing of other feed streams
Direct co-feed of aqueous bioethanol – save ethanol distillation cost
-
8/20/2019 Biomass2010 Track3 s2 Hansen
12/20
TIGASTIGASCCSRCCSR
GasolineGasolineGasolineGasoline
LightLightLightLight EndsEndsEndsEnds
SeparationSeparationSeparationSeparationGasolineGasolineGasolineGasolineGasolineGasolineGasolineGasoline
SynthesisSynthesisSynthesisSynthesisSynthesisSynthesisSynthesisSynthesis
Water Water Water Water
(From Gasifier)(From Gasifier)(From Gasifier)(From Gasifier) SeparationSeparationSeparationSeparationSeparationSeparationSeparationSeparationSeparationSeparationSeparationSeparationMeOH/DMEMeOH/DMEMeOH/DMEMeOH/DMEMeOH/DMEMeOH/DMEMeOH/DMEMeOH/DME
Combustor Combustor Combustor Combustor
COCOCOCO2222, H2, CO, CH4, C2H6, C3H8, N2, Ar
OOOO2222
COCOCOCO2222, N2, Ar HiHiHiHi----PPPP COCOCOCO2222
DME, CO2, H2, CO, CH4, C2H6, N2, Ar
-
8/20/2019 Biomass2010 Track3 s2 Hansen
13/20
Tar
reformingGasification
Gasoline
synthesis
Gascleaning
Waste Biomass
MeOH/DME
SynthesisSeparation
Light ends
Gasoline
Water
to power island
SeparationSeparation
Air
Air-Blown Synfuel Processes
-
8/20/2019 Biomass2010 Track3 s2 Hansen
14/20
TIGAS Demonstration PlantTIGAS Demonstration Plant
1T/d 8900 Runhours Houston,TX
-
8/20/2019 Biomass2010 Track3 s2 Hansen
15/20
TIGAS Product BreakdownTIGAS Product Breakdown
0< 0.111
07710
178976138
131157
18< 0.1186
16165
134
63
32
11
P-O-NAromaticsTotalC
77-81 wt% C5+
15-19 wt% C3-4
-
8/20/2019 Biomass2010 Track3 s2 Hansen
16/20
Wood toWood to GasolineGasoline
DOE ProjectDOE Project
Green Gasoline from Wood UsingGreen Gasoline from Wood Using CarbonaCarbona Gasification andGasification and TopsoeTopsoe TIGAS ProcessesTIGAS Processes
-
8/20/2019 Biomass2010 Track3 s2 Hansen
17/20
Wood to Gasoline DOE Project
2 atm (Air)
Gasoline
SynthesisGas
CleaningMeOH/DME
Synthesis
23 bbl/d
OXYGEN
http://www.energy.gov/news2009/releases.htm
Green Gasoline From Wood Using Carbona Gasification and Topsoe TIGAS Processes
-
8/20/2019 Biomass2010 Track3 s2 Hansen
18/20
Tarreforming
Gasification Gasolinesynthesis
Gas
cleaning
Waste biomass
MeOH/DMESynthesis
Separation
Light ends
Gasoline
Water
Power
SeparationSeparation
O2
TIGASTIGAS ProcessProcess LayoutLayout ((DOEDOE))
-
8/20/2019 Biomass2010 Track3 s2 Hansen
19/20
Tar ReformingTar Reforming
– Enabling Technology for Biomass Gasification
� Bio-syngas contains tars and contaminants
– 2500 ppm tar (toluene, benzene, naphthalene)
– 100 ppm S, particulates
– 850-930°C, 1-30 bar g
– Ammonia decompositionBIOMASS
ASH
GASIFIERTAR REFORMER
� Topsoe Multidisciplinary know how :
– Reformer design
– In depth understanding of reforming – Catalyst formulation
– High dust monolith operation
-
8/20/2019 Biomass2010 Track3 s2 Hansen
20/20
SummarySummary
Process intensification by TIGAS scheme – Cost reduction by process integration
– High syngas conversion efficiency
Simple process scheme – Also attractive for small-scale biomass-based plants
Flexible: Virtually any synthesis gas composition – Base: natural gas (SMR & ATR) ; coal ; biomass ; waste – Tolerates high inert levels (enabling air-blown gasification)
Co-convert bio fuels
– Aqueous bioethanol
Attractive options for efficient co-generation layouts
– Low investment add-on for IGCC plants
TIGAS is CCS-ready